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    Transition metal complexes
    12.
    发明授权
    Transition metal complexes 失效
    过渡金属络合物

    公开(公告)号：US06420301B1

    公开(公告)日：2002-07-16

    申请号：US09719428

    申请日：2000-12-12

    Applicant: Marc Oliver Kristen ,  Franz Langhauser ,  Günther Schweier ,  Helmut Sitzmann ,  Ralf Krammer ,  Dirk Saurenz

    Inventor： Marc Oliver Kristen ,  Franz Langhauser ,  Günther Schweier ,  Helmut Sitzmann ,  Ralf Krammer ,  Dirk Saurenz

    IPC: B01J3138

    CPC classification number: C08F10/00 ,  C07F7/10 ,  C07F7/12 ,  C07F17/00 ,  C08F4/65908 ,  C08F4/65912 ,  C08F4/65916 ,  C08F2420/01 ,  C08F2420/02 ,  Y10S526/943 ,  C08F4/6592 ,  C08F4/6492

    Abstract: Transition metal complexes of the formula (Ia) or (Ib), in which the substituents and indices have the following meanings: M is titanium, zirconium, hafnium, vanadium, niobium or tantalum or an element of the third subgroup of the Periodic Table or of the lanthanoids, X is fluorine, chlorine, bromine, iodine, hydrogen, C1-C10-alkyl, C6-C15-aryl, alkylaryl having 1 to 10 carbon atoms in the alkyl radical and 6 to 20 carbon atoms in the aryl radical, —OR5 or —NR5R6, n is 1, 2 or 3, where n is the valency of M minus the number 2, Z is a three-way bridge and A and A1 are two-way bridges. Process for preparing the transition metal complexes, compounds which are used as intermediates for their preparation, the use of the transition metal complexes for polymerizing olefins, processes for polymerizing olefins, homo- or copolymers of ethylene or of propylene with other C2-C12-alk-1-enes, their use for preparing films, fibers or moldings and the films, fibers or moldings made of these polymers.

    Abstract translation: 式（Ia）或（Ib）的过渡金属络合物，其中取代基和指数具有以下含义：M是钛，锆，铪，钒，铌或钽或元素周期表第三亚元素的元素或 的镧系元素，X是氟，氯，溴，碘，氢，C 1 -C 10 - 烷基，C 6 -C 15 - 芳基，在烷基中具有1至10个碳原子的烷基芳基和芳基中6至20个碳原子， -OR5或-NR5R6，n是1,2或3，其中n是M的化合价减去数2，Z是三向桥，A和A1是双向桥。制备过渡金属配合物的方法， 用作其制备中间体的化合物，使用过渡金属络合物用于聚合烯烃，聚合烯烃的方法，乙烯或丙烯与其它C 2 -C 12烷-1-烯的均聚物或共聚物，其用途 制备薄膜，纤维或模制品以及由这些聚合物制成的薄膜，纤维或模制品。

    Polymerisation catalysts
    13.
    发明授权
    Polymerisation catalysts 失效
    聚合催化剂

    公开(公告)号：US06774079B1

    公开(公告)日：2004-08-10

    申请号：US09633107

    申请日：2000-08-04

    Applicant: Michael John Taylor ,  Christel Marie-Claude Mealares ,  Ian McKenzie Munro

    Inventor： Michael John Taylor ,  Christel Marie-Claude Mealares ,  Ian McKenzie Munro

    IPC: B01J3138

    CPC classification number: C08F110/02 ,  C08F4/65916 ,  C08F4/65927 ,  C08F10/02 ,  C08F210/16 ,  Y10S526/943 ,  C08F4/027 ,  C08F4/025 ,  C08F4/65908 ,  C08F2500/12 ,  C08F2500/18 ,  C08F210/14

    Abstract: Supported inonic metallocene catalyst prepared by a process comprising the following steps; (i) mixing together in a suitable solvent (a) an metallocene complex, (b) an ionic compound comprising a cation and an anion having up to 100 non-hydrogen atoms and containing at least one substituent comprising a moiety having an active hydrogen, and (c) optionally a support material, (ii) treating the mixture obtained in (i) with an organometallic compound, and (iii) addition of a support material if not added in step (i), and (iv) removing the solvent.

