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11.发明申请Method of Making High Performance Mixed Matrix Membranes Using Suspensions Containing Polymers and Polymer Stabilized Molecular Sieves 有权使用含有聚合物和聚合物稳定分子筛的悬浮液制备高性能混合基质膜的方法公开(公告)号：US20080141863A1
公开(公告)日：2008-06-19
申请号：US11612366
申请日：2006-12-18
申请人： Chunqing Liu , Man-Wing Tang , Stephen T. Wilson , David A. Lesch
发明人： Chunqing Liu , Man-Wing Tang , Stephen T. Wilson , David A. Lesch
CPC分类号： B01D67/0079 , B01D61/362 , B01D69/148 , B01D71/028 , B01D2323/21 , Y10S55/05
摘要： The present invention discloses a novel method of making high performance mixed matrix membranes (MMMs) using stabilized concentrated suspensions of solvents, uniformly dispersed polymer stabilized molecular sieves, and at least two different types of polymers as the continuous blend polymer matrix. MMMs as dense films or asymmetric flat sheet or hollow fiber membranes fabricated by the method described in the current invention exhibit significantly enhanced permeation performance for separations over the polymer membranes made from the continuous blend polymer matrix. MMMs of the present invention are suitable for a wide range of gas, vapor, and liquid separations such as alcohol/water, CO2/CH4, H2/CH4, O2/N2, CO2/N2, olefin/paraffin, iso/normal paraffins, and other light gases separations.
摘要翻译： 本发明公开了使用稳定的溶剂浓缩悬浮液，均匀分散的聚合物稳定化分子筛和至少两种不同类型的聚合物作为连续共混聚合物基质制备高性能混合基质膜（MMM）的新方法。 通过本发明所述方法制造的致密膜或非对称平板或中空纤维膜的MMM显示出从由连续共混聚合物基质制成的聚合物膜上的分离显着增强的渗透性能。 本发明的MMM适用于各种气体，蒸汽和液体分离，例如醇/水，CO 2 / CH 4，H 2 CH 2，N 2，N 2，CO 2，N 2，N 2， 烯烃/石蜡，异/正链烷烃和其它轻质气体分离。
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12.发明授权Polymer membranes prepared from aromatic polyimide membranes by thermal treating and UV crosslinking 有权通过热处理和UV交联由芳族聚酰亚胺膜制备的聚合物膜公开(公告)号：US09138692B2
公开(公告)日：2015-09-22
申请号：US13547313
申请日：2012-07-12
申请人： Chunqing Liu , Peter K. Coughlin , Man-Wing Tang , Raisa Minkov , Lubo Zhou
发明人： Chunqing Liu , Peter K. Coughlin , Man-Wing Tang , Raisa Minkov , Lubo Zhou
CPC分类号： B01D71/62 , B01D53/228 , B01D67/0093 , B01D2323/08 , B01D2323/30 , B01D2323/345 , C08G73/1039 , C08G73/1042 , C08G73/1046 , C08G73/1064 , C08G73/16 , C08L79/08 , Y02C20/20
摘要： The present invention discloses a new type of high performance polymer membranes prepared from aromatic polyimide membranes by thermal treating and crosslinking and methods for making and using these membranes. The polymer membranes were prepared from aromatic polyimide membranes by thermal treating under inert atmosphere followed by crosslinking preferably by using a UV radiation source. The aromatic polyimide membranes were made from aromatic polyimide polymers comprising both pendent hydroxy functional groups ortho to the heterocyclic imide nitrogen and cross-linkable functional groups in the polymer backbone. The membranes showed significantly improved selectivity and permeability for gas separations compared to the aromatic polyimide membranes without any treatment. The membranes can be fabricated into any convenient geometry and are not only suitable for a variety of liquid, gas, and vapor separations, but also can be used for other applications such as for catalysis and fuel cell applications.
