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公开(公告)号：US5064885A
公开(公告)日：1991-11-12
申请号：US655204
申请日：1991-02-11
摘要： This invention relates to aliphatic polycarbonates including sequential copolymers based on cyclic aliphatic carbonates and esters and block copolymers of blocks of polymerised cyclic aliphatic carbonates and blocks of polymerised vinyl compounds stabilized against thermal degradation containing 0.01 to 3.0% by weight, based on polymer, of a compound of trivalent phosphorus.
摘要翻译： 本发明涉及脂肪族聚碳酸酯，其包括基于环状脂族碳酸酯的顺序共聚物和聚合的环状脂肪族碳酸酯的嵌段的嵌段共聚物和稳定的耐热降解的聚合的乙烯基化合物的嵌段的嵌段共聚物，其包含基于聚合物的0.01至3.0重量％ 三价磷化合物。
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公开(公告)号：US5071921A
公开(公告)日：1991-12-10
申请号：US426460
申请日：1989-10-20
申请人： Herbert Eichenauer , Christian Lindner , Edgar Leitz , Karl-Heinz Ott , Hans-Josef Buysch , Peter Mues , Hartwig Hocker , Helmut Keul
发明人： Herbert Eichenauer , Christian Lindner , Edgar Leitz , Karl-Heinz Ott , Hans-Josef Buysch , Peter Mues , Hartwig Hocker , Helmut Keul
摘要： Thermoplastic block copolymers of the idealized formulae (I)A--B--A; B--A--B or (A--B).sub.x (I)in whichx=1 to 40,and whereinA is the radical of a homopolymer of styrene, vinylnaphthalene, butadiene and isoprene, andB the radical of a homopolymer of a cyclic polycarbonate or lactone,the average molecular weight of blocks A and B being greater than 800, and a process for the preparation of these blocks copolymers in several reaction stages.
摘要翻译： 理想化的式（I）A-B-A的热塑性嵌段共聚物; BAB或（AB）x（I），其中x = 1-40，并且其中A是苯乙烯，乙烯基萘，丁二烯和异戊二烯的均聚物的基团，B是环状聚碳酸酯或内酯的均聚物的基团， 嵌段A和B的平均分子量大于800，以及在几个反应阶段制备这些嵌段共聚物的方法。
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3.发明授权Process for the preparation of linear aliphatic polycarbonate from cyclic aliphatic carbonate 失效由环状脂肪族碳酸酯制备直链脂肪族聚碳酸酯的方法
公开(公告)号：US4754017A
公开(公告)日：1988-06-28
申请号：US17879
申请日：1987-02-24
申请人： Edgar Leitz , Christian Lindner , Herbert Eichenauer , Karl-Heinz Ott , Hans-Josef Buysch , Peter Mues , Hartwig Hocker , Helmut Keul
发明人： Edgar Leitz , Christian Lindner , Herbert Eichenauer , Karl-Heinz Ott , Hans-Josef Buysch , Peter Mues , Hartwig Hocker , Helmut Keul
CPC分类号： C08G64/30 , C08G64/0208
摘要： Process for the polymerization of cyclic aliphatic carbonates in the presence of aprotic organic solvents with exclusion of atmospheric oxygen and atmospheric moisture, wherein organometallic compounds of elements of main group 1 of the periodic table are used as initiators, the monomer/solvent ratio is in the range from 1 part by weight to 50 parts by weight of monomer per 100 parts by weight of solvent and the polymerization temperature is between -100.degree. C. and +20.degree. C.
摘要翻译： 在非质子有机溶剂的存在下，在排除大气中的氧气和大气水分的情况下环状脂族碳酸酯的聚合方法，其中使用周期表主族1元素的有机金属化合物作为引发剂，单体/溶剂比为 范围为1重量份至50重量份单体/ 100重量份溶剂，聚合温度为-100℃至+ 20℃。
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4.发明授权Trialkylsilyloxy-1,1-diphenyl ethylenes and polymers produced therewith 失效三烷基甲硅烷氧基-1,1-二苯基乙烯和由其制备的聚合物
公开(公告)号：US5153291A
公开(公告)日：1992-10-06
申请号：US492843
申请日：1990-03-13
CPC分类号： C07F7/1852 , C08F30/08 , C08F8/00 , C08F8/42
摘要： Trialkylsilyloxy-1,1-diphenyl ethylenes corresponding to general formula I, new polymers produced therewith terminated by aryl trialkylsilyl ether groups or by phenolic hydroxyl groups and a process for the production of these polymers by anionic polymerization ##STR1## in which R.sup.1, R.sup.2 .dbd.H, C.sub.1 -C.sub.4 alkyl, OCH.sub.3,R.sup.3 .dbd.H, C.sub.1 -C.sub.4 alkyl, O--C.sub.1 -C.sub.4 alkyl,R.sup.4 .dbd.H, C.sub.1 -C.sub.4 alkyl,R.sup.5 .dbd.C.sub.1 -C.sub.4 alkyl,R.sup.6 .dbd.H, C.sub.1 -C.sub.4 alkyl.
