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    Process for the preparation of a nickel/phosphorous ligand catalyst
    11.
    发明申请
    Process for the preparation of a nickel/phosphorous ligand catalyst 有权
    制备镍/磷配体催化剂的方法

    公开(公告)号：US20040204312A1

    公开(公告)日：2004-10-14

    申请号：US10409482

    申请日：2003-04-08

    Inventor： Scott Christopher Jackson ,  Ronald J. McKinney

    IPC: B01J031/00

    CPC classification number: B01J31/185 ,  B01J2231/323 ,  B01J2531/847 ,  C07F9/145

    Abstract: Process for preparing a nickel/ligand catalyst in which a crude ligand mixture is contacted with at least one member selected from the group consisting of (i) a weakly acidic organic resin, (ii) a weakly basic organic resin, (iii) a high-surface-area organic resin, (iv) activated carbon, (v) aluminosilicate zeolite, (vi) a two phase solvent system for liquid-liquid extraction and (vii) a Lewis acid; recovering a solution containing a ligand of the formula (R1O)2POZOP(OR1)2; and contacting the solution with nickel chloride in the presence of a nitrile solvent and a reducing metal which is more electropositive than nickel to produce the nickel/ligand catalyst.

    Abstract translation: 制备镍/配体催化剂的方法，其中粗配体混合物与选自（i）弱酸性有机树脂，（ii）弱碱性有机树脂，（iii）高碱性有机树脂， 表面积有机树脂，（iv）活性炭，（v）硅铝酸盐沸石，（vi）用于液 - 液萃取的两相溶剂体系和（vii）路易斯酸; 回收含有式（R 1 O）2 POZOP（OR 1）2的配体的溶液; 并在腈溶剂和还原金属存在下使氯化镍接触，镍还原金属比镍更正电以产生镍/配体催化剂。

    Catalyst-imparting treatment solution and electroless plating method
    14.
    发明申请
    Catalyst-imparting treatment solution and electroless plating method 审中-公开
    催化剂赋予处理液和无电镀法

    公开(公告)号：US20040186008A1

    公开(公告)日：2004-09-23

    申请号：US10477172

    申请日：2004-05-06

    Inventor： Hiroaki Inoue ,  Kenji Nakamura ,  Moriji Matsumoto

    IPC: B01J031/00 ,  C25D005/10

    CPC classification number: H01L21/76843 ,  C23C18/166 ,  C23C18/1806 ,  C23C18/1831 ,  C23C18/36 ,  H01L21/288 ,  H01L21/76849 ,  H01L21/76874

    Abstract: The present invention provides a catalyst-imparting treatment solution and an electroless plating method that can form a protective film of a phosphorus-containing alloy to protect the surface of copper inter-connects of an electronic device without forming voids in the copper inter-connects. The catalyst-imparting treatment solution, for use in a catalyst-imparting pretreatment before carrying out electroless plating of at least part of an electronic device having an embedded copper-interconnect structure using a hypophosphite as a reducing agent, includes at least one complex compound of a noble metal of Group IB or Group VIII of the Periodic Table.

    Abstract translation: 本发明提供一种能够形成含磷合金保护膜的催化剂赋予处理溶液和化学镀方法，以保护电子器件的铜互连表面，而不会在铜互连中形成空隙。 在使用次磷酸盐作为还原剂的具有嵌入铜互连结构的电子器件的至少一部分进行无电解电镀之前，用于催化剂赋予预处理的催化剂赋予处理液包含至少一种配位化合物 IB族元素的贵金属或元素周期表第八族。

    Catalyst and process for alkyl group dehydrogenation of organic compounds
    15.
    发明申请
    Catalyst and process for alkyl group dehydrogenation of organic compounds 审中-公开
    有机化合物烷基脱氢的催化剂和方法

    公开(公告)号：US20040181104A1

    公开(公告)日：2004-09-16

    申请号：US10791565

    申请日：2004-03-02

    Applicant: ABB Lummus Global Inc.

    Inventor： Chuen Y. Yeh ,  Zhiping Shan ,  Philip J. Angevine ,  Dinesh Gandhi

    IPC: C07C004/02 ,  B01J031/00

    CPC classification number: B01J29/0308 ,  B01J31/1633 ,  B01J31/18 ,  B01J2531/0244 ,  B01J2531/10 ,  B01J2531/80 ,  C07C5/3332 ,  C07C5/367 ,  C07C2521/08 ,  Y02P20/127 ,  Y02P20/52 ,  Y02P20/588 ,  C07C15/46 ,  C07C15/06

    Abstract: A dehydrogenation catalyst includes an organometallic pincer complex bonded to a mesoporous inorganic oxide support, the organometallic pincer complex possessing catalytic activity for alkyl group dehydrogenation. The pincer complex includes at least one element selected from Group VIII or Group IB of the Periodic Table of the elements, and at least one element selected from Group VA of the Periodic Table of the elements in each of two molecular arms, the Group VIII or Group IB element being bonded to each of the Group VA elements. The catalyst is advantageously employed in conjunction with catalytic distillation to permit the dehydrogenation of organic compounds at lower temperatures and at lower cost than conventional methods.

