Thermally Reversible Crosslinked Polyurethane

    公开(公告)号:US20170226271A1

    公开(公告)日:2017-08-10

    申请号:US15329017

    申请日:2015-07-29

    摘要: The polymer compositions described herein include the reaction product obtained from a mixture that includes: (i) a hydroxyl terminated intermediate containing at least one furan functional group; and (ii) a polyisocyanate component. The polymer compositions may further include a polymaleimide compound which may be (a) added as a component of the polymer composition, (b) incorporated into the structure of the hydroxyl terminated intermediate containing at least one furan functional group, or (c) both. The resulting polymer composition is capable of thermally reversible crosslinking. Also described are processes for making such polymer compositions, methods of reversibly increasing and/or decreasing the amount of crosslinking in a polymer composition thermally, through utilization of the Diels-Alder cycloaddition mechanism between furan functional groups and the polymaleimide compound, and methods of using the described furan functional group containing materials to prepare polymer compositions capable of thermally reversible crosslinking.

    Polyimide foam precursor and its use in reinforcing open-cell materials
    12.
    发明授权
    Polyimide foam precursor and its use in reinforcing open-cell materials 失效
    聚酰亚胺泡沫前体及其在增强开孔材料中的应用

    公开(公告)号:US4824874A

    公开(公告)日:1989-04-25

    申请号:US905718

    申请日:1986-09-09

    申请人: Kyu W. Lee

    发明人: Kyu W. Lee

    摘要: Open-cell structures are filled with polyimide foam formed in place by the use of a foam precursor in powdered form comprised of a combination of (a) the reaction product of an excess of organic polyisocyanate and a member selected from the group consisting of furfuryl alcohol and condensation products thereof, and (b) an organic polycarboxylic compound containing two carboxylic anhydride groups. The precursor is prepared by combining the species under conditions which favor the reaction of the furfuryl alcohol with the polyisocyanate, but not the polyimide-forming reaction. The polyimide-forming reaction itself is then performed by adding preselected amounts of the powdered precursor, depending on the desired ultimate density of the foam, to each cell of the open-cell structure, then heating to initiate the polyimide reaction, and permitting the carbon dioxide generated by the reaction to escape while confining the resulting foam to the cells.

    摘要翻译: 开孔结构填充有聚酰亚胺泡沫,通过使用粉末形式的泡沫前体填充形成的聚酰亚胺泡沫,粉末形式由以下组合组成:(a)过量有机多异氰酸酯的反应产物和选自糠醇 及其缩合产物,和(b)含有两个羧酸酐基团的有机多元羧酸化合物。 通过在有利于糠醇与多异氰酸酯的反应的条件下组合物种制备前体,而不是聚酰亚胺形成反应。 然后通过将预定量的粉末前体(取决于泡沫的期望的最终密度)加入到开孔结构的每个电池中,然后加热以引发聚酰亚胺反应,并允许碳 通过反应产生的二氧化碳逸出,同时将所得泡沫限制在细胞中。

    Crosslinkable composition comprising aminoepoxy resins-1
    13.
    发明授权
    Crosslinkable composition comprising aminoepoxy resins-1 失效
    包含氨基环氧树脂-1的可交联组合物

    公开(公告)号:US4582880A

    公开(公告)日:1986-04-15

    申请号:US566068

    申请日:1983-12-27

    申请人: Joseph W. Holubka

    发明人: Joseph W. Holubka

    摘要: A crosslinkable composition of matter is provided, which comprises certain diene functional aminoepoxy resin and certain functional aminoepoxy blocked dieneophile resin, which two resins are co-reactive at elevated cure temperature. The diene functional aminoepoxy resin comprises the reaction product of diepoxide with amine functional diene chain extending reactant and, optionally, monofunctional end-capping reactant such as monohydroxy functional diene. The blocked dieneophile functional aminoepoxy resin comprises the reaction product of diepoxide with amine functional blocked dieneophile chain extending reactant and, optionally, monofunctional end-capping reactant such as monohydroxy functional blocked dieneophile. The composition may further comprise crosslinking agent reactive with hydroxy functionality of the resins. The crosslinkable composition of matter is useful in coating and other applications, especially solvent based primer coating compositions and cathodic electrocoating compositions.

    摘要翻译: 提供了可交联的物质组合物,其包含某些二烯官能的氨基环氧树脂和某些官能的氨基环氧基封闭的亲环氧树脂,这两种树脂在升高的固化温度下是共反应的。 二烯官能氨基环氧树脂包括二环氧化物与胺官能二烯链延伸反应物的反应产物和任选的单官能封端反应物如单羟基官能二烯。 封闭的双极亲本功能性氨基环氧树脂包括二环氧化物与胺官能封闭的含双链亲链扩链反应物的反应产物,以及任选的单官能封端反应物如单羟基官能封闭的亲油体。 组合物还可以包含与树脂的羟基官能团反应的交联剂。 物质的可交联组合物可用于涂覆和其它应用,特别是溶剂型底漆涂料组合物和阴极电泳涂料组合物。

    Furan polyols
    17.
    发明授权
    Furan polyols 失效
    呋喃多元醇

    公开(公告)号:US4973715A

    公开(公告)日:1990-11-27

    申请号:US229169

    申请日:1988-08-22

    摘要: This invention relates to novel furan polyols, which are characterized in that they are the product of reaction of a strain selected from the group or consisting of a polyalcohol, a monoamine or polyamine, said polyalcohol or said amine possibly containing a furan cycle and mixtures thereof with a chain extension agent constituted by an organic epoxide, with the proviso that this organic epoxide is a furannic oxiran when this polyalcohol does not contain a furan cycle with the exclusion of 2,5(bis-hydroxy)furan as sole strain, when the chain extension agent does not contain any furan cycle. These furan polyols are used for the preparation of polyurethane foams having improved properties.

