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公开(公告)号：US08809563B2
公开(公告)日：2014-08-19
申请号：US13535875
申请日：2012-06-28
Applicant: Matthew W. Holtcamp , Catherine A. Faler , Caol P. Huff , Matthew S. Bedoya , John R. Hagadorn
Inventor： Matthew W. Holtcamp , Catherine A. Faler , Caol P. Huff , Matthew S. Bedoya , John R. Hagadorn
CPC classification number: C07F15/0046 , B01J31/2226 , B01J31/2265 , B01J2231/543 , B01J2531/821 , C07C6/04 , C07C2531/26 , C07D207/06 , C10G3/47 , C10G2300/1014 , C10G2300/1018 , C10G2300/1088 , C10G2300/4025 , C10G2400/20 , C10G2400/22 , Y02E50/13 , C07C11/02
Abstract: This invention relates to a Group 8 metal containing catalyst compound for the metathesis of olefins.This invention also relates to process to make alphaolefins comprising contacting an olefin, such as ethylene, with a feed oil containing a triacylglyceride (typically a fatty acid ester (such as methyl oleate)) with a Group 8 metal containing catalyst compound. The fatty acid ester may be a fatty acid methyl ester derived from biodiesel.
Abstract translation: 本发明涉及用于烯烃复分解的含8族金属的催化剂化合物。 本发明还涉及制备α-烯烃的方法，包括使烯烃如乙烯与含有三酰基甘油酯（通常为脂肪酸酯（如油酸甲酯））的原料油与含有第8族金属的催化剂化合物接触。 脂肪酸酯可以是衍生自生物柴油的脂肪酸甲酯。
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2.发明授权Functionalization of vinyl terminated polymers by ring opening cross metathesis 有权乙烯基封端聚合物通过开环交叉复分解的功能化公开(公告)号：US08604148B2
公开(公告)日：2013-12-10
申请号：US13306263
申请日：2011-11-29
Applicant: Matthew W. Holtcamp , Donna J. Crowther , Caol P. Huff , Patrick Brant , Jacqueline A. Lovell
Inventor： Matthew W. Holtcamp , Donna J. Crowther , Caol P. Huff , Patrick Brant , Jacqueline A. Lovell
IPC: C08F293/00 , C08F285/00
CPC classification number: C08F222/04 , C08F293/00 , C08G61/08 , C08G61/124 , C08G61/125 , C08G61/126 , C08G2261/3324 , C08G2261/3342 , C08G2261/418
Abstract: This invention relates to a polymer of a cyclic olefin and a vinyl terminated macromonomer, and processes for the production thereof.
Abstract translation: 本发明涉及环烯烃和乙烯基封端的大分子单体的聚合物及其生产方法。
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公开(公告)号：US20130281626A1
公开(公告)日：2013-10-24
申请号：US13449939
申请日：2012-04-18
Applicant: Mun F. Tse , Aspy K. Mehta , Joann M. Canich , Matthew W. Holtcamp , John R. Hagadorn , Charles J. Ruff
Inventor： Mun F. Tse , Aspy K. Mehta , Joann M. Canich , Matthew W. Holtcamp , John R. Hagadorn , Charles J. Ruff
CPC classification number: C08F290/048 , C08F8/50 , C08F290/044 , C08F299/00 , C08F2800/20 , C08F2810/30 , C08F2810/40 , C08K5/134 , C08K5/526 , C08L23/0815 , C08L27/12 , C08L51/06 , C08F297/04 , C08F210/02
Abstract: This invention relates to methods for producing an alkene terminated polystyrene, including: contacting a styrenic block copolymer and an alkene in the presence of a metathesis catalyst under conditions sufficient to produce an alkene terminated polystyrene having an unsaturation functionality of at least 0.7 and a MWD of about 1.5 or less. Methods for producing functionalized polymers and polyethylene blend composition comprising these functionalized polymers are also disclosed.
