公开(公告)号：US20180237564A1

公开(公告)日：2018-08-23

申请号：US15750123

申请日：2016-07-19

Applicant: BASELL POLIOLEFINE ITALIA S.R.L.

Inventor： PAOLA MASSARI ,  FABRIZIO PIEMONTESI ,  GIANNI VITALE ,  CAROLINE CATHELIN ,  GIAMPIERO MORINI ,  CLAUDIO CAVALIERI ,  MARCO CIARAFONI ,  ROBERTO PANTALEONI

IPC: C08F210/06 ,  C08J5/18

Abstract: A polyolefin composition made from or containing:A) from about 19 wt % to about 50 wt % of a propylene ethylene copolymer having an ethylene derived units content ranging from about 1.5 wt % to about 6.0 wt %B) from about 50 wt % to about 81 wt % of a propylene ethylene 1-butene terpolymer having an ethylene derived units content ranging from about 1.5 wt % to about 6.0 wt % and 1-butene derived units content between about 4.8 wt % and about 12.4 wt %;the sum of the amount of component A) and B) being 100;the polyolefin composition being characterized by the following features: molecular weight distribution (MWD), expressed in terms of Mw/Mn, greater than about 4.0; the creep and recovery curve measured on the polymer fuse at 200° C. shows a maximum value between 600 and 1200 seconds, lower than about 53×10−4 l/Pa.

公开(公告)号：US20180230253A1

公开(公告)日：2018-08-16

申请号：US15750391

申请日：2016-07-14

Applicant: BASELL POLIOLEFINE ITALIA S.R.L.

Inventor： GIUSEPPINA MARIA ALGOZZINI ,  DIEGO BRITA ,  MASSIMO CENCI ,  GIANNI COLLINA ,  TIZIANO DALL'OCCO ,  MARIA DI DIEGO ,  BENEDETTA GADDI ,  OFELIA FUSCO ,  GIAMPIERO MORINI ,  LORELLA PEDRIALI

IPC: C08F110/06 ,  C08F110/02 ,  C08F2/34 ,  C08F4/649 ,  C08F4/651

CPC classification number: C08F110/06 ,  C08F2/34 ,  C08F4/6492 ,  C08F4/651 ,  C08F10/06 ,  C08F110/02 ,  C08F2500/12 ,  C08F2500/15 ,  C08F2500/18 ,  C08F4/6543

Abstract: A Prepolymerized catalyst component for the polymerization of olefins comprising a solid catalyst component which comprises Mg, Ti, and chlorine atoms and an electron donor (ID) said prepolymerized catalyst component being characterized by the fact that: the electron donor (ID) is constituted by at least 80% mol of 1,3 diethers with respect to the total molar amount of electron donor compounds; the prepolymerized catalyst has a porosity due to pores with diameters up to 1 μm of less than 0.2 cm3/g; it contains an amount of ethylene prepolymer of less than 45% with respect to the total weight of prepolymerized catalyst.

公开(公告)号：US20180230247A1

公开(公告)日：2018-08-16

申请号：US15516651

申请日：2015-09-28

Applicant: BASELL POLIOLEFINE ITALIA S.R.L.

Inventor： SIMON GUIDOTTI

IPC: C08F4/649 ,  C08F4/645 ,  C08F4/642 ,  C08F10/06

CPC classification number: C08F4/6494 ,  C08F4/642 ,  C08F4/6455 ,  C08F4/6493 ,  C08F10/06 ,  C08F110/06 ,  C08F4/025 ,  C08F4/6574 ,  C08F2500/15

Abstract: A catalyst component comprising Ti, Mg, Cl, and an electron donor compound having porosity of at least 0.2 cm3/g and characterized by the fact that it further comprises Cu oxide, with the proviso that when the electron donor compound is selected from esters of phthalic acids, the porosity is of at least 0.45 cm3/g.

公开(公告)号：US09938359B2

公开(公告)日：2018-04-10

申请号：US14760949

申请日：2013-12-18

Applicant: Basell Poliolefine Italia S.r.l.

