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11.发明申请CARBONYLATION PROCESS FOR THE PRODUCTION OF ACETIC ACID USING METAL-PINCER LIGAND CATALYSTS 有权使用金属引线配体催化剂生产乙酸的碳化工艺公开(公告)号：US20100324332A1
公开(公告)日：2010-12-23
申请号：US12451755
申请日：2008-05-23
摘要： A process for the production of acetic acid by the liquid phase carbonylation of an alcohol and/or a reactive derivative thereof in which there is employed a catalyst comprising a complex of rhodium or iridium with a pincer ligand.
摘要翻译： 通过醇和/或其反应性衍生物的液相羰基化制备乙酸的方法，其中使用包含铑或铱的络合物和蒎烯配体的催化剂。
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12.发明授权公开(公告)号：US09212117B2
公开(公告)日：2015-12-15
申请号：US13392551
申请日：2010-08-31
摘要： Process for the production of acetic acid and dimethyl ether by contacting methanol and methyl acetate with a catalyst composition at a temperature in the range 140 to 250 ° C. The catalyst composition contains a zeolite having a 2-dimensional channel system comprising at least one channel which has a 10-membered ring.
摘要翻译： 通过使甲醇和乙酸甲酯与催化剂组合物在140-250℃的温度下接触来生产乙酸和二甲醚的方法。催化剂组合物含有具有二维通道系统的沸石，其包含至少一个通道 其具有10元环。
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13.发明授权Carbonylation process using bound silver and/or copper mordenite catalysts 有权使用结合的银和/或铜丝光沸石催化剂的羰基化方法公开(公告)号：US08471058B2
公开(公告)日：2013-06-25
申请号：US12998845
申请日：2009-11-16
CPC分类号： C07C51/12 , B01J29/22 , B01J29/24 , B01J35/1009 , B01J35/1014 , B01J35/1019 , B01J37/0009 , B01J37/0201 , B01J2229/42 , C07C67/37 , C07C53/08 , C07C69/14
摘要： Process for the carbonylation of a carbonylatable reactant selected from at least one of dimethyl ether and methanol, by carbonylating the carbonylatable reactant with carbon monoxide in the presence of a catalyst to produce a carbonylation product selected from at least one of methyl acetate and acetic acid. The catalyst is formed by compositing a mordenite loaded with at least one of silver and copper, with an inorganic oxide binder.
摘要翻译： 通过在催化剂存在下用一氧化碳羰基化可羰基化的反应物以产生选自乙酸甲酯和乙酸中的至少一种的羰基化产物，羰基化选自二甲醚和甲醇中的至少一种的羰基化反应物的方法。 催化剂通过将负载有银和铜中的至少一种的丝光沸石与无机氧化物粘合剂合并而形成。
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公开(公告)号：US08431732B2
公开(公告)日：2013-04-30
申请号：US12735121
申请日：2008-12-16
IPC分类号： C07C67/36
摘要： Process for the manufacture of methyl acetate by carbonylating a carbonylatable reactant selected from dimethyl ether and dimethyl carbonate containing less than 2.5 wt % water with carbon monoxide in the presence of a mordenite catalyst. The mordenite has been ion-exchanged with at least one Group IB metal, and the molar ratio of the Group IB metal to total aluminum present in the mordenite is in the range 5 to 50 mol %.
摘要翻译： 通过在丝光沸石催化剂存在下羰基化选自含有少于2.5重量％水的二甲醚和碳酸二甲酯的羰基化反应物的方法。 丝光沸石与至少一种IB族金属进行离子交换，并且丝光沸石中存在的IB族金属与总铝的摩尔比为5〜50摩尔％。
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公开(公告)号：US20100317888A1
公开(公告)日：2010-12-16
申请号：US12735123
申请日：2008-12-16
申请人： Evert Jan Ditzel , David John Law , George Ernest Morris , Mark Stephen Roberts , Stephan Andreas Schunk , Martin Smit , John Glenn Sunley
发明人： Evert Jan Ditzel , David John Law , George Ernest Morris , Mark Stephen Roberts , Stephan Andreas Schunk , Martin Smit , John Glenn Sunley
CPC分类号： B01J29/90 , B01J29/20 , B01J38/14 , C07C51/12 , C07C67/37 , Y02P20/584 , C07C53/08 , C07C69/14
摘要： A process for the carbonylation of dimethyl ether, dimethyl carbonate and/or methanol with carbon monoxide and hydrogen in the presence of a mordenite catalyst to produce at least one of acetic acid and methyl acetate in which process the mordenite catalyst is regenerated in-situ by contacting the catalyst with a regenerating gas comprising a molecular oxygen-containing gas and an inert diluent at a total pressure in the range 1 to 100 bar and wherein the partial pressure of the molecular oxygen-containing gas is such that the temperature of the catalyst is maintained within the range 225 to 325° C.
