公开(公告)号：US20120208079A1

公开(公告)日：2012-08-16

申请号：US13252290

申请日：2011-10-04

申请人： Shoichiro Sakai ,  Atsushi Fukunaga ,  Koji Nitta ,  Masatoshi Majima ,  Shinji Inazawa

发明人： Shoichiro Sakai ,  Atsushi Fukunaga ,  Koji Nitta ,  Masatoshi Majima ,  Shinji Inazawa

IPC分类号： H01M10/02 ,  B05D5/12 ,  H01M4/46 ,  H01M4/64 ,  H01M4/42

CPC分类号： H01M4/661 ,  H01M4/0438 ,  H01M4/38 ,  H01M4/667 ,  H01M10/3909 ,  H01M10/399

摘要： A negative electrode precursor material is provided for preparing a negative electrode, which has a reduced thickness, good current collecting performance, and suppresses deformation and generation of dendrites during operation. A molten salt battery comprises a positive electrode formed by providing an active material film on an Al current collector, a separator comprising a glass cloth impregnated with a molten salt as an electrolyte, and the negative electrode formed by providing a Zn film and an active material film on an Al, current collector, which are respectively contained in a substantially rectangular parallelepiped Al case. The active material absorbs and releases Na ions contained in the molten salt.

摘要翻译： 提供负极前体材料用于制备负极，其具有减小的厚度，良好的集流性能，并且在操作期间抑制变形和产生枝晶。 熔融盐电池包括通过在Al集电体上提供活性材料膜而形成的正极，包含浸渍有作为电解质的熔融盐的玻璃布的隔膜，以及通过提供Zn膜和活性物质形成的负极 Al集电体上的膜分别包含在大致长方体的Al壳中。 活性物质吸收并释放熔融盐中所含的Na离子。

公开(公告)号：US20120208068A1

公开(公告)日：2012-08-16

申请号：US13252295

申请日：2011-10-04

申请人： Atsushi Fukunaga ,  Shoichiro Sakai ,  Chihiro Hiraiwa ,  Koji Nitta ,  Masatoshi Majima ,  Shinji Inazawa

发明人： Atsushi Fukunaga ,  Shoichiro Sakai ,  Chihiro Hiraiwa ,  Koji Nitta ,  Masatoshi Majima ,  Shinji Inazawa

IPC分类号： H01M2/16 ,  B05D5/12 ,  B05D3/06 ,  H01M10/04

CPC分类号： H01M10/0525 ,  H01M2/145 ,  H01M2/1653 ,  H01M2/18 ,  H01M10/0568 ,  H01M10/0569 ,  H01M2300/0048 ,  Y10T29/49115

摘要： A separator of a molten salt battery made of a porous resin sheet. The separator is improved in wettability to a molten salt by giving hydrophilicity to the resin sheet. In the case of a fluororesin sheet, the sheet is impregnated with water, and irradiated with ultraviolet rays so that C—F bonds in the fluororesin are cleaved and the resultant reacts with water to generate hydrophilic groups, such as OH groups, in each surface layer thereof. The separator gains hydrophilicity through the hydrophilic groups. The separator made of the resin can be made into a bag form. In a molten salt battery having the bag-form separator, the growth of a dendrite is prevented.

摘要翻译： 由多孔树脂片制成的熔盐电池的隔板。 通过赋予树脂片亲水性，隔膜对熔融盐的润湿性提高。 在氟树脂片的情况下，用水浸渍片材，并用紫外线照射，使氟树脂中的C-F键断开，并与水反应以在每个表面中产生诸如OH基团的亲水基团 层。 分离器通过亲水基团获得亲水性。 由树脂制成的隔板可以制成袋形。 在具有袋状分离器的熔盐电池中，防止枝晶的生长。

公开(公告)号：US20120171524A1

公开(公告)日：2012-07-05

申请号：US13252289

申请日：2011-10-04

申请人： Chihiro Hiraiwa ,  Masatoshi Majima ,  Koji Nitta ,  Shoichiro Sakai ,  Atsushi Fukunaga ,  Shinji Inazawa

