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11.发明授权
公开(公告)号：US4737534A
公开(公告)日：1988-04-12
申请号：US720722
申请日：1985-04-08
摘要： The instant invention relates to a process for controlling the viscosity of organic liquids by incorporating in said liquid a minor amount of polymer complex, and optionally a cosolvent for the ionic groups of said polymer. The polymer complex comprises the reaction product of a metal neutralized sulfonated polymer and a basic nitrogen-containing polymer, wherein the polymer complex is substantially soluble in said organic liquid, and pendant sulfonate groups which are substantially insoluble in said organic liquid. The optional cosolvent is selected which will solubilize the pendant sulfonate groups and provide a reasonably homogeneous mixture of solvent, cosolvent and polymer complex. The preferred compositions prepared by the method of the instant invention comprise an organic liquid having a solubility parameter of from 6 to 10.5 in combination with a polymer complex containing from 0.2 up to 10.0 mole % sulfonate groups and nitrogen-containing groups, and optionally a nonvolatile alcohol or amine cosolvent.
摘要翻译： 本发明涉及通过在所述液体中加入少量聚合物络合物和任选的所述聚合物的离子基团的共溶剂来控制有机液体的粘度的方法。 聚合物复合物包括金属中和的磺化聚合物和碱性含氮聚合物的反应产物，其中聚合物络合物基本上可溶于所述有机液体，以及基本上不溶于所述有机液体的侧链磺酸酯基团。 选择可选的共溶剂，其将溶解磺酸侧基，并提供溶剂，共溶剂和聚合物络合物的合理均匀的混合物。 通过本发明的方法制备的优选组合物包含溶解度参数为6至10.5的有机液体与含有0.2至10.0摩尔％磺酸盐基团和含氮基团的聚合物配合物以及任选的非挥发性的 醇或胺助溶剂。
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12.发明授权Polymer compositions based on sulfonated ionomers and amine containing polymers 失效基于磺化离聚物和含胺聚合物的聚合物组合物
公开(公告)号：US4552916A
公开(公告)日：1985-11-12
申请号：US663123
申请日：1984-10-22
摘要： This invention relates to thermoplastic and/or elastomer blend compositions having a viscosity at 200.degree. C., at 0.73 sec.sup.-1 of about 5000 to about 5.times.10.sup.6 poises, wherein the compositions used for elastomeric articles which include a polymer complex of a neutralized sulfonated polymer and a polymer containing basic nitrogen atoms can also include about 25 to about 150 parts by weight of a nonpolar process oil per 100 parts of the polymer complex and about 50 to 300 parts by weight of a filler per 100 parts of the polymer complex. These blend compositions can be processed on conventional plastic fabrication equipment into polymeric articles having excellent physical properties.
摘要翻译： 本发明涉及热塑性和/或弹性体共混物组合物，其在200℃，在0.73秒-1下具有约5000至约5×10 6泊的粘度，其中用于弹性体制品的组合物包括中和的磺化聚合物 含有碱性氮原子的聚合物还可包含每100份聚合物复合物约25至约150重量份的非极性加工油，每100份聚合物配合物约含有50至300重量份的填料。 这些共混组合物可以在常规塑料制造设备上加工成具有优异物理性能的聚合物制品。
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公开(公告)号：US4517333A
公开(公告)日：1985-05-14
申请号：US560516
申请日：1983-12-12
IPC分类号： C08L101/00 , C08L33/00 , C08L33/26 , C08L41/00
CPC分类号： C08L101/00 , C10M2201/02 , C10M2217/024 , C10M2217/06 , C10M2221/02 , C10N2240/06 , C10N2240/08 , C10N2250/02 , Y10S260/31 , Y10S525/919
摘要： The present invention relates to viscosification agents for aqueous solutions in which the viscosification agents are mixtures of water soluble polymer backbone containing an anionic comonomer and a copolymer of a water soluble polymer backbone containing a cationic comonomer.
摘要翻译： 本发明涉及用于水溶液的增粘剂，其中增粘剂是含有阴离子共聚单体的水溶性聚合物主链和含有阳离子共聚单体的水溶性聚合物主链的共聚物的混合物。
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14.发明授权Polymer compositions based on sulfonated ionomers and amine containing polymers 失效基于磺化离聚物和含胺聚合物的聚合物组合物
公开(公告)号：US4480063A
公开(公告)日：1984-10-30
申请号：US547911
申请日：1983-11-02
摘要： This invention relates to thermoplastic and/or elastomer blend compositions having a viscosity at 200.degree. C., at 0.73 sec.sup.-1 of about 5000 to about 5.times.10.sup.6 poises, wherein the compositions used for elastomeric articles which include a polymer complex of a neutralized sulfonated polymer and a polymer containing basic nitrogen atoms can also include about 25 to about 150 parts by weight of a nonpolar process oil per 100 parts of the polymer complex and about 50 to 300 parts by weight of a filler per 100 parts of the polymer complex. These blend compositions can be processed on conventional plastic fabrication equipment into polymeric articles having excellent physical properties.
