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公开(公告)号：US08575414B2
公开(公告)日：2013-11-05
申请号：US13287582
申请日：2011-11-02
Applicant: Chunqing Liu , Syed A. Faheem , Raisa Minkov
Inventor： Chunqing Liu , Syed A. Faheem , Raisa Minkov
IPC: C07C7/144
CPC classification number: C10L3/104 , B01D53/22 , B01D2256/245 , B01D2257/504 , C10L3/101 , Y02C10/04 , Y02C10/10
Abstract: The present invention involves the use of a novel membrane system for natural gas upgrading. This membrane system includes a first-stage membrane such as a membrane prepared from the polymer of intrinsic microporosity (PIM) to selectively remove hydrocarbons from C3 to C35 to control the dew point of natural gas, and a second-stage membrane such as a polybenzoxazole (PBO) or crosslinked PBO membrane to selectively remove CO2 from natural gas. The new membrane system described in the current invention eliminates the use of high cost and high footprint membrane pretreatment. Therefore, the membrane system can significantly reduce the footprint and cost for natural gas upgrading compared to the current commercially available membrane systems that include a non-membrane-related pretreatment system.
Abstract translation: 本发明涉及使用新型膜系统进行天然气升级。 该膜系统包括由本征微孔聚合物（PIM）制备的膜的第一级膜，以选择性地从C3至C35去除烃，以控制天然气的露点;以及第二级膜，例如聚苯并恶唑 （PBO）或交联的PBO膜以选择性地从天然气中除去CO 2。 本发明描述的新膜系统消除了高成本和高占地面积的膜预处理的使用。 因此，与目前市场上可买到的膜系统（包括非膜相关的预处理系统）相比，膜系统可显着减少天然气升级的占地面积和成本。
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公开(公告)号：US20120322911A1
公开(公告)日：2012-12-20
申请号：US13278388
申请日：2011-10-21
Applicant: Chunqing Liu , Travis C. Bowen , Emily G. Harbert , Raisa Minkov , Syed A. Faheem , Zara Osman
Inventor： Chunqing Liu , Travis C. Bowen , Emily G. Harbert , Raisa Minkov , Syed A. Faheem , Zara Osman
CPC classification number: C08G73/1042 , B01D53/228 , B01D61/362 , B01D67/0009 , B01D67/009 , B01D69/02 , B01D69/06 , B01D69/08 , B01D71/64 , B01D71/82 , B01D2323/30 , B01D2323/345 , B01D2325/20 , C08G73/1046 , C08G73/1064 , Y02P20/152
Abstract: The present invention discloses a new type of polyimide membrane with high permeances and high selectivities for gas separations and particularly for CO2/CH4 and H2/CH4 separations. The polyimide membranes have CO2 permeability of 50 Barrers or higher and single-gas selectivity for CO2/CH4 of 15 or higher at 50° C. under 791 kPa for CO2/CH4 separation. The polyimide membranes have UV cross-linkable functional groups and can be used for the preparation of UV cross-linked polyimide membranes having CO2 permeability of 20 Barrers or higher and single-gas selectivity for CO2/CH4 of 35 or higher at 50° C. under 791 kPa for CO2/CH4 separation.
Abstract translation: 本发明公开了一种具有高渗透性和高选择性的新型聚酰亚胺膜，用于气体分离，特别是用于CO2 / CH4和H2 / CH4分离。 聚酰亚胺膜具有50巴尔或更高的CO 2渗透性，对于CO 2 / CH 4分离，在791kPa下，在50℃，CO 2 / CH 4的单气体选择性为15或更高。 聚酰亚胺膜具有UV可交联官能团，可用于制备二氧化碳透过率为20巴尔或更高的紫外线交联聚酰亚胺膜，在50℃下二氧化碳/氯化氢的单气选择性为35或更高。 在791 kPa下CO2 / CH4分离。
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公开(公告)号：US20100326913A1
公开(公告)日：2010-12-30
申请号：US12879249
申请日：2010-09-10
Applicant: Chunqing Liu , Raisa Minkov , Syed A. Faheem , Man-Wing Tang , Lubo Zhou , Jeffery C. Bricker
Inventor： Chunqing Liu , Raisa Minkov , Syed A. Faheem , Man-Wing Tang , Lubo Zhou , Jeffery C. Bricker
CPC classification number: B01D53/228 , B01D61/025 , B01D61/362 , B01D71/62 , B01D2323/30 , B01D2323/345 , C02F1/441 , C02F2103/08 , C08G69/26 , C08G69/32 , C08G73/22 , C08L79/04 , H01M8/1018 , H01M8/1025 , H01M8/103 , H01M8/1032 , H01M8/1039 , H01M8/106 , H01M8/1069 , Y02A20/131 , Y02C20/20 , Y02P70/56
Abstract: The present invention discloses high performance polybenzoxazole membranes prepared from aromatic poly(o-hydroxy amide) membranes by thermal cyclization and a method for using these membranes. The polybenzoxazole membranes were prepared by thermal treating aromatic poly(o-hydroxy amide) membranes in a temperature range of 200° to 550° C. under inert atmosphere. The aromatic poly(o-hydroxy amide) membranes used for making the polybenzoxazole membranes were prepared from aromatic poly(o-hydroxy amide) polymers comprising pendent phenolic hydroxyl groups ortho to the amide nitrogen in the polymer backbone. In some embodiments of the invention, the polybenzoxazole membranes may be subjected to an additional crosslinking step to increase the selectivity of the membranes. These polybenzoxazole membranes showed significantly improved permeability for gas separations compared to the precursor aromatic poly(o-hydroxy amide) membranes and are not only suitable for a variety of liquid, gas, and vapor separations, but also can be used in catalysis and fuel cells.
