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277 条记录 (耗时 0.031 秒)

    Preparation of amines
    14.
    发明授权
    Preparation of amines 失效
    胺的制备

    公开(公告)号：US6057442A

    公开(公告)日：2000-05-02

    申请号：US159089

    申请日：1998-09-23

    申请人： Joachim Wulff-Doring ,  Michael Hesse ,  Johann-Peter Melder ,  Philipp Buskens ,  Guido Voit ,  Frank Funke

    发明人： Joachim Wulff-Doring ,  Michael Hesse ,  Johann-Peter Melder ,  Philipp Buskens ,  Guido Voit ,  Frank Funke

    IPC分类号： C07D295/02 ,  B01J23/755 ,  B01J23/889 ,  C07B61/00 ,  C07C209/16 ,  C07D295/023

    CPC分类号： C07D295/023 ,  B01J23/755 ,  B01J23/8892 ,  C07C209/16 ,  B01J23/8898 ,  Y02P20/582

    摘要： Amines are prepared from primary or secondary alcohols and nitrogen compounds selected from the group of ammonia, primary and secondary amines, at from 80 to 250.degree. C. under pressures from 0.1 to 40 MPa with hydrogen in the presence of a catalyst comprising zirconium, copper and nickel, wherein the catalytically active composition comprises20-85% by weight of oxygen-containing zirconium compounds, calculated as ZrO.sub.2,1-30% by weight of oxygen-containing copper compounds, calculated as CuO,14-70% by weight of oxygen-containing nickel compounds, calculated as NiO, where the molar ratio of nickel to copper is greater than 1,0-10% by weight of oxygen-containing aluminum and/or manganese compounds, calculated as Al.sub.2 O.sub.3 and/or MnO.sub.2,and no oxygen-containing cobalt or molybdenum compounds.

    摘要翻译： 在含有锆，铜和铜的催化剂存在下，在氢气压力为0.1至40MPa的压力下，从伯，仲醇和选自氨，伯胺和仲胺的氮化合物制备胺。 和镍，其中催化活性组合物包含20-85重量％的以ZrO 2计算的含氧锆化合物，1-30重量％的以CuO计的含氧铜化合物，14-70重量％ 以NiO计算的含氧镍化合物，其中镍与铜的摩尔比大于1-10重量％，以Al 2 O 3和/或MnO 2计算的含氧铝和/或锰化合物为0-10重量％ 含氧钴或钼化合物。

    Process for producing caprolactam
    16.
    发明授权
    Process for producing caprolactam 失效
    己内酰胺的制备方法

    公开(公告)号：US06683177B1

    公开(公告)日：2004-01-27

    申请号：US08952208

    申请日：1997-11-06

    申请人： Eberhard Fuchs ,  Johann-Peter Melder ,  Werner Schnurr ,  Rolf Fischer

    发明人： Eberhard Fuchs ,  Johann-Peter Melder ,  Werner Schnurr ,  Rolf Fischer

    IPC分类号： C07D20108

    CPC分类号： C07D201/08 ,  C07D223/12

    摘要： A process for preparing caprolactam by reacting 6-aminocapronitrile with water in the presence of catalysts comprises using a starting mixture of 6-aminocapronitrile and the tetrahydroazepine derivative of the formula and conducting the reaction in liquid phase in the presence of a heterogeneous catalyst. Also describes a process for preparing said tetrahydroazepine derivative I and its use for preparing caprolactam and polycaprolactam.

    摘要翻译： 在催化剂存在下使6-氨基己腈与水反应制备己内酰胺的方法包括使用6-氨基己腈和下式的四氢氮杂衍生物的起始混合物，并在非均相催化剂存在下进行液相反应。 还描述了制备所述四氢氮杂衍生物I的方法及其制备己内酰胺和聚己内酰胺的用途。

    Process for preparing a cyclic tertiary methylamine
    18.
    发明授权
    Process for preparing a cyclic tertiary methylamine 有权
    制备环状叔甲胺的方法

    公开(公告)号：US08637668B2

    公开(公告)日：2014-01-28

    申请号：US13158667

    申请日：2011-06-13

    申请人： Christof Wilhelm Wigbers ,  Johann-Peter Melder ,  Bernd Stein ,  Harald Meiβner

    发明人： Christof Wilhelm Wigbers ,  Johann-Peter Melder ,  Bernd Stein ,  Harald Meiβner

    IPC分类号： C07D295/03

    CPC分类号： C07D295/03

    摘要： Process for preparing a cyclic tertiary methylamine of the formula I where A is a C4-alkylene group, a C5-alkylene group or a —(CH2)2—B—(CH2)2— group, where B is oxygen (O) or an N—R1 radical and R1 is C1-C5-alkyl, aryl or C5-C7-cycloalkyl, wherein an amino alcohol II from the group consisting of 1,4-aminobutanol, 1,5-aminopentanol, aminodiglycol (ADG) or aminoethylethanolamine of the formula IIa where R1 is as defined above or is hydrogen (H), in which case R1═CH3 in the amine I, is reacted with methanol in a reactor at a temperature in the range from 150 to 270° C. in the liquid phase in the presence of a copper-comprising heterogeneous catalyst.

