公开(公告)号：US11591462B2

公开(公告)日：2023-02-28

申请号：US16495133

申请日：2018-03-14

Applicant: INEOS STYROLUTION GROUP GMBH

Inventor： Tobias Schulz

IPC: C08L25/14 ,  B29C45/00 ,  C08L25/12 ,  B29K25/00 ,  B29L31/30

Abstract: The invention relates to polymer blends of a styrene copolymer A selected from the group consisting of styrene acrylonitrile copolymers (SAN), styrene acrylonitrile maleic anhydride terpolymers (SMA), styrene acrylic copolymers, acrylonitrile butadiene styrene terpolymers (ABS), acrylonitrile butadiene styrene terpolymers with polyamide (ABS/PA), and acrylonitrile styrene acrylate terpolymers (ASA); and at least one copolymer B selected from the group consisting of styrene-butadiene block copolymers (SBC) and styrene-isoprene block copolymers (SIS); wherein the mold shrinkage of the polymer blend is reduced by at least 5% compared to the mold shrinkage of the pure styrene copolymer A.A process for the preparation of the polymer blends and the uses of the polymer blends in an injection molding process are described.

公开(公告)号：US11525052B2

公开(公告)日：2022-12-13

申请号：US16627448

申请日：2018-07-03

Applicant: INEOS STYROLUTION GROUP GMBH

Inventor： Tobias Schulz ,  Felix Rattay

IPC: C08L25/12 ,  C08L51/00 ,  C08F220/18 ,  C08K3/22 ,  C08K5/3432

Abstract: Thermoplastic styrene copolymer resin composition comprising: (a1) at least one styrene-acrylonitrile copolymer component A1, (a2) at least one acrylonitrile styrene acrylate graft copolymer A2 as impact modifier, (a3) optionally at least one thermoplastic polymer A3 other than components A1 and A2, (b) at least one transition metal oxide pigment B, (cl) at least one hindered amine UV light stabilizer C1, (c2) optionally at least one UV absorber C2 different from Cl, (d) optionally further polymer additives D, other than components B, C1, C2, and E, and (e) optionally one metal scavenger component E, wherein at least 99.0 wt.-% of the transition metal oxide pigment B consist of transition metal atoms and oxygen atoms.

公开(公告)号：US11505688B2

公开(公告)日：2022-11-22

申请号：US16633284

申请日：2018-07-25

Applicant: INEOS STYROLUTION GROUP GMBH

Inventor： Tobias Schulz ,  Norbert Niessner ,  Eike Jahnke ,  Hans-Werner Schmidt ,  Tristan Kolb

IPC: C08L25/12 ,  C08L25/14 ,  C08J3/20

Abstract: A scratch-resistant thermoplastic polymer composition (P) comprising 88 to 99.9 wt.-% of at least one styrene-based copolymer, 0.1 to 5 wt.-% of at least one modified organopolysiloxane compound, and optionally at least one colorant, dye or pigment, and/or at least one further additive, provides with improved properties.

公开(公告)号：US10717911B2

公开(公告)日：2020-07-21

申请号：US15765780

申请日：2016-10-06

Applicant: INEOS STYROLUTION GROUP GMBH

Inventor： Tobias Schulz ,  Janna Michaelis De Vasconcellos ,  Gisbert Michels ,  Norbert Niessner ,  Hans-Werner Schmidt ,  Florian Wieberger ,  Tristan Kolb

IPC: C09K5/14 ,  C08K3/04 ,  C08K3/34 ,  C08K3/38 ,  C08K3/18 ,  B29B7/90 ,  B29C45/00 ,  C08F293/00 ,  B29K9/06 ,  B82Y30/00

Abstract: Thermally conductive polymer (TCP) resin compositions are described, comprising: 50 to 75% matrix polymer (I) comprising styrenic polymers (Γ) such as ABS (acrylonitrile-butadiene-styrene) resins, ASA (acrylonitrile-styrene-acrylate) resins and elastomeric block copolymers of the structure (S-(B/S))n-S; and 25 to 50% thermally conductive filler material (II) (D50 0.1 to 200 μm), consisting of carbonyl iron powder (11-1) in mixture with multi wall carbon nanotubes, silicon carbide, diamond, graphite, aluminosilicates and/or boron nitride (II-2); wherein the volume ratio of (ll-1)/(ll-2) is 15:1 to 0.1:1. Shaped articles made thereof can be used for materials with antistatic finish, electrical and electronic housings, toys and helmet inlays.

公开(公告)号：US12152099B2

公开(公告)日：2024-11-26

申请号：US17262018

申请日：2019-07-22

Applicant: INEOS STYROLUTION GROUP GMBH

Inventor： Tobias Schulz ,  Wolfgang Fischer ,  Norbert Niessner ,  Christian Ruthard ,  Hannes Kerschbaumer

IPC: C08F257/02 ,  C08F2/22 ,  C08F212/08 ,  C08F220/44 ,  C08F265/06 ,  C08L25/12 ,  C08L33/20 ,  C08L51/04

Abstract: Polyacrylate graft rubber copolymer B and an impact modified thermoplastic molding composition thereof, where the graft copolymer B is composed of: B1: 50 to 70 wt.-% crosslinked acrylate polymer graft base B1 B2: 30 to 50 wt.-% graft shell B2 comprising a first layer B21 of vinylaromatic monomers, and a second layer B22 of vinylaromatic monomers B21-1 and nitrile monomers B22-2: wherein the particle diameter dw of the graft base BI is 255 to 290 nm; the fraction of B21 is 10 to 26 wt.-%; and the amount of B22-2, is 20 to 30 wt.-%.

