公开(公告)号：US20050159560A1

公开(公告)日：2005-07-21

申请号：US10761643

申请日：2004-01-21

申请人： Karsten Danielmeier ,  Charles Gambino ,  Rolf Gertzmann ,  Richard Roesler ,  Terrell Wayt ,  Michele Vargo ,  Edward Squiller ,  Karen Henderson

发明人： Karsten Danielmeier ,  Charles Gambino ,  Rolf Gertzmann ,  Richard Roesler ,  Terrell Wayt ,  Michele Vargo ,  Edward Squiller ,  Karen Henderson

IPC分类号： C07D207/40 ,  C07D207/416 ,  C08G18/00 ,  C08G18/38 ,  C08G18/79 ,  C09D175/04 ,  C08G63/02 ,  C08G69/26

CPC分类号： C07D207/416 ,  C08G18/3821 ,  C08G18/792 ,  C09D175/04

摘要： The present invention relates to novel aspartates, their method of production and the use of these aspartates as reactive components for polyisocyanates in two-component polyurethane coating compositions and for preparing polyurethane prepolymers. The aspartates are prepared by first reacting a di- or polyamine with an unsaturated ester and then reacting the resultant product with a maleimide.

摘要翻译： 本发明涉及新型天冬氨酸盐，其制备方法和这些天冬氨酸盐作为双组分聚氨酯涂料组合物中多异氰酸酯的反应性组分和用于制备聚氨酯预聚物的用途。 天冬氨酸酯通过首先使二胺或多胺与不饱和酯反应，然后使所得产物与马来酰亚胺反应来制备。

公开(公告)号：US20050075476A1

公开(公告)日：2005-04-07

申请号：US10678491

申请日：2003-10-03

申请人： Richard Roesler ,  Douglas Wicks ,  Terrell Wayt ,  Brian Long ,  Karsten Danielmeier ,  Charles Gambino

发明人： Richard Roesler ,  Douglas Wicks ,  Terrell Wayt ,  Brian Long ,  Karsten Danielmeier ,  Charles Gambino

IPC分类号： C07C233/00 ,  C07C235/10 ,  C07C269/04 ,  C07C271/00 ,  C07C271/20 ,  C07C271/24 ,  C08G18/38 ,  C08G18/79 ,  C08G69/02 ,  C09D175/02 ,  C08G18/00 ,  C08G2/00

CPC分类号： C07C235/10 ,  C07C271/20 ,  C07C271/24 ,  C07C2601/14 ,  C08G18/3821 ,  C08G18/792 ,  C09D175/02

摘要： The present invention relates to novel aspartates, their method of produciotn and the use of these mono and polyaspartates as reactive components for polyisocyanates in two-component polyurethane coating compositions and for preparing polyurethane prepolymers.

公开(公告)号：US20060122338A1

公开(公告)日：2006-06-08

申请号：US10539226

申请日：2003-12-05

申请人： Richard Roesler ,  Derek Crawford

发明人： Richard Roesler ,  Derek Crawford

IPC分类号： C08L75/08 ,  C08L83/00 ,  B32B27/40

CPC分类号： C09J175/04 ,  B32B27/40 ,  C08G18/12 ,  C08G18/283 ,  C08G18/3893 ,  C08G18/4866 ,  C08G2190/00 ,  C09D175/04 ,  C08G18/289

摘要： The present invention relates to moisture-curable, polyether urethanes having terminal cyclic urea/reactive silane groups and containing a) 20 to 100% by weight, based on the weight of a) and b), of a polyether urethane containing two or more terminal cyclic urea/reactive silane groups and one or more polyether segments, wherein the polyether segments have a number average molecular weight of at least 3000 and a degree of unsaturation of less than 0.04 milliequivalents/g, provided that the sum of the number average molecular weights of all of the polyether segments per molecule averages 6000 to 20,000, and wherein the terminal cyclic urea/reactive silane groups are incorporated as the reaction product of an isocyanate group with an aspartate silane to form a urea group which is converted to a cyclic urea group in the presence of a catalyst and heat, and b) 0 to 80% by weight, based on the weight of a) and b), of a polyether urethane containing one reactive silane group and one or more polyether segments having a number average molecular weight of 1000 to 15,000. The present invention also relates to sealant, adhesive and coating compositions containing these polyether urethanes.

