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公开(公告)号：US20100317888A1
公开(公告)日：2010-12-16
申请号：US12735123
申请日：2008-12-16
申请人： Evert Jan Ditzel , David John Law , George Ernest Morris , Mark Stephen Roberts , Stephan Andreas Schunk , Martin Smit , John Glenn Sunley
发明人： Evert Jan Ditzel , David John Law , George Ernest Morris , Mark Stephen Roberts , Stephan Andreas Schunk , Martin Smit , John Glenn Sunley
CPC分类号： B01J29/90 , B01J29/20 , B01J38/14 , C07C51/12 , C07C67/37 , Y02P20/584 , C07C53/08 , C07C69/14
摘要： A process for the carbonylation of dimethyl ether, dimethyl carbonate and/or methanol with carbon monoxide and hydrogen in the presence of a mordenite catalyst to produce at least one of acetic acid and methyl acetate in which process the mordenite catalyst is regenerated in-situ by contacting the catalyst with a regenerating gas comprising a molecular oxygen-containing gas and an inert diluent at a total pressure in the range 1 to 100 bar and wherein the partial pressure of the molecular oxygen-containing gas is such that the temperature of the catalyst is maintained within the range 225 to 325° C.
摘要翻译： 一种在丝光沸石催化剂存在下用一氧化碳和氢气二甲醚，二甲基碳酸酯和/或甲醇羰基化的方法，以产生乙酸和乙酸甲酯中的至少一种，其中丝光沸石催化剂原位再生 使催化剂与包含含分子氧的气体和惰性稀释剂的再生气体在1至100巴的总压力下接触，并且其中分子氧气体的分压使得催化剂的温度为 维持在225至325℃的范围内
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公开(公告)号：US08158815B2
公开(公告)日：2012-04-17
申请号：US12735123
申请日：2008-12-16
申请人： Evert Jan Ditzel , David John Law , George Ernest Morris , Mark Stephen Roberts , Stephan Andreas Schunk , Martin Smit , John Glenn Sunley
发明人： Evert Jan Ditzel , David John Law , George Ernest Morris , Mark Stephen Roberts , Stephan Andreas Schunk , Martin Smit , John Glenn Sunley
CPC分类号： B01J29/90 , B01J29/20 , B01J38/14 , C07C51/12 , C07C67/37 , Y02P20/584 , C07C53/08 , C07C69/14
摘要： A process for the carbonylation of dimethyl ether, dimethyl carbonate and/or methanol with carbon monoxide and hydrogen in the presence of a mordenite catalyst to produce at least one of acetic acid and methyl acetate in which process the mordenite catalyst is regenerated in-situ by contacting the catalyst with a regenerating gas comprising a molecular oxygen-containing gas and an inert diluent at a total pressure in the range 1 to 100 bar and wherein the partial pressure of the molecular oxygen-containing gas is such that the temperature of the catalyst is maintained within the range 225 to 325° C.
摘要翻译： 一种在丝光沸石催化剂存在下用一氧化碳和氢气二甲醚，二甲基碳酸酯和/或甲醇羰基化的方法，以产生乙酸和乙酸甲酯中的至少一种，其中丝光沸石催化剂原位再生 使催化剂与包含含分子氧的气体和惰性稀释剂的再生气体在1至100巴的总压下接触，并且其中分子氧气体的分压使得催化剂的温度为 维持在225至325℃的范围内
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公开(公告)号：US08329606B2
公开(公告)日：2012-12-11
申请号：US12735122
申请日：2008-12-16
申请人： Edo Johann Becker , Evert Jan Ditzel , Harry Kaiser , George Ernest Morris , Mark Stephen Roberts , Stephan Andreas Schunk , Martin Smit , John Glenn Sunley
发明人： Edo Johann Becker , Evert Jan Ditzel , Harry Kaiser , George Ernest Morris , Mark Stephen Roberts , Stephan Andreas Schunk , Martin Smit , John Glenn Sunley
CPC分类号： B01J29/06 , B01J29/20 , B01J29/50 , B01J29/65 , B01J29/86 , B01J29/87 , B01J29/88 , B01J29/90 , C07C51/12 , C07C67/37 , Y02P20/584 , C07C53/08 , C07C69/14
摘要： Process for the in-situ regeneration of a zeolite catalyst in a carbonylation process for the production of at least one of methyl acetate and acetic acid. The process is carried out by (a) contacting a carbonylatable reactant selected from methanol, dimethyl ether and dimethyl carbonate and carbon monoxide in a reactor with a zeolite catalyst and recovering a product stream containing at least one of methyl acetate and acetic acid from the reactor, (b) ceasing contact of the catalyst with the carbonylatable reactant, (c) regenerating the catalyst with a regenerating gas selected from hydrogen or a mixture of hydrogen and carbon monoxide at a temperature in the range 250 to 600 C, and (d) terminating the hydrogen regenerating step and resuming contact of the catalyst with the carbonylatable reactant and carbon monoxide.