    摘要翻译： 制备式I的环状叔甲胺的方法，其中A是C 4 - 亚烷基，C 5-亚烷基或 - （CH 2）2 -B-（CH 2）2 - 基，其中B是氧（O）或 R 1是C 1 -C 5 - 烷基，芳基或C 5 -C 7 - 环烷基，其中由1,4-氨基丁醇，1,5-氨基戊醇，氨基二甘醇（ADG）或氨基乙基乙醇胺组成的组中的氨基醇II 其中R 1如上定义或是氢（H），在这种情况下，胺I中的R 1 = CH 3在反应器中在150-270℃的温度下与甲醇反应，在 在含铜的非均相催化剂存在下的液相。

    Method for producing N,N-substituted-3-aminopropan-1-ols
    19.
    发明授权
    Method for producing N,N-substituted-3-aminopropan-1-ols 有权
    制备N，N-取代-3-氨基丙-1-醇的方法

    公开(公告)号：US08536377B2

    公开(公告)日：2013-09-17

    申请号：US13127828

    申请日：2009-11-02

    申请人： Christof Wilhelm Wigbers ,  Johann-Peter Melder ,  Martin Ernst

    发明人： Christof Wilhelm Wigbers ,  Johann-Peter Melder ,  Martin Ernst

    IPC分类号： C07C213/00

    CPC分类号： C07C213/02 ,  C07C227/08 ,  Y02P20/582 ,  C07C215/08 ,  C07C229/12

    摘要： The present invention relates to a process for preparing N,N-substituted 3-aminopropan-1-ols by a) reacting secondary amine with acrolein at a temperature of (−50) to 100° C. and a pressure of 0.01 to 300 bar, and b) reacting the reaction mixture obtained in stage a) with hydrogen and ammonia in the presence of a hydrogenation catalyst at a pressure of 1 to 400 bar, wherein the molar ratio of secondary amine to acrolein in stage a) is 1:1 or more and the temperature in stage b) is in the range from (−50) to 70° C. In a preferred embodiment, acrolein which has been obtained from glycerol based on renewable raw materials is used. The invention further relates to the use of an N,N-dimethyl-3-aminopropan-1-ol (DMAPOL) based on renewable raw materials as a catalyst for polyurethane preparation, as a scrubbing fluid in gas scrubbing, in the electronics chemicals and electroplating sectors, as a feedstock in organic synthesis, and as an intermediate in the production of pharmaceuticals and crop protection compositions.

    摘要翻译： 本发明涉及一种通过以下步骤制备N，N-取代的3-氨基丙-1-醇的方法：a）在（-50）至100℃的温度和0.01至300巴的压力下使仲胺与丙烯醛反应 ，和b）在加氢催化剂存在下，在1至400巴的压力下，将a）中获得的反应混合物与氢气和氨反应，其中a）步中仲胺与丙烯醛的摩尔比为1:1 或更高，步骤b）中的温度在（-50）至70℃的范围内。在优选的实施方案中，使用了基于可再生原料从甘油获得的丙烯醛。 本发明还涉及使用基于可再生原料的N，N-二甲基-3-氨基丙-1-醇（DMAPOL）作为聚氨酯制备的催化剂，在电气化学品中用作气体洗涤中的洗涤液， 电镀部门，作为有机合成中的原料，以及作为药物和作物保护组合物生产中的中间体。

    Method for producing N,N-substituted-1,3-propandiamines
    20.
    发明授权
    Method for producing N,N-substituted-1,3-propandiamines 有权
    制备N，N-取代-1,3-丙二胺的方法

    公开(公告)号：US08461391B2

    公开(公告)日：2013-06-11

    申请号：US12991767

    申请日：2009-05-11

    申请人： Martin Ernst ,  Johann-Peter Melder ,  Christof Wilhelm Wigbers

    发明人： Martin Ernst ,  Johann-Peter Melder ,  Christof Wilhelm Wigbers

    IPC分类号： C07C209/60

    CPC分类号： C07C211/11 ,  C07C209/60 ,  Y02P20/582

    摘要： The present invention relates to a process for preparing N,N-substituted 1,3-propanediamine by a) reacting secondary amine with acrolein at a temperature of from (−50) to 100° C. and a pressure of from 0.01 to 300 bar, and b) reacting the reaction mixture obtained in stage a) with hydrogen and ammonia in the presence of a hydrogenation catalyst at a temperature of from 40 to 400° C. and a pressure of from 1 to 400 bar, wherein the molar ratio of secondary amine to acrolein in stage a) is 2:1 or more and the hydrogenation catalyst used in stage b) comprises cobalt. In a preferred embodiment, acrolein which has been obtained from glycerol based on renewable raw materials is used. The invention further relates to the use of N,N-dimethyl-1,3-propanediamine (DMAPA) based on renewable raw materials as a feedstock for lubricant soaps and other detergents, coagulants, polymers and comb polymers. In a further preferred embodiment, stage b) is performed in the presence of water.

    摘要翻译： 本发明涉及一种通过以下步骤制备N，N-取代的1,3-丙二胺的方法：a）在（-50）至100℃的温度和0.01至300巴的压力下使仲胺与丙烯醛反应 和b）在加氢催化剂存在下，在40〜400℃，压力为1〜400巴下，使a）中获得的反应混合物与氢气和氨反应，其中摩尔比 阶段a）中的仲胺与丙烯醛的比例为2:1或更高，而阶段b）中使用的氢化催化剂包括钴。 在优选的实施方式中，使用从基于可再生原料的甘油获得的丙烯醛。 本发明还涉及基于可再生原料的N，N-二甲基-1,3-丙二胺（DMAPA）作为润滑剂皂和其它洗涤剂，凝结剂，聚合物和梳状聚合物的原料的用途。 在另一优选实施方案中，步骤b）在水的存在下进行。