摘要:
Provided is a method for producing an MTW-type zeolite. The reaction mixture contains a silica source, an alumina source, an alkali source, and water is reacted with a seed crystal of a zeolite to produce an MTW-type zeolite. The reaction mixture has a composition, which makes a synthesized zeolite contain an MFI-type zeolite when the zeolite is synthesized solely from the reaction mixture, is used. As the seed crystal, a beta-type zeolite which has a ratio of SiO2/Al2O3 of 8 to 50 and does not contain a structure direction agent is used. The seed crystal is added to the reaction mixture, in a proportion of 0.1% by mass to 20% by mass based on a silica component in the reaction mixture. The reaction mixture to which the seed crystal has been added is heated at 100° C. to 200° C. in a sealed state.
摘要翻译:提供了一种MTW型沸石的制造方法。 反应混合物含有二氧化硅源,氧化铝源,碱源,水与沸石晶种反应生成MTW型沸石。 反应混合物具有组合物,当使用仅由反应混合物合成沸石时,使合成的沸石含有MFI型沸石。 作为晶种,使用SiO 2 / Al 2 O 3的比例为8〜50,不含结构方向试剂的β型沸石。 相对于反应混合物中的二氧化硅成分,将该晶种以0.1质量%〜20质量%的比例添加到反应混合物中。 已加入晶种的反应混合物在密封状态下在100℃加热至200℃。
摘要:
The method for producing an MTW-type zeolite according to the present invention includes: mixing a silica source, an alumina source, an alkali source, a lithium source, and water so as to obtain a reaction mixture having a composition represented by specific molar ratios; (2) adding an MTW-type zeolite which has a SiO2/Al2O3 ratio of 10 to 500 and does not contain an organic compound, as a seed crystal, to the reaction mixture in a proportion of 0.1 to 20% by weight relative to the silica component in the reaction mixture; and (3) airtightly heating the reaction mixture, to which the seed crystal has been added, at 100 to 200° C.
摘要翻译:根据本发明的MTW型沸石的制造方法包括:将二氧化硅源,氧化铝源,碱源,锂源和水混合,得到具有以比摩尔比表示的组成的反应混合物 ; (2)将SiO 2 / Al 2 O 3比例为10〜500,并且不含作为晶种的有机化合物的MTW型沸石相对于反应混合物的比例为0.1〜20重量% 反应混合物中的二氧化硅组分; 和(3)在100〜200℃下将加入了晶种的反应混合物气密加热
摘要:
A method of treating a cold-start engine exhaust gas stream comprising hydrocarbons and other pollutants, the method comprising: flowing the exhaust gas stream over a molecular sieve bed, the molecular sieve bed comprising an alkali metal cation-exchanged molecular sieve having intersecting 10- and 12-membered ring pore channels, to provide a first exhaust stream; flowing the first exhaust gas stream over a catalyst to convert any residual hydrocarbons and other pollutants contained in the first exhaust gas stream to innocuous products to provide a treated exhaust stream; and discharging the treated exhaust stream into the atmosphere.
摘要:
A zeolite beta according to the present invention has a SiO2/Al2O3 ratio of 10 to 16 and is aluminum-rich. The zeolite beta has a BET specific surface area measured in the state of a sodium type of 500 to 700 m2/g, a micropore specific surface area of 350 to 500 m2/g, and a micropore volume of 0.15 to 0.25 cm3/g.
摘要翻译:本发明的沸石β的SiO 2 / Al 2 O 3比为10〜16,富铝。 沸石β具有在500至700m 2 / g的钠类型,微孔比表面积为350至500m 2 / g,微孔体积为0.15至0.25cm 3 / g的状态下测量的BET比表面积。
摘要:
Molecular sieves and the use of such materials as hydrocarbon traps, particularly for reducing the emissions associated with the combustion of hydrocarbon fuels are described. Specifically, the use of molecular sieves such as zeolites as adsorbents for hydrocarbon gases, especially exhaust gases such as are formed during the combustion of hydrocarbons, and more particularly to the adsorption of hydrocarbon gases formed during the cold start operation of an internal combustion engine is described. In one embodiment, a method of treating exhaust gas that comprises a hydrocarbon combustion product is provided, the method comprising contacting the exhaust gas with a CON topology molecular sieve for a time period effective to facilitate adsorption of the hydrocarbon combustion product by the molecular sieve; passing a purge gas through the molecular sieve to remove adsorbed hydrocarbon combustion product; and contacting the purge gas containing the removed hydrocarbon combustion product with a hydrocarbon conversion catalyst.