摘要翻译： 对应于通式I的三烷基甲硅烷氧基-1,1-二苯基乙烯，通过芳基三烷基甲硅烷基醚基团或酚羟基封端的新聚合物和通过阴离子聚合制备这些聚合物的方法（I），其中R 1 ，R2 = H，C1-C4烷基，OCH3，R3 = H，C1-C4烷基，O-C1-C4烷基，R4 = H，C1-C4烷基，R5 = C1-C4烷基，R6 = H，C1- C4烷基。
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5.发明授权Block copolymers based on cyclic aliphatic carbonates and/or esters on the one hand and cyclic aromatic carbonates on the other hand 失效基于循环碳酸氢钠和/或其他手段和循环芳香碳酸酯的嵌段共聚物
公开(公告)号：US5084524A
公开(公告)日：1992-01-28
申请号：US407166
申请日：1989-09-14
申请人： Edgar Leitz , Karl-Heinz Ott , Alfred Jung , Ulrich Grigo , Hans-Josef Buysch , Norbert Schon
发明人： Edgar Leitz , Karl-Heinz Ott , Alfred Jung , Ulrich Grigo , Hans-Josef Buysch , Norbert Schon
CPC分类号： C08G64/18
摘要： Copolymers of blocks of polymers of cyclic aliphatic carbonates, cyclic aliphatic esters or cyclic aliphatic carbonates and cyclic aliphatic esters on the one hand and blocks of polymers of cyclic aromatic carbonates on the other hand and a process for their production by multistage polymerization, in which a block polymer is initially prepared from the aliphatic monomer and the aromatic polymer is produced in the presence of this block.
摘要翻译： 另一方面，环状脂肪族碳酸酯，环状脂肪族酯或环状脂族碳酸酯和环状脂肪族碳酸酯的聚合物的嵌段和环状脂肪族酯的共聚物和环状芳族碳酸酯的聚合物的嵌段和通过多段聚合制备的方法，其中 最初由脂族单体制备嵌段聚合物，并且在该嵌段存在下制备芳族聚合物。
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公开(公告)号：US4956485A
公开(公告)日：1990-09-11
申请号：US367002
申请日：1989-06-16
CPC分类号： C08F8/00 , C07F7/1852 , C08F30/08 , C08F8/42
摘要： Trialkylsilyloxy-1,1-diphenyl ethylenes corresponding to general formula I, new polymers produced therewith terminated by aryl trialkylsilyl ether groups or by phenolic hydroxyl groups and a process for the production of these polymers by anionic polymerization ##STR1## in which R.sup.1, R.sup.2 =H, C.sub.1 -C.sub.4 alkyl, OCH.sub.3,R.sup.3 =H, C.sub.1 -C.sub.4 alkyl, O--C.sub.1 -C.sub.4 alkyl,R.sup.4 =H, C.sub.1 -C.sub.4 alkyl,R.sup.5 =C.sub.1 -C.sub.4 alkyl,R.sup.6 =H, C.sub.1 -C.sub.4 alkyl.
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7.发明授权Antistatic, thermoplastic moulding compounds based on aromatic vinyl polymers II 失效基于芳族乙烯基聚合物的抗静电，热塑性成型化合物II
公开(公告)号：US5061752A
公开(公告)日：1991-10-29
申请号：US373341
申请日：1989-06-29
IPC分类号： C08K5/06 , C08K5/05 , C08L25/00 , C08L25/02 , C08L25/04 , C08L25/12 , C08L31/04 , C08L33/00 , C08L33/04 , C08L33/24 , C08L35/06 , C08L51/04 , C08L51/08 , C08L55/02 , C08L71/00 , C08L71/12
摘要： Thermoplastic moulding compositions composed ofI) 99.8-95% by weight of(A) 0-100% by weight of one or more graft polymers comprise the monomers styrene, .alpha.-methyl styrene, methyl methacrylate or a mixture of 95-50% by weight of styrene, .alpha.-methyl styrene, ring substituted styrene, methyl methacrylate or mixtures thereof with 5-50% by weight of methacrylonitrile, acrylonitrile, maleric acid anhydride, N-substituted malerimides or mixtures thereof, grafted onto a rubber substrate, andB) 100 to 0%, by weight of one or more thermoplastic vinyl polymers, andII) 0.2 to 5% by weight of a polyalkylene ether modified by a radical former which can be compounds conventionally used as an initiator for radical polymerization such as peroxides.
