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163 条记录 (耗时 0.027 秒)

    Method of grafting ethylenically unsaturated carboxylic acid derivatives onto thermoplastic using hydroxylamine esters
    11.
    发明授权
    Method of grafting ethylenically unsaturated carboxylic acid derivatives onto thermoplastic using hydroxylamine esters 有权
    使用羟胺酯将烯属不饱和羧酸衍生物接枝到热塑性塑料上的方法

    公开(公告)号：US06900268B2

    公开(公告)日：2005-05-31

    申请号：US10477364

    申请日：2002-05-07

    申请人： Jochen Fink ,  Michael Roth ,  Rudolf Pfaendner ,  Peter Nesvadba ,  Andreas Kramer

    发明人： Jochen Fink ,  Michael Roth ,  Rudolf Pfaendner ,  Peter Nesvadba ,  Andreas Kramer

    IPC分类号： C08F8/46 ,  C08F8/32 ,  C08F255/00 ,  C08F291/00 ,  C08F2/38 ,  C08K5/32 ,  C08L51/06

    CPC分类号： C08F255/00 ,  C08F291/00 ,  C08F222/06

    摘要： The invention relates to a method of grafting unsaturated carboxylic acid derivatives onto thermoplastic polymers, which comprises heating a mixture of thermoplastic polymer, unsaturated carboxylic acid or carboxylic acid derivative and a hydroxy-lamine ester having at least one structural unit of formula (I) or (I′) wherein X is hydrogen, C1-C36alkyl, C2-C36alkenyl, C2-C18alkynyl, C6-C10aryl, —O—C1-C18alkyl —O—C6-C10aryl, —NH—C1-C18alkyl, —NH—C6-C10aryl, —N(C1-C6alkyl)2; X′ is a direct bond or C1-C36alkylene, C2-C36alkenylene, C2-C36alkynylene, —(C1-C6alkylene)-phenyl-(C1-C6alkylene) or a group in a processing apparatus for thermoplastic polymers, to above the softening point/melting point of the thermoplastic polymer and allowing the components of the mixture to react with one another

    摘要翻译： 本发明涉及将不饱和羧酸衍生物接枝到热塑性聚合物上的方法，其包括加热热塑性聚合物，不饱和羧酸或羧酸衍生物和具有至少一个式（I）结构单元的羟基 - （I'）其中X是氢，C 1 -C 36烷基，C 2 -C 36 - 烯基 C 2 -C 18炔基，C 6 -C 10芳基，-OC 1， C 1 -C 14烷基-C 1 -C 6 -C 10芳基，-NH-C 1 -C 烷基，-NH-C 6 -C 10芳基，-N（C 1 -C 3 - 亚芳基） > 6个烷基）2 1 -C 6亚烷基）或热塑性聚合物的加工装置中的基团，高于热塑性聚合物的软化点/熔点，并允许混合物的组分反应 彼此之间

    Grafting of nitroxyl terminated oligomers or polymers onto thermoplastic polymers
    14.
    发明授权
    Grafting of nitroxyl terminated oligomers or polymers onto thermoplastic polymers 失效
    将硝酰基封端的低聚物或聚合物接枝到热塑性聚合物上

    公开(公告)号：US07632891B2

    公开(公告)日：2009-12-15

    申请号：US10518873

    申请日：2003-06-12

    申请人： Jochen Fink ,  Michael Roth ,  Rudolf Pfaendner

    发明人： Jochen Fink ,  Michael Roth ,  Rudolf Pfaendner

    IPC分类号： C08L53/02 ,  C08L51/02

    CPC分类号： C08F293/005 ,  C08F4/00 ,  C08F8/30 ,  C08F10/00 ,  C08F2438/02 ,  C08G81/021 ,  C08F2/38

    摘要： The instant invention relates to a process for the preparation of grafted polymers wherein in a first step A) a oligomer or polymer is prepared by controlled radical polymerization in the presence of a stable free nitroxyl radical or a nitroxylether to obtain a nitroxyl terminated oligomer or polymer and in a second step B) the nitroxyl terminated oligomer or polymer is mixed and reacted with a thermoplastic or elastomeric polymer or copolymer in its molten state at a temperature at which cleavage of the nitroxyl-polymer/oligomer bond occurs, whereby the nitroxyl terminated oligomer or polymer is grafted onto the thermoplastic or elastomeric polymer. A further subject of the present invention is a grafted polymer prepared by said process.