发明人： Chihiro Hiraiwa ,  Masatoshi Majima ,  Koji Nitta ,  Shoichiro Sakai ,  Atsushi Fukunaga ,  Shinji Inazawa

IPC分类号： H01M10/50

CPC分类号： H01M10/399 ,  H01M10/486 ,  H01M10/613 ,  H01M10/615 ,  H01M10/6568 ,  H01M10/657

摘要： In a molten salt battery device, molten salt batteries are arranged in a container to cause a space to be present around the molten salt batteries, and a heating medium is filled into the space around the molten salt batteries. When an electrothermal heater is used to control the temperature of the heating medium through a temperature controlling section, the heating medium is caused to flow. Between the flowing heating medium and the molten salt batteries, heat is exchanged, whereby the molten salt battery device controls the temperature of the molten salt batteries. Since the molten salt batteries attain the heat exchange with the heating medium, which surrounds the batteries, the internal temperature thereof is evenly controlled. Moreover, the molten salt battery device makes it possible to lower the temperature of the heating medium to cool the molten salt batteries easily.

摘要翻译： 在熔融盐电池装置中，将熔融盐电池配置在容器内，使熔融盐电池周围存在空间，将加热介质填充在熔盐电池周围的空间内。 当使用电热加热器通过温度控制部分控制加热介质的温度时，使加热介质流动。 在流动的加热介质和熔融盐电池之间，更换热量，由此熔融盐电池装置控制熔融盐电池的温度。 由于熔融盐电池与包围电池的加热介质进行热交换，所以其内部温度被均匀地控制。 此外，熔融盐电池装置可以使加热介质的温度降低，容易地冷却熔融盐电池。

公开(公告)号：US20130295003A1

公开(公告)日：2013-11-07

申请号：US13980640

申请日：2011-09-26

申请人： Atsushi Fukunaga ,  Shoichiro Sakai ,  Koji Nitta ,  Masatoshi Majima ,  Shinji Inazawa

发明人： Atsushi Fukunaga ,  Shoichiro Sakai ,  Koji Nitta ,  Masatoshi Majima ,  Shinji Inazawa

IPC分类号： C01D1/02

CPC分类号： C01D1/02 ,  C01G37/00 ,  C01G37/14 ,  C01P2002/72

摘要： According to this production method, the water content of a mixture of a chromium oxide (Cr2O3) powder and a sodium carbonate (Na2CO3) powder is brought to 1000 ppm or less, and the mixture is heated in an inert gas atmosphere at a calcination temperature (850 DEG C.) where the sodium carbonate and the chromium oxide undergo a calcination reaction. Sodium chromite is thereby obtained.

摘要翻译： 根据该制造方法，将氧化铬（Cr 2 O 3）粉末和碳酸钠（Na 2 CO 3）粉末的混合物的含水量设定为1000ppm以下，并将混合物在惰性气体气氛中以煅烧温度 （850℃），其中碳酸钠和氧化铬经历煅烧反应。 从而得到亚铬酸钠。

公开(公告)号：US20130294997A1

公开(公告)日：2013-11-07

申请号：US13978980

申请日：2012-01-13

申请人： Atsushi Fukunaga ,  Shoichiro Sakai ,  Koji Nitta ,  Atsushi Yamaguchi ,  Masatoshi Majima ,  Shinji Inazawa

发明人： Atsushi Fukunaga ,  Shoichiro Sakai ,  Koji Nitta ,  Atsushi Yamaguchi ,  Masatoshi Majima ,  Shinji Inazawa

IPC分类号： C01B21/086

CPC分类号： C01B21/086 ,  C01B21/093 ,  H01M10/0525 ,  H01M10/0568

摘要： KN(SO2F)2 is synthesized by adding HN(SO2Cl)2 dropwise to KF to form an intermediate product, and then allowing the intermediate product and KF to react with each other in an aqueous solvent.

