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公开(公告)号：US06774190B1
公开(公告)日：2004-08-10
申请号：US09949675
申请日：2001-09-12
申请人： Mamoru Takahashi , Akira Todo , Seiichi Ikeyama , Toshiyuki Tsutsui , Shinya Matsunaga , Norio Kaneshige
发明人： Mamoru Takahashi , Akira Todo , Seiichi Ikeyama , Toshiyuki Tsutsui , Shinya Matsunaga , Norio Kaneshige
IPC分类号： C08L2304
CPC分类号： C08L23/0815 , C08L23/06 , C08L2314/06 , Y10T428/1345 , C08L2666/04
摘要： An ethylene copolymer composition comprising an ethylene/&agr;-olefin copolymer (A-1), which has a density, a melt flow rate (MFR), an amount of a n-decane-soluble portion in the specific ranges and whose melt tension (MT) at 190° C. and MFR satisfy the relation MT>2.2×MFR−0.84, and one (co)polymer selected from the group consisting of (B-1) a low-density polyethylene obtained by high-pressure radical polymerization, (B-2) a crystalline polyolefin and (B-3) an olefin type elastomer. Also disclosed is an ethylene copolymer composition comprising an ethylene/&agr;-olefin copolymer composition and the low-density polyethylene (B-1) obtained by high-pressure radical polymerization, said ethylene/&agr;-olefin copolymer (A-2) and (A-3) both having physical properties similar to those of the above ethylene/&agr;-olefin copolymer (A-1) and having intrinsic viscosities different from each other. The ethylene copolymer compositions of the invention are excellent in heat stability and moldability, and able to form films of high transparency, high mechanical strength and anti-blocking resistance.
摘要翻译： 一种包含乙烯/α-烯烃共聚物（A-1）的乙烯共聚物组合物，其具有密度，熔体流动速率（MFR），特定范围内的正癸烷可溶部分的量及其熔体张力（ MT）和MFR满足MT> 2.2×MFR <-0.84>的关系，以及选自（B-1）由（B-1）组成的组中的一种（共）聚合物，通过高压自由基聚合获得的低密度聚乙烯 ，（B-2）结晶聚烯烃和（B-3）烯烃类弹性体。 还公开了包含乙烯/α-烯烃共聚物组合物和通过高压自由基聚合获得的低密度聚乙烯（B-1）的乙烯共聚物组合物，所述乙烯/α-烯烃共聚物（A-2）和（A -3），其物理性质与上述乙烯/α-烯烃共聚物（A-1）的物理性质相似，并且具有彼此不同的特性粘度。 本发明的乙烯共聚物组合物的热稳定性和成型性优异，能够形成高透明度，高机械强度和抗粘连性的薄膜。
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公开(公告)号：US5663236A
公开(公告)日：1997-09-02
申请号：US396888
申请日：1995-03-01
IPC分类号： C08F10/02 , C08F110/02 , C08F210/16 , C08F210/18 , C08L23/06 , C08L23/08 , C08L23/10 , C08L23/12 , C08L23/14 , C08L23/16 , C08L23/20 , C08L23/22 , C08L51/06 , C08L23/18
CPC分类号： C08L23/0815 , C08F10/02 , C08L23/06 , C08F110/02 , C08F210/16 , C08F210/18 , C08L2205/02 , C08L23/10 , C08L23/12 , C08L23/14 , C08L23/16 , C08L23/20 , C08L23/22 , C08L51/06 , Y10S526/943
摘要： An ethylene copolymer composition comprising an ethylene/.alpha.-olefin copolymer obtained by using a catalyst for olefin polymerization containing an organoaluminum oxy-compound (a) and at least two kinds of specific metallocene compounds (b), and a low-density polyethylene obtained by high-pressure radical polymerization.The ethylene/.alpha.-olefin copolymer compositions of the invention are excellent in moldability. From these copolymer compositions, films having high transparency and high mechanical strength can be produced.