    摘要翻译： 本发明涉及制备接枝聚合物的方法，其中在第一步骤A）中，通过在稳定的游离硝酰基或硝酰基醚的存在下通过可控自由基聚合制备低聚物或聚合物，以获得硝酰基封端的低聚物或聚合物 并且在第二步骤B）中，将硝酰基封端的低聚物或聚合物与其熔融状态下的热塑性或弹性体聚合物或共聚物在发生硝酰基聚合物/低聚物键断裂的温度下反应，由此将硝酰基封端的低聚物 或聚合物接枝到热塑性或弹性聚合物上。 本发明的另一个主题是通过所述方法制备的接枝聚合物。

    Comb copolymers with defined side chains and process for their manufacture
    15.
    发明授权
    Comb copolymers with defined side chains and process for their manufacture 失效
    具有限定侧链的梳状共聚物及其制造方法

    公开(公告)号：US07528194B2

    公开(公告)日：2009-05-05

    申请号：US10543427

    申请日：2004-02-02

    申请人： Jochen Fink ,  Michael Roth ,  Rudolf Pfaendner

    发明人： Jochen Fink ,  Michael Roth ,  Rudolf Pfaendner

    IPC分类号： C08L51/06 ,  C08F2/38

    CPC分类号： C08F255/023 ,  C08F255/02 ,  C08F257/02 ,  C08F265/00 ,  C08F285/00 ,  C08F287/00 ,  C08F291/00 ,  C08F293/005 ,  Y10T428/2978

    摘要： The present invention relates to the modification of copolymers, in particular of grafted copolymers into comb copolymers. The modification comprises the steps (i) of controlled radical polymerization of a polymer or copolymer bearing a epoxide group at one end resulting from the initiation step, and (ii) a heating step of the polymer prepared under (i) and a copolymer bearing a functional group either in the backbone or attached to a side chain, which is able to react with the epxide group. The result is a comb copolymer with well controlled chain length of the grafted side arms expressed for example by a low polydispersity.

    摘要翻译： 本发明涉及共聚物，特别是将接枝共聚物改性成梳型共聚物。 所述改性包括步骤（i）在起始步骤产生的一端承载环氧基的聚合物或共聚物的受控自由基聚合，和（ii）在（i）下制备的聚合物的加热步骤和带有 官能团在骨架中或附着于侧链，其能够与表面活性剂基团反应。 结果是具有良好控制的链接长度的梳状共聚物，例如通过低多分散性表示的接枝侧臂的链长度。

    Grafting of ethylenically unsaturated monomers onto polymers
    17.
    发明授权
    Grafting of ethylenically unsaturated monomers onto polymers 失效
    将烯属不饱和单体接枝到聚合物上