摘要翻译： 用于在羰基化方法中原位再生沸石催化剂以生产乙酸甲酯和乙酸中的至少一种的方法。 该方法通过以下步骤进行：（a）在反应器中使沸石催化剂使选自甲醇，二甲醚和碳酸二甲酯的羰基化反应物与一氧化碳接触，并从反应器中回收含有至少一种乙酸甲酯和乙酸的产物流 （b）停止催化剂与可羰基化反应物的接触，（c）在选自氢气或氢气和一氧化碳的混合物中的再生气体在250至600℃的温度范围内再生催化剂，和（d） 终止氢再生步骤并恢复催化剂与可羰基化反应物和一氧化碳的接触。
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公开(公告)号：US07741512B2
公开(公告)日：2010-06-22
申请号：US12226150
申请日：2007-03-27
CPC分类号： B01J29/22 , B01J2229/186 , C07C51/12 , C07C53/08
摘要： Process for preparing an aliphatic carboxylic acid having (n+1) carbon atoms, where n is an integer up to 6, and/or the ester derivative thereof by contacting an aliphatic alcohol having n carbon atoms and/or a reactive derivative thereof selected from dialkyl ether, ester of the alcohol and an alkyl halide with carbon monoxide in the presence of a catalyst. The catalyst consists of mordenite which has been ion- exchanged or otherwise loaded with silver.
摘要翻译： 具有（n + 1）（n + 1）个碳原子的脂肪族羧酸，其中n为6以下的整数的方法，和/或其具有n个碳原子的脂族醇和/或其反应性衍生物的酯衍生物选自 二烷基醚，醇的酯和烷基卤与一氧化碳在催化剂存在下反应。 催化剂由离子交换或以其他方式负载银的丝光沸石组成。
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公开(公告)号：US20090182165A1
公开(公告)日：2009-07-16
申请号：US12226150
申请日：2007-03-27
CPC分类号： B01J29/22 , B01J2229/186 , C07C51/12 , C07C53/08
摘要： Process for preparing a carboxylic acid and/or ester thereof by carbonylating an alcohol and/or reactive derivative thereof with carbon monoxide in the presence of a silver loaded mordenite catalyst.
摘要翻译： 通过在银负载的丝光沸石催化剂存在下，用一氧化碳羰基化醇和/或其活性衍生物来制备羧酸和/或酯的方法。
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公开(公告)号：US20130172177A1
公开(公告)日：2013-07-04
申请号：US13824113
申请日：2011-09-13
申请人： Imme Domke , Wolfgang Rohde , Piotr Antoni Bazula , Norbert Mronga , Yong Liu , Martin Dieterle , Stanley Roth , Curtis Zimmermann , Xinyi Wei , Philipp Raff , Stephan Andreas Schunk , Olga Gerlach , Andreas Strasser , Michael Paul
发明人： Imme Domke , Wolfgang Rohde , Piotr Antoni Bazula , Norbert Mronga , Yong Liu , Martin Dieterle , Stanley Roth , Curtis Zimmermann , Xinyi Wei , Philipp Raff , Stephan Andreas Schunk , Olga Gerlach , Andreas Strasser , Michael Paul
IPC分类号： B01J23/42
CPC分类号： B01J23/42 , B01D53/945 , B01D2255/1021 , B01D2255/1023 , B01D2255/1025 , B01D2255/1026 , B01D2255/104 , B01D2255/2065 , B01D2255/20707 , B01D2255/20715 , B01D2255/20723 , B01D2255/2073 , B01D2255/20738 , B01D2255/20746 , B01D2255/20753 , B01D2255/20761 , B01D2255/20769 , B01D2255/20784 , B01D2255/20792 , B01D2255/9202 , B01D2255/9205 , B01D2255/9207 , B01D2258/012 , B01J21/04 , B01J21/08 , B01J35/0013 , B01J35/0086 , B01J35/08 , B01J35/1014 , B01J35/1019 , B01J37/0072 , B01J37/0203 , B01J37/0205 , B01J37/0211 , B01J37/036 , B01J37/088 , B01J37/16 , Y02T10/22
摘要： A catalyst comprising (i) a support, (ii) metal particles and (iii) a shell which is arranged between the metal particles, wherein the shell (iii) comprises silicon oxide.