摘要翻译： 包含通过使用含有有机铝氧化合物（a）和至少两种特定茂金属化合物（b）的烯烃聚合催化剂获得的乙烯/α-烯烃共聚物的乙烯共聚物组合物和由 高压自由基聚合。 本发明的乙烯/α-烯烃共聚物组合物的成型性优异。 从这些共聚物组合物可以制造具有高透明度和高机械强度的膜。
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公开(公告)号：US5594071A
公开(公告)日：1997-01-14
申请号：US429572
申请日：1995-04-27
申请人： Mamoru Takahashi , Akira Todo , Seiichi Ikeyama , Toshiyuki Tsutsui , Shinya Matsunaga , Norio Kaneshige
发明人： Mamoru Takahashi , Akira Todo , Seiichi Ikeyama , Toshiyuki Tsutsui , Shinya Matsunaga , Norio Kaneshige
CPC分类号： C08L23/0815 , C08L23/06 , C08L2314/06 , Y10S526/943 , Y10T428/1397
摘要： An ethylene copolymer composition comprising an ethylene/.alpha.-olefin copolymer [A-I] which has a density, a melt flow rate (MFR), an amount of a n-decane-soluble portion in the specific ranges and whose melt tension (MT) at 190.degree. C. and MFR satisfy the relation MT>2.2.times.MFR.sup.-0.84 and one (co)polymer selected from the group consisting of [B-1] a low-density polyethylene obtained by high-pressure radical polymerization, [B-2] a crystalline polyolefin and [B-3] an olefin type elastomer. Also disclosed is an ethylene copolymer composition comprising an ethylene/.alpha.-olefin copolymer composition and the low-density polyethylene [B-1] obtained by high-pressure radical polymerization, said ethylene/.alpha.-olefin copolymer composition comprising ethylene/.alpha.-olefin copolymers [A-2] and [A-3] both having physical properties similar to those of the above ethylene/.alpha.-olefin copolymer [A-1] and having intrinsic viscosities different from each other. Further disclosed is an ethylene copolymer composition comprising an ethylene/.alpha.-olefin copolymer [A-4] which has a density, a melt flow rate (MFR), a weight of a n-decane-soluble portion in the specific ranges and whose melt tension (MT) at 190.degree. C. and MFR satisfy the relation MT
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14.发明授权Catalyst for olefin polymerization, process for olefin polymerization using the same, ethylene/.alpha.-olefin copolymer, graft modified ethylene/.alpha.-olefin copolymer, and ethylene copolymer composition 失效用于烯烃聚合的催化剂，使用其的烯烃聚合方法，乙烯/α-烯烃共聚物，接枝改性的乙烯/α-烯烃共聚物和乙烯共聚物组合物
公开(公告)号：US5703180A
公开(公告)日：1997-12-30
申请号：US618109
申请日：1996-03-19
IPC分类号： C08F4/64 , C08F4/653 , C08F4/655 , C08F4/659 , C08F4/6592 , C08F10/00 , C08F210/16 , C08F255/00 , C08F255/02 , C08J5/18 , C08L23/02 , C08L23/08 , C08L51/06
CPC分类号： C08J5/18 , C08F10/00 , C08F210/16 , C08F255/00 , C08F255/02 , C08L23/02 , C08L23/0815 , C08L51/06 , C08F4/65904 , C08F4/65912 , C08F4/65916 , C08F4/65925 , C08F4/65927 , C08J2323/08 , Y10S526/943
摘要： An ethylene/.alpha.-olefin copolymer obtained by copolymerizing ethylene with an .alpha.-olefin of 3 to 20 carbon atoms in the presence of a catalyst for olefin polymerization comprising an organoaluminum oxy-compound (a) and at least two kinds of transition metal compounds (b). This ethylene/.alpha.-olefin copolymer has high melt tension and high flowability.
