公开(公告)号：US20120115002A1

公开(公告)日：2012-05-10

申请号：US13252298

申请日：2011-10-04

申请人： Atsushi Fukunaga ,  Shoichiro Sakai ,  Chihiro Hiraiwa ,  Koji Nitta ,  Masatoshi Majima ,  Shinji Inazawa

发明人： Atsushi Fukunaga ,  Shoichiro Sakai ,  Chihiro Hiraiwa ,  Koji Nitta ,  Masatoshi Majima ,  Shinji Inazawa

IPC分类号： H01M10/39

CPC分类号： H01M10/399

摘要： To provide a molten salt battery which is highly safe and has long charge/discharge cycle life. The molten salt battery of the present invention includes a negative electrode 1 in which a negative electrode active material 12 is predominantly composed of carbon such as hard carbon. The negative electrode active material 12 is surface-treated for imparting hydrophilicity to the negative electrode active material 12 to improve the affinity for the molten salt. Further, a transition metal such as iron is added to the negative electrode active material 12 predominantly composed of hard carbon in order to enhance the affinity for the active material. The molten salt battery has higher safety in production and use and longer charge/discharge cycle life than conventional molten salt batteries using metallic sodium as an electrode.

摘要翻译： 提供高度安全且具有长充放电循环寿命的熔盐电池。 本发明的熔盐电池包括负极1，其中负极活性物质12主要由诸如硬碳的碳组成。 对负极活性物质12进行表面处理，赋予负极活性物质12亲水性，提高对熔融盐的亲和性。 此外，为了提高对活性物质的亲和性，向负极活性物质12添加铁等过渡金属，主要由硬碳构成。 与使用金属钠作为电极的常规熔盐电池相比，熔盐电池的生产和使用安全性更高，充电/放电循环寿命更长。

公开(公告)号：US09276241B2

公开(公告)日：2016-03-01

申请号：US13335242

申请日：2011-12-22

申请人： Koji Nitta ,  Shoichiro Sakai ,  Shinji Inazawa ,  Chihiro Hiraiwa ,  Atsushi Fukunaga ,  Masatoshi Majima

发明人： Koji Nitta ,  Shoichiro Sakai ,  Shinji Inazawa ,  Chihiro Hiraiwa ,  Atsushi Fukunaga ,  Masatoshi Majima

IPC分类号： H01M2/02 ,  H01M10/054 ,  H01M10/0569

CPC分类号： H01M2/025 ,  H01M2/0285 ,  H01M4/387 ,  H01M4/483 ,  H01M10/054 ,  H01M10/0563 ,  H01M10/0569 ,  H01M2300/0022 ,  H01M2300/0045

摘要： The case for a molten salt battery is used for a molten salt battery containing as an electrolyte a molten salt containing sodium ions. The case is formed of aluminum or an aluminum alloy containing 90% by mass or more of aluminum.

摘要翻译： 熔融盐电池的情况用于含有钠离子的熔融盐作为电解质的熔盐电池。 该壳由铝或含有90质量％以上的铝的铝合金形成。

公开(公告)号：US20130224566A1

公开(公告)日：2013-08-29

申请号：US13879560

申请日：2011-10-17

申请人： Shoichiro Sakai ,  Atsushi Fukunaga ,  Koji Nitta ,  Masatoshi Majima ,  Shinji Inazawa

发明人： Shoichiro Sakai ,  Atsushi Fukunaga ,  Koji Nitta ,  Masatoshi Majima ,  Shinji Inazawa

IPC分类号： H01M2/04

CPC分类号： H01M2/04 ,  H01M2/0247 ,  H01M2/0252 ,  H01M2/0439 ,  H01M2/0447 ,  H01M2/0473 ,  H01M2/24 ,  H01M10/399

摘要： This molten-salt battery is provided with a battery container for housing a power generation element that contains molten salt. The battery container is provided with a container body (1) and a lid (7). An opening (1E) is provided in the upper surface of the container body (1). The lid (7) is fitted in the opening (1E) of the container body (1) and is welded to the container body (1). A step (1G) is formed to the opening (1E) of the container body (1) along the inner edge of the container body (1). By means of the step (1G), the rim (7A) of the lid (7) is supported with respect to the upper corner of side walls (1A, 1B). Laser light is radiated from above to the rim (7A) of the lid (7) and the upper surface of the side walls (1A, 1B) adjacent thereto. In this way, the rim (7A) of the lid (7) is welded to the container body (1). The molten-salt battery connected body is configured from a plurality of molten-salt batteries. The molten-salt batteries are connected aligned in the horizontal direction in the state of the outer peripheral surfaces of the container bodies (1) of adjacent molten-salt batteries being caused to face each other.