公开(公告)号：US11667780B2

公开(公告)日：2023-06-06

申请号：US16633278

申请日：2018-07-25

Applicant: INEOS STYROLUTION GROUP GMBH

Inventor： Tobias Schulz ,  Norbert Niessner ,  Janna Michaelis de Vasconcellos ,  Hans-Werner Schmidt ,  Tristan Kolb

IPC: C08L25/12 ,  C08J3/22

CPC classification number: C08L25/12 ,  C08J3/226 ,  C08J2325/12 ,  C08J2413/00 ,  C08J2425/12 ,  C08J2483/04 ,  C08L2205/025 ,  C08L2205/035

Abstract: Thermoplastic polymer compositions (P) comprising at least one styrene-based polymer composition (A) comprising at least one graft copolymer (A-1), at least one organopolysiloxane compound, and optionally at least one colorant, dye or pigment, and/or at least one further additive, shows improved properties with respect to residual gloss after abrasion combined with improved melt flow characteristics while heat resistance is not affected.

公开(公告)号：US11352490B2

公开(公告)日：2022-06-07

申请号：US16771504

申请日：2018-12-10

Applicant: INEOS STYROLUTION GROUP GMBH

Inventor： Tobias Schulz ,  Gisbert Michels

IPC: C08L51/04 ,  C08L25/12

Abstract: The present invention relates to a process for producing a thermoplastic moulding composition comprising a thermoplastic copolymer A, a graft copolymer B and optionally a further polymer component C as well as optional further additives K, wherein the preparation of the graft copolymer B is carried out via emulsion polymerization, and wherein at least one surfactant S2 is used in grafting step of emulsion polymerization in a volume concentration in the range of 0.46 to 0.75 mol/m3, based on the volume of the graft copolymer B latex particles obtained; and wherein the mean particle diameter Dw of the latex particles of graft copolymer B is in the range of 60 to 800 nm.

公开(公告)号：US11059965B2

公开(公告)日：2021-07-13

申请号：US16334936

申请日：2017-09-25

Applicant: INEOS STYROLUTION GROUP GMBH

Inventor： Wolfgang Fischer ,  Ulrich Jansen ,  Tobias Schulz

IPC: C08L51/00 ,  C08L25/12 ,  C08L25/16 ,  C08L51/04 ,  C08F6/00 ,  C08L69/00

Abstract: The invention relates to a process for producing thermoplastic molding materials based on acrylonitrile-styrene-acrylate copolymers (ASA) having improved surface properties, in particular an improved stability of surface quality during storage in a hot and humid environment and a reduced content of residual monomers. The invention further relates to the use of a fluidized bed dryer and/or a flow dryer in the production of thermoplastic ASA molding materials for improving surface quality and the use of a fluidized bed dryer and/or a flow dryer in the production of thermoplastic ASA molding materials for reducing the content of residual monomers. The invention further provides ASA molding materials producible by means of the process according to the invention and also moldings.

公开(公告)号：US10920037B2

公开(公告)日：2021-02-16

申请号：US15765894

申请日：2016-10-06

Applicant: INEOS STYROLUTION GROUP GMBH

Inventor： Tobias Schulz ,  Norbert Niessner ,  Gisbert Michels ,  Hans-Werner Schmidt ,  Tristan Kolb

IPC: C08K3/38 ,  C08K3/34 ,  C08K3/18 ,  C08K3/04 ,  B29B7/90 ,  B29C45/00 ,  B29K55/02 ,  B29K509/04

Abstract: Thermally conductive polymer (TCP) resin compositions are described, comprising components (X) and (Y): 90 to 99.9% component (X) comprising components (I) and (II): 60 to 85% matrix polymer (I) comprising styrenic polymers (F) selected from: ABS resins, ASA resins, and elastomeric block copolymers of the structure (S—(B/S))n—S; 15 to 40% thermally conductive filler material (II) (D50 1 to 200 μηη), consisting of a ceramic material and/or graphite; 0.1 to 10% chemical foaming agent (Y). Shaped articles made thereof can be used for automotive applications, as a heat sink for high performance electronics, LED sockets or electrical and electronic housings.

公开(公告)号：US11680127B2

公开(公告)日：2023-06-20

申请号：US17267906

申请日：2019-08-27

Applicant: INEOS STYROLUTION GROUP GMBH

Inventor： Tobias Schulz ,  Wolfgang Fischer ,  Ulrich Jansen ,  Gisbert Michels

IPC: C08F285/00 ,  C08F2/22 ,  C08F6/00 ,  C08F212/08 ,  C08F220/44 ,  C08L51/00 ,  C08L55/02

CPC classification number: C08F285/00 ,  C08F2/22 ,  C08F6/005 ,  C08F212/08 ,  C08F220/44 ,  C08L51/003 ,  C08L55/02

Abstract: The present invention is directed to a process for the production of graft copolymer compositions which are based on acrylonitrile-styrene-acrylate (ASA) or acrylonitrile-butadiene-styrene (ABS) graft copolymers. The graft copolymers compositions are obtained by emulsion polymerization and afterwards precipitation, dewatering, drying and optionally cooling of the dried graft copolymer powder, wherein the graft copolymer B powder obtained is mixed with an aeration gas, preferably air and/or nitrogen, wherein the bulk density of the graft copolymer B powder is equal or less than 98.5% of the bulk density of the non-aerated graft copolymer B, during the whole aeration step. The graft copolymer powders show higher powder flowability and less tendency of caking during storage, for example in a silo.