摘要:
A graphite fibril material comprised primarily of an aggregate of an average particle diameter of 0.1 to 100 μm in which-fibrils are intertwined, the fibrils being graphite fibrils of a fiber diameter of 0.0035 to 0.075 μm and spacing of the carbon hexagonal net plane as determined by the X-ray diffraction method of 3.36 to 3.53 angstroms. It is of high crystallinity and purity and is of superior conductivity, chemical stability, solvent absorption capacity and reinforcing capacity.
摘要:
Carbon fiber including graphitized fiber is processed electrochemically in an acidic solution for a time sufficient to run a layer reaction such that the reaction extends to the inside of the fiber and thereafter, as required, heat-treated accurately at 100null C. or more to expand layer spacing to form multifibrous carbon fiber, with which hydrogen is brought into contact, adsorbing hydrogen in the inside of the multifibrous carbon fiber.
摘要:
The present invention relates to a process for manufacturing activated carbon fibers having greatly improved adsorption performance time and adsorption performance when in contact with surface oxides such as in the case where gas and liquid impurities are treated. The process of the present invention comprises the following steps: a) placing conventional activated carbon fibers between an anode and a cathode plate in an acidic or an alkaline electrolytic solution, and b) applying a certain voltage at a current density between said graphite anode and graphite cathode plate. The present invention also relates to the product resulting from this process and the use of this product.
摘要:
A process for preparing an ignition resistant carbonaceous material by exposing a meltblown or spunbonded acrylic precursor material in the form of at least one ply of a generally planar fibrous web, matt or batt to ionizing radiation to crosslink said acrylic material which is then heat treated in an inert atmosphere to increase the carbon content of said irradiated material to form said carbonaceous material. The invention also resides in a continuous self bonded fibrous carbonaceous material having a carbon content of from about 65% to less than about 92%, an oxygen content of less than about 2%, and a specific resistivity of from about 10.sup.-1 to about 10.sup.10 ohm-cm. Preferably said carbonaceous material has an oxygen content of less than about 1% and a nitrogen content of from about 5% to about 30%.
摘要:
Carbon fibers with a surface oxygen concentration (O/C ratio) of 0.20 or less as measured by X-ray photoelectron spectroscopy, a surface concentration of hydroxyl groups (C--OH/C ratio) of 0.5% or greater as measured by chemical modification X-ray photoelectron spectroscopy and a surface concentration of carboxylic groups (COOH/C ratio) of 2.0% or less as measured by chemical modification X-ray photoelectron spectroscopy, and comprising applied as a sizing agent an aliphatic compound which has multiple epoxy groups or an aromatic compound which has multiple epoxy groups, the number of atoms between the epoxy groups and an aromatic ring being 6 or greater. They are prepared by electrolyzing a carbon fiber in an alkaline aqueous solution, or electrolyzing a carbon fiber in an acidic aqueous solution followed by washing with an alkaline aqueous solution, and then applying a sizing agent of an aliphatic compound with multiple epoxy groups or an aromatic compound with multiple epoxy groups in which the number of atoms between the epoxy groups and an aromatic ring is 6 or greater. Alternatively, they are prepared by electrolyzing a carbon fiber in an aqueous solution of an ammonium salt and then applying a sizing agent of an aliphatic compound with multiple epoxy groups or an aromatic compound with multiple epoxy groups in which the number of atoms between the epoxy groups and an aromatic ring is 6 or greater.
摘要:
A method is taught for the preparation of metal oxide sols particularly suited for the electrophoretic deposition of metal oxide coatings upon a fiber core.
摘要:
A method of finishing carbon fibers with phenolic triazine to promote adhesing of the carbon fibers with a resin matrix to retain up to 92% of the room temperature dry strength at a temperature of 500.degree. F.
摘要:
Disclosed is a method for modifying and improving the surface characteristics of a carbon substrate which comprises subjecting the carbon substrate to alternating treatment as an anode and a cathode by passage of current in an electrolytic cell wherein the carbon substrate acts as one electrode and there is provided a second electrode, both in an aqueous electrolyte solution. The modified carbon substrates impart improved mechanical properties to composite articles produced using same as reinforcing elements.
摘要:
1. A PROCESS FOR THE PRODUCTION OF A STRONG, FLEXIBLE, HIGHLY ACTIVATED FIBROUS CARBON HAVING A BREAKING STRENGTH OF AT LEAST 30,000 P.S.I., A CARBON TETRACHLORIDE SORBENCY OF AT LEAST 50% BY WEIGHT AND SUFFICIENTLY FLEXIBLE TO FOLD BACK UPON ITSELF WITHOUT FRACTURE AROUND A RADIUS OF CURVATURE OF 0.5 MM., FROM A FIBROUS CELLULOSIC MATERIAL, SAID PROCESS COMPRISING: CONTACTING THE SAID FIBROUS CELLULOSIC MATERIAL WITH AN AQUEOUS SOLUTION CONTAINING BETWEEN 1-30% BY WEIGHT OF AT LEAST ONE IMPREGNATED SELECTED FROM THE GROUP CONSISTING OF HALIDES OF ZINC, ALUMINUM, BARIUM, CALCIUM, MAGNESIUM AND IRON TO IMPREGNATE THE FIBROUS CARBOHYDRATE MATERIAL WITH BETWEEN 0.1 AND 10% BY WEIGHT OF THE SAID IMPREGNANT CATIONS, DRYING THE IMPREGNATED FIBROUS CELLULOSIC MATERIAL AT A TEMPERATURE IN THE RANGE OF 100* TO 140*C., FLEXING THE FIBERS OF THE DRIED MATERIAL TO RESTORE A MAJOR PROPORTION OF ANY FLEXIBILITY LOST DURING THE IMPREGNATION AND DRYING OF THE FIBROUS CELLULOSIC MATERIAL, CARBONIZING THE MATERIAL BY HEATING IN AN INERT ATMOSPHERE TO A CARBONIZING TEMPERATURE THROUGH THE CRITICAL DECOMPOSITION TEMPERATURE RANGE WHICH EXTENDS FOR BETWEEN 40*C. AND 80*C. WITHIN THE TEMPERATURE LIMITS 70*C. AND 300*C. AND MAINTAINING THE TEMPERATURE WITHIN THE SAID CRITICAL TEMPERATURE RANGE FOR A TIME WHICH IS AT LEAST FIFTEEN MINUTES FOR A CRITICAL TEMPERATURE RANGE OF 40*C. INCREASING PROGRESSIVELY TO AT LEAST THIRTY MINUTES FOR A CRITICAL TEMPERATURE RANGE OF 80*C., AND ACTIVATING THE CARBONIZED MATERIAL BY CONTACT AT AN ACTIVATION TEMPERATURE BETWEEN 600*C. AND 1000*C. WITH AN ACTIVATING GAS SELECTED FROM THE GROUP CONSISTING OF STEAM AND CARBON DIOXIDE UNTIL THE ACTIVATE HAS A CARBON TETRACHLORIDE SORBENCY OF AT LEAST 50% BY WEIGHT.
摘要:
Carbon fiber or yarn as used in fiber reinforced composites is electrolytically treated to improve the surface characteristics and thereby to improve its bonding or adhesion to the matrix material. By this improved bonding, shear strengths of resultant fiber resin or plastic composites have been more than doubled. The electrolytic treatment is conducted by using the fiber or yarn as the anode and using en electrolyte such as an aqueous caustic solution.