公开(公告)号：US20140170458A1

公开(公告)日：2014-06-19

申请号：US13989223

申请日：2011-11-07

申请人： Koji Nitta ,  Shinji Inazawa ,  Masatoshi Majima ,  Atsushi Yamaguchi ,  Shoichiro Sakai ,  Atsushi Fukunaga ,  Rika Hagiwara ,  Toshiyuki Nohira ,  Kazuhiko Matsumoto

发明人： Koji Nitta ,  Shinji Inazawa ,  Masatoshi Majima ,  Atsushi Yamaguchi ,  Shoichiro Sakai ,  Atsushi Fukunaga ,  Rika Hagiwara ,  Toshiyuki Nohira ,  Kazuhiko Matsumoto

IPC分类号： H01M10/39

CPC分类号： H01M10/399 ,  H01M2300/0048

摘要： A separator (3) of a molten salt battery is impregnated with a molten salt that serves as the electrolyte. The molten salt contains, as cations, at least one kind of ions selected from among quaternary ammonium ions, imidazolium ions, imidazolinium ions, pyridinium ions, pyrrolidinium ions, piperidinium ions, morpholinium ions, phosphonium ions, piperazinium ions and sulfonium ions in addition to sodium ions. These cations do not have adverse effects on a positive electrode (1). In addition, the melting point of the molten salt, which contains sodium ions and the above-mentioned cations, is significantly lower than the operating temperature of sodium-sulfur batteries, said operating temperature being 280-360 DEG C. Consequently, the molten salt battery is capable of operating at lower temperatures than sodium-sulfur batteries.

摘要翻译： 熔融盐电池的分离器（3）浸渍有用作电解质的熔融盐。 作为阳离子，熔融盐除了季铵离子，咪唑鎓离子，咪唑啉鎓离子，吡啶鎓离子，吡咯烷鎓离子，哌啶鎓离子，吗啉鎓离子，鏻离子，哌嗪鎓离子和锍离子中外还含有至少一种离子 钠离子。 这些阳离子对正极没有不利影响（1）。 此外，含有钠离子和上述阳离子的熔融盐的熔点显着低于钠硫电池的工作温度，所述操作温度为280-360℃。因此，熔融盐 电池能够在低于钠硫电池的温度下工作。

公开(公告)号：US20120237827A1

公开(公告)日：2012-09-20

申请号：US13368643

申请日：2012-02-08

申请人： Atsushi FUKUNAGA ,  Shinji Inazawa ,  Masatoshi Majima ,  Atsushi Yamaguchi ,  Koji Nitta ,  Shoichiro Sakai

发明人： Atsushi FUKUNAGA ,  Shinji Inazawa ,  Masatoshi Majima ,  Atsushi Yamaguchi ,  Koji Nitta ,  Shoichiro Sakai

IPC分类号： H01M4/38 ,  B32B15/01 ,  B32B5/18

CPC分类号： C23C28/023 ,  C25D1/006 ,  C25D3/30 ,  C25D3/44 ,  C25D3/66 ,  H01M4/661 ,  H01M4/808 ,  H01M10/399 ,  Y10T428/12479

摘要： A porous metal body includes a porous skeleton that forms a three-dimensional network structure and includes an aluminum layer having a thickness of 1 to 100 μm, and tin layers disposed on an internal surface and an external surface of the aluminum layer. Such a porous metal body can be produced by an internal-tin-layer formation step of forming a tin layer on a surface of a resin molded body having a three-dimensional network structure; an aluminum-skeleton formation step of forming an aluminum layer serving as an aluminum skeleton on a surface of the internal tin layer; an external-tin-layer formation step of forming a tin layer on a surface of the aluminum skeleton; and a resin removal step of removing the resin molded body, the resin removal step being performed after the aluminum-skeleton formation step or after the external-tin-layer formation step.

摘要翻译： 多孔金属体包括形成三维网状结构的多孔骨架，并且包括厚度为1〜100μm的铝层和设置在铝层的内表面和外表面上的锡层。 这种多孔金属体可以通过在具有三维网状结构的树脂成型体的表面上形成锡层的内锡层形成工序来制造; 在所述内部锡层的表面上形成作为铝骨架的铝层的铝骨架形成工序; 在铝骨架的表面上形成锡层的外锡层形成工序; 以及去除树脂成形体的树脂除去工序，在铝 - 骨架形成工序之后或在外部锡层形成工序之后进行树脂除去工序。

公开(公告)号：US20130294997A1

公开(公告)日：2013-11-07

申请号：US13978980

申请日：2012-01-13

申请人： Atsushi Fukunaga ,  Shoichiro Sakai ,  Koji Nitta ,  Atsushi Yamaguchi ,  Masatoshi Majima ,  Shinji Inazawa

发明人： Atsushi Fukunaga ,  Shoichiro Sakai ,  Koji Nitta ,  Atsushi Yamaguchi ,  Masatoshi Majima ,  Shinji Inazawa

IPC分类号： C01B21/086

CPC分类号： C01B21/086 ,  C01B21/093 ,  H01M10/0525 ,  H01M10/0568

摘要： KN(SO2F)2 is synthesized by adding HN(SO2Cl)2 dropwise to KF to form an intermediate product, and then allowing the intermediate product and KF to react with each other in an aqueous solvent.

