Thiocarboxylic acid derivatives
    17.
    发明授权
    Thiocarboxylic acid derivatives 失效
    硫代羧酸衍生物

    公开(公告)号:US5318945A

    公开(公告)日:1994-06-07

    申请号:US994254

    申请日:1992-12-21

    摘要: Thiocarboxylic acid derivatives useful as herbicides or plant growth regulators are of the general formula I ##STR1## where R.sup.1 is unsubstituted or substituted alkyl, unsubstituted or substituted cycloalkyl or cycloalkenyl, unsubstituted or substituted alkenyl or alkynyl or unsubstituted or substituted phenyl;R.sup.2 is halogen, alkyl, haloalkyl, alkoxy, haloalkoxy or alkylthio;X is nitrogen or CR.sup.6, where R.sup.6 is hydrogen or, together with R.sup.3, forms a C.sub.3 - or C.sub.4 -alkylene chain or C.sub.3 - or C.sub.4 -alkenylene chain in which a methylene group is replaced with oxygen;R.sup.3 is halogen, alkyl, haloalkyl, alkoxy, haloalkoxy or alkylthio or R.sup.3 is bonded to R.sup.6 as stated above to give a 5-membered or 6-membered ring;R.sup.4 is unsubstituted or substituted alkyl, unsubstituted or substituted alkenyl or alkynyl, an unsubstituted or substituted 5-membered or 6-membered heteroaromatic structure containing from one to three nitrogen atoms and/or one sulfur or oxygen atom, or unsubstituted or substituted phenyl or naphthyl;R.sup.4 and R.sup.5 together with the adjacent carbon atom form a 3-membered to 6-membered ring which may contain an oxygen or sulfur atom and may be substituted;R.sup.5 is hydrogen, alkyl, haloalkyl, alkoxy, haloalkoxy, or alkylthio;and Y and Z are each oxygen or sulfur.

    摘要翻译: 可用作除草剂或植物生长调节剂的二羧酸衍生物具有通式I其中R 1为未取代或取代的烷基,未取代或取代的环烷基或环烯基,未取代或取代的烯基或炔基或未取代或取代的苯基; R2是卤素,烷基,卤代烷基,烷氧基,卤代烷氧基或烷硫基; X是氮或CR 6,其中R6是氢或与R3一起形成其中亚甲基被氧取代的C3-或C4-亚烷基链或C3-或C4-亚烯基链; R3是卤素,烷基,卤代烷基,烷氧基,卤代烷氧基或烷硫基,或R3如上所述与R6键合,得到5元或6元环; R4是未取代或取代的烷基,未取代或取代的烯基或炔基,含有1至3个氮原子和/或一个硫或氧原子的未取代或取代的5元或6元杂芳族结构,或未取代或取代的苯基或萘基 ; R4和R5与相邻的碳原子一起形成可含有氧或硫原子并且可以被取代的3元至6元环; R5是氢,烷基,卤代烷基,烷氧基,卤代烷氧基或烷硫基; Y和Z各自为氧或硫。

    O-(oximino)ethylcyclohexenone oxime ethers and their use as herbicides
    18.
    发明授权
    O-(oximino)ethylcyclohexenone oxime ethers and their use as herbicides 失效
    O-(肟基)乙基环己烯酮肟醚及其作为除草剂的用途