摘要翻译： 该熔盐电池设置有容纳含有熔融盐的发电元件的电池容器。 电池容器设置有容器主体（1）和盖（7）。 在容器主体（1）的上表面设有开口（1E）。 盖（7）装配在容器主体（1）的开口（1E）中并焊接到容器主体（1）上。 沿着容器主体（1）的内边缘向容器主体（1）的开口（1E）形成台阶（1G）。 通过步骤（1G），盖（7）的边缘（7A）相对于侧壁（1A，1B）的上角被支撑。 激光从上方辐射到盖（7）的边缘（7A）和与其相邻的侧壁（1A，1B）的上表面。 以这种方式，盖（7）的边缘（7A）被焊接到容器主体（1）上。 熔盐电池连接体由多个熔盐电池构成。 在相邻的熔盐电池的容器主体（1）的外周表面的状态下，使熔盐电池在水平方向上连接成对准。

公开(公告)号：US20120237827A1

公开(公告)日：2012-09-20

申请号：US13368643

申请日：2012-02-08

申请人： Atsushi FUKUNAGA ,  Shinji Inazawa ,  Masatoshi Majima ,  Atsushi Yamaguchi ,  Koji Nitta ,  Shoichiro Sakai

发明人： Atsushi FUKUNAGA ,  Shinji Inazawa ,  Masatoshi Majima ,  Atsushi Yamaguchi ,  Koji Nitta ,  Shoichiro Sakai

IPC分类号： H01M4/38 ,  B32B15/01 ,  B32B5/18

CPC分类号： C23C28/023 ,  C25D1/006 ,  C25D3/30 ,  C25D3/44 ,  C25D3/66 ,  H01M4/661 ,  H01M4/808 ,  H01M10/399 ,  Y10T428/12479

摘要： A porous metal body includes a porous skeleton that forms a three-dimensional network structure and includes an aluminum layer having a thickness of 1 to 100 μm, and tin layers disposed on an internal surface and an external surface of the aluminum layer. Such a porous metal body can be produced by an internal-tin-layer formation step of forming a tin layer on a surface of a resin molded body having a three-dimensional network structure; an aluminum-skeleton formation step of forming an aluminum layer serving as an aluminum skeleton on a surface of the internal tin layer; an external-tin-layer formation step of forming a tin layer on a surface of the aluminum skeleton; and a resin removal step of removing the resin molded body, the resin removal step being performed after the aluminum-skeleton formation step or after the external-tin-layer formation step.

摘要翻译： 多孔金属体包括形成三维网状结构的多孔骨架，并且包括厚度为1〜100μm的铝层和设置在铝层的内表面和外表面上的锡层。 这种多孔金属体可以通过在具有三维网状结构的树脂成型体的表面上形成锡层的内锡层形成工序来制造; 在所述内部锡层的表面上形成作为铝骨架的铝层的铝骨架形成工序; 在铝骨架的表面上形成锡层的外锡层形成工序; 以及去除树脂成形体的树脂除去工序，在铝 - 骨架形成工序之后或在外部锡层形成工序之后进行树脂除去工序。

公开(公告)号：US20140170458A1

公开(公告)日：2014-06-19

申请号：US13989223

申请日：2011-11-07

申请人： Koji Nitta ,  Shinji Inazawa ,  Masatoshi Majima ,  Atsushi Yamaguchi ,  Shoichiro Sakai ,  Atsushi Fukunaga ,  Rika Hagiwara ,  Toshiyuki Nohira ,  Kazuhiko Matsumoto

发明人： Koji Nitta ,  Shinji Inazawa ,  Masatoshi Majima ,  Atsushi Yamaguchi ,  Shoichiro Sakai ,  Atsushi Fukunaga ,  Rika Hagiwara ,  Toshiyuki Nohira ,  Kazuhiko Matsumoto

IPC分类号： H01M10/39

CPC分类号： H01M10/399 ,  H01M2300/0048

摘要： A separator (3) of a molten salt battery is impregnated with a molten salt that serves as the electrolyte. The molten salt contains, as cations, at least one kind of ions selected from among quaternary ammonium ions, imidazolium ions, imidazolinium ions, pyridinium ions, pyrrolidinium ions, piperidinium ions, morpholinium ions, phosphonium ions, piperazinium ions and sulfonium ions in addition to sodium ions. These cations do not have adverse effects on a positive electrode (1). In addition, the melting point of the molten salt, which contains sodium ions and the above-mentioned cations, is significantly lower than the operating temperature of sodium-sulfur batteries, said operating temperature being 280-360 DEG C. Consequently, the molten salt battery is capable of operating at lower temperatures than sodium-sulfur batteries.

