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    Olefin oxidation process
    13.
    发明授权
    Olefin oxidation process 失效

    公开(公告)号：US4237331A

    公开(公告)日：1980-12-02

    申请号：US088717

    申请日：1979-10-26

    申请人： Paul R. Stapp

    发明人： Paul R. Stapp

    IPC分类号： C07C7/148 ,  C07C45/34 ,  C07C7/152

    CPC分类号： C07C45/34 ,  C07C7/14816

    摘要： Olefins are oxidized to carbonyl compounds, for example, 2-hexene to a mixture of 2-hexanone and 3-hexanone, with a palladium/copper/boric acid catalyst and a suitable surfactant or phase transfer agent. The reaction takes place in a diluent system comprising at least two liquid phases, wherein at least one liquid phase is an aqueous phase, and in the presence of free oxygen. The catalyst system can be used to oxidize internal olefins, as well as terminal olefins, at reasonable rates. The catalyst system can also be used for the selective oxidation of linear olefins in a mixed stream containing linear and branched olefins.

    Selective oxidation of acetylenes
    14.
    发明授权
    Selective oxidation of acetylenes 失效
    乙炔的选择性氧化

    公开(公告)号：US4035433A

    公开(公告)日：1977-07-12

    申请号：US704884

    申请日：1976-07-13

    申请人： Lewis E. Drehman ,  Thomas Davis

    发明人： Lewis E. Drehman ,  Thomas Davis

    IPC分类号： C07C7/148 ,  C07C7/02

    CPC分类号： C07C7/14816

    摘要： Acetylenic compounds are selectively removed from hydrocarbon mixtures containing same by oxidation in the presence of a copper chromite catalyst. In one embodiment, acetylenic compounds are selectively removed from streams containing C.sub.4 unsaturated hydrocarbons containing same by contacting oxygen and the stream with a catalyst of copper, chromium, and oxygen under oxidizing conditions.

    摘要翻译： 在亚铬酸铜催化剂的存在下，通过氧化从含有它们的烃混合物中选择性除去乙炔化合物。 在一个实施方案中，通过在氧化条件下使氧和所述物流与铜，铬和氧的催化剂接触，从含有其中含有C 4不饱和烃的流中选择性地除去炔属化合物。

    PROCESS
    17.
    发明申请
    PROCESS 有权
    处理

    公开(公告)号：US20170022121A1

    公开(公告)日：2017-01-26

    申请号：US15303928

    申请日：2015-03-20

    申请人： JOHNSON MATTHEY PUBLIC LIMITED COMPANY

    发明人： Peter Edward James ABBOTT

    IPC分类号： C07C1/04

    CPC分类号： C07C1/0435 ,  C07C1/04 ,  C07C1/12 ,  C07C7/14816 ,  C07C2523/46 ,  C07C2523/755 ,  C10G2/332 ,  C10K3/02 ,  C10L3/08 ,  C10L3/101 ,  C10L2290/141 ,  C07C9/04

    摘要： A process for producing a methane-containing gas mixture includes the steps of: (i) passing a first feed gas mixture including hydrogen and carbon dioxide through a bed of methanation catalyst to react a portion of the hydrogen with at least a portion of the carbon dioxide and form a methane-containing gas mixture containing residual hydrogen, (ii) adding an oxygen-containing gas to the methane-containing gas mixture containing residual hydrogen to form a second feed gas mixture, and (iii) passing the second feed gas mixture through a bed of an oxidation catalyst to react the residual hydrogen and oxygen to form a hydrogen depleted methane-containing gas mixture.

    摘要翻译： 描述了一种用于生产含甲烷的气体混合物的方法，其包括以下步骤：（i）将包含氢气和二氧化碳的第一进料气体混合物通过甲烷化催化剂床，使一部分氢与至少一部分 二氧化碳并形成含有残余氢的含甲烷气体混合物，（ii）向含有残留氢气的含甲烷气体混合物中加入含氧气体以形成第二进料气体混合物，和（iii）使第二进料 气体混合物通过氧化催化剂床反应残余的氢气和氧气以形成贫氢的含甲烷气体混合物。 第一进料气体混合物可以是包含氢气，二氧化碳和一氧化碳的合成气，并且可以在甲烷化步骤之前脱硫。