摘要翻译： 本发明涉及热塑性和/或弹性体共混物组合物，其在200℃，在0.73秒-1下具有约5000至约5×10 6泊的粘度，其中用于弹性体制品的组合物包括中和的磺化聚合物 含有碱性氮原子的聚合物还可包含每100份聚合物复合物约25至约150重量份的非极性加工油，每100份聚合物配合物约含有50至300重量份的填料。 这些共混组合物可以在常规塑料制造设备上加工成具有优异物理性能的聚合物制品。
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公开(公告)号：US4412028A
公开(公告)日：1983-10-25
申请号：US335450
申请日：1981-12-29
摘要： The present invention relates to a process for forming a gel having improved creep resistance at elevated temperatures and having a viscosity of at least about 100,000 cps which includes the steps forming a solvent system of an organic liquid and a water miscible cosolvent, the water miscible cosolvent being less than about 15 wt. % of the solvent system, a viscosity of the solvent system being less than about 1000 cps; dissolving a neutralized sulfonated polymer in the solvent system to form a solution, adding a free radical generating initiator to the solution at a concentration level of about 0.01 to about 1%, a concentration of the neutralized sulfonated polymer in the solution being about 0.5 to about 20 wt. %, a viscosity of the solution being less than about 20,000 cps; and adding under shear conditions about 5 to about 500 vol. % water to the solution having a viscosity less than about 20,000 cps, the water being immiscible with the solution and the water miscible cosolvent transferring from the solution phase to the water phase thereby causing the viscosity of said solution to increase from less than 20,000 cps to greater than 100,000 cps.
摘要翻译： 本发明涉及形成凝胶的方法，其在高温下具有改善的抗蠕变性，并且具有至少约100,000cps的粘度，其包括形成有机液体和水混溶性共溶剂的溶剂体系的步骤，水混溶性共溶剂 小于约15wt。 ％的溶剂体系，溶剂系统的粘度小于约1000cps; 将中和的磺化聚合物溶解在溶剂体系中以形成溶液，以约0.01至约1％的浓度水平向溶液中加入产生自由基的引发剂，溶液中中和的磺化聚合物的浓度为约0.5至约 20重量％ ％，溶液的粘度小于约20,000cps; 并在剪切条件下加入约5至约500vol。 ％的水溶于具有小于约20,000cps的粘度的溶液中，水与溶液不混溶，水可混溶的共溶剂从溶液相转移到水相，从而使所述溶液的粘度从小于20,000cps增加至 大于100,000 cps。
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16.发明授权
公开(公告)号：US4970260A
公开(公告)日：1990-11-13
申请号：US198525
申请日：1988-05-25
IPC分类号： B63B1/38 , C08J3/03 , C08L33/26 , C08L101/00 , C09K3/00 , C09K8/035 , C09K8/588 , C10M173/02
CPC分类号： C08J3/03 , B63B1/38 , C08L101/00 , C08L33/26 , C09K3/00 , C09K8/035 , C09K8/588 , C10M173/02 , C08J2300/10 , C08L2205/02 , C10M2201/02 , C10M2217/024 , C10M2217/06 , C10M2221/02 , C10N2240/06 , C10N2240/08 , C10N2250/02 , Y02T70/122
摘要： A polymeric solution comprising: water; about 0.005 to about 0.5 moles of an inorganic acid, an inorganic case or an inorganic salt per 100 ml of such water; and about 0.1 to about 5.0 grams of a polymeric complex per 100 grams of said water, said polymeric complex produced by the interaction of a first water soluble copolymer formed from a water soluble nonionic monomer and an anionic comonomer by a free radical copolymerization, said first water soluble nonionic monomer being selected from the group consisting of acrylamide, methacrylamide and vinylpyrrolidone, said anionic comonomer being about 1 to about 35 weight percent of said first water soluble copolymer, said anionic comonomer containing anionic groups, said anionic comonomer being selected from the group consisting of metal styrene sulfonate, metal vinyl sulfonate, and a metal salt of 2-acrylamide-2-methyl propane sulfonate; and a second water soluble copolymer formed from a second water soluble monomer and a cationic comonomer by a free radical copolymerization, said second water soluble monomer being selected from the group consisting of acrylamide, methacrylamide and vinyl pyrrolidone, said cationic comonomer being about 1 to about 34 weight percent of said second water soluble copolymer, said cationic comonmer containing cation group, said cationic comonomer being selected from the group consisting of N,N,N-trimethylammoniumpropylmethacrylamide and vinylpyridine or their quarternary salts, wherein the molar ratio of anionic to cationic functional groups in the water soluble polymer complex is about 50/1 to about 1.2/1 or from about 0.8/1 to about 1/50, said ratio always being such that there is at least an excess of said water soluble copolymers over the other said water soluble copolymer of at least about 20 mole percent.
