公开(公告)号：US06797761B2

公开(公告)日：2004-09-28

申请号：US10169473

申请日：2002-06-28

申请人： Maximilian Bendix ,  Heinz-Peter Rink

发明人： Maximilian Bendix ,  Heinz-Peter Rink

IPC分类号： C08K320

CPC分类号： C08F2/44 ,  C08F2/22 ,  C08F212/32 ,  C08F261/00 ,  C08F261/02 ,  C08F265/04 ,  C08F277/00 ,  C08F291/00 ,  C09D151/003 ,  C09J151/003

摘要： Aqueous primary dispersions comprising dispersed and/or emulsified, solid and/or liquid polymer particles and/or dispersed solid core-shell particles having a diameter≦500 nm, preparable by free-radical microemulsion or miniemulsion polymerization of at least one olefinically unsaturated monomer (A) in the presence of at least one polyhydroxy-functionalized cyclic and/or acyclic alkare having from 9 to 16 carbon atoms in the molecule, and their use in automotive OEM finishing and refinishing, in furniture coating and in industrial coating, including coil coating, container coating and the coating of electrical components.

摘要翻译： 包含分散和/或乳化的固体和/或液体聚合物颗粒和/或分散的直径<= 500nm的固体核 - 壳颗粒的水性初级分散体，可通过自由基微乳液或至少一种烯属不饱和单体的微乳液聚合制备 （A）在分子中存在至少一个具有9至16个碳原子的多羟基官能化的环状和/或非环状烷烃的存在下，以及它们在汽车OEM整理和修补，家具涂料和工业涂料中的应用，包括线圈 涂层，容器涂层和电气部件的涂层。

公开(公告)号：US07479520B2

公开(公告)日：2009-01-20

申请号：US10250694

申请日：2002-02-13

申请人： Ralf Nickolaus ,  Heinz-Peter Rink ,  Reinhold Clauss ,  Elisabeth Wessling ,  Wilma Löcken ,  Maximilian Bendix ,  Dunja Mikolajetz

发明人： Ralf Nickolaus ,  Heinz-Peter Rink ,  Reinhold Clauss ,  Elisabeth Wessling ,  Wilma Löcken ,  Maximilian Bendix ,  Dunja Mikolajetz

IPC分类号： C08F3/00

CPC分类号： C09D151/00 ,  C08F291/00 ,  C08G18/0823 ,  C08G18/6659 ,  C08G18/807 ,  C09D175/04 ,  C08F2/22 ,  C08L2666/14 ,  C08L75/04

摘要： An aqueous coating material, substantially or completely free from volatile organic compounds and preparable by mixing with one another (A) at least one aqueous primary dispersion comprising dispersed and/or emulsified, solid and/or liquid polymer particles and/or dispersed solid core/shell particles with a diameter ≦500 nm, preparable by free-radical microemulsion or miniemulsion polymerization of at least one olefinically unsaturated monomer in the presence of at least one hydrophobic additive, and (B) at least one secondary aqueous polyurethane dispersion comprising at least one polyurethane and at least one light stabilizer selected from the group of the regenerable free-radical scavengers, a process for preparing it and its use.

摘要翻译： 基本上或完全不含挥发性有机化合物并可通过彼此混合制备的水性涂料（A）至少一种包含分散和/或乳化的固体和/或液体聚合物颗粒和/或分散的固体核/ 在至少一种疏水性添加剂的存在下，通过自由基微乳液或至少一种烯属不饱和单体的细乳液聚合制备直径<= 500nm的壳颗粒，和（B）至少一种至少一种第二水性聚氨酯分散体，至少包含 一种聚氨酯和至少一种选自可再生自由基清除剂的光稳定剂，其制备方法及其用途。

公开(公告)号：US06884839B1

公开(公告)日：2005-04-26

申请号：US10148428

申请日：2000-11-08

申请人： Maximilian Bendix ,  Reinhold Clauss ,  Ralf Nickolaus ,  Wolfgang Bremser

发明人： Maximilian Bendix ,  Reinhold Clauss ,  Ralf Nickolaus ,  Wolfgang Bremser

IPC分类号： C08F2/00 ,  C08F2/22 ,  C08F2/44 ,  C08F220/14 ,  C08F220/18 ,  C08F283/00 ,  C08G18/08 ,  C08G18/62 ,  C08G18/80 ,  C09D5/02 ,  C09D133/00 ,  C09D151/00 ,  C09D157/00 ,  C09D161/20 ,  C09D175/04 ,  C08F210/14