    摘要翻译: PCT No.PCT / FR87 / 00491 Sec。 371日期1988年8月22日 102(e)日期1988年8月22日PCT Filted 1987年12月10日PCT公布。 出版物WO88 / 04295 日本6月16日,1988年。本发明涉及新型的呋喃多元醇,其特征在于它们是选自该组的一种或多种醇,单胺或多胺,所述多元醇或所述胺可能的反应的产物 含有呋喃循环及其与由有机环氧化物构成的扩链剂的混合物,条件是当该多元醇不含呋喃循环时,该有机环氧化物是呋喃基环氧乙烷,排除了2,5(双 - 羟基) 呋喃作为唯一的应变,当链延长剂不含任何呋喃循环时。 这些呋喃多元醇用于制备具有改进性能的聚氨酯泡沫体。

    Crosslinkable composition comprising aminoepoxy resin-II
    18.
    发明授权
    Crosslinkable composition comprising aminoepoxy resin-II 失效
    包含氨基环氧树脂-II的可交联组合物

    公开(公告)号:US4565852A

    公开(公告)日:1986-01-21

    申请号:US566063

    申请日:1983-12-27

    摘要: A crosslinkable composition of matter is provided, which comprises first and second chain extended diepoxide resins, one or both of which are prepared using an excess of diepoxide reactant and modified by reaction with hydroxy functional secondary amine. The first resin, diene functional aminoepoxy resin, and the second resin, blocked dieneophile functional aminoepoxy resin, are co-reactive at elevated cure temperature. The diene functional aminoepoxy resin comprises the reaction product of diepoxide with amine functional diene chain extending reactant and, optionally, monofunctional end-capping reactant such as monohydroxy functional diene. The blocked dieneophile functional aminoepoxy resin comprises the reaction product of diepoxide with amine functional blocked dieneophile chain extending reactant and, optionally, monofunctional end-capping reactant such as monohydroxy functional blocked dieneophile. The composition may further comprise crosslinking agent reactive with hydroxy functionality of the resins. The crosslinkable composition of matter is useful in coating and other applications, especially solvent-based primer coating compositions and cathodic electrocoating compositions.

    摘要翻译: 提供了可交联的物质组合物,其包含第一和第二链延长的二环氧化物树脂,其中一种或两种使用过量的二环氧化物反应物制备并通过与羟基官能的仲胺反应进行改性。 第一种树脂,二烯官能氨基环氧树脂和第二种树脂,封闭的亲水性官能氨基环氧树脂,在升高的固化温度下是共反应的。 二烯官能氨基环氧树脂包括二环氧化物与胺官能二烯链延伸反应物的反应产物和任选的单官能封端反应物如单羟基官能二烯。 封闭的双极亲本功能性氨基环氧树脂包括二环氧化物与胺官能封闭的含双链亲链扩链反应物的反应产物,以及任选的单官能封端反应物如单羟基官能封闭的亲油体。 组合物还可以包含与树脂的羟基官能团反应的交联剂。 物质的可交联组合物可用于涂覆和其它应用,特别是溶剂型底漆涂料组合物和阴极电泳涂料组合物。

    Polyurethanes or isocyanurates from alkoxylated hydroxymethylfuran
    20.
    发明授权
    Polyurethanes or isocyanurates from alkoxylated hydroxymethylfuran 失效
    来自烷氧基化羟甲基呋喃的聚氨酯或异氰脲酸酯

    公开(公告)号:US4426460A

    公开(公告)日:1984-01-17

    申请号:US291446

    申请日:1981-08-10

    申请人: William J. Pentz

    发明人: William J. Pentz

    摘要: Improved rigid urethane and isocyanurate foam compositions having improved fire resistance are described. The urethane foams are based on furan compositions having the formula: ##STR1## and from about 100% to about 500% of a stoichiometric amount of a reactive polyisocyanate to produce a foamable composition, and sufficient blowing agent to create a foam having a density from about 1.5 to about 5 pounds per cubic foot. The product has improved fire resistence. The disclosure also described the method of decreasing the flame hazard potential of a rigid foam by adding two urethane or isocyanurate foaming ingredients the appropriate amount of one or more of the compositions listed above. The polymers described are chiefly made from adding propelyne oxide to bis (hydroxymethyl) furan.

    摘要翻译: 描述了具有改进的耐火性的改进的刚性聚氨酯和异氰脲酸酯泡沫组合物。 聚氨酯泡沫是基于具有下式的呋喃组合物:其中L是低级烷基或M,M是< IMAGE>>> + TR< IMAGE>和 约100%至约500%的化学计量的反应性多异氰酸酯以产生可发泡组合物,以及足够的发泡剂以产生密度为约1.5至约5磅/立方英尺的泡沫。 该产品具有改善的耐火性能。 本公开还描述了通过添加适量的上述一种或多种组合物的两种氨基甲酸酯或异氰脲酸酯发泡成分来降低硬质泡沫的火焰潜在危害的方法。 所描述的聚合物主要是通过向二(羟甲基)呋喃中加入丙烯氧化物制成的。