    公开(公告)号:US5739085A

    公开(公告)日:1998-04-14

    申请号:US435450

    申请日:1995-05-05

    摘要: O-(Oximino)ethylcyclohexenone oxime ethers I ##STR1## (R.sup.1 and R.sup.2 =C.sub.1 -C.sub.6 -alkyl; R.sup.3 =unsubstituted or substituted phenyl, C.sub.1 -C.sub.4 -alkyl, C.sub.3 -C.sub.4 -alkenyl or C.sub.3 -C.sub.4 -alkynyl, which in each case can be substituted by halogen, C.sub.1 -C.sub.3 -alkyl, unsubstituted or substituted phenyl or unsubstituted or substituted phenoxy; R.sup.4 =C.sub.1 -C.sub.4 -alkoxy-C.sub.1 -C.sub.6 -alkyl or C.sub.1 -C.sub.4 -alkylthio-C.sub.1 -C.sub.6 -alkyl, unsubstituted or substituted phenylthio-C.sub.1 -C.sub.6 -alkyl, N-(C.sub.1 -C.sub.4 -alkylsulfonyl)-N-(C.sub.1 -C.sub.4 -alkyl)aminomethyl, unsubstituted or substituted C.sub.3 -C.sub.7 -cycloalkyl or C.sub.5 -C.sub.7 -cycloalkenyl, 5-membered saturated heterocyclyl having one or two oxygen and/or sulfur atoms, which can carry one to three substituents, saturated or unsaturated 6-/7-membered heterocyclyl having 1 or 2 non-adjacent oxygen and/or sulfur atoms, which can carry 1 to 3 substituents, 5-membered heteroaryl, containing 1 to 2 nitrogen atoms and an oxygen or sulfur atom, where the heteroaromatic can carry 1 to 3 substituents, phenyl or pyridyl, which can carry 1 to 3 of the following substituents: halogen, nitro, cyano, C.sub.1 -C.sub.4 -alkyl, C.sub.1 -C.sub.4 -alkoxy, C.sub.1 -C.sub.4 -alkylthio, C.sub.1 -C.sub.4 -haloalkyl, C.sub.3 -C.sub.6 -alkenyloxy, C.sub.3 -C.sub.6 -alkynyloxy and --NR.sup.a R.sup.b ; R.sup.a =H, C.sub.1 -C.sub.4 -alkyl, C.sub.3 -C.sub.6 -alkenyl or C.sub.3 -C.sub.6 -alkynyl; R.sup.b =H, C.sub.1 -C.sub.4 -alkyl, C.sub.3 -C.sub.6 -alkenyl, C.sub.3 -C.sub.6 -alkynyl, C.sub.1 -C.sub.6 -acyl or unsubstituted or substituted benzoyl) and their agriculturally utilizable salts and esters are described.

    摘要翻译: O-(肟基)乙基环己烯酮肟醚I(R1和R2 = C1-C6-烷基; R3 =未取代或取代的苯基,C1-C4-烷基,C3-C4-烯基或C3-C4-炔基,其中 在每种情况下可以被卤素,C 1 -C 3 - 烷基,未取代或取代的苯基或未取代或取代的苯氧基取代; R 4 = C 1 -C 4 - 烷氧基-C 1 -C 6烷基或C 1 -C 4 - 烷硫基-C 1 -C 6烷基 ,未取代或取代的苯硫基-C 1 -C 6烷基,N-(C 1 -C 4 - 烷基磺酰基)-N-(C 1 -C 4 - 烷基)氨基甲基,未取代或取代的C 3 -C 7 - 环烷基或C 5 -C 7 - 环烯基, 具有一个或两个氧和/或硫原子的五元饱和杂环基,其可以携带一至三个取代基,具有1或2个不相邻的氧和/或硫原子的饱和或不饱和的6-元/ 7元杂环基,其可携带1 包含1至2个氮原子和氧或硫原子的3个取代基,5元杂芳基,其中杂芳族可以带有1-3个取代基,苯基或吡啶基,其可以携带1至3个 C 1 -C 4烷氧基,C 1 -C 4 - 烷硫基,C 1 -C 4卤代烷基,C 3 -C 6 - 烯氧基,C 3 -C 6 - 炔氧基和-NR a R b;取代基:卤素,硝基,氰基, R a = H,C 1 -C 4 - 烷基,C 3 -C 6 - 烯基或C 3 -C 6炔基; 描述了Rb = H,C 1 -C 4 - 烷基,C 3 -C 6 - 烯基,C 3 -C 6炔基,C 1 -C 6酰基或未取代或取代的苯甲酰基)和它们的农业可利用的盐和酯。