    Abstract translation: 脱氢催化剂包括与介孔无机氧化物载体结合的有机金属夹子络合物，具有烷基脱氢催化活性的有机金属螯合物。 钳形复合物包括选自元素周期表第VIII族或第IB族中的至少一种元素，以及选自两种分子臂中的每一种元素的元素周期表第VA族中的至少一种元素，第VIII族或 IB族元素键合到每个VA族元素上。 催化剂有利地与催化蒸馏结合使用以允许有机化合物在较低温度下以比常规方法更低的成本脱氢。

    High productivity bisphenol-a-catalyst
    16.
    发明申请
    High productivity bisphenol-a-catalyst 审中-公开
    高效双酚a催化剂

    公开(公告)号：US20040181100A1

    公开(公告)日：2004-09-16

    申请号：US10805792

    申请日：2004-03-22

    Inventor： Eric Gustave Lundquist

    IPC: B01J031/00 ,  C07C039/16

    CPC classification number: B01J31/10 ,  B01J2231/347 ,  C07C37/20 ,  C07C39/16

    Abstract: A high productivity catalyst for bisphenol-A has been discovered which comprises strongly acidic cation-exchange resin spheres produced from a polystyrene/divinylbenzene (PS/DVB) copolymer sulfonated under conditions to introduce sulfone cross-linking. Surprisingly, the sulfone cross-linking improves the resistance to deformation but does not have a negative effect on the activity and selectivity of the catalyst in bisphenol-A production.

    Abstract translation: 已经发现了用于双酚A的高生产率催化剂，其包括在引入砜交联的条件下由聚苯乙烯/二乙烯基苯（PS / DVB）共聚物制备的强酸性阳离子交换树脂球。 令人惊奇的是，砜交联改善了耐变形性，但对双酚A生产中催化剂的活性和选择性没有负面影响。

    Catalyst for bulk polymerization
    19.
    发明申请
    Catalyst for bulk polymerization 审中-公开
    用于本体聚合的催化剂

    公开(公告)号：US20040162407A1

    公开(公告)日：2004-08-19

    申请号：US10779840

    申请日：2004-02-17

    Inventor： Syuji Okamoto ,  Hiroshi Ueno

    IPC: B01J031/00 ,  C08F004/44

    CPC classification number: C08F4/00

    Abstract: A catalyst for bulk polymerization of a polymerizable unsaturated compound of the invention comprises a compound having at least one thiol group and a secondary hydroxyl group and represented by the following formula (I): 1 wherein R1 to R5 are each a hydrogen atom or an alkyl group, and R6 is a hydroxyl group, an alkyl group or the like. Also a process for bulk polymerization of the invention comprises polymerizing a polymerizable unsaturated compound in an inert gas atmosphere substantially in the absence of a solvent using, as a catalyst, a compound having at least one thiol group and a secondary hydroxyl group and represented by the above formula (I). According to the catalyst or the process of the invention, bulk polymerization can be carried out in one-component catalyst system in a high yield without suffering a runaway reaction.

    Abstract translation: 用于本发明的可聚合不饱和化合物的本体聚合用催化剂包括具有至少一个硫醇基和仲羟基并由下式（I）表示的化合物：其中R 1至R 5各自为 氢原子或烷基，R 6为羟基，烷基等。 本发明的本体聚合方法还包括使用基本上不存在溶剂的惰性气体气氛中使用具有至少一个硫醇基和仲羟基的化合物作为催化剂聚合，并由 上述式（I）。 根据本发明的催化剂或方法，本体聚合可以以高产率在单组分催化剂体系中进行，而不会发生失控反应。

    Polyolefin catalysts, production thereof and method of use
    20.
    发明申请
    Polyolefin catalysts, production thereof and method of use 有权
    聚烯烃催化剂，其生产方法和使用方法

    公开(公告)号：US20040162401A1

    公开(公告)日：2004-08-19

    申请号：US10370365

    申请日：2003-02-18

    Inventor： Steven D. Gray ,  Tim J. Coffy ,  Edwar S. Shamshoum ,  Hong Chen

    IPC: C08F004/44 ,  B01J031/00

    CPC classification number: C08F10/00 ,  C08F110/02 ,  C08F4/6492 ,  C08F4/6557

    Abstract: A method of modifying a Ziegler-Natta type polyolefin catalyst comprises contacting the Ziegler-Natta catalyst with olefin monomer to form a prepolymerized catalyst. The prepolymerized catalyst can comprise a reduced number of catalyst particles having a size of 40 microns or less. The prepolymerized catalyst can be used in a polymerization process to produce polymer fluff particles with a reduced number of polymer fluff fines than the Ziegler-Natta type catalyst.

    Abstract translation: 修饰齐格勒 - 纳塔型聚烯烃催化剂的方法包括使齐格勒 - 纳塔催化剂与烯烃单体接触以形成预聚合的催化剂。 预聚合的催化剂可以包含减少数量的具有40微米或更小尺寸的催化剂颗粒。 预聚合的催化剂可用于聚合过程中，以生产具有比齐格勒 - 纳塔型催化剂低的聚合物绒毛数量的聚合物绒毛颗粒。

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