摘要翻译： 本发明公开了通过热处理和交联由芳族聚酰亚胺膜制备的新型高性能聚合物膜以及制造和使用这些膜的方法。 聚合物膜由芳族聚酰亚胺膜通过在惰性气氛下热处理制备，然后优选通过使用UV辐射源进行交联。 芳族聚酰亚胺膜由芳族聚酰亚胺聚合物制成，其中包含杂环酰亚胺氮原子的邻接羟基官能团和聚合物主链中的可交联官能团。 与没有任何处理的芳族聚酰亚胺膜相比，膜显示出气体分离的选择性和渗透性显着提高。 膜可以制造成任何方便的几何形状，并且不仅适用于各种液体，气体和蒸汽分离，而且还可以用于其它应用，例如用于催化和燃料电池应用。
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公开(公告)号：US08931646B2
公开(公告)日：2015-01-13
申请号：US12879208
申请日：2010-09-10
申请人： Chunqing Liu , Raisa Minkov , Man-Wing Tang , Lubo Zhou , Jeffery C. Bricker
发明人： Chunqing Liu , Raisa Minkov , Man-Wing Tang , Lubo Zhou , Jeffery C. Bricker
IPC分类号： B01D71/64 , B01D71/28 , B01D53/22 , B01D67/00 , B01D71/62 , B01D71/82 , B01D69/00 , B01D61/36
CPC分类号： B01D53/228 , B01D61/362 , B01D67/0011 , B01D71/62 , B01D71/82 , B01D2323/08
摘要： The present invention discloses a blends of an aromatic polyimide polymer and a polymer containing aromatic sulfonic acid groups that can be converted into polybenzoxazole (PBO) membranes for gas, vapor, and liquid separations. The PBO membranes that were prepared by thermal treating aromatic polyimide membranes containing between 0.05 and 20 wt-% of a poly(styrene sulfonic acid) polymer. These polymers showed up to 95% improvement in selectivity for CO2/CH4 and H2/CH4 separations compared to PBO membranes prepared from corresponding aromatic polyimide membranes without a poly(styrene sulfonic acid) polymer.
摘要翻译： 本发明公开了芳族聚酰亚胺聚合物和含有芳族磺酸基团的聚合物的混合物，其可以转化成用于气体，蒸气和液体分离的聚苯并恶唑（PBO）膜。 通过热处理含有0.05至20重量％聚（苯乙烯磺酸）聚合物的芳族聚酰亚胺膜制备的PBO膜。 与没有聚（苯乙烯磺酸）聚合物的相应芳族聚酰亚胺膜制备的PBO膜相比，这些聚合物显示出对CO 2 / CH 4和H 2 / CH 4分离的选择性提高高达95％。
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公开(公告)号：US08613362B2
公开(公告)日：2013-12-24
申请号：US12412653
申请日：2009-03-27
申请人： Chunqing Liu , Raisa Serbayeva , Man-Wing Tang , Lubo Zhou , Peter K. Coughlin
发明人： Chunqing Liu , Raisa Serbayeva , Man-Wing Tang , Lubo Zhou , Peter K. Coughlin
CPC分类号： B01D71/64 , B01D67/0088 , B01D2323/08 , B01D2323/30
摘要： The present invention discloses a new type of high performance polymer membranes derived from aromatic polyimide membranes and methods for making and using these membranes. The polymer membranes described in the present invention were derived from aromatic polyimide membranes by crosslinking followed by thermal treating. The aromatic polyimide membranes were made from aromatic polyimide polymers comprising both pendent hydroxy functional groups ortho to the heterocyclic imide nitrogen and cross-linkable functional groups in the polymer backbone. The high performance polymer membranes showed significantly improved permeability for gas separations compared to the aromatic polyimide membranes without any treatment. The high performance polymer membranes also showed significantly improved selectivity for gas separations compared to the thermal-treated but non-UV-crosslinked aromatic polyimide membranes. The high performance polymer membranes of the present invention are suitable for liquid, gas, and vapor separations, as well as for catalysis and fuel cell applications.