摘要翻译： 一种聚合物溶液，其包含：水; 约0.005至约0.5摩尔无机酸，无机壳或无机盐/ 100ml水; 和约0.1至约5.0克聚合物复合物/ 100克所述水，所述聚合物复合物通过由水溶性非离子单体形成的第一水溶性共聚物和阴离子共聚单体通过自由基共聚相互作用而产生，所述第一 水溶性非离子单体选自丙烯酰胺，甲基丙烯酰胺和乙烯基吡咯烷酮，所述阴离子共聚单体为所述第一水溶性共聚物的约1至约35重量％，所述阴离子共聚单体含有阴离子基团，所述阴离子共聚单体选自 由金属苯乙烯磺酸盐，金属乙烯基磺酸盐和2-丙烯酰胺-2-甲基丙磺酸盐的金属盐组成; 和由第二水溶性单体和阳离子共聚单体通过自由基共聚形成的第二水溶性共聚物，所述第二水溶性单体选自丙烯酰胺，甲基丙烯酰胺和乙烯基吡咯烷酮，所述阳离子共聚单体为约1至约 34重量％的所述第二水溶性共聚物，所述阳离子共聚单体含有阳离子基团，所述阳离子共聚单体选自N，N，N-三甲基铵丙基甲基丙烯酰胺和乙烯基吡啶或其季盐，其中阴离子与阳离子官能团的摩尔比 所述水溶性聚合物络合物中的基团为约50/1至约1.2 / 1或约0.8 / 1至约1/50，所述比例总是使得至少过量的所述水溶性共聚物在另一个上存在 至少约20摩尔％的水溶性共聚物。
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17.发明授权Hydrocarbon soluble complexes based on metal salts of polyolefinic dicarboxylic acids 失效基于聚烯烃二羧酸金属盐的烃溶性络合物
公开(公告)号：US4751011A
公开(公告)日：1988-06-14
申请号：US941095
申请日：1986-12-12
IPC分类号： C10M157/00 , C08F255/00 , C08L23/26 , C08L33/04 , C08L35/02 , C10M157/04 , C10M161/00 , C10M167/00 , C10N10/02 , C10N10/04 , C10N20/02 , C10N20/04 , C10N30/02 , C10N40/00 , C10N40/25 , F02B1/04 , C10M123/00
CPC分类号： C10M167/00 , C10M161/00 , C10M2205/00 , C10M2205/02 , C10M2207/027 , C10M2207/028 , C10M2207/09 , C10M2207/123 , C10M2207/125 , C10M2207/126 , C10M2207/129 , C10M2207/144 , C10M2207/146 , C10M2207/16 , C10M2207/22 , C10M2207/26 , C10M2207/262 , C10M2207/288 , C10M2209/02 , C10M2209/086 , C10M2215/04 , C10M2215/042 , C10M2215/08 , C10M2215/082 , C10M2215/086 , C10M2215/22 , C10M2215/221 , C10M2215/224 , C10M2215/225 , C10M2215/226 , C10M2215/26 , C10M2215/28 , C10M2215/30 , C10M2217/028 , C10M2217/046 , C10M2217/06 , C10M2219/044 , C10M2219/046 , C10M2219/068 , C10M2219/089 , C10M2223/045 , C10N2210/00 , C10N2210/01 , C10N2210/02 , C10N2210/03 , C10N2240/10 , C10N2240/101 , C10N2240/102 , C10N2240/103 , C10N2240/104 , C10N2240/106 , C10N2270/02 , F02B1/04
摘要： This invention relates to oil soluble additives particularly useful in lubricating oil compositions, and to concentrates or lubricating compositions containing these additives. The additives are various metal salts of mono- or dicarboxylic acids, anhydrides, esters, etc., which have been substituted with a high molecular weight hydrocarbon group, and derivatives thereof. The high molecular weight hydrocarbon group has a number average-molecular weight (M.sub.n) of greater than about 900. The metal salt additives are especially useful in combination with certain grafted ethylene-olefin copolymers or copolymers of 4-vinyl pyridine and esters of aliphatic mono-, di- or polycarboxylic acids as viscosifying agents.