摘要翻译： 本发明涉及具有末端环状脲/反应性硅烷基团并且含有a）基于a）和b）重量的20至100重量％的含有两个或更多个末端的聚醚聚氨酯的可湿气固化的聚醚氨酯 环状脲/反应性硅烷基团和一个或多个聚醚链段，其中聚醚链段的数均分子量至少为3000，不饱和度小于0.04毫当量/克，条件是数均分子量 的每个分子的所有聚醚链段平均为6000至20,000，并且其中末端环脲/反应性硅烷基团作为异氰酸酯基团与天冬氨酸硅烷的反应产物引入以形成转化为环状脲基团的脲基 在催化剂和热的存在下，和b）基于a）和b）的重量，0至80重量％的含有一个反应性硅烷基团和一个或多个 数均分子量为1000〜15000的聚醚链段。 本发明还涉及含有这些聚醚氨酯的密封剂，粘合剂和涂料组合物。

公开(公告)号：US20060052568A1

公开(公告)日：2006-03-09

申请号：US10539218

申请日：2003-12-05

申请人： Richard Roesler ,  Derek Crawford

发明人： Richard Roesler ,  Derek Crawford

IPC分类号： C08G77/452 ,  C08G77/46

CPC分类号： C09J175/04 ,  C08G18/12 ,  C08G18/283 ,  C08G18/4866 ,  C08G77/38 ,  C08G2190/00 ,  C08L83/06 ,  C09D175/04 ,  C08G18/289 ,  C08L83/00

摘要： A process for preparing a moisture-curable, polyether urethane containing terminal cyclic urea/reactive silane groups by reacting at an NCO:OH equivalent ratio of 1.5:1 to 2.5:1 a) a hydroxyl component containing i) a polyether containing two hydroxyl groups and one or more polyether segments, wherein the polyether segments have a number average molecular weight of at least 3000 and a degree of unsaturation of less than 0.04 milliequivalents/g, and ii) a polyether containing one hydroxyl group and one or more polyether segments having a number average molecular weight of 1000 to 15,000, with b) an isocyanate component containing i) a compound containing two isocyanate groups, and ii) a compound containing one isocyanate group, and subsequently reacting this reaction product at an equivalent ratio of isocyanate groups to isocyanate-reactive groups of 0.8:1 to 1.1:1 with c) a compound containing an aspartate group and a reactive silane group to form an intermediate polyether urethane containing terminal non-cyclic urea/reactive silane groups and converting the non-cyclic urea groups to cyclic urea groups by reacting the intermediate polyether urethane.

摘要翻译： 通过以1.5：1至2.5：1的NCO:OH当量比反应制备具有末端环状脲/反应性硅烷基团的可湿气固化的聚醚型氨基甲酸酯的方法a）含有i）含有两个羟基的聚醚的羟基组分 和一个或多个聚醚链段，其中聚醚链段的数均分子量至少为3000，不饱和度小于0.04毫当量/ g，和ii）含有一个羟基的聚醚和一个或多个聚醚链段， 数均分子量为1000至15,000，其中b）异氰酸酯组分，其含有i）含有两个异氰酸酯基团的化合物，和ii）含有一个异氰酸酯基团的化合物，随后使该反应产物以异氰酸酯基团的当量比与 异氰酸酯反应性基团为0.8:1至1.1:1，c）含有天冬氨酸基团和反应性硅烷基团的化合物以形成中间体聚醚聚氨酯树脂 通过使中间聚醚聚氨酯反应，将末端非环状尿素/反应性硅烷基团转化为环状脲基团，形成环状脲基。

公开(公告)号：US20050137323A1

公开(公告)日：2005-06-23

申请号：US10741871

申请日：2003-12-19

申请人： Richard Roesler ,  Derek Crawford

发明人： Richard Roesler ,  Derek Crawford

IPC分类号： B32B27/00 ,  C08G18/28 ,  C08G18/38 ,  C08G18/80 ,  C08K3/00 ,  C08L75/04 ,  C09J5/06

CPC分类号： C08G18/3893 ,  C08G18/283 ,  C08G18/8064 ,  C08G18/809 ,  C08G2190/00 ,  C08L75/04 ,  C09J5/06 ,  C09J2475/00 ,  Y10T428/31551 ,  Y10T428/31591

摘要： A curable, alkoxysilane-functional polyether urethane composition formed by combining a) a first silane terminated polyurethane prepared by reacting i) a mono-functional compounds with ii) an isocyanate component containing two isocyanate groups, the reaction product reacted with iii) a compound containing an isocyanate-reactive group and one or more reactive silane groups to form a moisture-curable, alkoxysilane-functional polyether urethane; and b) a second silane terminated polyurethane prepared by reacting i) an alkyl monofunctional alcohol, amine, and/or thiol, with ii) an isocyanate component containing two isocyanate groups, the reaction product reacted with iii) a compound containing an isocyanate-reactive group and one more reactive silane groups. The urethane composition can be used in coating, sealant and/or adhesive compositions. The coating compositions are used to form a coated substrate. The sealant and/or adhesive compositions are used in a method of joining a first adherend and a second adherend to form a bonded assembly.