摘要翻译： 在烯烃聚合催化剂存在下，使乙烯与3-20个碳原子的α-烯烃共聚得到的乙烯/α-烯烃共聚物，包括有机铝氧化合物（a）和至少两种过渡金属化合物（ b）。 该乙烯/α-烯烃共聚物具有高熔体张力和高流动性。
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公开(公告)号：US5371146A
公开(公告)日：1994-12-06
申请号：US115661
申请日：1993-09-03
CPC分类号： C08J5/18 , C08L23/0815 , C08J2323/08 , C08L2205/02 , C08L2314/06 , Y10S526/943
摘要： Disclosed is an ethylene copolymer composition having a density of 0.980 to 0.955 g/cm.sup.3 and a melt flow rate (MFR) of 0.1 to 100 g/10 min., which is formed from two kinds of ethylene/.alpha.-olefin copolymers having specific properties and having density and MFR different from each other. The ethylene copolymer composition of the invention is excellent in melt tension and flow index within the high-shear-region, and able to form films of high transparency, high mechanical strength and blocking resistance.
摘要翻译： 公开了由具有特定性质的两种乙烯/α-烯烃共聚物形成的密度为0.980〜0.955g / cm 3，熔体流动速率（MFR）为0.1〜100g / 10分钟的乙烯共聚物组合物 并且具有彼此不同的密度和MFR。 本发明的乙烯共聚物组合物在高剪切区域内的熔体张力和流动指数优异，并且能够形成高透明度，高机械强度和抗粘连性的膜。
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公开(公告)号：US07687579B2
公开(公告)日：2010-03-30
申请号：US11211477
申请日：2005-08-26
申请人： Mamoru Takahashi , Tetsuji Kasai , Junji Saito , Naoto Matsukawa , Kazutaka Tsuru , Makoto Mitani , Terunori Fujita , Shiro Otsuzuki , Tetsuhiro Matsumoto , Toshiyuki Tsutsui
发明人： Mamoru Takahashi , Tetsuji Kasai , Junji Saito , Naoto Matsukawa , Kazutaka Tsuru , Makoto Mitani , Terunori Fujita , Shiro Otsuzuki , Tetsuhiro Matsumoto , Toshiyuki Tsutsui
CPC分类号： C08F255/02 , C08F10/00 , C08F10/02 , C08F110/02 , C08F210/16 , C08L23/04 , C08L23/0815 , C08L2205/02 , C08L2205/025 , C08F4/64048 , C08L2666/04 , C08F2500/10 , C08F2500/17 , C08F2500/12 , C08F2500/03 , C08F2500/07 , C08F2500/11 , C08F2500/14 , C08F210/14 , C08F210/08
摘要： An ethylene (co)polymer of the present invention is a (co)polymer with excellent moldability and mechanical properties and either an ethylene homopolymer or a copolymer of ethylene and an α-olefin of 4 to 20 carbon atoms. The (co)polymer has methyl branches measured by 13C-NMR less than 0.1 in number per 1,000 carbon atoms and Mw/Mn measured by GPC not lower than 1.8 and lower than 4.5. The (co)polymer is either an ethylene homopolymer or a copolymer of ethylene and an α-olefin of 3 to 20 carbon atoms. The melt tension (MT) and the swell ratio (SR) satisfy the relation; log(MT)>12.9−7.15×SR; and the intrinsic viscosity ([η]) and the melt flow rate (MFR) satisfy the relation; [η]>1.85×MFR−0.192 in the case of MFR 1.85×MFR−0.213 in the case of MFR≧1. Such an ethylene (co)polymer can be usable for various molding applications and especially suitable for pipes.
