Stabilized Propyl Bromide Compositions
    13.
    发明申请
    Stabilized Propyl Bromide Compositions 有权
    稳定的丙基溴化合物

    公开(公告)号:US20090253608A1

    公开(公告)日:2009-10-08

    申请号:US11577899

    申请日:2004-11-05

    IPC分类号: C07C17/42 C09K15/08 C11D17/08

    摘要: Certain substituted phenolic compounds when used with or without 1,2-epoxides as the sole stabilizer components are very effective in stabilizing n-propyl bromide (NPB). In a standard commercially important 60° C. stability test, representative substituted phenolic compounds used pursuant to this invention, can enable NPB to pass the test even though present at levels of about 50 ppm (wt/wt) or less in NPB containing no other stabilizer additive component. In fact, amounts as low as 1 ppm have been found effective with various substituted phenolic compounds. In addition, it has been found that one of the preferred stabilizers of this invention—2,6-di-tert-butyl-p-cresol—even though higher boiling than NPB, left inconsequential amounts of residue at least throughout the range of 1 to 30 ppm (wt/wt). Also, it has been found that certain other preferred stabilizers of this invention can provide synergistically improved stability in passing the 60° C. stability test when used with at least one 1,2-epoxide, notably butylene oxide.

    摘要翻译: 当使用或不使用1,2-环氧化物作为唯一稳定剂组分时,某些取代的酚类化合物在稳定正丙基溴(NPB)方面非常有效。 在标准的商业上重要的60℃稳定性试验中,根据本发明使用的代表性取代的酚类化合物可以使得NPB通过试验,即使在不含其它物质的NPB中,以约50ppm(wt / wt)或更低的水平存在 稳定剂添加剂组分。 事实上,已发现低至1ppm的量与各种取代的酚类化合物有效。 此外,已经发现,本发明的一种优选的稳定剂-2,6-二叔丁基对甲酚 - 尽管比NPB沸点更高,但至少在1的范围内留下无关紧要的残余量 至30ppm(wt / wt)。 此外,已经发现,当与至少一种1,2-环氧化物,特别是环氧丁烷一起使用时,本发明的某些其它优选的稳定剂可以提供协同改进的通过60℃稳定性试验的稳定性。

    Absorbent sheet incorporating regenerated cellulose microfiber
    14.
    发明申请
    Absorbent sheet incorporating regenerated cellulose microfiber 有权
    含再生纤维素超细纤维的吸收片

    公开(公告)号:US20090020248A1

    公开(公告)日:2009-01-22

    申请号:US12284147

    申请日:2008-09-17

    IPC分类号: D21H11/00

    摘要: An absorbent paper sheet includes cellulosic papermaking fiber and up to about 75 percent by weight fibrillated regenerated cellulose microfiber which may be regenerated from a cellulosic dope utilizing a tertiary amine N-oxide solvent or selected ionic liquids. Fibrillation of the microfiber is controlled such that it has a reduced coarseness and a reduced freeness as compared with unfibrillated regenerated cellulose microfiber from which it is made and provides at least one of the following attributes to the absorbent sheet: (a) the absorbent sheet exhibits an elevated SAT value and an elevated wet tensile value as compared with a like sheet prepared without fibrillated regenerated cellulose microfiber; (b) the absorbent sheet exhibits an elevated wet/dry CD tensile ratio as compared with a like sheet prepared without fibrillated regenerated cellulose microfiber; (c) the absorbent sheet exhibits a lower GM Break Modulus than a like sheet having like tensile values prepared without fibrillated regenerated cellulose microfiber; or (d) the absorbent sheet exhibits an elevated bulk as compared with a like sheet having like tensile values prepared without fibrillated regenerated cellulose microfiber.

    摘要翻译: 吸收性纸张包括纤维素造纸纤维和高达约75重量%的原纤化再生纤维素微纤维,其可以使用叔胺N-氧化物溶剂或选择的离子液体从纤维素原液再生。 控制微纤维的纤维颤动,使其与未被原纤化的再生纤维素微纤维相比具有降低的粗糙度和降低的游离度,并且向吸收片提供以下属性中的至少一个:(a)吸收性片材展现 与没有原纤化再生纤维素微纤维制备的类似片材相比,提高的SAT值和升高的湿拉伸值; (b)与不经原纤化的再生纤维素超细纤维制备的类似片材相比,吸收片材具有较高的湿/干CD拉伸比; (c)所述吸收性片材比具有如下拉伸值的类似片材具有较低的GM断裂模量,所述拉伸值不需要原纤化的再生纤维素超细纤维; 或者(d)与没有原纤维化的再生纤维素超细纤维制备的具有类似拉伸值的类似片材相比,吸收性片材呈现较高的体积。

    Methods of making a belt-creped absorbent cellulosic sheet prepared with a perforated polymeric belt
    16.
    发明授权
    Methods of making a belt-creped absorbent cellulosic sheet prepared with a perforated polymeric belt 有权
    制造带有起皱的吸收性纤维素片材的方法,其用穿孔聚合物带制备

    公开(公告)号:US08652300B2

    公开(公告)日:2014-02-18

    申请号:US13488597

    申请日:2012-06-05

    IPC分类号: B31F1/16 B31F1/12 B31F1/07

    摘要: A method of making a belt-creped absorbent cellulosic sheet. A paper making furnish is compactively dewatered to form a dewatered web having an apparently random distribution of papermaking fiber orientation. The dewatered web is applied to a translating transfer surface that is moving at a transfer surface speed. The web is belt-creped from the transfer surface at a consistency of from about 30% to about 60% utilizing a generally planar polymeric creping belt having a plurality of perforations, under pressure, in a belt creping nip defined between the transfer surface and the creping belt. The belt travels at a belt speed that is slower than the speed of the transfer surface. The web is creped from the transfer surface and redistributed on the creping belt to form a web having a plurality of interconnected regions of different local basis weights. The web is then dried.