Abstract translation: 本发明涉及烯烃封端聚苯乙烯的制备方法，包括：在复分解催化剂存在下，使苯乙烯嵌段共聚物和烯烃接触，条件是足以产生不饱和官能度至少为0.7的烯烃封端聚苯乙烯，MWD为 约1.5以下。 还公开了制备官能化聚合物的方法和包含这些官能化聚合物的聚乙烯共混组合物。
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公开(公告)号：US20130274425A1
公开(公告)日：2013-10-17
申请号：US13446145
申请日：2012-04-13
Applicant: Matthew W. Holtcamp , Donna J. Crowther , Caol P. Huff , Patrick Brant
Inventor： Matthew W. Holtcamp , Donna J. Crowther , Caol P. Huff , Patrick Brant
CPC classification number: C08G61/02 , C08G2261/126 , C08G2261/352 , C08G2261/419 , C08F110/06 , C08F2500/02 , C08F2500/17 , C08F210/06 , C08F210/14
Abstract: This invention relates to processes for increasing the viscosity of an oligomer composition including contacting the oligomer composition comprising one or more vinyl terminated oligomer with a supported mixed metal oxide catalyst; wherein the contacting causes the reaction of the vinyl terminated oligomers; and producing a product oligomer composition having a higher viscosity than the oligomer composition.
Abstract translation: 本发明涉及提高低聚物组合物粘度的方法，包括将包含一种或多种乙烯基封端的低聚物的低聚物组合物与负载的混合金属氧化物催化剂接触; 其中所述接触引起所述乙烯基封端的低聚物的反应; 并制备粘度高于低聚物组合物的产物低聚物组合物。
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5.发明申请公开(公告)号：US20130150541A1
公开(公告)日：2013-06-13
申请号：US13754422
申请日：2013-01-30
Applicant: Donna J. Crowther , Matthew W. Holtcamp , John R. Hagadorn , Charles J. Ruff , George Rodriguez , Patrick Brant
Inventor： Donna J. Crowther , Matthew W. Holtcamp , John R. Hagadorn , Charles J. Ruff , George Rodriguez , Patrick Brant
IPC: C08F232/08 , C08F210/14
CPC classification number: C08F232/08 , C08F210/14 , Y10S526/943 , C08F210/06 , C08F2500/02
Abstract: This invention relates to a vinyl terminated higher olefin copolymer having an Mn of 300 g/mol or more (measured by 1H NMR) comprising: (i) from about 20 to about 99.9 mol % of at least one C5 to C40 higher olefin monomer; and (ii) from about 0.1 to about 80 mol % of propylene; wherein the higher olefin copolymer has at least 40% allyl chain ends. The copolymer may also have an isobutyl chain end to allyl chain end ratio of less than 0.7:1 and/or an allyl chain end to vinylidene chain end ratio of greater than 2:1.
Abstract translation: 本发明涉及Mn为300g / mol或更高（通过1 H NMR测量）的乙烯基封端的高级烯烃共聚物，其包含：（i）约20-约99.9mol％的至少一种C 5至C 40高级烯烃单体; 和（ii）约0.1至约80mol％的丙烯; 其中所述较高级烯烃共聚物具有至少40％的烯丙基链端。 该共聚物也可以具有小于0.7:1的异丁基链端与烯丙基链末端比和/或烯丙基链端与亚乙烯基链末端比大于2:1。
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Patent Agency Ranking
6.发明申请Functionalization of Vinyl Terminated Polymers by Ring Opening Cross Metathesis 有权乙烯基封端聚合物通过开环交叉复分解功能化公开(公告)号：US20130137829A1
公开(公告)日：2013-05-30
申请号：US13306263
申请日：2011-11-29
Applicant: Matthew W. Holtcamp , Donna J. Crowther , Caol P. Huff , Patrick Brant , Jacqueline A. Lovell
Inventor： Matthew W. Holtcamp , Donna J. Crowther , Caol P. Huff , Patrick Brant , Jacqueline A. Lovell
IPC: C08F222/04 , C08F255/08 , C08F255/10
CPC classification number: C08F222/04 , C08F293/00 , C08G61/08 , C08G61/124 , C08G61/125 , C08G61/126 , C08G2261/3324 , C08G2261/3342 , C08G2261/418
Abstract: This invention relates to a polymer of a cyclic olefin and a vinyl terminated macromonomer, and processes for the production thereof.