    METHOD FOR PURIFYING ORGANIC SOLVENT
    18.
    发明申请
    METHOD FOR PURIFYING ORGANIC SOLVENT 审中-公开
    净化有机溶剂的方法

    公开(公告)号：US20120059204A1

    公开(公告)日：2012-03-08

    申请号：US13320124

    申请日：2010-04-30

    申请人： Masaharu Kurooka ,  Tomohiro Itoh ,  Yuichi Makino

    发明人： Masaharu Kurooka ,  Tomohiro Itoh ,  Yuichi Makino

    IPC分类号： C07C17/395 ,  C10G29/00 ,  C07C7/00

    CPC分类号： C07C7/14816 ,  C07C7/005 ,  C07C7/13 ,  C07C17/389 ,  C07C17/395 ,  C10G2300/201 ,  C10G2400/18 ,  C07C25/10 ,  C07C25/06 ,  C07C25/22

    摘要： The present invention relates to a method for purifying a compound selected from a compound represented by the following general formula [1] or [2], a saturated aliphatic hydrocarbon having no substituent, or kerosene: (R represents a halogen atom or a lower alkyl group having 1 to 3 carbon atoms, and n represents an integer of 1 to 5); (R is the same as above, p and q independently represent an integer of 0 to 4, with the proviso that at least one of p and q is not 0), comprising: removing a impurity contained in said compound by a first step comprising contacting said compound with ozone gas, and then a second step comprising contacting said compound with an adsorbent selected from zeolite or a basic adsorbent.

    摘要翻译： 本发明涉及一种纯化选自下列通式[1]或[2]表示的化合物，无取代基的饱和脂族烃或煤油的化合物的方法：（R表示卤素原子或低级烷基 具有1至3个碳原子的基团，n表示1至5的整数）; （R与上述相同，p和q独立地表示0至4的整数，条件是p和q中的至少一个不为0），其包括：通过第一步骤除去所述化合物中所含的杂质，所述第一步骤包括 使所述化合物与臭氧气体接触，然后第二步骤包括使所述化合物与选自沸石或碱性吸附剂的吸附剂接触。

    Process for selectively separating hydrogen, or both hydrogen and carbon monoxide from olefinic hydrocarbons
    19.
    发明授权
    Process for selectively separating hydrogen, or both hydrogen and carbon monoxide from olefinic hydrocarbons 失效
    从烯烃选择性地分离氢气或氢气和一氧化碳两者的方法

    公开(公告)号：US5907076A

    公开(公告)日：1999-05-25

    申请号：US880611

    申请日：1997-06-23

    申请人： Di-Yi Ou ,  Stephen Neil Vaughn ,  Lawrence Gilbert Daniel

    发明人： Di-Yi Ou ,  Stephen Neil Vaughn ,  Lawrence Gilbert Daniel

    IPC分类号： B01D53/86 ,  C07C7/148 ,  C07C7/00

    CPC分类号： B01D53/8671 ,  B01D53/864 ,  B01D53/869 ,  C07C7/14816 ,  B01D2257/108 ,  B01D2257/504 ,  Y02P20/152

    摘要： A process is disclosed for the separation and removal of hydrogen, alone or together with carbon monoxide, from a mixture of these gases with olefinic hydrocarbons by contacting the mixture with oxygen over a catalyst at conditions sufficient to oxidize the hydrogen to form water while suppressing reaction of the reactive, unsaturated hydrocarbons. The catalyst contains at least one metal or metal oxide from Groups Ib, IIb, IIIa, IVa and Va of the Periodic Table, and the temperature of the reaction may range from about 40.degree. C. to 300.degree. C. and a pressure of about 14.7 psig to 1,000 psig, and the flow rate of the entering feed ranges from about 1 GHSV to about 50,000 GHSV. The process can be conducted using one, two or three reaction zones.

    摘要翻译： 公开了用于通过在足以氧化氢气以形成水同时抑制反应的条件下通过催化剂将混合物与氧气接触而将这些气体与烯烃的混合物单独或与一氧化碳一起分离和除去氢的方法 的反应性不饱和烃。 该催化剂含有元素周期表Ib，IIb，IIIa，IVa和Va族中至少一种金属或金属氧化物，反应温度范围为约40℃至300℃，压力约为 14.7psig至1,000psig，并且进料进料的流速范围为约1GHSV至约50,000GHSV。 该方法可以使用一个，两个或三个反应区进行。