    Abstract translation: 通过包括以下步骤的方法制备的负载型金属茂催化剂：（i）在合适的溶剂（a）茂金属络合物，（b）包含阳离子和具有多达100个非氢原子的阴离子的离子化合物和 含有至少一个包含具有活性氢的部分的取代基，和（c）任选的载体材料，（ii）用有机金属化合物处理在（i）中获得的混合物，和（iii）如果不加入载体材料， 在步骤（i）中，和（iv）除去溶剂。

    Olefin polymerization catalysis with aryl substituted carbenium cationic complexes
    15.
    发明授权
    Olefin polymerization catalysis with aryl substituted carbenium cationic complexes 失效
    烯烃聚合催化与芳基取代的碳鎓阳离子络合物

    公开(公告)号：US06475946B1

    公开(公告)日：2002-11-05

    申请号：US09693300

    申请日：2000-10-20

    Applicant: Francis C. Rix

    Inventor： Francis C. Rix

    IPC: B01J3138

    CPC classification number: C08F10/00 ,  C08F4/65927 ,  C08F10/02 ,  C08F110/02 ,  C08F210/16 ,  C08F4/65908 ,  C08F2/06 ,  C08F2500/01 ,  C08F210/06 ,  C08F2500/03

    Abstract: This description addresses a process for the preparation of polyolefins from one or more olefinic monomers comprising combining under polymerization conditions said olefins with the product of combining i) an organometallic catalyst compound and ii) a cocatalyst complex comprising a trialkylsilyl-substituted carbenium cation and a suitable noncoordinating or weakly coordinating anion. These complexes exhibit good solubility in aliphatic solvents such that use in aliphatic solution based polymerization reaction processes can be conducted without the use of aromatic solvents or co-solvents and without the need for slurry means of introduction into chemical reaction environments. High number-average molecular weight polymers and copolymers at high rates of productivity were observed from the use of metallocene catalysts complexes when activated with [(3,5-(Et3Si)2Ph)3C]+[(C6F5)B]− and used in a hexane-based solution polymerization.

    Abstract translation: 该描述涉及从一种或多种烯烃单体制备聚烯烃的方法，其包括在聚合条件下将所述烯烃与i）有机金属催化剂化合物和ii）包含三烷基甲硅烷基取代的碳鎓阳离子的助催化剂络合物和合适的 非配位或弱配位阴离子。 这些配合物在脂肪族溶剂中表现出良好的溶解性，从而可以在不使用芳香族溶剂或助溶剂的情况下进行基于脂肪族溶液的聚合反应方法的使用，并且不需要引入化学反应环境中的浆料装置。 当用[（3,5-（Et 3 Si）2 Ph）3C] + [（C6F5）B]活化时，使用茂金属催化剂配合物观察到高生产率的高数均分子量聚合物和共聚物，并用于 己烷基溶液聚合。

    Catalysts for the synthesis of alternating ethylene/alpha-olefin copolymers
    16.
    发明授权
    Catalysts for the synthesis of alternating ethylene/alpha-olefin copolymers 有权
    用于合成交替乙烯/α-烯烃共聚物的催化剂

    公开(公告)号：US06380125B1

    公开(公告)日：2002-04-30

    申请号：US09672108

    申请日：2000-09-27

    Applicant: Robert Waymouth ,  Margrete K. LeClerc

    Inventor： Robert Waymouth ,  Margrete K. LeClerc

    IPC: B01J3138

    CPC classification number: C08F210/16 ,  C08F4/65912 ,  C08F10/00 ,  C08F210/06 ,  Y10S526/943 ,  C08F4/65927 ,  C08F2500/15 ,  C08F2500/04

