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11.发明授权Cobalt-titania catalysts, process utilizing these catalysts for the preparation of hydrocarbons from synthesis gas, and process for the preparation of said catalysts 失效钴 - 二氧化钛催化剂，利用这些催化剂从合成气中制备烃的方法，以及制备所述催化剂的方法
公开(公告)号：US4962078A
公开(公告)日：1990-10-09
申请号：US252215
申请日：1988-10-03
CPC分类号： B01J37/0232 , B01J23/75 , B01J23/83 , B01J23/8896 , B01J23/8913 , C07C1/0435 , C07C1/0445 , C07C2521/06 , C07C2523/10 , C07C2523/12 , C07C2523/36 , C07C2523/46 , C07C2523/75 , C07C2523/83 , C07C2523/889
摘要： A supported particulate cobalt catalyst is formed by dispersing cobalt, alone or with a metal promoter, particularly rhenium, as a thin catalytically active film upon a particulate titania or titania-containing support, especially one wherein the rutile:anatase ratio of the support is at least about 3:2. This catalyst can be used to convert an admixture of carbon monoxide and hydrogen to a distillate fuel constituted principally of an admixture of linear paraffins and olefins, particularly a C.sub.10+ distillate, at high productivity, with low methane selectivity. A process is also disclosed for the preparation of these catalysts.
摘要翻译： 通过将单独或与金属促进剂，特别是铼作为薄催化活性膜分散在颗粒二氧化钛或二氧化钛载体上，特别是其中载体的金红石：锐钛矿比在 至少约3：2。 该催化剂可用于将一氧化碳和氢气的混合物转化为主要由线性链烷烃和烯烃，特别是C10 +馏出物的混合物组成的馏出物燃料，其生产率高，甲烷选择性低。 还公开了制备这些催化剂的方法。
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12.发明授权
公开(公告)号：US5817702A
公开(公告)日：1998-10-06
申请号：US850566
申请日：1997-05-02
摘要： A reversibly deactivated, particulate catalyst in a slurry hydrocarbon synthesis slurry is rejuvenated by circulating the slurry from a slurry body through (i) a gas disengaging zone to remove gas bubbles from the slurry, (ii) a catalyst rejuvenation zone in which a catalyst rejuvenating gas contacts the catalyst in the slurry to rejuvenate it and form a rejuvenated catalyst slurry and, (iii) back into the slurry body. Removing at least a portion of the gas bubbles improves the rejuvenation process.
摘要翻译： 通过（i）气体分离区使浆料从淤浆体循环而从浆液中除去气泡，使浆料烃合成浆料中的可逆失活的颗粒催化剂再生，（ii）催化剂再生区 气体与浆料中的催化剂接触以使其再生，并形成复原的催化剂浆料，和（iii）回到浆料体中。 去除至少一部分气泡改善了复原过程。
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公开(公告)号：US4065516A
公开(公告)日：1977-12-27
申请号：US642538
申请日：1975-12-19
IPC分类号： B01J27/00 , C07B61/00 , C07C1/00 , C07C2/62 , C07C5/25 , C07C9/14 , C07C9/16 , C07C11/02 , C07C67/00 , C07C3/54
CPC分类号： C07C2/62 , C07C9/16 , C07C2527/03 , C07C2531/025
摘要： Alkylates of enhanced product quality are prepared by isomerizing a mixed butenes-containing feed prior to alkylating said feed with a saturated hydrocarbon, preferably an isoparaffin, in the presence of a catalyst comprising a strong acid such as halosulfuric acid, trihalomethanesulfonic acid or mixtures thereof and a moderator containing at least one oxygen atom per molecule. A preferred catalyst is fluorosulfuric acid and water.
摘要翻译： 在含有强酸例如卤代硫酸，三卤甲烷磺酸或其混合物的催化剂存在下，用饱和烃，优选异链烷烃烷基化之前，将混合的含丁烯的进料异构化，从而制备提高产物质量的烷基化物， 每分子含有至少一个氧原子的调节剂。 优选的催化剂是氟代硫酸和水。
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公开(公告)号：US06284807B1
公开(公告)日：2001-09-04
申请号：US09134304
申请日：1998-08-14
申请人： Stephen C. Leviness , Charles J. Mart , William C. Behrmann , Stephen J. Hsia , Daniel R. Neskora
发明人： Stephen C. Leviness , Charles J. Mart , William C. Behrmann , Stephen J. Hsia , Daniel R. Neskora
IPC分类号： C07C104
CPC分类号： C10K1/34 , B01D53/14 , B01D53/8621 , B01D2255/20707 , B01D2257/406 , B01D2257/408 , C01B3/52 , C01B3/56 , C01B3/58 , C01B2203/0415 , C01B2203/0435 , C01B2203/0465 , C10G2/30
摘要： A slurry catalytic hydrocarbon synthesis process which employs a catalyst comprising a supported cobalt component achieves a short term catalyst half life of more than 10 days, by using a syngas feed which contains less than fifty parts per billion of a combined total amount of HCN and NH3.