摘要:
Disclosed is a method for readily and inexpensively producing zeolite without using an organic structure-directing agent (organic SDA). Specifically disclosed is a method whereby a gel containing a silica source, an alumina source, an alkaline source and water is reacted with zeolite seed crystals, to produce a zeolite with the same kind of skeletal structure as the zeolite. The gel used is a gel of a composition whereby, when a zeolite is synthesized from this gel only, the synthesized zeolite comprises at least one of the kinds of composite building units of the target zeolite.
摘要:
To provide an Fe(II)-substituted beta type zeolite which has been ion-exchanged with Fe(II) ions and can effectively adsorb and remove nitrogen monoxide or hydrocarbon contained in gas to be cleaned, even if oxygen is present in the gas at a high concentration or the temperature of the gas is low. In the Fe(II)-substituted beta type zeolite, a ratio of SiO2/Al2O3 is preferably 10 to 18, a BET specific surface area is preferably 400 m2/g to 700 m2/g, a micropore specific surface area is preferably 290 m2/g to 500 m2/g, and a micropore volume is preferably 0.15 cm3/g to 0.25 cm3/g. The amount of Fe(II) supported is preferably 0.01% by mass to 6.5% by mass based on the Fe(II)-substituted beta type zeolite.
摘要:
Disclosed is a method for readily and inexpensively producing zeolite without using an organic structure-directing agent (organic SDA). Specifically disclosed is a method whereby a gel containing a silica source, an alumina source, an alkaline source and water is reacted with zeolite seed crystals, to produce a zeolite with the same kind of skeletal structure as the zeolite. The gel used is a gel of a composition whereby, when a zeolite is synthesized from this gel only, the synthesized zeolite comprises at least one of the kinds of composite building units of the target zeolite.
摘要:
To provide an Fe(II)-substituted beta type zeolite which has been ion-exchanged with Fe(II) ions and can effectively adsorb and remove nitrogen monoxide or hydrocarbon contained in gas to be cleaned, even if oxygen is present in the gas at a high concentration or the temperature of the gas is low. In the Fe(II)-substituted beta type zeolite, a ratio of SiO2/Al2O3 is preferably 10 to 18, a BET specific surface area is preferably 400 m2/g to 700 m2/g, a micropore specific surface area is preferably 290 m2/g to 500 m2/g, and a micropore volume is preferably 0.15 cm3/g to 0.25 cm3/g. The amount of Fe(II) supported is preferably 0.01% by mass to 6.5% by mass based on the Fe(II)-substituted beta type zeolite.
摘要:
Provided is a method for producing an MTW-type zeolite. The reaction mixture contains a silica source, an alumina source, an alkali source, and water is reacted with a seed crystal of a zeolite to produce an MTW-type zeolite. The reaction mixture has a composition, which makes a synthesized zeolite contain an MFI-type zeolite when the zeolite is synthesized solely from the reaction mixture, is used. As the seed crystal, a beta-type zeolite which has a ratio of SiO2/Al2O3 of 8 to 50 and does not contain a structure direction agent is used. The seed crystal is added to the reaction mixture, in a proportion of 0.1% by mass to 20% by mass based on a silica component in the reaction mixture. The reaction mixture to which the seed crystal has been added is heated at 100° C. to 200° C. in a sealed state.
摘要翻译:提供了一种MTW型沸石的制造方法。 反应混合物含有二氧化硅源,氧化铝源,碱源,水与沸石晶种反应生成MTW型沸石。 反应混合物具有组合物,当使用沸石仅由反应混合物合成时,其使合成的沸石含有MFI型沸石。 作为晶种,使用SiO 2 / Al 2 O 3的比例为8〜50,不含结构方向试剂的β型沸石。 相对于反应混合物中的二氧化硅成分,将该晶种以0.1质量%〜20质量%的比例添加到反应混合物中。 已加入晶种的反应混合物在密封状态下在100℃加热至200℃。