摘要翻译： 本发明的乙烯（共）聚合物是具有优异的成型性和机械性能的（共）聚合物，乙烯均聚物或乙烯与4-20个碳原子的α-烯烃的共聚物。 （共）聚合物具有通过13 C-NMR测量的甲基支链，每1000个碳原子数小于0.1，GPC测得的Mw / Mn不低于1.8，低于4.5。 （共）聚合物是乙烯均聚物或乙烯与3-20个碳原子的α-烯烃的共聚物。 熔体张力（MT）和溶胀比（SR）满足关系; log（MT）> 12.9-7.15×SR; 并且特性粘度（[＆eggr]）和熔体流动速率（MFR）满足关系; 在MFR <1的情况下为1.85×MFR-0.192，关系为 在MFR≥1的情况下为1.85×MFR-0.213。 这种乙烯（共）聚合物可用于各种模塑应用，特别适用于管道。
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公开(公告)号：US07563849B2
公开(公告)日：2009-07-21
申请号：US11211845
申请日：2005-08-26
申请人： Mamoru Takahashi , Tetsuji Kasai , Junji Saito , Naoto Matsukawa , Kazutaka Tsuru , Makoto Mitani , Terunori Fujita , Shiro Otsuzuki , Tetsuhiro Matsumoto , Toshiyuki Tsutsui
发明人： Mamoru Takahashi , Tetsuji Kasai , Junji Saito , Naoto Matsukawa , Kazutaka Tsuru , Makoto Mitani , Terunori Fujita , Shiro Otsuzuki , Tetsuhiro Matsumoto , Toshiyuki Tsutsui
IPC分类号： C08F267/04
CPC分类号： C08F255/02 , C08F10/00 , C08F10/02 , C08F110/02 , C08F210/16 , C08L23/04 , C08L23/0815 , C08L2205/02 , C08L2205/025 , C08F4/64048 , C08L2666/04 , C08F2500/10 , C08F2500/17 , C08F2500/12 , C08F2500/03 , C08F2500/07 , C08F2500/11 , C08F2500/14 , C08F210/14 , C08F210/08
摘要： An ethylene (co)polymer of the present invention is a (co)polymer with excellent moldability and mechanical properties and either an ethylene homopolymer or a copolymer of ethylene and an α-olefin of 4 to 20 carbon atoms. The (co)polymer has methyl branches measured by 13C-NMR less than 0.1 in number per 1,000 carbon atoms and Mw/Mn measured by GPC not lower than 1.8 and lower than 4.5. The (co)polymer is either an ethylene homopolymer or a copolymer of ethylene and an α-olefin of 3 to 20 carbon atoms. The melt tension (MT) and the swell ratio (SR) satisfy the relation; log(MT)>12.9−7.15×SR; and the intrinsic viscosity ([η]) and the melt flow rate (MFR) satisfy the relation; [η]>1.85×MFR−0.192 in the case of MFR 1.85×MFR−0.213 in the case of MFR≧1. Such an ethylene (co)polymer can be usable for various molding applications and especially suitable for pipes.
摘要翻译： 本发明的乙烯（共）聚合物是具有优异的成型性和机械性能（乙烯均聚物或乙烯与4-20个碳原子的α-烯烃的共聚物）的（共）聚合物。 （共）聚合物具有通过13 C-NMR测量的甲基支链，每1000个碳原子数小于0.1，GPC测得的Mw / Mn不低于1.8，低于4.5。 （共）聚合物是乙烯均聚物或乙烯与3-20个碳原子的α-烯烃的共聚物。 熔体张力（MT）和溶胀比（SR）满足关系; log（MT）> 12.9-7.15xSR; 特性粘度（η）和熔体流动速率（MFR）满足关系; 在MFR <1的情况下，η> 1.85×MFR-0.192和关系; 在MFR> = 1的情况下，η> 1.85×MFR-0.213。 这种乙烯（共）聚合物可用于各种模塑应用，特别适用于管道。
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公开(公告)号：US20060047079A1
公开(公告)日：2006-03-02
申请号：US11211477
申请日：2005-08-26
申请人： Mamoru Takahashi , Tetsuji Kasai , Junji Saito , Naoto Matsukawa , Kazutaka Tsuru , Makoto Mitani , Terunori Fujita , Shiro Otsuzuki , Tetsuhiro Matsumoto , Toshiyuki Tsutsui
发明人： Mamoru Takahashi , Tetsuji Kasai , Junji Saito , Naoto Matsukawa , Kazutaka Tsuru , Makoto Mitani , Terunori Fujita , Shiro Otsuzuki , Tetsuhiro Matsumoto , Toshiyuki Tsutsui
IPC分类号： C08L23/04