摘要翻译： 本发明涉及特别可用于润滑油组合物的油溶性添加剂，以及含有这些添加剂的浓缩物或润滑组合物。 添加剂是已被高分子量烃基取代的单酸或二羧酸，酸酐，酯等的各种金属盐及其衍生物。 高分子量烃基的数均分子量（Mn）大于约900.金属盐添加剂特别适用于某些接枝的乙烯 - 烯烃共聚物或4-乙烯基吡啶与脂族单体的酯的共聚物 - 二元或多元羧酸作为增粘剂。
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公开(公告)号：US4692268A
公开(公告)日：1987-09-08
申请号：US814403
申请日：1985-12-30
IPC分类号： C08F8/30 , C08F8/44 , C10M157/06 , C10M159/18 , C10M149/00 , C10M155/00
CPC分类号： C10M159/18 , C08F8/30 , C08F8/44 , C10M157/06 , C10M2205/00 , C10M2205/02 , C10M2217/02 , C10M2217/024 , C10M2217/028 , C10M2217/06 , C10M2221/00 , C10M2221/041
摘要： A method for controlling the viscosity of organic liquids, said organic liquid having a solubility parameter of from about 6 to about 10.5, which comprises incorporating in said organic liquid a minor amount of a polymer complex, said complex being formed from the interaction of polymer A, containing neutralized sulfonate groups and polymer B, containing basic nitrogen groups, both functional groups being presented at a level of from about 4 to 500 meq. per 100 g. of polymer, wherein the polymeric backbone of polymer A and polymer B are the same.
摘要翻译： 一种用于控制有机液体的粘度的方法，所述有机液体的溶解度参数为约6至约10.5，其包括在所述有机液体中引入少量的聚合物配合物，所述复合物由聚合物A的相互作用形成 ，含有中和的磺酸盐基团和含有碱性氮基团的聚合物B，两个官能团的存在量为约4至500meq。 每100克 的聚合物，其中聚合物A和聚合物B的聚合物主链相同。
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公开(公告)号：US4665115A
公开(公告)日：1987-05-12
申请号：US781029
申请日：1985-09-27
IPC分类号： C10M159/18 , C08K5/01 , C08L39/08
CPC分类号： C10M159/18 , C10M2205/00 , C10M2205/02 , C10M2217/02 , C10M2217/028 , C10M2217/06 , C10M2221/00 , C10M2221/041
摘要： A method for controlling the viscosity of organic liquids, said organic liquid having a solubility parameter of from about 6 to about 10.5, which comprises incorporating in said organic liquid a minor amount of a polymer complex, said complex being comprised of polymer A, containing neutralized sulfonate groups and polymer B, containing basic nitrogen groups, both functional groups being presented at a level of from about 4 to 500 meq. per 100 g. of polymer, wherein polymer B has the formula: ##STR1## wherein R.sub.1 is H or an alkyl group having about 1 to about 8 carbon atoms, R.sub.2 is an alkyl group having about 1 to about 18 carbon atoms, x is about 50.0 to 99.8 weight percent and x is about 0.2 to about 50.0 weight percent.
摘要翻译： 一种用于控制有机液体的粘度的方法，所述有机液体的溶解度参数为约6至约10.5，其包括在所述有机液体中引入少量的聚合物配合物，所述复合物包含聚合物A，其包含中和的 磺酸盐基团和含有碱性氮基团的聚合物B，两个官能团的存在量为约4至500meq。 每100克 的聚合物，其中聚合物B具有下式：其中R 1为H或具有约1至约8个碳原子的烷基，R 2为具有约1至约18个碳原子的烷基，x为约50.0至99.8 重量百分比，x为约0.2至约50.0重量％。
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20.发明授权Polymer complexes of a neutralized ionic polymer and a polycaprolactone polymer 失效中和离子聚合物和聚己内酯聚合物的聚合物络合物
公开(公告)号：US4536547A
公开(公告)日：1985-08-20
申请号：US566347
申请日：1983-12-28
IPC分类号： C08L25/18 , C09J125/18 , C08L51/04 , C08L51/08 , C08L51/00
CPC分类号： C08L25/18 , C09J125/18
摘要： This invention relates to unique and novel polymer complexes between a metal neutralized sulfonated polymer and a tertiary amine terminated polylactone composition. The resulting polymer complexes have a variety of uses including those as diverse as adhesive agents, thermoplastic elastomers, additive uses wherein these materials can be utilized to compatibilize two different polymers which are normally incompatible. These polymer complexes can also be blended with fillers and/or oils when the sulfonated polymer is elastomeric. The materials display thermoplastic character.
摘要翻译： 本发明涉及金属中和的磺化聚合物和叔胺封端的聚内酯组合物之间独特且新颖的聚合物络合物。 所得聚合物复合物具有多种用途，包括粘合剂，热塑性弹性体，添加剂用途，其中这些材料可用于增容通常不相容的两种不同聚合物。 当磺化聚合物是弹性体时，这些聚合物复合物也可与填料和/或油混合。 材料显示热塑性。
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