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    Fluorinated organosilicon compounds and process for the preparation thereof
    11.
    发明授权
    Fluorinated organosilicon compounds and process for the preparation thereof 有权
    氟化有机硅化合物及其制备方法

    公开(公告)号：US06197989B1

    公开(公告)日：2001-03-06

    申请号：US09147542

    申请日：1999-03-17

    Applicant: Yutaka Furukawa ,  Mami Kotera ,  Seisaku Kumai ,  Robert E. Ruckle, Jr. ,  Gerald J. Murphy

    Inventor： Yutaka Furukawa ,  Mami Kotera ,  Seisaku Kumai ,  Robert E. Ruckle, Jr. ,  Gerald J. Murphy

    IPC: C07F702

    CPC classification number: C08G77/385 ,  C08G77/24 ,  C08G77/46

    Abstract: A fluorine-containing organic silicon compound represented by the following formula 1, which is useful as various industrial base materials required to have performances such as water and oil repellency, anti-fouling properties or release properties and as raw materials therefor. Here, Af represents a specific polyfluorohydrocarbon group-containing organic group; R1 and R2 which are independent of each other, represent bivalent organic groups; R3 to R9 which are independent of one another, represent monovalent organic groups; a is an integer of at least 1, and b is an integer of at least 0:

    Abstract translation: 由下式1表示的含氟有机硅化合物，其可用作要具有防斥油性，防污性或脱模性等性能的各种工业基材，作为其原料。 这里，Af表示具体的含多氟烃基的有机基团， 彼此独立的R 1和R 2表示二价有机基团; 彼此独立的R3至R9表示一价有机基团; a是至少为1的整数，b是至少为0的整数：

    Method for producing a fluorine-containing silicone compound
    12.
    发明授权
    Method for producing a fluorine-containing silicone compound 失效
    含氟硅氧烷化合物的制造方法

    公开(公告)号：US5834614A

    公开(公告)日：1998-11-10

    申请号：US847454

    申请日：1997-04-23

    Applicant: Yutaka Furukawa ,  Mami Kotera ,  Seisaku Kumai ,  Gerald J. Murphy

    Inventor： Yutaka Furukawa ,  Mami Kotera ,  Seisaku Kumai ,  Gerald J. Murphy

    IPC: C08G77/22 ,  C08G77/385 ,  C07F7/08

    CPC classification number: C08G77/385

    Abstract: A method for producing a fluorine-containing silicone compound, which comprises subjecting a fluorine-containing unsaturated compound of the following formula (1) and a hydrosilicone compound having at least one hydrogen atom bonded to a silicon atom to hydrosilylation in the presence of a catalyst to obtain a fluorine-containing silicone compound having a R.sup.f --Q--CR.sup.1 R.sup.2 --CHR.sup.3 --CR.sup.4 R.sup.5 -- group bonded to the silicon atom: R.sup.f --Q--CR.sup.1 R.sup.2 --CR.sup.3 .dbd.CR.sup.4 R.sup.5( 1) wherein R.sup.f is a monovalent fluorine-containing organic group, Q is a single bond or a bivalent organic group, and each of R.sup.1 to R.sup.5 which are independent of one another, is a hydrogen atom or a monovalent organic group, wherein the hydrosilylation is carried out substantially in the absence of a solvent.

    Abstract translation: 一种含氟硅氧烷化合物的制造方法，其特征在于，将下述式（1）所示的含氟不饱和化合物与至少一个与硅原子键合的氢原子的氢硅氧烷化合物在催化剂存在下进行氢化硅烷化 得到具有与硅原子键合的Rf-Q-CR1R2-CHR3-CR4R5-基团的含氟硅氧烷化合物：Rf-Q-CR1R2-CR3 = CR4R5（1）其中Rf是一价含氟有机基团， Q是单键或二价有机基团，R 1〜R 5彼此独立的是氢原子或一价有机基团，其中氢化硅烷化基本上在没有溶剂的情况下进行。