Inventor： Massimo Covezzi ,  Gabriele Mei ,  Pietro Baita ,  Lorella Marturano

IPC: C08F10/02 ,  C08F2/34 ,  C08F2/44 ,  C08F2/00 ,  C08F110/02

CPC classification number: C08F10/02 ,  C08F2/005 ,  C08F2410/02 ,  C08F110/02 ,  C08F2500/12 ,  C08F2500/18 ,  C08F2500/24

Abstract: A process for the preparation of ethylene polymers comprising polymerizing ethylene, optionally with one or more α-olefin comonomers, in the presence of:(i) a solid catalyst component comprising titanium, magnesium, halogen and optionally an internal electron-donor compound,(ii) an aluminum alkyl compound, and(iii) an antistatic compound selected among the hydroxyesters with at least two free hydroxyl groups,wherein the weight ratio of aluminum alkyl compound to solid catalyst component is higher than 0.80 and the weight ratio of antistatic compound to aluminum alkyl compound is higher than 0.10.

公开(公告)号：US20180057621A1

公开(公告)日：2018-03-01

申请号：US15557014

申请日：2016-03-07

Applicant: BASELL POLIOLEFINE ITALIA S.R.L.

Inventor： Alessandro MIGNOGNA ,  Giampiero MORINI

IPC: C08F110/06

CPC classification number: C08F110/06 ,  C08F4/649 ,  C08F4/6495 ,  C08F4/6498 ,  C08F4/654 ,  C08F4/655 ,  C08F2410/01 ,  C08F4/651 ,  C08F2500/12 ,  C08F2500/15

Abstract: A solid catalyst component for the polymerization of olefins made from or containing Mg, Ti, halogen and an electron donor of formula (I) or (II): When activated with an aluminum alkyl and optionally an external electron donor, the solid catalyst component can give high activity and stereospecificity in the polymerization of olefins.

公开(公告)号：US20170327613A1

公开(公告)日：2017-11-16

申请号：US15531804

申请日：2015-11-17

Applicant: BASELL POLIOLEFINE ITALIA S.R.L.

Inventor： Marco CIARAFONI ,  Mara DESTRO ,  Paola MASSARI ,  Tiziana CAPUTO ,  Thomas BÖHM

IPC: C08F210/06 ,  B65D1/02

CPC classification number: C08F210/06 ,  B65D1/02 ,  C08F10/06 ,  C08F210/14 ,  C08F210/16 ,  C08F2500/12 ,  C08F2500/21 ,  C08F2/001

Abstract: The present disclosure relates to a container comprising a propylene, ethylene, and 1-hexene terpolymer comprising: (i) an ethylene content of 0.6-1.1 wt %; (ii) a 1-hexene content of 1.1-2.8 wt %; (iii) an ethylene to 1-hexene ratio (C2/C6) that fulfills the following equation (I); C2/C6

公开(公告)号：US09803074B2

公开(公告)日：2017-10-31

申请号：US14645488

申请日：2015-03-12

Applicant: Equistar Chemicals, LP ,  Basell Poliolefine Italia S.r.l.

Inventor： Maged G. Botros ,  Enrico Costantini ,  Charles S. Holland ,  Chun Lee ,  Enrico Masarati

IPC: C08L23/10

CPC classification number: C08L23/10 ,  C08L23/14 ,  C08L23/16 ,  C08L51/06 ,  C08L2203/16 ,  C09J123/14 ,  C08L23/02

Abstract: The present disclosure provides a polyolefin-based composition suitable for use as adhesives and/or tie-layer adhesive compositions as well as a multi-layered structure made from and/or containing the polyolefin-based composition. The polyolefin-based composition is made from and/or contains (a) a grafted polyolefin composition, (b) a first polymer composition, (c) a polypropylene-containing blend composition, and (d) optionally, an additives composition having one or more additives.

