摘要:
Provided is a method for producing a negative electrode for an electric storage device, the method comprising the steps of: preparing a negative electrode composition comprising a negative electrode active material that reversibly carries a sodium ion, metal sodium, and a liquid dispersion medium for dispersing them; allowing a negative electrode current collector to hold the negative electrode composition; evaporating at least part of the liquid dispersion medium from the negative electrode composition held by the negative electrode current collector, thereby giving a negative electrode precursor comprising the negative electrode active material, the metal sodium, and the negative electrode current collector; and bringing the negative electrode precursor into contact with an electrolyte having sodium ion conductivity, thereby doping the negative electrode active material with sodium eluted from the metal sodium.
摘要:
A separator for use in a molten salt battery has the problem that due to usage specific to the molten salt battery, the separator is placed under mechanical, thermal and chemical stress, so that cracking or rupture easily occurs, leading to a degradation in battery performance such as an internal short-circuit. The molten salt battery of the present invention includes a separator containing a metal oxide, particularly aluminum oxide and/or zirconium oxide in an amount of 75% or more. The separator improves mechanical, thermal and chemical resistance, and thus an internal short-circuit ascribable to the separator is hard to occur, so that the molten salt battery can be stably operated for a long period of time. The separator has high heat stability, so that the safety of the molten salt battery can be improved.
摘要:
There is provided with a molten-salt battery which can prevent relative positional displacement between a positive electrode or a negative electrode and a separator. Both faces of the negative electrodes are covered with the separators which are formed to bend along a lower end part of the respective positive electrodes. The separators respectively have a V-shaped or U-shaped cross section, a bent part is formed to have a valley-like (groove-like) shape, and the respective bent parts are disposed along a lower side of the positive electrodes. The positive electrodes having both faces covered with the respective separators as described above and the negative electrodes are laminated alternately. The dimension of the separators after being bent is made larger than that of the positive electrodes and the negative electrodes by 1 to 10%.
摘要:
Provided is a charge/discharge control device 1 for controlling charge and discharge of a molten salt battery 2 containing molten salt as an electrolyte, the device including: a temperature sensor 12 configured to measure a temperature of the molten salt battery 2; and a control unit 13 configured to control a current value for charge and discharge such that when the temperature measured by the temperature sensor 12 is equal to or lower than a predetermined temperature, the current value for charge and discharge decreases as the measured temperature becomes lower, the predetermined temperature being higher than a melting point of the molten salt.
摘要:
The molten salt used as an electrolyte of a molten salt battery is a mixed salt between a salt in which the anion is an ion represented by [R1-SO2—N—SO2—R2]— such as FSA ion and the cation is Na ion, and a salt in which the cation is an alkali metal ion other than Na ion or an alkaline earth metal ion. The active material of a positive electrode 1 is a metal oxide represented by NaxM1yM21-yO2 (wherein M1 is Fe or Ni, M2 is Mn or Ti, 0
摘要:
According to this production method, the water content of a mixture of a chromium oxide (Cr2O3) powder and a sodium carbonate (Na2CO3) powder is brought to 1000 ppm or less, and the mixture is heated in an inert gas atmosphere at a calcination temperature (850 DEG C.) where the sodium carbonate and the chromium oxide undergo a calcination reaction. Sodium chromite is thereby obtained.
摘要翻译:根据该制造方法,将氧化铬(Cr 2 O 3)粉末和碳酸钠(Na 2 CO 3)粉末的混合物的含水量设定为1000ppm以下,并将混合物在惰性气体气氛中以煅烧温度 (850℃),其中碳酸钠和氧化铬经历煅烧反应。 从而得到亚铬酸钠。
摘要:
KN(SO2F)2 is synthesized by adding HN(SO2Cl)2 dropwise to KF to form an intermediate product, and then allowing the intermediate product and KF to react with each other in an aqueous solvent.
摘要:
A molten-salt battery is provided with rectangular plate-like negative electrodes (21) and rectangular plate-like positive electrodes (41) each housed in a bag-shaped separator (31). The negative electrodes (21) and positive electrodes (41) are arranged laterally and alternately in a standing manner. A lower end of a rectangular tab (22) for collecting current is joined to an upper end of each negative electrode (21) close to a side wall (1A) of a container body (1). The upper ends of the tabs (22) are joined to the lower surface of a rectangular plate-like tab lead (23). A lower end of a rectangular tab (42) for collecting current is joined to an upper end of each positive electrode (41) close to a side wall (1B) of the container body (1). The upper ends of the tabs (42) are joined to the lower surface of a rectangular plate-like tab lead (43).
摘要:
Provided is a molten salt battery whose cycle life is improved by using an electrolyte that is unlikely to cause corrosion of aluminum. In the molten salt battery of the present invention, the total concentration of iron ions and nickel ions contained as impurities in the electrolyte composed of a molten salt is set to be 0.1% by weight or less, preferably 0.01% by weight or less. Because of the low total concentration of iron ions and nickel ions contained in the electrolyte, corrosion of the electrode current collector composed of aluminum is inhibited, and the cycle life of the molten salt battery is improved.
摘要:
A main object is to produce a porous metal body that can be used as a battery electrode, in particular, that can be used as a negative electrode of a molten-salt battery using sodium. The porous metal body includes a hollow metal skeleton composed of a metal layer containing nickel or copper as a main component, and an aluminum covering layer that covers at least an outer surface of the metal skeleton. The porous metal body further includes a tin covering layer that covers the aluminum covering layer, and is used as a battery electrode. Preferably, the porous metal body has continuous pores due to a three-dimensional network structure thereof, and has a porosity of 90% or more.