Graphite fibril material
    11.
    发明申请
    Graphite fibril material 审中-公开
    石墨原纤材料

    公开(公告)号:US20070003473A1

    公开(公告)日:2007-01-04

    申请号:US11515264

    申请日:2006-08-31

    IPC分类号: C01B31/04

    CPC分类号: D01F11/16 D01F9/12

    摘要: A graphite fibril material comprised primarily of an aggregate of an average particle diameter of 0.1 to 100 μm in which-fibrils are intertwined, the fibrils being graphite fibrils of a fiber diameter of 0.0035 to 0.075 μm and spacing of the carbon hexagonal net plane as determined by the X-ray diffraction method of 3.36 to 3.53 angstroms. It is of high crystallinity and purity and is of superior conductivity, chemical stability, solvent absorption capacity and reinforcing capacity.

    摘要翻译: 主要由平均粒径为0.1至100微米的聚集体组成的石墨原纤材料,其中原纤维缠结在一起,原纤维为纤维直径为0.0035至0.075μm的石墨原纤维,并确定了碳六方网平面的间距 通过X射线衍射法测得3.36〜3.53埃。 具有高结晶度和纯度,具有优良的导电性,化学稳定性,溶剂吸收能力和增强能力。

    Process for manufacturing functional activated carbon fibers treated by anodic oxidation
    13.
    发明授权
    Process for manufacturing functional activated carbon fibers treated by anodic oxidation 失效
    通过阳极氧化处理功能性活性炭纤维的方法

    公开(公告)号:US06214201B1

    公开(公告)日:2001-04-10

    申请号:US09231390

    申请日:1999-01-13

    IPC分类号: C25F100

    CPC分类号: D01F9/12 D01F11/16

    摘要: The present invention relates to a process for manufacturing activated carbon fibers having greatly improved adsorption performance time and adsorption performance when in contact with surface oxides such as in the case where gas and liquid impurities are treated. The process of the present invention comprises the following steps: a) placing conventional activated carbon fibers between an anode and a cathode plate in an acidic or an alkaline electrolytic solution, and b) applying a certain voltage at a current density between said graphite anode and graphite cathode plate. The present invention also relates to the product resulting from this process and the use of this product.

    摘要翻译: 本发明涉及一种制造活性炭纤维的方法,其具有大大改善的吸附性能时间和与表面氧化物接触时的吸附性能,例如在处理气体和液体杂质的情况下。 本发明的方法包括以下步骤:a)在酸性或碱性电解液中在阳极和阴极板之间放置常规的活性碳纤维,和b)在所述石墨阳极和石墨之间以电流密度施加一定电压 阴极板。本发明还涉及由该方法产生的产品和该产品的使用。

    Ignition resistant carbonaceous material
    14.
    发明授权
    Ignition resistant carbonaceous material 失效
    耐燃碳质材料

    公开(公告)号:US5582908A

    公开(公告)日:1996-12-10

    申请号:US552610

    申请日:1995-11-03

    摘要: A process for preparing an ignition resistant carbonaceous material by exposing a meltblown or spunbonded acrylic precursor material in the form of at least one ply of a generally planar fibrous web, matt or batt to ionizing radiation to crosslink said acrylic material which is then heat treated in an inert atmosphere to increase the carbon content of said irradiated material to form said carbonaceous material. The invention also resides in a continuous self bonded fibrous carbonaceous material having a carbon content of from about 65% to less than about 92%, an oxygen content of less than about 2%, and a specific resistivity of from about 10.sup.-1 to about 10.sup.10 ohm-cm. Preferably said carbonaceous material has an oxygen content of less than about 1% and a nitrogen content of from about 5% to about 30%.