摘要翻译： 由I）99.8-95重量％（A）0-100重量％的一种或多种接枝聚合物组成的热塑性模塑组合物包括单体苯乙烯，α-甲基苯乙烯，甲基丙烯酸甲酯或95-50％ 苯乙烯，α-甲基苯乙烯，环取代的苯乙烯，甲基丙烯酸甲酯或其混合物与5-50重量％的甲基丙烯腈，丙烯腈，苹果酸酐，N-取代的马来酰亚胺或其混合物接枝到橡胶基材上，B ）100至0重量％的一种或多种热塑性乙烯基聚合物，和II）0.2至5重量％的通过基团原子改性的聚亚烷基醚，其可以是常规用作自由基聚合如过氧化物的引发剂的化合物。
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8.发明授权Antistatic, thermoplastic moulding compounds based on aromatic vinyl polymers 失效基于芳族聚合物的抗静电，热塑性成型化合物
公开(公告)号：US5064899A
公开(公告)日：1991-11-12
申请号：US497817
申请日：1990-03-22
IPC分类号： C08K5/06 , C08K5/05 , C08L25/00 , C08L25/04 , C08L25/12 , C08L31/04 , C08L33/00 , C08L33/04 , C08L33/24 , C08L35/06 , C08L51/00 , C08L51/04 , C08L51/08 , C08L55/02
摘要： Thermoplastic moulding compounds composed of99.8-95% by weight of A) 0-100% by weight of a graft polymer B) 100-0% by weight of a thermoplastic polymer of vinyl monomers and0.2 to 5% by weight of a polyalkylene ether which has been grafted with a polymer of C.sub.1 -C.sub.6 alkyl acrylates, cycloalkyl acrylates or methacrylates and optionally styrene or .alpha.-methyl styrene.
摘要翻译： 由99.8-95重量％的A）0-100重量％的接枝聚合物B）组成的热塑性模塑料100重量％的乙烯基单体的热塑性聚合物和0.2-5重量％的聚亚烷基醚 其已经用丙烯酸C 1 -C 6烷基酯，丙烯酸环烷基酯或甲基丙烯酸环烷基酯和任选的苯乙烯或α-甲基苯乙烯的聚合物接枝。
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9.发明授权Composition of polycarbonate, ABS, a basic additive and a carboxylic and compound 失效聚碳酸酯，ABS，碱性添加剂和羧酸和化合物的组成
公开(公告)号：US5420181A
公开(公告)日：1995-05-30
申请号：US320115
申请日：1994-10-07
IPC分类号： C08G64/06 , C08G64/00 , C08K5/00 , C08K5/09 , C08L55/00 , C08L55/02 , C08L69/00 , C08L101/00 , C08K5/092
CPC分类号： C08K5/0008 , C08L55/02 , C08L69/00
摘要： Thermoplastic molding compositions containingA) ABS-type resin,B) aromatic polycarbonate resins,C) a compound bearing several carboxyl groups or mixtures thereof and optionallyD) further polymer resins,characterized in that an ABS resin with at least one basically acting additive is used as component A, component C is selected from compounds having a molecular weight of from 150 to 260 having at least two carboxyl groups (--COOH) in the molecule, and the weight ratio of basically acting additive in A: carboxyl groups in C is from 5:1 to 1:1.
摘要翻译： 含有A）ABS型树脂，B）芳香族聚碳酸酯树脂的热塑性成型组合物，C）具有若干羧基的化合物或其混合物和任选的D）另外的聚合物树脂，其特征在于具有至少一种基本上作用的添加剂的ABS树脂是 作为组分A，组分C选自分子中具有至少两个羧基（-COOH）的分子量为150至260的化合物，并且基本上作用的添加剂在A中的羧基中的重量比为 从5：1到1：1。
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公开(公告)号：US4965300A
公开(公告)日：1990-10-23
申请号：US443041
申请日：1989-11-27
申请人： Herbert Eichenauer , Edgar Leitz , Karl-Heinz Ott
发明人： Herbert Eichenauer , Edgar Leitz , Karl-Heinz Ott
CPC分类号： C08G64/18
摘要： Polymers having a sequential structure of the following formula--A--X--B].sub.r (I)with r=1 to 20, in which --A-- is a polymer of a cyclic carbonate, --B-- is a polymer of a lactone and --X-- is a link, with a decreasing concentration of residues of the cyclic carbonate in the --B-- direction and a decreasing concentration of residues of the lactone in the --A-- direction, and the use of the these products as molding compositions.
摘要翻译： 具有以下式的顺序结构的聚合物-AXB] r（I），其中r = 1至20，其中-A-是环状碳酸酯的聚合物，-B-是内酯的聚合物，-X-是 一个环节，环状碳酸酯在-B-方向的残留浓度降低，内酯残留在-A-方向上的浓度降低，以及这些产物用作模塑组合物。
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