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公开(公告)号：US20100133188A1
公开(公告)日：2010-06-03
申请号：US12491473
申请日：2009-06-25
Applicant: Chunqing Liu , Raisa Minkov , Syed A. Faheem , Man-Wing Tang , Lubo Zhou , Jeffery C. Bricker
Inventor： Chunqing Liu , Raisa Minkov , Syed A. Faheem , Man-Wing Tang , Lubo Zhou , Jeffery C. Bricker
CPC classification number: B01D71/62 , B01D53/228 , B01D2323/30 , B01D2323/345 , C08G69/26 , C08G73/22 , H01M8/1027 , H01M8/103 , H01M2300/0082
Abstract: The present invention discloses high performance polybenzoxazole membranes prepared from aromatic poly(o-hydroxy amide) membranes by thermal cyclization and a method for using these membranes. The polybenzoxazole membranes were prepared by thermal treating aromatic poly(o-hydroxy amide) membranes in a temperature range of 200° to 550° C. under inert atmosphere. The aromatic poly(o-hydroxy amide) membranes used for making the polybenzoxazole membranes were prepared from aromatic poly(o-hydroxy amide) polymers comprising pendent phenolic hydroxyl groups ortho to the amide nitrogen in the polymer backbone. In some embodiments of the invention, the polybenzoxazole membranes may be subjected to an additional crosslinking step to increase the selectivity of the membranes. These polybenzoxazole membranes showed significantly improved permeability for gas separations compared to the precursor aromatic poly(o-hydroxy amide) membranes and are not only suitable for a variety of liquid, gas, and vapor separations, but also can be used in catalysis and fuel cells.
Abstract translation: 本发明公开了通过热环化由芳族聚（邻羟基酰胺）膜制备的高性能聚苯并恶唑膜和使用这些膜的方法。 通过在惰性气氛下在200〜550℃的温度范围内热处理芳族聚（邻羟基酰胺）膜来制备聚苯并恶唑膜。 用于制备聚苯并恶唑膜的芳族聚（邻羟基酰胺）膜是由芳族聚（邻羟基酰胺）聚合物制备的，该聚合物包括聚合物骨架中酰胺氮原子邻位的酚羟基。 在本发明的一些实施方案中，聚苯并恶唑膜可以进行额外的交联步骤以增加膜的选择性。 与前体芳族聚（邻羟基酰胺）膜相比，这些聚苯并恶唑膜显示出显着改善气体分离的渗透性，并且不仅适用于各种液体，气体和蒸气分离，而且还可用于催化和燃料电池 。
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公开(公告)号：US20100069234A1
公开(公告)日：2010-03-18
申请号：US12552037
申请日：2009-09-01
Applicant: Richard R. Willis , John J. Low , Syed A. Faheem , Annabelle I. Benin , Randall Q. Snurr , Ahmet Ozgur Yazaydin
Inventor： Richard R. Willis , John J. Low , Syed A. Faheem , Annabelle I. Benin , Randall Q. Snurr , Ahmet Ozgur Yazaydin
IPC: B01J20/22
CPC classification number: B01J20/22 , B01D53/02 , B01D2253/204 , B01D2257/504 , B01J20/226 , Y02C10/08
Abstract: The present invention involves the use of certain metal organic frameworks that have been treated with water or another metal titrant in the storage of carbon dioxide. The capacity of these frameworks is significantly increased through this treatment.