摘要翻译： 本发明公开了一种衍生自芳族聚酰亚胺膜的新型高性能聚合物膜以及制造和使用这些膜的方法。 本发明中描述的聚合物膜通过交联然后进行热处理从芳族聚酰亚胺膜得到。 芳族聚酰亚胺膜由芳族聚酰亚胺聚合物制成，其中包含杂环酰亚胺氮原子的邻接羟基官能团和聚合物主链中的可交联官能团。 与没有任何处理的芳族聚酰亚胺膜相比，高性能聚合物膜显示出显着改善气体分离的渗透性。 与热处理但非UV交联的芳族聚酰亚胺膜相比，高性能聚合物膜还显示出对气体分离的选择性显着提高。 本发明的高性能聚合物膜适用于液体，气体和蒸汽分离，以及催化和燃料电池应用。
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15.发明授权Polymer membranes prepared from aromatic polyimide membranes by thermal treating and UV crosslinking 有权通过热处理和UV交联由芳族聚酰亚胺膜制备的聚合物膜公开(公告)号：US08241501B2
公开(公告)日：2012-08-14
申请号：US13165939
申请日：2011-06-22
申请人： Chunqing Liu , Peter K. Coughlin , Man-Wing Tang , Raisa Minkov , Lubo Zhou
发明人： Chunqing Liu , Peter K. Coughlin , Man-Wing Tang , Raisa Minkov , Lubo Zhou
CPC分类号： B01D71/62 , B01D53/228 , B01D67/0093 , B01D2323/08 , B01D2323/30 , B01D2323/345 , C08G73/1039 , C08G73/1042 , C08G73/1046 , C08G73/1064 , C08G73/16 , C08L79/08 , Y02C20/20
摘要： The present invention discloses a new type of high performance polymer membranes prepared from aromatic polyimide membranes by thermal treating and crosslinking and methods for making and using these membranes. The polymer membranes were prepared from aromatic polyimide membranes by thermal treating under inert atmosphere followed by crosslinking preferably by using a UV radiation source. The aromatic polyimide membranes were made from aromatic polyimide polymers comprising both pendent hydroxy functional groups ortho to the heterocyclic imide nitrogen and cross-linkable functional groups in the polymer backbone. The membranes showed significantly improved selectivity and permeability for gas separations compared to the aromatic polyimide membranes without any treatment. The membranes can be fabricated into any convenient geometry and are not only suitable for a variety of liquid, gas, and vapor separations, but also can be used for other applications such as for catalysis and fuel cell applications.
摘要翻译： 本发明公开了通过热处理和交联由芳族聚酰亚胺膜制备的新型高性能聚合物膜以及制造和使用这些膜的方法。 聚合物膜由芳族聚酰亚胺膜通过在惰性气氛下热处理制备，然后优选通过使用UV辐射源进行交联。 芳族聚酰亚胺膜由芳族聚酰亚胺聚合物制成，其中包含杂环酰亚胺氮原子的邻接羟基官能团和聚合物主链中的可交联官能团。 与没有任何处理的芳族聚酰亚胺膜相比，膜显示出气体分离的选择性和渗透性显着提高。 膜可以制造成任何方便的几何形状，并且不仅适用于各种液体，气体和蒸汽分离，而且还可以用于其它应用，例如用于催化和燃料电池应用。
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公开(公告)号：US20120085697A1
公开(公告)日：2012-04-12
申请号：US13329412
申请日：2011-12-19
申请人： Man-Wing Tang
发明人： Man-Wing Tang
CPC分类号： B01D71/70 , B01D67/0006 , B01D69/105 , B01D69/125 , B01D71/14 , B01D71/16 , B01D71/64 , B01D71/68 , B01D2323/30 , B01D2323/345 , D06M15/07 , D06M15/55 , D06M15/59 , D06M15/63 , D06M15/643 , D06N3/183 , D06N7/0094 , Y10T428/23957
摘要： The present invention the manufacture of a membrane for gas and liquid separations in which a polymer layer is applied directly to a tricot fabric instead of the conventional cloth or glass or metal substrate.