Abstract translation: 本发明涉及环烯烃和乙烯基封端的大分子单体的聚合物及其生产方法。
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7.发明申请公开(公告)号：US20120309998A1
公开(公告)日：2012-12-06
申请号：US13149012
申请日：2011-05-31
Applicant: Matthew W. HOLTCAMP , Matthew S. BEDOYA
Inventor： Matthew W. HOLTCAMP , Matthew S. BEDOYA
CPC classification number: C07F15/0046 , B01J31/2265 , B01J31/24 , B01J2231/543 , B01J2531/821 , B01J2531/825 , C07C6/06 , C07C2531/22 , C07C2531/24 , C07C13/44 , C07C13/68
Abstract: This invention relates to a metathesis catalyst comprising a Group 8 metal complex represented by the formula: wherein: M is a Group 8 metal; each X is independently an anionic ligand; R1 and R2 are independently selected from the group consisting of hydrogen, a C1 to C30 hydrocarbyl, and a C1 to C30 substituted hydrocarbyl; R3 and R4 are independently selected from the group consisting of hydrogen, C1 to C12 hydrocarbyl groups, substituted C1 to C12 hydrocarbyl groups, and halides; and L is a neutral donor ligand. This invention also relates to processes for performing a metathesis reaction, in particular ring opening cross metathesis reactions and ring opening metathesis polymerization reactions, using the Group 8 metal complexes.
Abstract translation: 本发明涉及包含由下式表示的第8族金属络合物的复分解催化剂：其中：M是第8族金属; 每个X独立地是阴离子配体; R 1和R 2独立地选自氢，C 1至C 30烃基和C 1至C 30取代的烃基; R3和R4独立地选自氢，C1至C12烃基，取代的C1至C12烃基和卤化物; L是中性供体配体。 本发明还涉及使用第8族金属络合物进行复分解反应，特别是开环交叉复分解反应和开环易位聚合反应的方法。
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8.发明授权Class of olefin metathesis catalysts, methods of preparation, and processes for the use thereof 有权烯烃复分解催化剂类，制备方法及其使用方法公开(公告)号：US08227371B2
公开(公告)日：2012-07-24
申请号：US12890315
申请日：2010-09-24
Applicant: Matthew W. Holtcamp , Matthew S. Bedoya , Laughlin G. McCullough
Inventor： Matthew W. Holtcamp , Matthew S. Bedoya , Laughlin G. McCullough
CPC classification number: C07F15/002 , B01J31/0231 , B01J31/2414 , B01J2231/543 , B01J2531/0213 , B01J2531/821 , B01J2531/825 , C07F15/0046
Abstract: This invention relates to a metathesis catalyst comprising (i) a Group 8 metal hydride-dihydrogen complex represented by the formula: wherein M is a Group 8 metal; X is an anionic ligand; and L1 and L2 are neutral donor ligands; and (ii) a ligand exchange agent represented by the formula J-Y, wherein J is selected from the group consisting of hydrogen, a C1 to C30 hydrocarbyl, and a C1 to C30 substituted hydrocarbyl; and Y is selected from the group consisting of halides, alkoxides, aryloxides, and alkyl sulfonates.