摘要翻译： 通过向KF中滴加HN（SO2Cl）2以形成中间产物，然后使中间产物和KF在水性溶剂中彼此反应来合成KN（SO 2 F）2。

公开(公告)号：US20130202942A1

公开(公告)日：2013-08-08

申请号：US13879962

申请日：2011-10-19

申请人： Shoichiro Sakai ,  Atsushi Fukunaga ,  Atsushi Yamaguchi ,  Koji Nitta ,  Masatoshi Majima ,  Shinji Inazawa

发明人： Shoichiro Sakai ,  Atsushi Fukunaga ,  Atsushi Yamaguchi ,  Koji Nitta ,  Masatoshi Majima ,  Shinji Inazawa

IPC分类号： H01M2/26 ,  H01M2/18 ,  H01M10/39

CPC分类号： H01M2/266 ,  H01M2/18 ,  H01M2/263 ,  H01M10/0459 ,  H01M10/3909 ,  H01M10/3981 ,  H01M10/399 ,  H01M2300/0048

摘要： A molten-salt battery is provided with rectangular plate-like negative electrodes (21) and rectangular plate-like positive electrodes (41) each housed in a bag-shaped separator (31). The negative electrodes (21) and positive electrodes (41) are arranged laterally and alternately in a standing manner. A lower end of a rectangular tab (22) for collecting current is joined to an upper end of each negative electrode (21) close to a side wall (1A) of a container body (1). The upper ends of the tabs (22) are joined to the lower surface of a rectangular plate-like tab lead (23). A lower end of a rectangular tab (42) for collecting current is joined to an upper end of each positive electrode (41) close to a side wall (1B) of the container body (1). The upper ends of the tabs (42) are joined to the lower surface of a rectangular plate-like tab lead (43).

摘要翻译： 熔盐电池设置有矩形板状负极（21）和矩形板状的正极（41），各自容纳在袋状隔板（31）中。 负极（21）和正极（41）以直立的方式横向和交替地布置。 用于收集电流的矩形突片（22）的下端接合到靠近容器主体（1）的侧壁（1A）的每个负极（21）的上端。 突片（22）的上端与矩形板状突片引线（23）的下表面接合。 用于收集电流的矩形突片（42）的下端接合到靠近容器主体（1）的侧壁（1B）的每个正电极（41）的上端。 突片（42）的上端部与矩形的板状突片（43）的下表面接合。

公开(公告)号：US20130171513A1

公开(公告)日：2013-07-04

申请号：US13823595

申请日：2011-09-27

申请人： Masatoshi Majima ,  Koji Nitta ,  Atsushi Fukunaga ,  Shoichiro Sakai ,  Atsushi Yamaguchi ,  Shinji Inazawa

发明人： Masatoshi Majima ,  Koji Nitta ,  Atsushi Fukunaga ,  Shoichiro Sakai ,  Atsushi Yamaguchi ,  Shinji Inazawa

IPC分类号： H01M10/39

CPC分类号： H01M10/399 ,  H01M4/661

摘要： Provided is a molten salt battery whose cycle life is improved by using an electrolyte that is unlikely to cause corrosion of aluminum. In the molten salt battery of the present invention, the total concentration of iron ions and nickel ions contained as impurities in the electrolyte composed of a molten salt is set to be 0.1% by weight or less, preferably 0.01% by weight or less. Because of the low total concentration of iron ions and nickel ions contained in the electrolyte, corrosion of the electrode current collector composed of aluminum is inhibited, and the cycle life of the molten salt battery is improved.