摘要翻译： 熔融盐电池的分离器（3）浸渍有用作电解质的熔融盐。 作为阳离子，熔融盐除了季铵离子，咪唑鎓离子，咪唑啉鎓离子，吡啶鎓离子，吡咯烷鎓离子，哌啶鎓离子，吗啉鎓离子，鏻离子，哌嗪鎓离子和锍离子中外还含有至少一种离子 钠离子。 这些阳离子对正极没有不利影响（1）。 此外，含有钠离子和上述阳离子的熔融盐的熔点显着低于钠硫电池的工作温度，所述操作温度为280-360℃。因此，熔融盐 电池能够在低于钠硫电池的温度下工作。

公开(公告)号：US20120208079A1

公开(公告)日：2012-08-16

申请号：US13252290

申请日：2011-10-04

申请人： Shoichiro Sakai ,  Atsushi Fukunaga ,  Koji Nitta ,  Masatoshi Majima ,  Shinji Inazawa

发明人： Shoichiro Sakai ,  Atsushi Fukunaga ,  Koji Nitta ,  Masatoshi Majima ,  Shinji Inazawa

IPC分类号： H01M10/02 ,  B05D5/12 ,  H01M4/46 ,  H01M4/64 ,  H01M4/42

CPC分类号： H01M4/661 ,  H01M4/0438 ,  H01M4/38 ,  H01M4/667 ,  H01M10/3909 ,  H01M10/399

摘要： A negative electrode precursor material is provided for preparing a negative electrode, which has a reduced thickness, good current collecting performance, and suppresses deformation and generation of dendrites during operation. A molten salt battery comprises a positive electrode formed by providing an active material film on an Al current collector, a separator comprising a glass cloth impregnated with a molten salt as an electrolyte, and the negative electrode formed by providing a Zn film and an active material film on an Al, current collector, which are respectively contained in a substantially rectangular parallelepiped Al case. The active material absorbs and releases Na ions contained in the molten salt.

摘要翻译： 提供负极前体材料用于制备负极，其具有减小的厚度，良好的集流性能，并且在操作期间抑制变形和产生枝晶。 熔融盐电池包括通过在Al集电体上提供活性材料膜而形成的正极，包含浸渍有作为电解质的熔融盐的玻璃布的隔膜，以及通过提供Zn膜和活性物质形成的负极 Al集电体上的膜分别包含在大致长方体的Al壳中。 活性物质吸收并释放熔融盐中所含的Na离子。

公开(公告)号：US20120208068A1

公开(公告)日：2012-08-16

申请号：US13252295

申请日：2011-10-04

申请人： Atsushi Fukunaga ,  Shoichiro Sakai ,  Chihiro Hiraiwa ,  Koji Nitta ,  Masatoshi Majima ,  Shinji Inazawa

发明人： Atsushi Fukunaga ,  Shoichiro Sakai ,  Chihiro Hiraiwa ,  Koji Nitta ,  Masatoshi Majima ,  Shinji Inazawa

IPC分类号： H01M2/16 ,  B05D5/12 ,  B05D3/06 ,  H01M10/04

CPC分类号： H01M10/0525 ,  H01M2/145 ,  H01M2/1653 ,  H01M2/18 ,  H01M10/0568 ,  H01M10/0569 ,  H01M2300/0048 ,  Y10T29/49115

摘要： A separator of a molten salt battery made of a porous resin sheet. The separator is improved in wettability to a molten salt by giving hydrophilicity to the resin sheet. In the case of a fluororesin sheet, the sheet is impregnated with water, and irradiated with ultraviolet rays so that C—F bonds in the fluororesin are cleaved and the resultant reacts with water to generate hydrophilic groups, such as OH groups, in each surface layer thereof. The separator gains hydrophilicity through the hydrophilic groups. The separator made of the resin can be made into a bag form. In a molten salt battery having the bag-form separator, the growth of a dendrite is prevented.