    摘要翻译: 制造带状起皱吸收性纤维素片材的方法。 造纸配料被压实脱水以形成具有造纸纤维取向的显然随机分布的脱水网。 脱水网被施加到以转印表面速度移动的平移转印表面。 使用具有多个穿孔的大体上平坦的聚合起皱带,在转印表面上以从约30%至约60%的浓度将纸幅带从起始带从起转辊表面起皱。 起皱带 皮带以比传送表面的速度慢的皮带速度行进。 幅材从转印表面起皱并重新分布在起皱带上以形成具有不同局部基重的多个相互连接的区域的幅材。 然后将纸幅干燥。

    Belt-creped, variable local basis weight multi-ply sheet with cellulose microfiber prepared with perforated polymeric belt
    17.
    发明授权
    Belt-creped, variable local basis weight multi-ply sheet with cellulose microfiber prepared with perforated polymeric belt 有权
    带状起皱,可变的局部基重多层纤维素用纤维素微纤维制成,带有多孔聚合物带

    公开(公告)号:US08540846B2

    公开(公告)日:2013-09-24

    申请号:US13137216

    申请日:2011-07-28

    摘要: A multi-ply wiper/towel product includes at least one wet laid web including at least 10% fibrillated cellulosic microfiber, and at least about 40% wood pulp derived papermaking fibers. The at least one wet laid web has formed therein (i) a plurality of fiber-enriched hollow domed regions on the upper side of the at least one wet laid web having a relatively high local basis weight, and (ii) connecting regions of a relatively lower local basis weight forming a network interconnecting the relatively high local basis weight domed regions of the one wet laid web. Transition areas are provided in the at least one wet laid web with upwardly and inwardly inflected consolidated fibrous regions transitioning from the connecting regions into the domed regions, and the at least one wet laid web exhibits a differential pore volume for pores under 5 microns in a diameter of at least about 75 mm3/g/micron.

    摘要翻译: 多层刮水器/毛巾产品包括至少一个包含至少10%原纤化纤维素超细纤维的湿法成网幅材和至少约40%的木浆衍生的造纸纤维。 至少一个湿法成网幅材在其中形成(i)在至少一个湿法成网幅材的上侧上具有相对较高的局部基重的多个纤维富集的中空圆顶区域,和(ii)连接区域 相对较低的局部基重,形成互连一个湿敷网的相对较高的局部基重的圆顶区域的网络。 在至少一个湿法成网幅材上提供了过渡区域,其中向上和向内弯曲的固结的纤维区域从连接区域转移到圆顶区域中,并且至少一个湿法成网幅材对于5微米以下的孔显示不同的孔体积 直径为至少约75mm 3 / g /微米。

    Multi-ply paper towel with creped plies
    18.
    发明授权
    Multi-ply paper towel with creped plies 有权
    多层纸巾与褶皱层

    公开(公告)号:US08409404B2

    公开(公告)日:2013-04-02

    申请号:US12438387

    申请日:2007-08-24

    IPC分类号: D21H27/40 B31F1/12 B31F1/07

    摘要: A multi-ply absorbent towel made from papermaking fiber comprising at least a first ply and a second ply bonded together, the towel having a basis weight of greater than 30 lbs per 3000 ft2 ream (48.8 gsm) and less than 50 lbs per 3000 ft2 ream (81.4 gsm), wherein the plies are selected and adhered together such that the towel typically exhibits (i) a GM TEA, mm-g/mm2 of greater than [0.00125 (GM Tensile, g/3″)−0.75] and (ii) a GM Tensile Modulus, g/in/%, less than [0.0083 (GM Tensile Strength, g/3″)+15.4] {(i) a GM TEA, mm g/mm2, of greater than [0.00952 (GM Tensile, g/cm)−0.75] and (ii) a GM Tensile Modulus, g/cm/%, less than [0.0249 (GM Tensile Strength, g/cm)+6.06}.

    摘要翻译: 由造纸纤维制成的多层吸收性毛巾包括至少第一层和第二层结合在一起,所述毛巾具有大于30磅/ 3000平方英尺(48.8克/平方米)的基重和小于50磅/ 3000平方英尺 (81.4gsm),其中层选择并粘合在一起,使得毛巾通常表现出(i)大于[0.00125(GM拉伸,g / 3“) - 0.75]的GM TEA,mm-g / mm 2和 (ii)g / in /%,小于[0.0083(GM拉伸强度,g / 3“)+ 15.4]的GM拉伸模量((i)GM TEA,mm g / mm 2,大于[0.00952 GM拉伸强度,g / cm)-0.75]和(ii)小于[0.0249(GM拉伸强度,g / cm)+6.06}的GM拉伸模量,g / cm /%。