摘要翻译： 本发明制造用于气液分离的膜，其中将聚合物层直接施加到特里科经编织物上而不是常规的布或玻璃或金属基底。
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公开(公告)号：US08132678B2
公开(公告)日：2012-03-13
申请号：US12412647
申请日：2009-03-27
申请人： Chunqing Liu , Man-Wing Tang , Raisa Serbayeva , Lubo Zhou
发明人： Chunqing Liu , Man-Wing Tang , Raisa Serbayeva , Lubo Zhou
CPC分类号： B01D69/148 , B01D53/228 , B01D67/0079 , B01D71/028 , B01D71/62 , B01D2256/16 , B01D2256/18 , B01D2256/24 , B01D2257/108 , B01D2257/304 , B01D2257/504 , B01D2258/06 , H01M8/1048 , H01M2300/0082 , Y02C10/10 , Y02C20/20
摘要： The present invention discloses new types of polybenzoxazole-based mixed matrix membranes and methods for making and using these membranes. The polybenzoxazole-based mixed matrix membranes are prepared by fabricating a polyimide-based mixed matrix membrane by dispersing molecular sieve particles in a continuous aromatic polyimide matrix with pendent hydroxyl groups ortho to the heterocyclic imide nitrogen; and then converting the polyimide-based mixed matrix membrane to a polybenzoxazole-based mixed matrix membrane by heating between 200° and 600° C. under inert atmosphere or vacuum. The polybenzoxazole-based mixed matrix membranes of the present invention can be fabricated into any convenient geometry such as flat sheet (or spiral wound), tube, hollow fiber, or thin film composite. These polybenzoxazole-based mixed matrix membranes exhibit high thermal stability, significantly higher selectivity than the neat polybenzoxazole polymer membranes, and much higher permeability than traditional mixed matrix membranes.
摘要翻译： 本发明公开了新型的基于苯并恶唑的混合基质膜，以及制造和使用这些膜的方法。 基于聚苯并恶唑的混合基质膜通过将分子筛颗粒分散在具有与杂环酰亚胺氮原子相邻的侧羟基的连续芳族聚酰亚胺基体中制备聚酰亚胺基混合基质膜来制备; 然后通过在惰性气氛或真空下在200℃和600℃之间加热将聚酰亚胺基混合基质膜转变成聚苯并恶唑类混合基质膜。 本发明的基于聚苯并恶唑的混合基质膜可以制成任何方便的几何形状，例如平板（或螺旋缠绕），管，中空纤维或薄膜复合材料。 这些基于聚苯并恶唑的混合基质膜具有高的热稳定性，比纯聚苯并恶唑聚合物膜显着更高的选择性，并且比传统的混合基质膜具有更高的渗透性。
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公开(公告)号：US20100331437A1
公开(公告)日：2010-12-30
申请号：US12879244
申请日：2010-09-10
申请人： Chunqing Liu , Raisa Minkov , Syed A. Faheem , Man-Wing Tang , Lubo Zhou , Jeffery C. Bricker
发明人： Chunqing Liu , Raisa Minkov , Syed A. Faheem , Man-Wing Tang , Lubo Zhou , Jeffery C. Bricker
IPC分类号： C08F24/00
CPC分类号： B01D53/228 , B01D71/62 , B01D2323/30 , B01D2323/345 , C08G69/26 , C08G69/32 , C08G73/22 , C08L79/04 , H01M8/1027 , H01M8/103
摘要： The present invention discloses high performance polybenzoxazole membranes prepared from aromatic poly(o-hydroxy amide) membranes by thermal cyclization and a method for using these membranes. The polybenzoxazole membranes were prepared by thermal treating aromatic poly(o-hydroxy amide) membranes in a temperature range of 200° to 550° C. under inert atmosphere. The aromatic poly(o-hydroxy amide) membranes used for making the polybenzoxazole membranes were prepared from aromatic poly(o-hydroxy amide) polymers comprising pendent phenolic hydroxyl groups ortho to the amide nitrogen in the polymer backbone. In some embodiments of the invention, the polybenzoxazole membranes may be subjected to an additional crosslinking step to increase the selectivity of the membranes. These polybenzoxazole membranes showed significantly improved permeability for gas separations compared to the precursor aromatic poly(o-hydroxy amide) membranes and are not only suitable for a variety of liquid, gas, and vapor separations, but also can be used in catalysis and fuel cells.