摘要翻译： 由多孔树脂片制成的熔盐电池的隔板。 通过赋予树脂片亲水性，隔膜对熔融盐的润湿性提高。 在氟树脂片的情况下，用水浸渍片材，并用紫外线照射，使氟树脂中的C-F键断开，并与水反应以在每个表面中产生诸如OH基团的亲水基团 层。 分离器通过亲水基团获得亲水性。 由树脂制成的隔板可以制成袋形。 在具有袋状分离器的熔盐电池中，防止枝晶的生长。

公开(公告)号：US20120171524A1

公开(公告)日：2012-07-05

申请号：US13252289

申请日：2011-10-04

申请人： Chihiro Hiraiwa ,  Masatoshi Majima ,  Koji Nitta ,  Shoichiro Sakai ,  Atsushi Fukunaga ,  Shinji Inazawa

发明人： Chihiro Hiraiwa ,  Masatoshi Majima ,  Koji Nitta ,  Shoichiro Sakai ,  Atsushi Fukunaga ,  Shinji Inazawa

IPC分类号： H01M10/50

CPC分类号： H01M10/399 ,  H01M10/486 ,  H01M10/613 ,  H01M10/615 ,  H01M10/6568 ,  H01M10/657

摘要： In a molten salt battery device, molten salt batteries are arranged in a container to cause a space to be present around the molten salt batteries, and a heating medium is filled into the space around the molten salt batteries. When an electrothermal heater is used to control the temperature of the heating medium through a temperature controlling section, the heating medium is caused to flow. Between the flowing heating medium and the molten salt batteries, heat is exchanged, whereby the molten salt battery device controls the temperature of the molten salt batteries. Since the molten salt batteries attain the heat exchange with the heating medium, which surrounds the batteries, the internal temperature thereof is evenly controlled. Moreover, the molten salt battery device makes it possible to lower the temperature of the heating medium to cool the molten salt batteries easily.

摘要翻译： 在熔融盐电池装置中，将熔融盐电池配置在容器内，使熔融盐电池周围存在空间，将加热介质填充在熔盐电池周围的空间内。 当使用电热加热器通过温度控制部分控制加热介质的温度时，使加热介质流动。 在流动的加热介质和熔融盐电池之间，更换热量，由此熔融盐电池装置控制熔融盐电池的温度。 由于熔融盐电池与包围电池的加热介质进行热交换，所以其内部温度被均匀地控制。 此外，熔融盐电池装置可以使加热介质的温度降低，容易地冷却熔融盐电池。

公开(公告)号：US20130295003A1

公开(公告)日：2013-11-07

申请号：US13980640

申请日：2011-09-26

申请人： Atsushi Fukunaga ,  Shoichiro Sakai ,  Koji Nitta ,  Masatoshi Majima ,  Shinji Inazawa

发明人： Atsushi Fukunaga ,  Shoichiro Sakai ,  Koji Nitta ,  Masatoshi Majima ,  Shinji Inazawa

IPC分类号： C01D1/02

CPC分类号： C01D1/02 ,  C01G37/00 ,  C01G37/14 ,  C01P2002/72

摘要： According to this production method, the water content of a mixture of a chromium oxide (Cr2O3) powder and a sodium carbonate (Na2CO3) powder is brought to 1000 ppm or less, and the mixture is heated in an inert gas atmosphere at a calcination temperature (850 DEG C.) where the sodium carbonate and the chromium oxide undergo a calcination reaction. Sodium chromite is thereby obtained.

摘要翻译： 根据该制造方法，将氧化铬（Cr 2 O 3）粉末和碳酸钠（Na 2 CO 3）粉末的混合物的含水量设定为1000ppm以下，并将混合物在惰性气体气氛中以煅烧温度 （850℃），其中碳酸钠和氧化铬经历煅烧反应。 从而得到亚铬酸钠。

公开(公告)号：US20130294997A1

公开(公告)日：2013-11-07

申请号：US13978980

申请日：2012-01-13

申请人： Atsushi Fukunaga ,  Shoichiro Sakai ,  Koji Nitta ,  Atsushi Yamaguchi ,  Masatoshi Majima ,  Shinji Inazawa

发明人： Atsushi Fukunaga ,  Shoichiro Sakai ,  Koji Nitta ,  Atsushi Yamaguchi ,  Masatoshi Majima ,  Shinji Inazawa

IPC分类号： C01B21/086

CPC分类号： C01B21/086 ,  C01B21/093 ,  H01M10/0525 ,  H01M10/0568

摘要： KN(SO2F)2 is synthesized by adding HN(SO2Cl)2 dropwise to KF to form an intermediate product, and then allowing the intermediate product and KF to react with each other in an aqueous solvent.

摘要翻译： 通过向KF中滴加HN（SO2Cl）2以形成中间产物，然后使中间产物和KF在水性溶剂中彼此反应来合成KN（SO 2 F）2。