摘要翻译： 通过向KF中滴加HN（SO2Cl）2以形成中间产物，然后使中间产物和KF在水性溶剂中彼此反应来合成KN（SO 2 F）2。

公开(公告)号：US20130202942A1

公开(公告)日：2013-08-08

申请号：US13879962

申请日：2011-10-19

申请人： Shoichiro Sakai ,  Atsushi Fukunaga ,  Atsushi Yamaguchi ,  Koji Nitta ,  Masatoshi Majima ,  Shinji Inazawa

发明人： Shoichiro Sakai ,  Atsushi Fukunaga ,  Atsushi Yamaguchi ,  Koji Nitta ,  Masatoshi Majima ,  Shinji Inazawa

IPC分类号： H01M2/26 ,  H01M2/18 ,  H01M10/39

CPC分类号： H01M2/266 ,  H01M2/18 ,  H01M2/263 ,  H01M10/0459 ,  H01M10/3909 ,  H01M10/3981 ,  H01M10/399 ,  H01M2300/0048

摘要： A molten-salt battery is provided with rectangular plate-like negative electrodes (21) and rectangular plate-like positive electrodes (41) each housed in a bag-shaped separator (31). The negative electrodes (21) and positive electrodes (41) are arranged laterally and alternately in a standing manner. A lower end of a rectangular tab (22) for collecting current is joined to an upper end of each negative electrode (21) close to a side wall (1A) of a container body (1). The upper ends of the tabs (22) are joined to the lower surface of a rectangular plate-like tab lead (23). A lower end of a rectangular tab (42) for collecting current is joined to an upper end of each positive electrode (41) close to a side wall (1B) of the container body (1). The upper ends of the tabs (42) are joined to the lower surface of a rectangular plate-like tab lead (43).

摘要翻译： 熔盐电池设置有矩形板状负极（21）和矩形板状的正极（41），各自容纳在袋状隔板（31）中。 负极（21）和正极（41）以直立的方式横向和交替地布置。 用于收集电流的矩形突片（22）的下端接合到靠近容器主体（1）的侧壁（1A）的每个负极（21）的上端。 突片（22）的上端与矩形板状突片引线（23）的下表面接合。 用于收集电流的矩形突片（42）的下端接合到靠近容器主体（1）的侧壁（1B）的每个正电极（41）的上端。 突片（42）的上端部与矩形的板状突片（43）的下表面接合。

公开(公告)号：US20130171513A1

公开(公告)日：2013-07-04

申请号：US13823595

申请日：2011-09-27

申请人： Masatoshi Majima ,  Koji Nitta ,  Atsushi Fukunaga ,  Shoichiro Sakai ,  Atsushi Yamaguchi ,  Shinji Inazawa

发明人： Masatoshi Majima ,  Koji Nitta ,  Atsushi Fukunaga ,  Shoichiro Sakai ,  Atsushi Yamaguchi ,  Shinji Inazawa

IPC分类号： H01M10/39

CPC分类号： H01M10/399 ,  H01M4/661

摘要： Provided is a molten salt battery whose cycle life is improved by using an electrolyte that is unlikely to cause corrosion of aluminum. In the molten salt battery of the present invention, the total concentration of iron ions and nickel ions contained as impurities in the electrolyte composed of a molten salt is set to be 0.1% by weight or less, preferably 0.01% by weight or less. Because of the low total concentration of iron ions and nickel ions contained in the electrolyte, corrosion of the electrode current collector composed of aluminum is inhibited, and the cycle life of the molten salt battery is improved.

摘要翻译： 提供一种通过使用不可能引起铝腐蚀的电解质来改善循环寿命的熔盐电池。 在本发明的熔盐电池中，由熔融盐构成的电解质中作为杂质含有的铁离子和镍离子的总浓度为0.1重量％以下，优选为0.01重量％以下。 由于电解液中含有的铁离子和镍离子的总浓度低，所以抑制了由铝构成的电极集电体的腐蚀，提高了熔融盐电池的循环寿命。

公开(公告)号：US20130130124A1

公开(公告)日：2013-05-23

申请号：US13812546

申请日：2011-07-25

申请人： Atsushi Fukunaga ,  Shinji Inazawa ,  Masatoshi Majima ,  Atsushi Yamaguchi ,  Koji Nitta ,  Shoichiro Sakai