摘要翻译： 一种催化剂，其包含（i）载体，（ii）金属颗粒和（iii）布置在金属颗粒之间的壳，其中壳（iii）包含氧化硅。
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公开(公告)号：US07202088B2
公开(公告)日：2007-04-10
申请号：US10333850
申请日：2001-07-27
申请人： Alfred Haas , Stephan Andreas Schunk , Dirk Demuth , Wolfgang Strehlau , Armin Brenner , Wolfram Stichert
发明人： Alfred Haas , Stephan Andreas Schunk , Dirk Demuth , Wolfgang Strehlau , Armin Brenner , Wolfram Stichert
IPC分类号： G01N31/10
CPC分类号： B01J19/0093 , B01J19/0046 , B01J2219/00313 , B01J2219/00319 , B01J2219/00351 , B01J2219/00495 , B01J2219/00585 , B01J2219/0068 , B01J2219/00698 , B01J2219/00704 , B01J2219/00747 , B01J2219/0081 , B01J2219/00835 , B01J2219/00871 , B01J2219/00873 , B01L7/00
摘要： The present invention relates to an arrangement, in particular for the parallel testing of a plurality of building blocks of a material library for performance characteristics, in which the arrangement has a block containing at least one reaction module and at least two heating/cooling modules.
摘要翻译： 本发明涉及一种布置，特别是用于并行测试用于性能特征的材料库的多个结构单元，其中该装置具有包含至少一个反应模块和至少两个加热/冷却模块的块。
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8.发明授权公开(公告)号：US06873414B2
公开(公告)日：2005-03-29
申请号：US09773534
申请日：2001-02-02
CPC分类号： G01N21/1702 , B01J19/0046 , B01J2219/00286 , B01J2219/00306 , B01J2219/00313 , B01J2219/00585 , B01J2219/00596 , B01J2219/00659 , B01J2219/00698 , B01J2219/00704 , B01J2219/00745 , B01J2219/00747 , C40B30/08 , C40B40/18
摘要： Method for determining useful properties of individual building blocks of a material library including a substrate having at least two individual building blocks in at least two sections separated from one another, which method includes: (ii) introducing at least one starting material into at least two sections of a substrate of a material library which are separated from one another, in order to carry out a chemical or physical or chemical and physical reaction of the starting material in the at least two substrate sections separated from another, in each case in the presence of the corresponding building block, obtaining in each case an effluent comprising at least one reaction product and/or starting material and, (iii) analysing the effluent obtained in the reaction according to (ii) comprising at least one reaction product and/or starting material; the effluent being analysed by recording and analysing at least one photoacoustic signal.
摘要翻译： 用于确定材料库的各个构件的有用特性的方法，该材料库包括在彼此分开的至少两个部分中具有至少两个单个结构单元的基底，所述方法包括：（ii）将至少一种起始材料引入至少两个 在彼此分离的材料库的基底的部分，以便在存在的情况下在每种情况下进行与另一个分开的至少两个基底部分中的起始材料的化学或物理或化学和物理反应 在每种情况下获得包含至少一种反应产物和/或起始材料的流出物，和（iii）分析根据（ii）在反应中获得的流出物，其包含至少一种反应产物和/或起始 材料; 通过记录和分析至少一个光声信号来分析流出物。
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9.发明授权Catalytic hydrogenation over rhenium-containing catalysts supported on activated carbon 失效通过负载在活性炭上的含铼催化剂进行催化氢化公开(公告)号：US07172989B2
公开(公告)日：2007-02-06
申请号：US11104408
申请日：2005-04-13
申请人： Rolf-Hartmuth Fischer , Rolf Pinkos , Stephan Andreas Schunk , Joachim Wulff-Döring , Frank Stein , Thomas Nöbel , Sylvia Huber
发明人： Rolf-Hartmuth Fischer , Rolf Pinkos , Stephan Andreas Schunk , Joachim Wulff-Döring , Frank Stein , Thomas Nöbel , Sylvia Huber
CPC分类号： C07C29/177 , B01J21/18 , B01J23/6567 , B01J23/8986 , C07C2601/20 , C07C31/207 , C07C31/20 , C07C31/133
摘要： In a process for preparing alcohols by catalytic hydrogenation of carbonyl compounds over a catalyst comprising rhenium on activated carbon, the catalyst used comprises rhenium (calculated as metal) in a weight ratio to the activated carbon of from 0.0001 to 0.5, platinum (calculated as metal) in a weight ratio to the activated carbon of from 0.0001 to 0.5 and, if appropriate, at least one further metal selected from among Zn, Cu, Ag, Au, Ni, Fe, Ru, Mn, Cr, Mo, W and V in a weight ratio to the activated carbon of from 0 to 0.25, and the activated carbon has been nonoxidatively pretreated. It is also possible to prepare ethers and lactones if the hydrogen pressure is not more than 25 bar. In this case, the activated carbon in the catalyst may also have been nonoxidatively pretreated.