摘要翻译： 使用包含负载的钴组分的催化剂的淤浆催化烃合成方法通过使用含有少于每十亿份HCN和NH 3的总量的合成气进料的短期催化剂半衰期超过10天 。
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公开(公告)号：US5288673A
公开(公告)日：1994-02-22
申请号：US994219
申请日：1992-12-18
CPC分类号： B01J38/10 , C07C1/045 , Y02P20/584
摘要： Catalyst in a slurry phase reactor is rejuvenated in said reactor using a substantially vertical draft tube fully immersed in the slurry which utilizes a rejuvenating gas injected substantially near the bottom of the substantially vertical draft tube whereby catalyst near the bottom of the slurry phase reactor is drawn up the draft tube and discharged from the top of the draft tube near the top of the slurry phase in said reactor, control over the rejuvenation temperature in the substantially vertical draft tube being achieved by means of insulating the draft tube and/or fitting the draft tube with heating or cooling means.
摘要翻译： 浆料相反应器中的催化剂在所述反应器中使用完全浸入浆料中的基本上垂直的导流管，在基本上垂直的引流管底部基本上接近注入的再生气体中，使得在浆料相反应器的底部附近的催化剂被拉伸 使引流管从引流管的顶部靠近所述反应器中的浆液相的顶部排出，控制在基本上垂直的通风管中的回弹温度，其通过使引流管绝缘和/或装配通风 管加热或冷却装置。
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16.发明授权Hydrocarbon synthesis catalyst slurry rejuvenation with gas disengagement (LAW 783) 有权烃合成催化剂浆液与气体分离反应（LAW 783）
公开(公告)号：US5973012A
公开(公告)日：1999-10-26
申请号：US182902
申请日：1998-10-30
CPC分类号： C07C1/045 , B01J38/48 , Y02P20/584
摘要： A reversibly deactivated, particulate catalyst in a slurry hydrocarbon synthesis slurry is rejuvenated by circulating the slurry from a slurry body through (i) a gas disengaging zone to remove gas bubbles from the slurry, (ii) a catalyst rejuvenation zone in which a catalyst rejuvenating gas contacts the catalyst in the slurry to rejuvenate it and form a rejuvenated catalyst slurry and, (iii) back into the slurry body. Removing at least a portion of the gas bubbles improves the rejuvenation process.
摘要翻译： 通过（i）气体分离区使浆料从淤浆体循环而从浆液中除去气泡，使浆料烃合成浆料中的可逆失活的颗粒催化剂再生，（ii）催化剂再生区 气体与浆料中的催化剂接触以使其再生，并形成复原的催化剂浆料，和（iii）回到浆料体中。 去除至少一部分气泡改善了复原过程。
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公开(公告)号：US4096199A
公开(公告)日：1978-06-20
申请号：US772636
申请日：1977-02-28
CPC分类号： C07C2/62 , C07C2527/03 , Y02P20/584
摘要： A process for regenerating an alkylation catalyst comprising fluorosulfuric acid, said catalyst being at least partially deactivated, which comprises:(1) contacting at least a portion of the fluorosulfuric acid with water to form an acid-water mixture, thereby converting at least a portion of the fluorosulfuric acid therein to hydrogen fluoride and sulfuric acid;(2) removing at least a portion of the hydrogen fluoride from said acid-water mixture formed in step (1) by contacting same with a stripping agent to form a gaseous phase containing hydrogen fluoride and said stripping agent and a liquid phase containing sulfuric acid and sludge;(3) cooling the gas phase formed in step (2) to a temperature sufficient to form a mixed phase comprising at least a liquid phase containing hydrogen fluoride; and(4) treating the mixed phase formed in step (3) with sulfur trioxide under substantially liquid phase conditions so as to regenerate the fluorosulfuric acid. In a preferred embodiment, at least a portion of the regenerated fluorosulfuric acid is recycled to the alkylation zone for use as an alkylation catalyst therein.