发明人： Atsushi Fukunaga ,  Shinji Inazawa ,  Masatoshi Majima ,  Atsushi Yamaguchi ,  Koji Nitta ,  Shoichiro Sakai

IPC分类号： H01M4/66 ,  H01M4/04

CPC分类号： H01M4/661 ,  H01M4/0402 ,  H01M4/387 ,  H01M4/667 ,  H01M4/80 ,  H01M4/808 ,  H01M10/39

摘要： A main object is to produce a porous metal body that can be used as a battery electrode, in particular, that can be used as a negative electrode of a molten-salt battery using sodium. The porous metal body includes a hollow metal skeleton composed of a metal layer containing nickel or copper as a main component, and an aluminum covering layer that covers at least an outer surface of the metal skeleton. The porous metal body further includes a tin covering layer that covers the aluminum covering layer, and is used as a battery electrode. Preferably, the porous metal body has continuous pores due to a three-dimensional network structure thereof, and has a porosity of 90% or more.

摘要翻译： 主要的目的是制造可用作电池电极的多孔金属体，特别是可以用作使用钠的熔盐电池的负极。 多孔金属体包括由以镍或铜为主要成分的金属层构成的中空金属骨架以及覆盖金属骨架的至少外表面的铝覆盖层。 多孔金属体还包括覆盖铝覆盖层的锡覆盖层，并且用作电池电极。 优选地，多孔金属体由于其三维网状结构而具有连续的孔，并且具有90％以上的孔隙率。

公开(公告)号：US20120100416A1

公开(公告)日：2012-04-26

申请号：US13335242

申请日：2011-12-22

申请人： Koji NITTA ,  Shoichiro Sakai ,  Shinji Inazawa ,  Chihiro Hiraiwa ,  Atsushi Fukunaga ,  Masatoshi Majima

发明人： Koji NITTA ,  Shoichiro Sakai ,  Shinji Inazawa ,  Chihiro Hiraiwa ,  Atsushi Fukunaga ,  Masatoshi Majima

IPC分类号： H01M2/02

CPC分类号： H01M2/025 ,  H01M2/0285 ,  H01M4/387 ,  H01M4/483 ,  H01M10/054 ,  H01M10/0563 ,  H01M10/0569 ,  H01M2300/0022 ,  H01M2300/0045

摘要： The case for a molten salt battery is used for a molten salt battery containing as an electrolyte a molten salt containing sodium ions. The case is formed of aluminum or an aluminum alloy containing 90% by mass or more of aluminum.

摘要翻译： 熔融盐电池的情况用于含有钠离子的熔融盐作为电解质的熔盐电池。 该壳由铝或含有90质量％以上的铝的铝合金形成。

公开(公告)号：US08859140B2

公开(公告)日：2014-10-14

申请号：US13328329

申请日：2011-12-16

申请人： Syoichiro Sakai ,  Shinji Inazawa ,  Masatoshi Majima ,  Koji Nitta ,  Atsushi Fukunaga

发明人： Syoichiro Sakai ,  Shinji Inazawa ,  Masatoshi Majima ,  Koji Nitta ,  Atsushi Fukunaga

IPC分类号： H01M10/056 ,  H01M10/26 ,  H01M10/39 ,  H01M4/66 ,  H01M4/80

CPC分类号： H01M10/399 ,  H01M4/661 ,  H01M4/808 ,  Y02E60/12 ,  Y10T29/49108 ,  Y10T29/49115

摘要： An electrode for a molten salt battery includes a current collector connectable to an electrode terminal of the molten salt battery and an active material. The current collector has an internal space in which small spaces are mutually coupled. The internal space of the current collector is filled with the active material.

摘要翻译： 用于熔融盐电池的电极包括可连接到熔融盐电池的电极端子的集电体和活性材料。 集电器具有内部空间，其中小空间相互耦合。 集电器的内部空间填充有活性材料。