    摘要翻译: 一种制备耐点燃碳质材料的方法,该方法是将熔喷或纺粘的丙烯酸前体材料以至少一层通常为平面的纤维网状物,无光泽或絮垫的形式暴露于电离辐射,以交联所述丙烯酸材料,然后将其热处理 惰性气氛以增加所述被照射材料的碳含量以形成所述含碳材料。 本发明还涉及碳含量为约65%至小于约92%,氧含量小于约2%,电阻率为约10-1至约10%的连续自粘纤维碳质材料 1010欧姆厘米。 优选地,所述碳质材料具有小于约1%的氧含量和约5%至约30%的氮含量。

    Carbon fibers and process for preparing same
    15.
    发明授权
    Carbon fibers and process for preparing same 失效
    碳纤维及其制备方法

    公开(公告)号:US5462799A

    公开(公告)日:1995-10-31

    申请号:US293817

    申请日:1994-08-22

    IPC分类号: D01F11/14 D01F11/16 D02G3/00

    摘要: Carbon fibers with a surface oxygen concentration (O/C ratio) of 0.20 or less as measured by X-ray photoelectron spectroscopy, a surface concentration of hydroxyl groups (C--OH/C ratio) of 0.5% or greater as measured by chemical modification X-ray photoelectron spectroscopy and a surface concentration of carboxylic groups (COOH/C ratio) of 2.0% or less as measured by chemical modification X-ray photoelectron spectroscopy, and comprising applied as a sizing agent an aliphatic compound which has multiple epoxy groups or an aromatic compound which has multiple epoxy groups, the number of atoms between the epoxy groups and an aromatic ring being 6 or greater. They are prepared by electrolyzing a carbon fiber in an alkaline aqueous solution, or electrolyzing a carbon fiber in an acidic aqueous solution followed by washing with an alkaline aqueous solution, and then applying a sizing agent of an aliphatic compound with multiple epoxy groups or an aromatic compound with multiple epoxy groups in which the number of atoms between the epoxy groups and an aromatic ring is 6 or greater. Alternatively, they are prepared by electrolyzing a carbon fiber in an aqueous solution of an ammonium salt and then applying a sizing agent of an aliphatic compound with multiple epoxy groups or an aromatic compound with multiple epoxy groups in which the number of atoms between the epoxy groups and an aromatic ring is 6 or greater.

    摘要翻译: 通过X射线光电子能谱测定,表面氧浓度(O / C比)为0.20以下的碳纤维,通过化学改性测定的羟基的表面浓度(C-OH / C比)为0.5%以上 通过化学修饰X射线光电子能谱法测定的X射线光电子能谱和羧基的表面浓度(COOH / C比)为2.0%以下,并且包括作为上浆剂应用具有多个环氧基的脂肪族化合物或 具有多个环氧基的芳族化合物,环氧基和芳香环之间的原子数为6以上。 它们是通过在碱性水溶液中电解碳纤维,或在酸性水溶液中电解碳纤维,然后用碱性水溶液洗涤来制备的,然后施加具有多个环氧基或芳香族的脂族化合物的施胶剂 具有多个环氧基的化合物,其中环氧基和芳环之间的原子数为6以上。 或者,它们通过在铵盐水溶液中电解碳纤维,然后将具有多个环氧基的脂肪族化合物或具有多个环氧基的芳族化合物的施胶剂,其中环氧基团之间的原子数 芳环为6以上。

    Flexible activated carbon fibers manufactured from salt impregnated cellulosic fibers
    19.
    发明授权
    Flexible activated carbon fibers manufactured from salt impregnated cellulosic fibers 失效
    从盐浸渍的纤维素纤维制成的柔性活性炭纤维