摘要翻译： 提供一种通过使用不可能引起铝腐蚀的电解质来改善循环寿命的熔盐电池。 在本发明的熔盐电池中，由熔融盐构成的电解质中作为杂质含有的铁离子和镍离子的总浓度为0.1重量％以下，优选为0.01重量％以下。 由于电解液中含有的铁离子和镍离子的总浓度低，所以抑制了由铝构成的电极集电体的腐蚀，提高了熔融盐电池的循环寿命。

公开(公告)号：US20130130124A1

公开(公告)日：2013-05-23

申请号：US13812546

申请日：2011-07-25

申请人： Atsushi Fukunaga ,  Shinji Inazawa ,  Masatoshi Majima ,  Atsushi Yamaguchi ,  Koji Nitta ,  Shoichiro Sakai

发明人： Atsushi Fukunaga ,  Shinji Inazawa ,  Masatoshi Majima ,  Atsushi Yamaguchi ,  Koji Nitta ,  Shoichiro Sakai

IPC分类号： H01M4/66 ,  H01M4/04

CPC分类号： H01M4/661 ,  H01M4/0402 ,  H01M4/387 ,  H01M4/667 ,  H01M4/80 ,  H01M4/808 ,  H01M10/39

摘要： A main object is to produce a porous metal body that can be used as a battery electrode, in particular, that can be used as a negative electrode of a molten-salt battery using sodium. The porous metal body includes a hollow metal skeleton composed of a metal layer containing nickel or copper as a main component, and an aluminum covering layer that covers at least an outer surface of the metal skeleton. The porous metal body further includes a tin covering layer that covers the aluminum covering layer, and is used as a battery electrode. Preferably, the porous metal body has continuous pores due to a three-dimensional network structure thereof, and has a porosity of 90% or more.

摘要翻译： 主要的目的是制造可用作电池电极的多孔金属体，特别是可以用作使用钠的熔盐电池的负极。 多孔金属体包括由以镍或铜为主要成分的金属层构成的中空金属骨架以及覆盖金属骨架的至少外表面的铝覆盖层。 多孔金属体还包括覆盖铝覆盖层的锡覆盖层，并且用作电池电极。 优选地，多孔金属体由于其三维网状结构而具有连续的孔，并且具有90％以上的孔隙率。

公开(公告)号：US09269941B2

公开(公告)日：2016-02-23

申请号：US13879962

申请日：2011-10-19

申请人： Shoichiro Sakai ,  Atsushi Fukunaga ,  Atsushi Yamaguchi ,  Koji Nitta ,  Masatoshi Majima ,  Shinji Inazawa

发明人： Shoichiro Sakai ,  Atsushi Fukunaga ,  Atsushi Yamaguchi ,  Koji Nitta ,  Masatoshi Majima ,  Shinji Inazawa

IPC分类号： H01M2/02 ,  H01M2/26 ,  H01M2/18 ,  H01M10/04 ,  H01M10/39

CPC分类号： H01M2/266 ,  H01M2/18 ,  H01M2/263 ,  H01M10/0459 ,  H01M10/3909 ,  H01M10/3981 ,  H01M10/399 ,  H01M2300/0048

摘要： A molten-salt battery is provided with rectangular plate-like negative electrodes (21) and rectangular plate-like positive electrodes (41) each housed in a bag-shaped separator (31). The negative electrodes (21) and positive electrodes (41) are arranged laterally and alternately in a standing manner. A lower end of a rectangular tab (22) for collecting current is joined to an upper end of each negative electrode (21) close to a side wall (1A) of a container body (1). The upper ends of the tabs (22) are joined to the lower surface of a rectangular plate-like tab lead (23). A lower end of a rectangular tab (42) for collecting current is joined to an upper end of each positive electrode (41) close to a side wall (1B) of the container body (1). The upper ends of the tabs (42) are joined to the lower surface of a rectangular plate-like tab lead (43).

摘要翻译： 熔盐电池设置有矩形板状负极（21）和矩形板状的正极（41），各自容纳在袋状隔板（31）中。 负极（21）和正极（41）以直立的方式横向和交替地布置。 用于收集电流的矩形突片（22）的下端接合到靠近容器主体（1）的侧壁（1A）的每个负极（21）的上端。 突片（22）的上端与矩形板状突片引线（23）的下表面接合。 用于收集电流的矩形突片（42）的下端接合到靠近容器主体（1）的侧壁（1B）的每个正电极（41）的上端。 突片（42）的上端部与矩形的板状突片（43）的下表面接合。

公开(公告)号：US20130224568A1

公开(公告)日：2013-08-29

申请号：US13882210

申请日：2011-10-28

申请人： Atsushi Fukunaga ,  Shoichiro Sakai ,  Koji Nitta ,  Atsushi Yamaguchi ,  Masatoshi Majima ,  Shinji Inazawa

发明人： Atsushi Fukunaga ,  Shoichiro Sakai ,  Koji Nitta ,  Atsushi Yamaguchi ,  Masatoshi Majima ,  Shinji Inazawa

IPC分类号： H01M2/02

CPC分类号： H01M2/02 ,  H01M2/0202 ,  H01M2/024 ,  H01M2/025 ,  H01M2/0277 ,  H01M2/0287 ,  H01M2/18 ,  H01M10/399

摘要： A plurality of rectangular plate-like negative electrodes and a plurality of rectangular plate-like positive electrodes are laterally stacked so as to face each other alternately with rectangular plate-like separators being respectively interposed therebetween, and are housed in a battery container formed of an aluminum alloy. The inner surface of the battery container is insulated by forming an alumite coating film thereon. Rectangular tabs (lead wires) for drawing a current from the positive electrodes are connected to one another via a tab lead, and rectangular tabs for drawing a current from the negative electrodes are connected to one another via a tab lead.