    Abstract: Catalysts, catalyst systems and processes for production of alternating copolymers of ethylene and alpha olefins, and to novel classes of atactic and isotactic alternating copolymers of ethylene and alpha olefins, which copolymers include a wide range of crystallinity and exhibit commercially useful properties. Appropriate selection of ligand substituents permit the catalysts to be symmetric or assymetric, resulting in atactic, or isotactic or atactic, respectively, alternating copolymers of ethylene with alpha olefins. The novel class of bridged flourenyl metallocene catalysts of the invention is assymetric structural form interconvert between states during polymerization of ethylene with alpha olefins to produce alternating isotactic or atactic copolymers. Exemplary metallocene components of the inventive catalyst systems comprised bridged cyclopentadienly-fluorenyl complexes of the general formula: in which: M is a Group 3, 4 or 5 Transition metal, a Lanthanide or an Actinide; X and X′ are the same or different uninegative ligands; L is a substituted or unsubstituted cyclopentadienyl (Cp) or indenyl ligand; Flu is a substituted or unsubstituted fluorenyl ligand; and Y is a bridging group. When the Cp ligand is symmetric, atactic alternating E/&agr;-olefin copolymers are produced and when the Cp ligand is assymetric, alternating isotactic or atactic E/&agr;-olefin copolymers are produced.

    Abstract translation: 用于制备乙烯和α-烯烃的交替共聚物的催化剂，催化剂体系和方法，以及乙烯和α-烯烃的新型无规立构和全同立构交替共聚物，该共聚物包括宽范围的结晶度并且具有商业上有用的性质。 配体取代基的适当选择允许催化剂对称或不对称，分别导致乙烯与α-烯烃的交替共聚物的无规或全同立构或无规立构。 本发明的新型桥联氟烯基茂金属催化剂是在乙烯与α-烯烃聚合过程中状态之间的交互结构形式的交互式结构形式，以产生交替的全同立构或无规立构共聚物。 本发明催化剂体系的示例性茂金属组分包括通式为桥连的环戊二烯基 - 芴基配合物：其中：M为第3,4或5族过渡金属，镧系元素或锕系元素; X和X'是相同或不同的非负配位体; L是取代或未取代的环戊二烯基（Cp）或茚基配体; Flu是取代或未取代的芴基配体; Y是桥接组。 当Cp配体对称时，产生无规交替的E /α-烯烃共聚物，当Cp配体不对称时，产生交替的全同立构或无规立构的E /α-烯烃共聚物。

    Catalyst system and its use in a polymerization process
    19.
    发明授权
    Catalyst system and its use in a polymerization process 有权
    催化剂体系及其在聚合过程中的应用

    公开(公告)号：US06660679B2

    公开(公告)日：2003-12-09

    申请号：US09882906

    申请日：2001-06-18

    Applicant: Matthew W. Holtcamp ,  Tan H. Pham

    Inventor： Matthew W. Holtcamp ,  Tan H. Pham

    IPC: B01J3138

    CPC classification number: C08F10/00 ,  C08F4/65925 ,  C08F4/65927 ,  C08F210/16 ,  C08F4/603 ,  C08F4/61908 ,  C08F210/14

    Abstract: Disclosed are polymerization catalyst activator complexes prepared from the reaction of a carbenium salt and Lewis base containing an aromatic group. Also disclosed are polymerization catalyst activator complexes prepared via the reaction of a Group 13 element containing salt including a Lewis base containing an aromatic group and a tritylhalide compound. Also disclosed are polymerization catalyst systems including the activator complex of the invention, and processes for polymerizing olefin(s) utilizing same.

    Abstract translation: 公开了由碳鎓盐与含芳族基团的路易斯碱的反应制备的聚合催化剂活化剂配合物。 还公开了通过含有含有芳族基团的路易斯碱和三苯甲基卤化合物的含13族元素盐的反应制备的聚合催化剂活化剂配合物。 还公开了包括本发明的活化剂配合物的聚合催化剂体系，以及利用它们聚合烯烃的方法。

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