摘要翻译： 一种用于再生包含氟代硫酸的烷基化催化剂的方法，所述催化剂至少部分失活，其包括：
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公开(公告)号：US5866621A
公开(公告)日：1999-02-02
申请号：US851863
申请日：1997-05-06
CPC分类号： C10G2/342 , B01J8/0065 , B01J8/226
摘要： Particulate solids and gas are removed from a three phase hydrocarbon synthesis slurry of solid catalyst particles, gas and liquid, by successively passing slurry from a slurry body through solids and gas disengaging zones in fluid communication, with the solids disengaging zone upstream of the gas disengaging zone. This is accomplished using a solids and gas disengaging downcomer immersed in the slurry wherein solids are disengaged in a quiescent zone adjacent the slurry body, from which the solids reduced slurry passes through an enclosed cup in which gas is disengaged and removed. The bottom of the cup terminates in a downwardly depending downcomer which hydraulically feeds the densified, solids and gas reduced slurry to the bottom of the reactor or to filtration.
摘要翻译： 颗粒状固体和气体从固体催化剂颗粒（气体和液体）的三相烃合成浆液中通过连续地将浆料从淤浆体通过流体连通的固体和气体分离区域而被从气相分离的上游固体分离区域中除去 区。 这是使用浸入浆料中的固体和气体分离降液管来实现的，其中固体在邻近淤浆体的静止区域中脱离，固体还原浆液从该悬浮液通过封闭的杯，气体被分离和除去。 杯的底部终止于向下的降液管，其将致密化的，固体和气体减少的浆液液压地进料到反应器的底部或过滤。
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公开(公告)号：US4479926A
公开(公告)日：1984-10-30
申请号：US563076
申请日：1983-12-19
摘要： A method for treating a waste stream from an alkylation process is disclosed, where the waste stream comprises a fluoride, sulfuric acid, and an acid soluble oil. The method comprises combusting the waste stream, scrubbing the combustion products to remove, fluorine, and recovering sulfur from the combustion products.
摘要翻译： 公开了一种用于处理来自烷基化方法的废物流的方法，其中废物流包含氟化物，硫酸和酸溶性油。 该方法包括燃烧废物流，洗涤燃烧产物以除去，氟并从燃烧产物中回收硫。
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公开(公告)号：US4071576A
公开(公告)日：1978-01-31
申请号：US772643
申请日：1977-02-28
CPC分类号： C07C2/62 , C07C2527/03 , Y02P20/584
摘要： The deactivated fluorosulfuric acid catalyst in olefin-paraffin alkylation is regenerated by (1) contacting the acid phase with water to form an acid-water mixture (2) stripping the acid-water mixture with a paraffin to form a gaseous phase of hydrogen fluoride and paraffin (3) cooling the gaseous phase with liquid paraffin to form a liquid fluorosulfuric acid and a vapor containing fluorosulfuric acid, hydrogen fluoride and paraffin (4) treating the vapor with liquid SO.sub.3, and utilizing liquid fluorosulfuric acid in the treating step in countercurrent flow to the vapor to convert the hydrogen fluoride to regenerated fluorosulfuric acid, (5) the remaining gas phase containing paraffin and a minor amount of fluorosulfuric acid is cooled to condense all the fluorosulfuric acid to liquid and (6) the regenerated liquid fluorosulfuric acid is used as the countercurrent flowing liquid fluorosulfuric acid in treating step (4).
摘要翻译： 通过（1）使酸相与水接触以形成酸 - 水混合物（2）用石蜡汽提酸 - 水混合物以形成氟化氢的气相，再生烯烃 - 烷烃烷基化中的失活的氟代硫酸催化剂， 石蜡（3）用液体石蜡冷却气相以形成液体氟代硫酸和含氟硫酸，氟化氢和石蜡的蒸汽（4）用液体SO 3处理蒸汽，并在处理步骤中利用液体氟代硫酸逆流 蒸汽将氟化氢转化为再生的氟代硫酸，（5）将含有石蜡和少量氟代硫酸的剩余气相冷却，将所有氟代硫酸冷凝成液体，（6）使用再生液体氟代硫酸 作为处理工序（4）中的逆流流动性氟代硫酸。
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