CPC分类号： C08F255/02 , C08F10/00 , C08F10/02 , C08F110/02 , C08F210/16 , C08L23/04 , C08L23/0815 , C08L2205/02 , C08L2205/025 , C08F4/64048 , C08L2666/04 , C08F2500/10 , C08F2500/17 , C08F2500/12 , C08F2500/03 , C08F2500/07 , C08F2500/11 , C08F2500/14 , C08F210/14 , C08F210/08
摘要： An ethylene (co)polymer of the present invention is a (co)polymer with excellent moldability and mechanical properties and either an ethylene homopolymer or a copolymer of ethylene and an α-olefin of 4 to 20 carbon atoms. The (co)polymer has methyl branches measured by 13C-NMR less than 0.1 in number per 1,000 carbon atoms and Mw/Mn measured by GPC not lower than 1.8 and lower than 4.5. The (co)polymer is either an ethylene homopolymer or a copolymer of ethylene and an α-olefin of 3 to 20 carbon atoms. The melt tension (MT) and the swell ratio (SR) satisfy the relation; log(MT)>12.9−7.15×SR; and the intrinsic viscosity ([η]) and the melt flow rate (MFR) satisfy the relation; [η]>1.85×MFR−0.192 in the case of MFR 1.85×MFR−0.213 in the case of MFR≧1. Such an ethylene (co)polymer can be usable for various molding applications and especially suitable for pipes.
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公开(公告)号：US07335716B1
公开(公告)日：2008-02-26
申请号：US09744904
申请日：2000-06-16
申请人： Mamoru Takahashi , Tetsuji Kasai , Junji Saito , Naoto Matsukawa , Kazutaka Tsuru , Makoto Mitani , Terunori Fujita , Shiro Otsuzuki , Tetsuhiro Matsumoto , Toshiyuki Tsutsui
发明人： Mamoru Takahashi , Tetsuji Kasai , Junji Saito , Naoto Matsukawa , Kazutaka Tsuru , Makoto Mitani , Terunori Fujita , Shiro Otsuzuki , Tetsuhiro Matsumoto , Toshiyuki Tsutsui
IPC分类号： C08F110/012 , C08F210/02 , C08F4/16 , C08F4/44
CPC分类号： C08F255/02 , C08F10/00 , C08F10/02 , C08F110/02 , C08F210/16 , C08L23/04 , C08L23/0815 , C08L2205/02 , C08L2205/025 , C08F4/64048 , C08L2666/04 , C08F2500/10 , C08F2500/17 , C08F2500/12 , C08F2500/03 , C08F2500/07 , C08F2500/11 , C08F2500/14 , C08F210/14 , C08F210/08
摘要： An ethylene (co)polymer of the present invention is a (co)polymer with excellent moldability and mechanical properties and either an ethylene homopolymer or a copolymer of ethylene and an α-olefin of 4 to 20 carbon atoms. The (co)polymer has methyl branches measured by 13C-NMR less than 0.1 in number per 1,000 carbon atoms and Mw/Mn measured by GPC not lower than 1.8 and lower than 4.5. The (co)polymer is either an ethylene homopolymer or a copolymer of ethylene and an α-olefin of 3 to 20 carbon atoms. The melt tension (MT) and the swell ratio (SR) satisfy the relation; log(MT)>12.9−7.15×SR; and the intrinsic viscosity ([η]) and the melt flow rate (MFR) satisfy the relation; [η]>1.85×MFR−0.192 in the case of MFR≧1 and the relation; [η]>1.85×MFR−0.213 in the case of MFR≧1. Such an ethylene (co)polymer can be usable for various molding applications and especially suitable for pipes.