    公开(公告)号:US3847833A

    公开(公告)日:1974-11-12

    申请号:US22378272

    申请日:1972-02-04

    申请人: SECR DEFENCE

    发明人: BAILEY A MAGGS F

    摘要: 1. A PROCESS FOR THE PRODUCTION OF A STRONG, FLEXIBLE, HIGHLY ACTIVATED FIBROUS CARBON HAVING A BREAKING STRENGTH OF AT LEAST 30,000 P.S.I., A CARBON TETRACHLORIDE SORBENCY OF AT LEAST 50% BY WEIGHT AND SUFFICIENTLY FLEXIBLE TO FOLD BACK UPON ITSELF WITHOUT FRACTURE AROUND A RADIUS OF CURVATURE OF 0.5 MM., FROM A FIBROUS CELLULOSIC MATERIAL, SAID PROCESS COMPRISING: CONTACTING THE SAID FIBROUS CELLULOSIC MATERIAL WITH AN AQUEOUS SOLUTION CONTAINING BETWEEN 1-30% BY WEIGHT OF AT LEAST ONE IMPREGNATED SELECTED FROM THE GROUP CONSISTING OF HALIDES OF ZINC, ALUMINUM, BARIUM, CALCIUM, MAGNESIUM AND IRON TO IMPREGNATE THE FIBROUS CARBOHYDRATE MATERIAL WITH BETWEEN 0.1 AND 10% BY WEIGHT OF THE SAID IMPREGNANT CATIONS, DRYING THE IMPREGNATED FIBROUS CELLULOSIC MATERIAL AT A TEMPERATURE IN THE RANGE OF 100* TO 140*C., FLEXING THE FIBERS OF THE DRIED MATERIAL TO RESTORE A MAJOR PROPORTION OF ANY FLEXIBILITY LOST DURING THE IMPREGNATION AND DRYING OF THE FIBROUS CELLULOSIC MATERIAL, CARBONIZING THE MATERIAL BY HEATING IN AN INERT ATMOSPHERE TO A CARBONIZING TEMPERATURE THROUGH THE CRITICAL DECOMPOSITION TEMPERATURE RANGE WHICH EXTENDS FOR BETWEEN 40*C. AND 80*C. WITHIN THE TEMPERATURE LIMITS 70*C. AND 300*C. AND MAINTAINING THE TEMPERATURE WITHIN THE SAID CRITICAL TEMPERATURE RANGE FOR A TIME WHICH IS AT LEAST FIFTEEN MINUTES FOR A CRITICAL TEMPERATURE RANGE OF 40*C. INCREASING PROGRESSIVELY TO AT LEAST THIRTY MINUTES FOR A CRITICAL TEMPERATURE RANGE OF 80*C., AND ACTIVATING THE CARBONIZED MATERIAL BY CONTACT AT AN ACTIVATION TEMPERATURE BETWEEN 600*C. AND 1000*C. WITH AN ACTIVATING GAS SELECTED FROM THE GROUP CONSISTING OF STEAM AND CARBON DIOXIDE UNTIL THE ACTIVATE HAS A CARBON TETRACHLORIDE SORBENCY OF AT LEAST 50% BY WEIGHT.

    Treatment of carbon or graphite fibers and yarns for use in fiber reinforced composites
    20.
    发明授权
    Treatment of carbon or graphite fibers and yarns for use in fiber reinforced composites 失效
    用于纤维增强复合材料的碳或石墨纤维和纱线的处理

    公开(公告)号:US3671411A

    公开(公告)日:1972-06-20

    申请号:US3671411D

    申请日:1970-03-03

    申请人: US AIR FORCE

    IPC分类号: D01F11/16 B01K1/00

    CPC分类号: D01F11/16

    摘要: Carbon fiber or yarn as used in fiber reinforced composites is electrolytically treated to improve the surface characteristics and thereby to improve its bonding or adhesion to the matrix material. By this improved bonding, shear strengths of resultant fiber resin or plastic composites have been more than doubled. The electrolytic treatment is conducted by using the fiber or yarn as the anode and using en electrolyte such as an aqueous caustic solution.

    摘要翻译: 用于纤维增强复合材料中的碳纤维或纱线进行电解处理以改善表面特性,从而改善其与基体材料的粘合或粘合。 通过这种改进的粘合,所得纤维树脂或塑料复合材料的剪切强度已经增加了一倍以上。 电解处理通过使用纤维或纱线作为阳极并使用电解质如苛性碱水溶液进行。