摘要翻译： 一种在丝光沸石催化剂存在下用一氧化碳和氢气二甲醚，二甲基碳酸酯和/或甲醇羰基化的方法，以产生乙酸和乙酸甲酯中的至少一种，其中丝光沸石催化剂原位再生 使催化剂与包含含分子氧的气体和惰性稀释剂的再生气体在1至100巴的总压力下接触，并且其中分子氧气体的分压使得催化剂的温度为 维持在225至325℃的范围内
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公开(公告)号：US20100274045A1
公开(公告)日：2010-10-28
申请号：US12735121
申请日：2008-12-16
IPC分类号： C07C67/00
摘要： A process for the manufacture of methyl acetate by the carbonylation of dimethyl ether or dimethyl carbonate with carbon monoxide under substantially anhydrous conditions in the presence of a Group TB metal loaded mordenite catalyst prepared by ion-exchanging mordenite with at least one Group IB metal, the ion-exchanged mordenite having a molar ratio of the Group IB metal to total aluminium present in the mordenite in the range 5 to 50 mol %.
摘要翻译： 在通过离子交换丝光沸石与至少一种IB族金属制备的组TB金属负载的丝光沸石催化剂的存在下，在基本无水条件下，通过二氧化碳或碳酸二甲酯与一氧化碳羰基化制备乙酸甲酯的方法， 离子交换的丝光沸石具有5-50mol％的丝光沸石中存在的IB族金属与总铝的摩尔比。
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公开(公告)号：US20090182165A1
公开(公告)日：2009-07-16
申请号：US12226150
申请日：2007-03-27
CPC分类号： B01J29/22 , B01J2229/186 , C07C51/12 , C07C53/08
摘要： Process for preparing a carboxylic acid and/or ester thereof by carbonylating an alcohol and/or reactive derivative thereof with carbon monoxide in the presence of a silver loaded mordenite catalyst.
摘要翻译： 通过在银负载的丝光沸石催化剂存在下，用一氧化碳羰基化醇和/或其活性衍生物来制备羧酸和/或酯的方法。
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18.发明授权公开(公告)号：US08450521B2
公开(公告)日：2013-05-28
申请号：US12998684
申请日：2009-10-08
CPC分类号： C07C67/37 , B01J29/18 , B01J35/023 , B01J35/1014 , B01J35/1019 , B01J35/1023 , B01J35/1061 , B01J35/109 , B01J37/0009 , B01J37/08 , B01J2229/42 , C07C51/12 , C07C53/08 , C07C69/14
摘要： Process for preparing methyl acetate and/or acetic acid by contacting a carbonylatable reactant selected from dimethyl ether and methanol with carbon monoxide in the presence of a catalyst. The catalyst is a H-mordenite bound with a mesoporous binder selected from silicas, aluminas, silica-aluminas, magnesium silicates and magnesium aluminum silicates.
摘要翻译： 在催化剂存在下使选自二甲醚和甲醇的羰基化反应物与一氧化碳接触来制备乙酸甲酯和/或乙酸的方法。 催化剂是与选自二氧化硅，氧化铝，二氧化硅 - 氧化铝，硅酸镁和硅酸镁铝的介孔粘合剂结合的H-丝光沸石。
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19.发明申请公开(公告)号：US20120165570A1
公开(公告)日：2012-06-28
申请号：US13392551
申请日：2010-08-31
IPC分类号： C07C53/08
摘要： A process for the production of acetic acid and dimethyl ether by contacting methanol and methyl acetate with a catalyst composition at a temperature in the range 140 to 250° C. wherein the catalyst composition contains a zeolite having a 2-dimensional channel system comprising at least one channel which has a 10-membered ring.
摘要翻译： 通过使甲醇和乙酸甲酯与催化剂组合物在140-250℃的温度下接触来生产乙酸和二甲醚的方法，其中催化剂组合物含有具有至少包含至少二维通道系统的二维通道系统的沸石 一个具有10元环的通道。
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公开(公告)号：US20120078005A1
公开(公告)日：2012-03-29
申请号：US13138991
申请日：2010-05-06
CPC分类号： C07C51/12 , B01J29/18 , B01J2229/16 , B01J2229/36 , B01J2229/38 , C07C67/37 , C07C57/08 , C07C69/14
摘要： A process for the production of acetic acid and/or methyl acetate by the carbonylation of methanol, methyl acetate and/or dimethyl ether with carbon monoxide in the presence of a desilicated mordenite catalyst.
摘要翻译： 在脱盐丝光沸石催化剂存在下，通过甲醇，乙酸甲酯和/或二甲醚与一氧化碳羰基化生产乙酸和/或乙酸甲酯的方法。
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