Abstract translation: 本发明涉及使用在二氧化碳储存中用水或另一种金属滴剂处理的某些金属有机骨架。 通过这种治疗，这些框架的能力大大增加。
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Patent Agency Ranking
公开(公告)号：US08704030B2
公开(公告)日：2014-04-22
申请号：US13278467
申请日：2011-10-21
Applicant: Chunqing Liu , Travis C. Bowen , Emily G. Harbert , Raisa Minkov , Syed A. Faheem , Zara Osman
Inventor： Chunqing Liu , Travis C. Bowen , Emily G. Harbert , Raisa Minkov , Syed A. Faheem , Zara Osman
IPC: C07C7/144
CPC classification number: C07C7/144 , B01D53/228 , B01D71/64 , B01D2256/10 , B01D2256/16 , B01D2256/245 , B01D2257/104 , B01D2257/304 , B01D2257/504 , B01D2257/80 , C01B3/503 , C01B2203/0405 , C10L3/104 , C10L2290/548 , Y02C10/10 , Y02C20/20 , Y02P20/152
Abstract: The present invention discloses a new type of polyimide membrane with high permeances and high selectivities for gas separations and particularly for CO2/CH4 and H2/CH4 separations. The polyimide membranes have CO2 permeability of 50 Barrers or higher and single-gas selectivity for CO2/CH4 of 15 or higher at 50° C. under 791 kPa for CO2/CH4 separation. The polyimide membranes have UV cross-linkable functional groups and can be used for the preparation of UV cross-linked polyimide membranes having CO2 permeability of 20 Barrers or higher and single-gas selectivity for CO2/CH4 of 35 or higher at 50° C. under 791 kPa for CO2/CH4 separation.
Abstract translation: 本发明公开了一种具有高渗透性和高选择性的新型聚酰亚胺膜，用于气体分离，特别是用于CO 2 / CH 4和H 2 / CH 4分离。 聚酰亚胺膜具有50巴尔或更高的CO 2渗透性，对于CO 2 / CH 4分离，在791kPa下，在50℃，CO 2 / CH 4的单气体选择性为15或更高。 聚酰亚胺膜具有UV可交联官能团，可用于制备二氧化碳透过率为20巴尔或更高的紫外线交联聚酰亚胺膜，在50℃下二氧化碳/氯化氢的单气选择性为35或更高。 在791 kPa下CO2 / CH4分离。
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公开(公告)号：US08459469B2
公开(公告)日：2013-06-11
申请号：US12879244
申请日：2010-09-10
Applicant: Chunqing Liu , Raisa Minkov , Syed A. Faheem , Man-Wing Tang , Lubo Zhou , Jeffery C. Bricker
Inventor： Chunqing Liu , Raisa Minkov , Syed A. Faheem , Man-Wing Tang , Lubo Zhou , Jeffery C. Bricker
CPC classification number: B01D53/228 , B01D71/62 , B01D2323/30 , B01D2323/345 , C08G69/26 , C08G69/32 , C08G73/22 , C08L79/04 , H01M8/1027 , H01M8/103
Abstract: The present invention discloses high performance polybenzoxazole membranes prepared from aromatic poly(o-hydroxy amide) membranes by thermal cyclization and a method for using these membranes. The polybenzoxazole membranes were prepared by thermal treating aromatic poly(o-hydroxy amide) membranes in a temperature range of 200° to 550° C. under inert atmosphere. The aromatic poly(o-hydroxy amide) membranes used for making the polybenzoxazole membranes were prepared from aromatic poly(o-hydroxy amide) polymers comprising pendent phenolic hydroxyl groups ortho to the amide nitrogen in the polymer backbone. In some embodiments of the invention, the polybenzoxazole membranes may be subjected to an additional crosslinking step to increase the selectivity of the membranes. These polybenzoxazole membranes showed significantly improved permeability for gas separations compared to the precursor aromatic poly(o-hydroxy amide) membranes and are not only suitable for a variety of liquid, gas, and vapor separations, but also can be used in catalysis and fuel cells.
Abstract translation: 本发明公开了通过热环化由芳族聚（邻羟基酰胺）膜制备的高性能聚苯并恶唑膜和使用这些膜的方法。 通过在惰性气氛下在200〜550℃的温度范围内热处理芳族聚（邻羟基酰胺）膜来制备聚苯并恶唑膜。 用于制备聚苯并恶唑膜的芳族聚（邻羟基酰胺）膜是由芳族聚（邻羟基酰胺）聚合物制备的，该聚合物包括聚合物骨架中酰胺氮原子邻位的酚羟基。 在本发明的一些实施方案中，聚苯并恶唑膜可以进行额外的交联步骤以增加膜的选择性。 与前体芳族聚（邻羟基酰胺）膜相比，这些聚苯并恶唑膜显示出显着改善气体分离的渗透性，并且不仅适用于各种液体，气体和蒸气分离，而且还可用于催化和燃料电池 。
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公开(公告)号：US08227375B2
公开(公告)日：2012-07-24
申请号：US12552037
申请日：2009-09-01
Applicant: Richard R. Willis , John J. Low , Syed A. Faheem , Annabelle I. Benin , Randall Q. Snurr , Ahmet Ozgur Yazaydin
Inventor： Richard R. Willis , John J. Low , Syed A. Faheem , Annabelle I. Benin , Randall Q. Snurr , Ahmet Ozgur Yazaydin
IPC: B01J20/22
CPC classification number: B01J20/22 , B01D53/02 , B01D2253/204 , B01D2257/504 , B01J20/226 , Y02C10/08
Abstract: The present invention involves the use of certain metal organic frameworks that have been treated with water or another metal titrant in the storage of carbon dioxide. The capacity of these frameworks is significantly increased through this treatment.