摘要翻译： 在通过羰基化合物催化氢化羰基化合物的方法中，所用的催化剂包括铼在活性炭上的催化剂，所用的催化剂包括铼（以金属计）与活性炭的重量比为0.0001至0.5，铂（以金属计算 ），活性炭的重量比为0.0001〜0.5，如果合适，选自Zn，Cu，Ag，Au，Ni，Fe，Ru，Mn，Cr，Mo，W和V中的至少一种以上的金属 活性炭的重量比为0至0.25，并且活性炭已经被非氧化预处理。 如果氢气压力不超过25巴，也可制备醚和内酯。 在这种情况下，催化剂中的活性炭也可以被非氧化预处理。
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10.发明授权Process and apparatus for the combinatorial production and testing of catalyst material libraries by using at least two analytical methods 失效通过使用至少两种分析方法组合生产和测试催化剂材料库的方法和设备公开(公告)号：US07374942B2
公开(公告)日：2008-05-20
申请号：US09809423
申请日：2001-03-16
申请人： Jens Klein , Wolfram Stichert , Wolfgang Strehlau , Armin Brenner , Stephan Andreas Schunk , Dirk Demuth
发明人： Jens Klein , Wolfram Stichert , Wolfgang Strehlau , Armin Brenner , Stephan Andreas Schunk , Dirk Demuth
CPC分类号： G01N31/10 , B01J19/0046 , B01J2219/00286 , B01J2219/00313 , B01J2219/00495 , B01J2219/00585 , B01J2219/00596 , B01J2219/00689 , B01J2219/00704 , B01J2219/00745 , B01J2219/00747 , C40B30/08 , C40B40/18 , Y10T436/21 , Y10T436/212 , Y10T436/214 , Y10T436/216 , Y10T436/24 , Y10T436/25875
摘要： A process and apparatus for testing material libraries, in particular catalysts, by means of coupled use of at least two analytical methods, preferably IR thermography and mass spectrometry. Owing to the selected arrangement, the disadvantages of the two previously known individual methods are compensated for: the subsequent selectivity determination for selected sections by means of mass spectrometry invalidates the argument against IR thermography, of only being able to determine activities; the rapid integrated determination of potentially “good” materials via IR thermography prevents an excessive loss of time by needing to test all materials of a library successively with the mass spectrometer. The reactor design permits, firstly, the integral recording of the entire reactor through a window which is transparent for the corresponding method and, secondly, permits the simultaneous, automated application of a second analytical method (for example mass spectrometry) to selected materials of a material library, which have been rated as active by the optical method. In the case described, the optical method provides information on the material activity for a set problem, and the second analytical method determines the selectivity of the materials.
摘要翻译： 用于通过耦合使用至少两种分析方法，优选IR热成像和质谱法来测试材料库，特别是催化剂的方法和装置。 由于所选择的布置，以前已知的两种方法的缺点得到补偿：通过质谱法对所选部分的随后的选择性测定使得仅针对红外热像仪的论证无效地确定活动; 通过红外热像仪快速综合测定潜在的“良好”材料，可以通过质谱连续测试所有材料，从而防止过多的时间损失。 反应器设计首先通过对于相应方法是透明的窗口整体记录整个反应器，其次允许将第二种分析方法（例如质谱法）同时自动应用于所选择的材料 材料库，通过光学方法被评为有效。 在所描述的情况下，光学方法提供关于集合问题的材料活性的信息，第二分析方法确定材料的选择性。
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