公开(公告)号：US09752023B2

公开(公告)日：2017-09-05

申请号：US14358753

申请日：2012-11-07

Applicant: Basell Poliolefine Italia S.r.l.

Inventor： Monica Galvan ,  Roberto Pantaleoni ,  Ofelia Fusco ,  Benedetta Gaddi ,  Andreas Neumann ,  Antonio Mazzucco ,  Gianni Collina ,  Marco Ciarafoni

IPC: C08L23/12 ,  C08F10/06

CPC classification number: C08L23/12 ,  C08F10/06 ,  C08F4/651 ,  C08F4/6543 ,  C08F2/00 ,  C08F210/16 ,  C08F210/06 ,  C08F2500/11 ,  C08F2500/12 ,  C08F2500/17 ,  C08F2500/21 ,  C08F2/001 ,  C08F110/06 ,  C08L23/16

Abstract: Preparing propylene polymer compositions comprising 50 to 90% by weight of a propylene (co)polymer, and 10 to 50% by weight of an ethylene copolymer. The polymerization process includes, in the presence of a catalyst system: (i) a first step of polymerizing propylene to produce the propylene (co)polymer; and (ii) a successive gas-phase polymerization step performed in the presence of the propylene (co)polymer, ethylene, and one or more α-olefins to produce the ethylene copolymer. The catalyst system contains the product obtained by contacting: (a) a solid catalyst component comprising at least two internal electron donor compounds, a succinate and a 1,3-diether; (b) an aluminum hydrocarbyl compound, and (c) optionally, an external electron donor compound.

公开(公告)号：US20170218100A1

公开(公告)日：2017-08-03

申请号：US15514871

申请日：2015-09-22

Applicant: BASELL POLIOLEFINE ITALIA S.R.L.

Inventor： PEITRO BAITA ,  TIZIANO DALL'OCCO ,  MARIA DI DIEGO ,  DARIO LIGUORI ,  LORELLA MARTURANO ,  GABRIELE MEI ,  GIAMPIERO MORINI ,  ROBERTA PICA

IPC: C08F110/02

CPC classification number: C08F110/02 ,  C08F2410/02 ,  C08F2500/12 ,  C08F2500/18 ,  C08F4/6494 ,  C08F4/6493 ,  C08F4/6492 ,  C08F4/6543

Abstract: The present disclosure provides a catalyst system made from or containing: (A) a solid catalyst component made from or containing (i) a titanium compound supported on a magnesium dichloride; (B) an aluminum alkyl compound; and (C) a halogenated organic ester of formula A-COOR, wherein R is a C1-C10 hydrocarbon group and A is a C1-C15 saturated or unsaturated hydrocarbon group in which at least one of the hydrogen atoms is replaced by a chlorine atom. The present disclosure also provides a process for preparing an olefinic polymer, including a polymerization step of polymerizing an olefin in the presence of the catalyst system. The present disclosure also provides an olefinic polymer made therefrom.

公开(公告)号：US20170198125A1

公开(公告)日：2017-07-13

申请号：US15321321

申请日：2015-06-08

Applicant: BASELL POLIOLEFINE ITALIA S.R.L.

Inventor： TAKESHI TSUKAHARA ,  NOBUYUKI TSURUMI ,  SHITOSHI KANNO ,  KUNIO YAMAMOTO ,  TAKESHI NAKAJIMA

IPC: C08L23/12

Abstract: The present disclosure generally relates to a heterophasic polypropylene composition comprising 68-76% by weight of a propylene homopolymer or copolymer matrix, 24-32% by weight of an ethylene-propylene copolymer, and a nucleating agent. In some embodiments, the composition has an intrinsic viscosity of the xylene soluble (XSIV) fraction at room temperature of up to 1.3 dl/g and a melt flow rate (230° C., 2.16 kg) of 30 to 70 g/10 min. The compositions disclosed herein can be used in molded articles, using techniques such as thin wall injection molding, that are endowed with excellent impact behavior.