ALIPHATIC-AROMATIC BIODEGRADABLE POLYESTER
    12.
    发明申请

    公开(公告)号:US20200079899A1

    公开(公告)日:2020-03-12

    申请号:US16682628

    申请日:2019-11-13

    Abstract: Disclosed are aliphatic-aromatic biodegradable polyesters obtained from aliphatic dicarboxylic acids, polyfunctional aromatic acids of renewable origin and particularly 2,5-furan dicarboxylic acid, and diols. Also disclosed are blends of the polyesters with other biodegradable polymers of either natural or synthetic origin. The polyesters have properties and viscosity values that make them suitable, after adjusting their molecular weight, for use in numerous practical applications such as films, injection molded products, extrusion coatings, fibers, foams, thermoformed products, extruded profiles and sheets, extrusion blow molding, injection blow molding, rotomolding, stretch blow molding.

    Process for the production and isolation of 5-hydroxymethylfurfural

    公开(公告)号:US10030001B2

    公开(公告)日:2018-07-24

    申请号:US15518861

    申请日:2015-10-16

    Abstract: The present invention relates to a process for the synthesis of 5-hydroxymethyl furfural (HMF) comprising the steps of: 1) dehydrating at least one saccharide selected from monosaccharides having 6 carbon atoms and disaccharides, oligosaccharides or polysaccharides formed from units having 6 carbon atoms or mixtures thereof in the presence of at least one quaternary ammonium salt R3R′N+X−; in which: —R, which is the same or different, represents a C1-C16 substituted or unsubstituted alkyl group; —R′ belongs to the group consisting of: hydrogen, C1-C16 substituted or unsubstituted alkyl group, monocyclic substituted or unsubstituted aryl group; —X− represents an anion selected from chloride, bromide, iodide, fluoride, hydroxide, BF4− and PF6−; at a temperature of between 80 and 120° C., removing water from the reaction medium (dehydration stage) and obtaining a reaction mixture comprising the quaternary ammonium salt, HMF, any unreacted saccharide and having a water content of less than 30% by weight relative to the weight of the product HMF; 2) separating HMF from the said reaction mixture (separation stage).

    Process for the synthesis of 5-hydroxymethylfurfural from saccharides
    15.
    发明授权
    Process for the synthesis of 5-hydroxymethylfurfural from saccharides 有权
    从糖类合成5-羟甲基糠醛的方法

    公开(公告)号:US09409877B2

    公开(公告)日:2016-08-09

    申请号:US14889526

    申请日:2014-05-09

    CPC classification number: C07D307/46 B01J27/188 B01J35/1019 C07D307/50

    Abstract: This invention relates to a process for the synthesis of 5-hydroxymethylfurfural (HMF) from saccharides. In particular this invention relates to a process for the dehydration of monosaccharides having 6 carbon atoms (hexoses), disaccharides, oligosaccharides, and polysaccharides to yield highly pure 5-hydroxymethylfurfural (HMF) in high yield.

    Abstract translation: 本发明涉及从糖类合成5-羟甲基糠醛(HMF)的方法。 特别是本发明涉及一种使6个碳原子(己糖),二糖,低聚糖和多糖脱水的方法,以高产率得到高纯度的5-羟甲基糠醛(HMF)。

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