Abstract translation: 本发明涉及使用在二氧化碳储存中用水或另一种金属滴剂处理的某些金属有机骨架。 通过这种治疗，这些框架的能力大大增加。
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公开(公告)号：US20080286196A1
公开(公告)日：2008-11-20
申请号：US11748656
申请日：2007-05-15
Applicant: Syed A. Faheem , Gregory J. Lewis , J.W. Adriaan Sachtler , John J. Low , David A. Lesch , Paul M. Dosek , Christopher M. Wolverton , Donald J. Siegel , Andrea C. Sudik , Jun Yang
Inventor： Syed A. Faheem , Gregory J. Lewis , J.W. Adriaan Sachtler , John J. Low , David A. Lesch , Paul M. Dosek , Christopher M. Wolverton , Donald J. Siegel , Andrea C. Sudik , Jun Yang
CPC classification number: C01B3/0031 , C01B3/001 , Y02E60/327
Abstract: A reversible hydrogen storage composition having an empirical formula of: Li(x+z)NxMgyBzHw where 0.4≦x≦0.8; 0.2≦y≦0.6; 0
Abstract translation: 具有以下经验式的可逆储氢组合物：<？in-line-formula description =“In-line Formulas”end =“lead”？> Li（x + z）N < β-in-line-formula description =“In-line Formulas”end =“ 尾“→>其中0.4 <= x <= 0.8; 0.2 <= y <= 0.6; 0
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公开(公告)号：US08912288B2
公开(公告)日：2014-12-16
申请号：US13278483
申请日：2011-10-21
Applicant: Chunqing Liu , Travis C. Bowen , Emily G. Harbert , Raisa Minkov , Syed A. Faheem , Zara Osman
Inventor： Chunqing Liu , Travis C. Bowen , Emily G. Harbert , Raisa Minkov , Syed A. Faheem , Zara Osman
IPC: C08G69/08 , B01D71/64 , B01D53/22 , B01D61/02 , B01D61/36 , B01D67/00 , B01D69/08 , C02F1/44 , C07K1/14 , C07C7/144 , C07C17/38 , C10G31/11
CPC classification number: B01D71/64 , A61K9/70 , B01D53/228 , B01D61/025 , B01D61/362 , B01D67/0093 , B01D69/08 , B01D71/68 , B01D2323/30 , B01D2323/345 , C02F1/441 , C02F1/448 , C07C7/144 , C07C17/38 , C07K1/14 , C10G31/11 , C10G2300/1044 , Y02E50/17 , Y02P20/152 , Y02P20/51 , C07C9/04 , C07C11/06 , C07C11/09 , C07C11/02 , C07C19/04
Abstract: The present invention discloses a new type of polyimide membrane with high permeances and high selectivities for gas separations and particularly for CO2/CH4 and H2/CH4 separations. The polyimide membranes have CO2 permeability of 50 Barrers or higher and single-gas selectivity for CO2/CH4 of 15 or higher at 50° C. under 791 kPa for CO2/CH4 separation. The polyimide membranes have UV cross-linkable functional groups and can be used for the preparation of UV cross-linked polyimide membranes having CO2 permeability of 20 Barrers or higher and single-gas selectivity for CO2/CH4 of 35 or higher at 50° C. under 791 kPa for CO2/CH4 separation.
Abstract translation: 本发明公开了一种具有高渗透性和高选择性的新型聚酰亚胺膜，用于气体分离，特别是用于CO 2 / CH 4和H 2 / CH 4分离。 聚酰亚胺膜具有50巴尔或更高的CO 2渗透性，对于CO 2 / CH 4分离，在791kPa下，在50℃，CO 2 / CH 4的单气体选择性为15或更高。 聚酰亚胺膜具有UV可交联官能团，可用于制备二氧化碳透过率为20巴尔或更高的紫外线交联聚酰亚胺膜，在50℃下二氧化碳/氯化氢的单气选择性为35或更高。 在791 kPa下CO2 / CH4分离。
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