摘要:
This invention relates to a process for standardized preparation of thermoplastic polyurethane elastomers by deactivating metal traces during the reaction, at an NCO:OH ratio of between about 0.85 and about 1.2:1, of(a) substantially linear hydroxyl-terminated polyols;(b) organic diisocyanates;(c) optional diol chain extenders; and(d) optional catalysts or other auxiliaries and/or additives, in the presence of(e) 0.000001 to 0.3% by weight, based on the total weight of the other components, of certain phosphorus compounds, wherein the phosphorus compounds are added to one or more of the other components before or during preparation of the thermoplastic polyurethane elastomers.
摘要:
This invention relates to aliphatic polycarbonates including sequential copolymers based on cyclic aliphatic carbonates and esters and block copolymers of blocks of polymerised cyclic aliphatic carbonates and blocks of polymerised vinyl compounds stabilized against thermal degradation containing 0.01 to 3.0% by weight, based on polymer, of a compound of trivalent phosphorus.
摘要:
Flameproofing additives for plastics materials consisting of a coating- and carrier material. The coating consists of metal oxides, the carrier of organic compounds, in which halogen is bound to carbon. The combination of the two components of the flameproofing additives has an inhibiting action on the fire and gives plastics materials an effective fire protection according to the invention, for example, V-2 to V-0 according to UL 94.
摘要:
The present invention relates to new flameproofing agent combinations of bisphthalimides and tetrafluoroethylene polymers and their use for providing thermoplastic moulding compositions of halogenated polycarbonates and ABS polymers with a flame-repellent finish.
摘要:
Transparent thermoplastic moulding compositions having improved mechanical properties consist essentially of a cellulose ester of aliphatic C.sub.1 -C.sub.5 -carboxylic acids and a graft copolymer of an ethylene vinyl ester copolymer having grafted thereon polymerized units of vinyl esters and/or alkyl esters of acrylic and/or methacrylic acid and, optionally, C.sub.2 -C.sub.4 -olefins.
摘要:
Thermoplastic moulding materials consisting of(1) 70 to 99.9% by weight of a cellulose ester or cellulose mixed ester(2) 0.1 to 30% by weight of a rubber polymer built up in the form of blocks from recurring structural units (I) with molecular weights of 10,000 to 1,000,000--A--B-- IwhereinA denotes bifunctional polysiloxane segements of the formula--(R.sup.1)(R.sup.2)SiO--.sub.x IIin whichR.sup.1 and R.sup.2 =aryl (in particular phenyl) or alkyl (in particular methyl) andx is a number such that the molecular weight is .gtoreq.500, andB denotes bifunctional aliphatic polyester and/or aliphatic polyester segments with molecular weights of .gtoreq.800,and the glass transition temperatures of the polymeric blocks A and B are less than 20.degree. C., which contains additionally(3) 0 to 30% by weight based on the mixture of (1) and (2) of a plasticizer.
摘要:
The invention relates to ABS moulding compositions based on selected copolymers and, optionally graft polymers of olefinically unsaturated monomers which are suitable for the preparation of ABS and silicon derivatives which are capable of copolymerization, the flame resistant properties of these moulding compositions being improved in comparison with conventional ABS material.
摘要:
A smokable product based on cellulose and combustion-modifying substances, containing(a) 0.1-10% by weight, based on the total weight of the smokable product, of finely divided solids, the average particle diameter of which is less than 2.mu., in a distribution which is heterogeneous over the cross-section of the smokable product, with an enrichment in or on the surfaces, and(b) 0.5-15% by weight, based on the total weight of the smokable product, of salts of monobasic or polybasic carboxylic acids. The product being prepared by saturating, spraying or coating a combustible, prefabricated material which is based on cellulose and optionally contains fillers customarily used in smokable products and which can be used as a smokable product with a dispersion of solids, the average particle diameter of which is less than 2.mu., in a solution of salts of monobasic or polybasic carboxylic acids.
摘要:
Contact lenses and scleral lenses formed of mixtures consisting essentially of(1) from 99 to 70% by weight of a cellulose ester of one or more aliphatic carboxylic acids, and(2) from 1 to 30% by weight of an ethylene/vinyl acetate copolymer containing from 30 to 98% by weight of incorporated vinyl acetate.
摘要:
A process for the continuous production of a thermoplastic molding composition containing a mixture of a TPU and a thermoplastic (co)polymer is disclosed. The process comprises (i) introducing into an extruder via a first feed point component I) with at least 3% by weight, with respect to component I), of at least one member selected from the group consisting of components A), B) and C), and(ii) metering in the balance of said A), B) and C) into said extruder via one or more subsequent feed points, (iii) extruding components I) and II) under conditions sufficient to cause A), B) and C) reaction to form TPU, and (iv) upon the completion of said reaction, removing the resulting mixture of TPU and (co)polymer from the extruder, wherein component I) comprises 1 to 60% by weight, with respect to the total mixture, of a thermoplastic (co)polymer, and wherein component II) comprises 99 to 40% by weight, with respect to the total mixture, of the polyurethane-forming components including A) an organic diisocyanate, B) a linear polyol having terminal hydroxyl groups and a number average molecular weight of 500 to 5000, and C) a chain extender having a molecular weight of 60 to 500, and wherein the molar ratio of NCO groups in A) to the groups which react with NCO in B) and C) is in the range of 0.9 to 1.2.