摘要翻译： 本发明的乙烯（共）聚合物是具有优异的成型性和机械性能（乙烯均聚物或乙烯与4-20个碳原子的α-烯烃的共聚物）的（共）聚合物。 （共）聚合物具有通过13 C-NMR测量的甲基支链，每1000个碳原子数小于0.1，GPC测量的Mw / Mn不低于1.8，低于4.5。 （共）聚合物是乙烯均聚物或乙烯与3-20个碳原子的α-烯烃的共聚物。 熔体张力（MT）和溶胀比（SR）满足关系; log（MT）> 12.9-7.15xSR; 特性粘度（η）和熔体流动速率（MFR）满足关系; 在MFR> = 1的情况下，η> 1.85×MFR -0.192 和关系; 在MFR> = 1的情况下，η> 1.85×MFR -0.213 。 这种乙烯（共）聚合物可用于各种模塑应用，特别适用于管道。
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公开(公告)号：US20060047096A1
公开(公告)日：2006-03-02
申请号：US11211845
申请日：2005-08-26
申请人： Mamoru Takahashi , Tetsuji Kasai , Junji Saito , Naoto Matsukawa , Kazutaka Tsuru , Makoto Mitani , Terunori Fujita , Shiro Otsuzuki , Tetsuhiro Matsumoto , Toshiyuki Tsutsui
发明人： Mamoru Takahashi , Tetsuji Kasai , Junji Saito , Naoto Matsukawa , Kazutaka Tsuru , Makoto Mitani , Terunori Fujita , Shiro Otsuzuki , Tetsuhiro Matsumoto , Toshiyuki Tsutsui
IPC分类号： C08F297/02 , C08F110/02
CPC分类号： C08F255/02 , C08F10/00 , C08F10/02 , C08F110/02 , C08F210/16 , C08L23/04 , C08L23/0815 , C08L2205/02 , C08L2205/025 , C08F4/64048 , C08L2666/04 , C08F2500/10 , C08F2500/17 , C08F2500/12 , C08F2500/03 , C08F2500/07 , C08F2500/11 , C08F2500/14 , C08F210/14 , C08F210/08
摘要： An ethylene (co)polymer of the present invention is a (co)polymer with excellent moldability and mechanical properties and either an ethylene homopolymer or a copolymer of ethylene and an α-olefin of 4 to 20 carbon atoms. The (co)polymer has methyl branches measured by 13C-NMR less than 0.1 in number per 1,000 carbon atoms and Mw/Mn measured by GPC not lower than 1.8 and lower than 4.5. The (co)polymer is either an ethylene homopolymer or a copolymer of ethylene and an α-olefin of 3 to 20 carbon atoms. The melt tension (MT) and the swell ratio (SR) satisfy the relation; log(MT)>12.9−7.15×SR; and the intrinsic viscosity ([η]) and the melt flow rate (MFR) satisfy the relation; [η]>1.85×MFR−0.192 in the case of MFR 1.85×MFR−0.213 in the case of MFR≧1. Such an ethylene (co)polymer can be usable for various molding applications and especially suitable for pipes.
摘要翻译： 本发明的乙烯（共）聚合物是具有优异的成型性和机械性能（乙烯均聚物或乙烯与4-20个碳原子的α-烯烃的共聚物）的（共）聚合物。 （共）聚合物具有通过13 C-NMR测量的甲基支链，每1000个碳原子数小于0.1，GPC测量的Mw / Mn不低于1.8，低于4.5。 （共）聚合物是乙烯均聚物或乙烯与3-20个碳原子的α-烯烃的共聚物。 熔体张力（MT）和溶胀比（SR）满足关系; log（MT）> 12.9-7.15xSR; 特性粘度（η）和熔体流动速率（MFR）满足关系; 在MFR <1的情况下，η> 1.85×MFR -0.192 和关系; 在MFR> = 1的情况下，η> 1.85×MFR -0.213 。 这种乙烯（共）聚合物可用于各种模塑应用，特别适用于管道。
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