摘要翻译： 通过组合a）通过使i）单官能化合物与ii）含有两个异氰酸酯基团的异氰酸酯组分反应制备的第一种硅烷封端的聚氨酯形成的可固化的烷氧基硅烷官能的聚氨酯组合物，所述反应产物与iii）含有 异氰酸酯反应性基团和一个或多个反应性硅烷基团以形成可湿气固化的烷氧基硅烷官能的聚醚聚氨酯; 和b）通过使i）烷基单官能醇，胺和/或硫醇与ii）含有两个异氰酸酯基团的异氰酸酯组分反应制备的第二个硅烷封端的聚氨酯，所述反应产物与iii）含有异氰酸酯反应性的化合物 基团和一个以上反应性硅烷基团。 聚氨酯组合物可用于涂料，密封剂和/或粘合剂组合物中。 涂料组合物用于形成涂布的基材。 密封剂和/或粘合剂组合物用于接合第一被粘物和第二被粘物以形成接合组件的方法。

公开(公告)号：US20070142610A1

公开(公告)日：2007-06-21

申请号：US11300957

申请日：2005-12-15

申请人： Stephen Harasin ,  Richard Roesler ,  Rick Starcher ,  Carol Kinney ,  James Garrett

发明人： Stephen Harasin ,  Richard Roesler ,  Rick Starcher ,  Carol Kinney ,  James Garrett

IPC分类号： C08G18/77

CPC分类号： C08G18/7837 ,  C08G18/10 ,  C08G18/1858 ,  C08G18/2063 ,  C08G18/4866 ,  C08G18/6674

摘要： This invention relates to polyurethane elastomers and to a process for their production. These elastomers comprise the reaction product of a polyisocyanate component comprising an allophanate modified (cyclo)aliphatic polyisocyanate which has an NCO group content of about 15 to about 35% or a prepolymer thereof, with an isocyanate-reactive component comprising a low unsaturation polyether polyols, a low molecular weight organic compound containing two hydroxyl groups and which is free of amine groups, and, optionally, one or more organic compounds having a molecular weight of about 200 to about 500, a hydroxyl functionality of 3 to 4 and comprising an amine-initiated polyether polyol.

摘要翻译： 本发明涉及聚氨酯弹性体及其生产方法。 这些弹性体包括包含NCO基团含量为约15至约35％的脲基甲酸酯改性（环）脂族多异氰酸酯或其预聚物的多异氰酸酯组分与包含低不饱和聚醚多元醇的异氰酸酯反应性组分的多异氰酸酯组分的反应产物， 含有两个羟基并且不含胺基的低分子量有机化合物，以及任选的一种或多种分子量为约200至约500，羟基官能度为3至4的有机化合物， 引发的聚醚多元醇。

公开(公告)号：US20060223969A1

公开(公告)日：2006-10-05

申请号：US11096590

申请日：2005-03-31

申请人： Richard Roesler ,  Carol Kinney ,  Aaron Lockhart ,  James Garrett

发明人： Richard Roesler ,  Carol Kinney ,  Aaron Lockhart ,  James Garrett

IPC分类号： C08G18/00

CPC分类号： C08G18/61 ,  C08G18/289 ,  C08G18/73 ,  C08G18/755 ,  C08G18/7831 ,  C08G18/7837 ,  C08G18/792 ,  C08G18/797 ,  C08G18/798 ,  C09D175/04

摘要： The present invention is directed to a polyisocyanate mixture i) having an NCO content of 5 to 35% by weight and a monomeric diisocyanate content of less than 3% by weight, and prepared from a polyisocyanate adduct, ii) containing allophanate groups in an amount such that there are more equivalents of allophanate groups than urethane groups and such that the polyisocyanate mixture remains stable and homogeneous in storage for 1 month at 25° C. and iii) containing siloxane groups (calculated as SiO, MW 44) in an amount of 0.002 to 50% by weight, wherein the preceding percentages are based on the solids content of the polyisocyanate mixture and wherein the siloxane groups are incorporated by reacting an isocyanate group with a compound containing one or more hydroxyl groups directly attached to a carbon atom and one or more siloxane groups. The present invention is also directed to a process for the production of this polyisocyanate mixture and to its use, optionally in blocked form, as an isocyanate component in one- or two-component coating compositions.