摘要翻译： 本发明公开了通过热环化由芳族聚（邻羟基酰胺）膜制备的高性能聚苯并恶唑膜和使用这些膜的方法。 通过在惰性气氛下在200〜550℃的温度范围内热处理芳族聚（邻羟基酰胺）膜来制备聚苯并恶唑膜。 用于制备聚苯并恶唑膜的芳族聚（邻羟基酰胺）膜是由芳族聚（邻羟基酰胺）聚合物制备的，该聚合物包括聚合物骨架中酰胺氮原子邻位的酚羟基。 在本发明的一些实施方案中，聚苯并恶唑膜可以进行额外的交联步骤以增加膜的选择性。 与前体芳族聚（邻羟基酰胺）膜相比，这些聚苯并恶唑膜显示出显着改善气体分离的渗透性，并且不仅适用于各种液体，气体和蒸气分离，而且还可用于催化和燃料电池 。
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公开(公告)号：US07810652B2
公开(公告)日：2010-10-12
申请号：US12566834
申请日：2009-09-25
申请人： Chunqing Liu , Raisa Minkov , Man-Wing Tang , Lubo Zhou , Jeffery C. Bricker
发明人： Chunqing Liu , Raisa Minkov , Man-Wing Tang , Lubo Zhou , Jeffery C. Bricker
CPC分类号： B01D53/228 , B01D67/0093 , B01D71/62 , B01D2323/08
摘要： The present invention discloses a novel method to improve the selectivities of polybenzoxazole (PBO) membranes prepared from aromatic polyimide membranes for gas, vapor, and liquid separations. The PBO membranes that were prepared by thermal treating aromatic polyimide membranes containing between 0.05 and 20 wt-% of a poly(styrene sulfonic acid) polymer. These polymers showed up to 95% improvement in selectivity for CO2/CH4 and H2/CH4 separations compared to PBO membranes prepared from corresponding aromatic polyimide membranes without a poly(styrene sulfonic acid) polymer.
摘要翻译： 本发明公开了一种提高由芳族聚酰亚胺膜制备的用于气体，蒸汽和液体分离的聚苯并恶唑（PBO）膜的选择性的新方法。 通过热处理含有0.05至20重量％聚（苯乙烯磺酸）聚合物的芳族聚酰亚胺膜制备的PBO膜。 与没有聚（苯乙烯磺酸）聚合物的相应芳族聚酰亚胺膜制备的PBO膜相比，这些聚合物显示出对CO 2 / CH 4和H 2 / CH 4分离的选择性提高高达95％。
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公开(公告)号：US20080141858A1
公开(公告)日：2008-06-19
申请号：US11612388
申请日：2006-12-18
申请人： Chunqing Liu , Man-Wing Tang , Stephen T. Wilson , David A. Lesch
发明人： Chunqing Liu , Man-Wing Tang , Stephen T. Wilson , David A. Lesch
IPC分类号： B01D53/22
CPC分类号： B01D69/141 , B01D53/228 , B01D61/362 , B01D67/0079
摘要： The present invention discloses a novel method of making high performance mixed matrix membranes (MMMs) using stabilized concentrated suspensions of solvents, uniformly dispersed polymer stabilized molecular sieves, and at least two different types of polymers as the continuous blend polymer matrix. MMMs as dense films or asymmetric flat sheet or hollow fiber membranes fabricated by the method described in the current invention exhibit significantly enhanced permeation performance for separations over the polymer membranes made from the continuous blend polymer matrix. MMMs of the present invention are suitable for a wide range of gas, vapor, and liquid separations such as alcohol/water, CO2/CH4, H2/CH4, O2/N2, CO2/N2, olefin/paraffin, iso/normal paraffins, and other light gases separations.
摘要翻译： 本发明公开了使用稳定的溶剂浓缩悬浮液，均匀分散的聚合物稳定化分子筛和至少两种不同类型的聚合物作为连续共混聚合物基质制备高性能混合基质膜（MMM）的新方法。 通过本发明所述方法制造的致密膜或非对称平板或中空纤维膜的MMM显示出从由连续共混聚合物基质制成的聚合物膜上的分离显着提高的渗透性能。 本发明的MMM适用于各种气体，蒸汽和液体分离，例如醇/水，CO 2 / CH 4，H 2 CH 2，N 2，N 2，CO 2，N 2，N 2， 烯烃/石蜡，异/正链烷烃和其它轻质气体分离。
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