    公开(公告)号：US06521710B1

    公开(公告)日：2003-02-18

    申请号：US09786183

    申请日：2001-03-01

    申请人： Michael Roth ,  Rudolf Pfaendner ,  Peter Nesvadba

    发明人： Michael Roth ,  Rudolf Pfaendner ,  Peter Nesvadba

    IPC分类号： C08F400

    CPC分类号： C08F285/00 ,  C08F255/00 ,  C08F255/04 ,  C08F255/06 ,  C08F257/02 ,  C08F279/02 ,  C08F287/00 ,  C09J151/003

    摘要： The present invention relates to a process for the preparation of a grafted polymer wherein in a first step A) a stable nitroxyl radical is grafted onto a polymer, which step comprises heating a polymer and a nitroxyl-ether containing a group (=NO-X), wherein X is selected such, that cleavage of the O-X bond occurs and a radical X, is formed at about the melting temperature of the polymer; and in a second step B) the grafted polymer of step A) is heated in the presence of an ethylenically unsaturated monomer or oligomer to a temperature at which cleavage of the nitroxyl-polymer bond occurs and polymerization of the ethylenically unsaturated monomer or oligomer is initiated at the polymer radical; maintaining said temperature for further polymerization and afterwards cooling down the mixture to a temperature below 60° C. Further subjects are grafted thermoplastic polymers prepared by said process, the intermediate polymeric radical initiator, the use of the polymeric radical initiator and the use of NO-ethers for grafting thermoplastic polymers.

    摘要翻译： 本发明涉及一种制备接枝聚合物的方法，其中在第一步骤A）中将稳定的硝酰基接枝到聚合物上，该步骤包括加热聚合物和含有基团的硝酰基醚（= NO-X ），其中选择X，发生OX键的裂解，并且在约聚合物的熔融温度下形成基团X; 并且在第二步骤B）中，将步骤A）的接枝聚合物在烯属不饱和单体或低聚物的存在下加热至发生硝酰基 - 聚合物键断裂的温度，并且引发烯属不饱和单体或低聚物的聚合 在聚合物基团上; 保持所述温度进一步聚合，然后将混合物冷却至低于60℃的温度。其它受试者是通过所述方法制备的接枝热塑性聚合物，中间体聚合自由基引发剂，使用聚合自由基引发剂和使用NO- 用于接枝热塑性聚合物的醚。

    Grafting of nitroxyl terminated oligomers or polymers onto thermoplastic polymers
    20.
    发明申请
    Grafting of nitroxyl terminated oligomers or polymers onto thermoplastic polymers 失效
    将硝酰基封端的低聚物或聚合物接枝到热塑性聚合物上

    公开(公告)号：US20050215720A1

    公开(公告)日：2005-09-29

    申请号：US10518873

    申请日：2003-06-12

    申请人： Jochen Fink ,  Michael Roth ,  Rudolf Pfaendner

    发明人： Jochen Fink ,  Michael Roth ,  Rudolf Pfaendner

    IPC分类号： C08F4/00 ,  C08F8/00 ,  C08F8/30 ,  C08F10/00 ,  C08F293/00 ,  C08G81/02 ,  C08F2/00

    CPC分类号： C08F293/005 ,  C08F4/00 ,  C08F8/30 ,  C08F10/00 ,  C08F2438/02 ,  C08G81/021 ,  C08F2/38

    摘要： The instant invention relates to a process for the preparation of grafted polymers wherein in a first step A) a oligomer or polymer is prepared by controlled radical polymerization in the presence of a stable free nitroxyl radical or a nitroxylether to obtain a nitroxyl terminated oligomer or polymer and in a second step B) the nitroxyl terminated oligomer or polymer is mixed and reacted with a thermoplastic or elastomeric polymer or copolymer in its molten state at a temperature at which cleavage of the nitroxyl-polymer/oligomer bond occurs, whereby the nitroxyl terminated oligomer or polymer is grafted onto the thermoplastic or elastomeric polymer. A further subject of the present invention is a grafted polymer prepared by said process.

    摘要翻译： 本发明涉及一种制备接枝聚合物的方法，其中在第一步骤A）中，通过在稳定的游离硝酰基或硝酰基醚的存在下通过可控自由基聚合制备低聚物或聚合物，得到硝酰基封端的低聚物或聚合物 并且在第二步骤B）中，将硝酰基封端的低聚物或聚合物与其熔融状态下的热塑性或弹性体聚合物或共聚物在发生硝酰基聚合物/低聚物键断裂的温度下反应，由此将硝酰基封端的低聚物 或聚合物接枝到热塑性或弹性聚合物上。 本发明的另一个主题是通过所述方法制备的接枝聚合物。