Multistage process for production of thermoplastic polyurethane
elastomers
    2.
    发明授权
    Multistage process for production of thermoplastic polyurethane elastomers 失效
    用于生产热塑性聚氨酯弹性体的多级方法

    公开(公告)号:US5795948A

    公开(公告)日:1998-08-18

    申请号:US654508

    申请日:1996-05-28

    CPC分类号: C08G18/10 C08G18/0895

    摘要: Thermoplastically processable polyurethane elastomers are produced by a process of A) mixing one or more substantially linear macrodiols with a diisocyanate, B) reacting the resultant mixture in a reactor at temperatures of >100.degree. C. to form a prepolymer, C) mixing the prepolymer with one or more low molecular weight chain extenders, and D) reacting the mixture prepared in stage C) to complete conversion in a high-shear, high-viscosity reactor.

    摘要翻译: 热塑性可加工的聚氨酯弹性体通过以下方法制备:A)将一种或多种基本上线性的大分子二醇与二异氰酸酯混合,B)在> 100℃的温度下将所得混合物反应在反应器中以形成预聚物,C)将预聚物 与一种或多种低分子量增链剂反应,和D)在阶段C)中制备的混合物反应,以在高剪切,高粘度的反应器中完成转化。

    Process for preparing TPU molding compositions
    3.
    发明授权
    Process for preparing TPU molding compositions 失效
    制备TPU模塑组合物的方法

    公开(公告)号:US5696205A

    公开(公告)日:1997-12-09

    申请号:US629983

    申请日:1996-04-08

    摘要: A process for the continuous production of a thermoplastic molding composition containing a mixture of TPU and a (co)polymer is disclosed. The process comprises (a) introducing into an extruder under time and temperature conditions sufficient to bring about the formation of thermoplastic polyurethane a (co)polymer, and polyurethane-forming components comprising A) an organic diisocyanate, B) a linear polyol having terminal hydroxyl groups and a molecular weight of 500 to 5000, and C) a chain extender having a molecular weight of 60 to 500, and upon completing the formation of said polyurethane (b) discharging the resulting TPU/(co)polymer mixture from the extruder. Importantly, the (co)polymer contains a flow enhancer and the molar ratio of the NCO groups in A) to the groups which react with NCO in B) and C) is 0.9 to 1.2.

    摘要翻译: 公开了一种连续生产含有TPU和(共)聚合物的混合物的热塑性模塑组合物的方法。 该方法包括(a)在足以导致形成热塑性聚氨酯a(共)聚合物的时间和温度条件下引入挤出机,以及包含A)有机二异氰酸酯的聚氨酯形成组分,B)具有末端羟基的线性多元醇 基团,分子量为500至5000,和C)分子量为60至500的扩链剂,并且在完成形成所述聚氨酯(b)时,从所述挤出机中排出所得TPU /(共)聚合物混合物。 重要的是,(共)聚合物含有流动增强剂,A)中的NCO基团与在B)和C)中与NCO反应的基团的摩尔比为0.9至1.2。

    Process for preparing TPU molding compositions
    7.
    发明授权
    Process for preparing TPU molding compositions 失效
    制备TPU模塑组合物的方法

    公开(公告)号:US5981655A

    公开(公告)日:1999-11-09

    申请号:US006064

    申请日:1998-01-12

    CPC分类号: C08L75/04 C08G18/0895

    摘要: A process for the continuous production of a thermoplastic molding composition containing a mixture of a TPU and a thermoplastic (co)polymer is disclosed. The process comprises(i) introducing into an extruder via a first feed point component I) with at least 3% by weight, with respect to component I), of at least one member selected from the group consisting of components A), B) and C), and(ii) metering in the balance of said A), B) and C) into said extruder via one or more subsequent feed points,(iii) extruding components I) and II) under conditions sufficient to cause A), B) and C) reaction to form TPU, and(iv) upon the completion of said reaction, removing the resulting mixture of TPU and (co)polymer from the extruder,wherein component I) comprises 1 to 60% by weight, with respect to the total mixture, of a thermoplastic (co)polymer, and wherein component II) comprises 99 to 40% by weight, with respect to the total mixture, of the polyurethane-forming components including A) an organic diisocyanate, B) a linear polyol having terminal hydroxyl groups and a number average molecular weight of 500 to 5000, and C) a chain extender having a molecular weight of 60 to 500, and wherein the molar ratio of NCO groups in A) to the groups which react with NCO in B) and C) is in the range of 0.9 to 1.2.

    摘要翻译: 公开了一种用于连续生产含有TPU和热塑性(共)聚合物的混合物的热塑性模塑组合物的方法。 该方法包括(i)通过第一进料点组分I)向至少一种选自组分A),B)中的至少一种成分引入至少3重量%的挤出机,相对于组分I) 和(ii)在所述A),B)和C)的余量中通过一个或多个后续进料点将所述A),B)和C)的余量计量加入到所述挤出机中,(iii)在足以导致A)和 ,B)和C)反应形成TPU,和(iv)在完成所述反应后,从挤出机中除去所得TPU和(共)聚合物的混合物,其中组分I)包含1至60重量% 相对于总混合物,热塑性(共)聚合物,并且其中组分II)包含相对于总混合物的99至40重量%的形成聚氨酯的组分,包括A)有机二异氰酸酯,B) 具有末端羟基,数均分子量为500〜5000的直链状多元醇,C)扩链剂 分子量为60至500,并且其中A)中的NCO基团与在B)和C)中与NCO反应的基团的摩尔比在0.9至1.2的范围内。