CPC分类号： C08G18/0866 ,  C08F2/22 ,  C08F220/14 ,  C08F220/18 ,  C08G18/6229 ,  C08G18/807 ,  C09D175/04 ,  C08F2220/1825 ,  C08F212/08 ,  C08F2220/281 ,  C08F212/32

摘要： Aqueous primary dispersions and coating materials comprising dispersed and/or emulsified, solid and/or liquid polymer particles and/or dispersed solid core shell particles having a diameter≦500 nm preparable by controlled free-radical microemulsion or miniemulsion polymerization of A) at least one olefinically unsaturated monomer and B) at least one olefinically unsaturated monomer which is different than the olefinically unsaturated monomer (A) and has the general formula I: R1R2C═CR3R4 (I), in which the radicals R1, R2, R3 and R4 independently of one another are hydrogen atoms or substituted or unsubstituted alkyl, cycloalkyl, alkylcycloalkyl, cycloalkylalkyl, aryl, alkylaryl, cycloalkylaryl, arylalkyl or arylcycloalkyl radicals, with the proviso that at least two of the variables R1, R2, R3 and R4 are substituted or unsubstituted aryl, arylalkyl or arylcycloalkyl radicals, especially substituted or unsubstituted aryl radicals; and in the presence of (C) at least one hydrophobic cross-linking agent for the copolymer resulting from the starting products (A) and (B).

摘要翻译： 包含分散和/或乳化的固体和/或液体聚合物颗粒和/或分散的固体核心壳颗粒的水性初级分散体和涂层材料，其具有通过控制的自由基微乳液或A的至少一种微乳液聚合可制备的直径<= 500nm的至少 一种烯属不饱和单体和B）至少一种不同于烯属不饱和单体（A）的烯属不饱和单体，并具有通式I：R 1 R 2 其中R 1，R 2，R 2，R 2，R 3，R 4， 独立地是3或3个独立的氢原子或取代或未取代的烷基，环烷基，烷基环烷基，环烷基烷基，芳基，烷基芳基，环烷基芳基，芳基烷基或芳基环烷基，条件是 变量R 1，R 2，R 3和R 4中的至少两个是取代或未取代的芳基 ，芳基烷基或芳基 特别是取代或未取代的芳基; 和（C）由起始产物（A）和（B）得到的共聚物的至少一种疏水性交联剂的存在下进行。

公开(公告)号：US06716905B1

公开(公告)日：2004-04-06

申请号：US09868769

申请日：2001-06-21

申请人： Wolfgang Bremser ,  Frank Strickmann ,  Maximilian Bendix ,  Wolfgang Paulus ,  Roman Benedikt Raether ,  David Christie

发明人： Wolfgang Bremser ,  Frank Strickmann ,  Maximilian Bendix ,  Wolfgang Paulus ,  Roman Benedikt Raether ,  David Christie

IPC分类号： C08K320

CPC分类号： C09D151/06 ,  C08F291/00 ,  C08F293/005 ,  C09D133/062 ,  C09D153/00 ,  C08L2666/02 ,  C08L2666/24

摘要： The invention relates to a coating agent, containing at least one conversion product (A) and at least one suitable additive (C), (A) being produced according to a method comprising the following step (i): (iv) reacting a reaction mixture comprising at least one radically convertible monomer in radical conditions, (a) in the presence of at least one radical initiator and a compound (I) of formula (II) wherein R1 to R4 each represent, independently of each other, hydrogen, an unsubstituted or substituted alkyl radical, cycloalkyl radical or aralkyl radical or an unsubstituted or a substituted aromatic hydrocarbon radical, on the condition that at least two of R1 to R4 represent an unsubstituted or a substituted aromatic hydrocarbon radical, in an aqueous phase

摘要翻译： 本发明涉及包含至少一种转化产物（A）和至少一种合适的添加剂（C）的包衣剂，（A）根据包括以下步骤（i）的方法生产：（ⅳ）使反应 在（a）在至少一种自由基引发剂和式（II）化合物（I）的存在下，其中R 1至R 4各自独立地表示氢，氢， 未取代或取代的烷基，环烷基或芳烷基或未取代或取代的芳族烃基，其中R 1至R 4中的至少两个表示未取代或取代的芳族烃基，在水相中