摘要翻译： 多个矩形板状负极和多个矩形板状正电极横向堆叠成彼此交替地彼此面对的矩形板状隔板，并且容纳在由 铝合金。 电池容器的内表面通过在其上形成耐氧化铝膜而被绝缘。 用于从正极吸取电流的矩形接头（引线）通过接头引线彼此连接，并且用于从负极吸取电流的矩形接头通过接头引线相互连接。

公开(公告)号：US20120115002A1

公开(公告)日：2012-05-10

申请号：US13252298

申请日：2011-10-04

申请人： Atsushi Fukunaga ,  Shoichiro Sakai ,  Chihiro Hiraiwa ,  Koji Nitta ,  Masatoshi Majima ,  Shinji Inazawa

发明人： Atsushi Fukunaga ,  Shoichiro Sakai ,  Chihiro Hiraiwa ,  Koji Nitta ,  Masatoshi Majima ,  Shinji Inazawa

IPC分类号： H01M10/39

CPC分类号： H01M10/399

摘要： To provide a molten salt battery which is highly safe and has long charge/discharge cycle life. The molten salt battery of the present invention includes a negative electrode 1 in which a negative electrode active material 12 is predominantly composed of carbon such as hard carbon. The negative electrode active material 12 is surface-treated for imparting hydrophilicity to the negative electrode active material 12 to improve the affinity for the molten salt. Further, a transition metal such as iron is added to the negative electrode active material 12 predominantly composed of hard carbon in order to enhance the affinity for the active material. The molten salt battery has higher safety in production and use and longer charge/discharge cycle life than conventional molten salt batteries using metallic sodium as an electrode.

摘要翻译： 提供高度安全且具有长充放电循环寿命的熔盐电池。 本发明的熔盐电池包括负极1，其中负极活性物质12主要由诸如硬碳的碳组成。 对负极活性物质12进行表面处理，赋予负极活性物质12亲水性，提高对熔融盐的亲和性。 此外，为了提高对活性物质的亲和性，向负极活性物质12添加铁等过渡金属，主要由硬碳构成。 与使用金属钠作为电极的常规熔盐电池相比，熔盐电池的生产和使用安全性更高，充电/放电循环寿命更长。

公开(公告)号：US20120208079A1

公开(公告)日：2012-08-16

申请号：US13252290

申请日：2011-10-04

申请人： Shoichiro Sakai ,  Atsushi Fukunaga ,  Koji Nitta ,  Masatoshi Majima ,  Shinji Inazawa

发明人： Shoichiro Sakai ,  Atsushi Fukunaga ,  Koji Nitta ,  Masatoshi Majima ,  Shinji Inazawa

IPC分类号： H01M10/02 ,  B05D5/12 ,  H01M4/46 ,  H01M4/64 ,  H01M4/42

CPC分类号： H01M4/661 ,  H01M4/0438 ,  H01M4/38 ,  H01M4/667 ,  H01M10/3909 ,  H01M10/399

摘要： A negative electrode precursor material is provided for preparing a negative electrode, which has a reduced thickness, good current collecting performance, and suppresses deformation and generation of dendrites during operation. A molten salt battery comprises a positive electrode formed by providing an active material film on an Al current collector, a separator comprising a glass cloth impregnated with a molten salt as an electrolyte, and the negative electrode formed by providing a Zn film and an active material film on an Al, current collector, which are respectively contained in a substantially rectangular parallelepiped Al case. The active material absorbs and releases Na ions contained in the molten salt.

摘要翻译： 提供负极前体材料用于制备负极，其具有减小的厚度，良好的集流性能，并且在操作期间抑制变形和产生枝晶。 熔融盐电池包括通过在Al集电体上提供活性材料膜而形成的正极，包含浸渍有作为电解质的熔融盐的玻璃布的隔膜，以及通过提供Zn膜和活性物质形成的负极 Al集电体上的膜分别包含在大致长方体的Al壳中。 活性物质吸收并释放熔融盐中所含的Na离子。