Abstract translation: 本发明涉及复分解催化剂，其包含（i）由下式表示的第8族金属氢化物 - 二氢配合物：其中M是第8族金属; X是阴离子配体; L1和L2是中性供体配体; 和（ii）由式J-Y表示的配体交换剂，其中J选自氢，C1至C30烃基和C1至C30取代的烃基; Y选自卤化物，醇盐，芳氧化物和烷基磺酸盐。
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9.发明申请公开(公告)号：US20120053309A1
公开(公告)日：2012-03-01
申请号：US13209215
申请日：2011-08-12
Applicant: Matthew W. Holtcamp , John R. Hagadorn , Matthew S. Bedoya
Inventor： Matthew W. Holtcamp , John R. Hagadorn , Matthew S. Bedoya
IPC: C08F236/20 , B01J19/00 , C08F4/76
CPC classification number: C08F236/20 , C08C2019/09 , C08F4/65908 , C08F210/14 , C08F4/65927 , C08F2500/17
Abstract: This invention relates to a process to produce a poly(alpha-olefin)(alpha, internally unsaturated, nonconjugated olefin) comprising: contacting at least one renewable feedstream with at least one lower olefin in the presence of a metathesis catalyst, wherein a mixture of at least one C4 to C40 linear alpha-olefin and at least one alpha, internally unsaturated, nonconjugated olefin is produced; and contacting the mixture with a metallocene catalyst system, wherein a poly(alpha-olefin)(alpha, internally unsaturated, nonconjugated olefin) is produced.
Abstract translation: 本发明涉及一种生产聚（α-烯烃）（α，内部不饱和的非共轭烯烃）的方法，包括：在复分解催化剂存在下使至少一种可再生的原料流与至少一种低级烯烃接触，其中将 产生至少一种C 4至C 40直链α-烯烃和至少一种α内部不饱和非共轭烯烃; 并使该混合物与金属茂催化剂体系接触，其中制备聚（α-烯烃）（α，内部不饱和的非共轭烯烃）。
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公开(公告)号：US07692046B2
公开(公告)日：2010-04-06
申请号：US11821020
申请日：2007-06-21
Applicant: Matthew W. Holtcamp , Renuka N. Ganesh , Tan-Jen Chen , Jihad M. Dakka
Inventor： Matthew W. Holtcamp , Renuka N. Ganesh , Tan-Jen Chen , Jihad M. Dakka
IPC: C07C409/00
CPC classification number: B01J23/745 , B01J31/0211 , B01J31/0252 , B01J35/0033 , B01J37/0203 , B01J2231/70 , C07C407/00 , C07C409/10 , C07C409/14 , C07C2601/14 , C07C409/08
Abstract: A promoter can have utility in selective heterogeneous oxidation of arylalkyl hydrocarbons such as, for example, cyclohexyl benzene and/or sec-butyl benzene to form hydroperoxides. The promoter can include the product of contacting a solid support comprising a metal oxide surface and an iron compound. The solid support can include, for example, titanium dioxide and/or an iron oxide such as magnetite and can have magnetic susceptibility. A method for the oxidation of arylalkyl hydrocarbons to form hydroperoxides can include contacting 16 an arylalkyl hydrocarbon with oxygen in the presence of the promoter under catalytic oxidation conditions to form arylalkyl hydroperoxide, which can then be converted to phenol via cleavage 26. The method can include recovery 22 of the promoter from the arylalkyl hydroperoxide and can further include recycling the recovered promoter to the contacting 16. Where the solid support has magnetic susceptibility, the recovery 22 can include magnetic separation of the promoter.
Abstract translation: 助催化剂可用于芳基烷基烃例如环己基苯和/或仲丁基苯的选择性异相氧化以形成氢过氧化物。 助催化剂可以包括使包含金属氧化物表面和铁化合物的固体载体接触的产物。 固体支持体可以包括例如二氧化钛和/或氧化铁如磁铁矿，并且可以具有磁化率。 用于氧化芳基烷基烃以形成氢过氧化物的方法可以包括在催化氧化条件下在助催化剂存在下使芳烷基烃与氧接触，形成芳基烷基氢过氧化物，然后可通过裂解将其转化为苯酚。该方法可包括 从芳基烷基氢过氧化物中回收22个启动子，并且可以进一步包括将回收的促进剂再循环到接触16.当固体支持物具有磁化率时，回收22可以包括促进剂的磁性分离。
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