摘要翻译： 本发明涉及NCO含量为5〜35重量％，单体二异氰酸酯含量小于3重量％，由多异氰酸酯加合物制备的多异氰酸酯混合物i），ii）含有量的脲基甲酸酯基 使得比氨基甲酸酯基团具有更多当量的脲基甲酸酯基团，并且使得多异氰酸酯混合物在25℃下保存稳定和均匀储存1个月，和iii）含有硅氧烷基团（以SiO，MW 44计） 0.002至50重量％，其中前述百分比基于多异氰酸酯混合物的固体含量，并且其中硅氧烷基团通过使异氰酸酯基团与含有一个或多个直接连接到碳原子上的羟基的化合物反应而引入，一个 或更多的硅氧烷基团。 本发明还涉及在单组分或双组分涂料组合物中制备该多异氰酸酯混合物及其用途，任选为封闭形式的异氰酸酯组分的方法。

公开(公告)号：US20050277732A1

公开(公告)日：2005-12-15

申请号：US10867146

申请日：2004-06-14

申请人： Poli Yu ,  Richard Roesler ,  Kei-Yi Wei ,  Sylvie Horgan

发明人： Poli Yu ,  Richard Roesler ,  Kei-Yi Wei ,  Sylvie Horgan

IPC分类号： C08G18/42 ,  C09D175/04 ,  C08K3/00

CPC分类号： C08G18/4263 ,  C09D175/04

摘要： A two-component coating composition that includes (A) a first component containing an acid functional aliphatic polyester polyol having an acid number of at least 20 mg KOH/g and a hydroxyl number of from 50 to 500 mg KOH/g, and (B) a second component comprising one or more polyisocyanates. The composition can be used to coat metal substrates by (i) mixing components (A) and (B) in the above-described composition to form a mixture; and (ii) applying the mixture to a surface of a metal substrate.

摘要翻译： 一种双组分涂料组合物，其包含（A）含有酸值为至少20mg KOH / g，羟值为50-500mg KOH / g的酸官能脂族聚酯多元醇的第一组分和（B ）包含一种或多种多异氰酸酯的第二组分。 组合物可以通过（i）在上述组合物中混合组分（A）和（B））来涂覆金属基材以形成混合物; 和（ii）将混合物施加到金属基材的表面。

公开(公告)号：US06306811B1

公开(公告)日：2001-10-23

申请号：US09142941

申请日：1999-03-30

申请人： Alun P. James ,  Graham R. Horne ,  Richard Roesler ,  Soraya Parvaneh ,  Romano Pardini ,  Pier-Luigi Deli

发明人： Alun P. James ,  Graham R. Horne ,  Richard Roesler ,  Soraya Parvaneh ,  Romano Pardini ,  Pier-Luigi Deli

IPC分类号： C11D300

CPC分类号： C11D3/128 ,  C01B15/103 ,  C11D3/3942

摘要： Sodium percarbonate exhibits a tendency to decompose in built compositions and particularly detergent compositions built with zeolites. The tendency can be ameliorated by selecting sodium percarbonate which intrinsically has a mean particle size of from 500 to 1000 microns and not more than 20% by weight of below 350 microns and has a moisture pick-up when measured in a test at 80% relative humidity and 32° C. after 24 hours of not greater than 30 g/1000 g sample. A suitable sodium percarbonate can be made most conveniently by crystallisation from a bulk saturated solution of sodium percarbonate in a crystalliser/classifier that does not employ a conventional chloride salting-out agent.

摘要翻译： 过碳酸钠表现出在内置组合物中分解的倾向，特别是用沸石构成的洗涤剂组合物。 通过选择过碳酸钠，其本质上具有500至1000微米且不大于20重量％低于350微米的平均粒度可以改善倾向，并且在80％相对的测试中测量时具有吸湿性 湿度为32℃，24小时后不大于30g / 1000g样品。 通过在不使用常规氯化物盐析剂的结晶器/分选机中从过饱碳酸钠的大量饱和溶液中结晶，可以最方便地制备合适的过碳酸钠。

公开(公告)号：US5290476A

公开(公告)日：1994-03-01

申请号：US709307

申请日：1991-06-03

申请人： Richard Roesler ,  Werner Doetsch ,  Werner Zeiss ,  Rudolf Siegel

发明人： Richard Roesler ,  Werner Doetsch ,  Werner Zeiss ,  Rudolf Siegel

IPC分类号： C01B15/12 ,  C11D3/39

CPC分类号： C01B15/12

摘要： A process for preparing microcrystalline perborate hydrate products and highly concentrated, storage stable aqueous solutions used for this purpose which have a stable active oxygen content and a boron content of 3 to 8% by wt. based on the total weight of the solution. The products of the invention are suitable for numerous uses in the field of bleaching agent, disinfectant and liquid detergent formulations, and other fields of use.

摘要翻译： 一种制备微晶过硼酸盐水合物产物和用于此目的的高浓度，储存稳定的水溶液的方法，其具有稳定的活性氧含量和3至8重量％的硼含量。 基于溶液的总重量。 本发明的产品适用于漂白剂，消毒剂和液体洗涤剂配方以及其它使用领域的众多用途。