    Alkylsiloxanes as adjuvants for agriculture
    14.
    发明授权
    Alkylsiloxanes as adjuvants for agriculture 失效
    烷基硅氧烷作为农业辅助剂

    公开(公告)号：US5561099A

    公开(公告)日：1996-10-01

    申请号：US135916

    申请日：1993-10-13

    Applicant: Gerald J. Murphy ,  George A. Policello

    Inventor： Gerald J. Murphy ,  George A. Policello

    IPC: A01M1/20 ,  A01N25/02 ,  A01N25/04 ,  A01N25/10 ,  A01N25/30 ,  A01N55/00 ,  A01N55/10 ,  A01N61/02 ,  C07F7/18 ,  C09K17/38

    CPC classification number: A01N55/00 ,  A01N25/30 ,  A01N61/02

    Abstract: Linear alkylsilicone compounds of the formula ##STR1## wherein x=0 to 20, preferably 0 to 10, most preferably 0 to 1; y=1 to 10, preferably 1 to 5, most preferably 1; and R is an alkyl or alkyl ester group containing 6 to 16 carbons, or cyclic alkylsilicone compounds of the formula ##STR2## where m is 0 to 4, preferably 0 to 2, most preferably 0, and n is 1 to 5, preferably 3 to 5, most preferably 4, provided that m+n=3 to 5,are adjuvants for agricultural applications of oil-containing compositions. Especially preferred alkylsilicone compounds have a degree of polymerization of .ltoreq.6 and an alkyl content of .ltoreq.50% by weight. The compounds potentiate spreading of mineral or vegetable oils or oil-containing emulsions in dormant spray oils, crop oil concentrates, pesticides, and the like on difficult-to wet surfaces such as waxy leaf cuticles and arthropod exoskeletons.

    Abstract translation: 其中x = 0至20，优选0至10，最优选0至1的直链烷基硅氧烷化合物。 y = 1〜10，优选1〜5，最优选1; 和R为含有6至16个碳原子的烷基或烷基酯基，或式“IMAGE”的环烷基硅氧烷化合物，其中m为0至4，优选0至2，最优选0，n为1至5，优选3 至5，最优选4，条件是m + n = 3至5，是用于含油组合物的农业应用的佐剂。 特别优选的烷基硅氧烷化合物的聚合度为＆lt; 6＆gt;烷基含量为<50重量％。 这些化合物加强了在难以湿润的表面如蜡状叶片角质层和节肢动物外骨骼上的休眠喷雾油，作物油浓缩物，农药等中的矿物油或植物油或含油乳剂的铺展。

    Heterocyclic amine modified siloxanes
    16.
    发明授权
    Heterocyclic amine modified siloxanes 有权
    杂环胺改性硅氧烷

    公开(公告)号：US06197876B1

    公开(公告)日：2001-03-06

    申请号：US09257150

    申请日：1999-02-24

    Applicant: George A. Policello ,  Gerald J. Murphy

    Inventor： George A. Policello ,  Gerald J. Murphy

    IPC: C08L8308

    CPC classification number: C08G77/388 ,  A01N25/30 ,  A01N55/00 ,  B01F17/0071 ,  C08G77/54 ,  C08L83/08

    Abstract: The present invention teaches heterocyclic amine modified siloxanes and their use, a preferred of which is as adjuvants for pesticides. The heterocyclic amine modified siloxanes have siloxane backbones with pendant, terminal or intermediate heterocyclic amine groups, which may contain one or more heteroatoms, i.e., nitrogen, sulfur or oxygen. The heterocyclic amine groups or the siloxane may be functionalized further with alkyl or alkyleneoxide groups.

    Abstract translation: 本发明教导了杂环胺改性的硅氧烷及其用途，其优选作为农药的佐剂。 杂环胺改性的硅氧烷具有具有侧基，末端或中间杂环胺基团的硅氧烷主链，其可以含有一个或多个杂原子，即氮，硫或氧。 杂环胺基或硅氧烷可以进一步用烷基或环氧烷基官能化。

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