公开(公告)号：US4644036A

公开(公告)日：1987-02-17

申请号：US604084

申请日：1984-04-26

Applicant: Gerd Walz ,  Ernst-August Theiling

Inventor： Gerd Walz ,  Ernst-August Theiling

IPC: C08F8/00 ,  C08G59/40 ,  C08G59/42 ,  C08G59/50 ,  C08G59/58 ,  C08G85/00 ,  C08K5/00 ,  C08K5/10 ,  C08K5/20 ,  C08L33/00 ,  C08L33/02 ,  C08L77/00 ,  C09D5/44 ,  C09D201/00 ,  C09D201/02 ,  C08G59/14

CPC classification number: C08G59/42 ,  C08G59/4014 ,  C08G59/58 ,  C08K5/0025 ,  C09D5/4496

Abstract: Michael addition products of monocarboxylic or dicarboxylic acid esters, capable of undergoing Michael addition, with compounds containing double bonds capable of undergoing Michael addition are suitable for use as a curing component for synthetic resins containing groups capable of amide formation and/or ester formation with carboxylic acids. In particular, the Michael addition products of acetoacetic esters or malonic esters with esters, amides or urea derivatives of .alpha., .beta.-unsaturated monocarboxylic or dicarboxylic acids are used. The structure and the functionality of the curing component can be varied in many ways. It can be attached directly to the synthetic resin molecule, so that self-curing synthetic resins are obtained.

Abstract translation: 能够进行迈克尔加成的单羧酸或二羧酸酯与含有能够进行迈克尔加成的双键的化合物的迈克尔加成产物适合用作含有能够与羧酸形成酰胺和/或与酯形成的基团的合成树脂的固化组分 酸。 特别地，使用乙酰乙酸酯或丙二酸酯与α，β-不饱和一元羧酸或二羧酸的酯，酰胺或脲衍生物的迈克尔加成产物。 固化组分的结构和功能可以以许多方式变化。 它可以直接连接到合成树脂分子上，从而获得自固化合成树脂。

公开(公告)号：US4622117A

公开(公告)日：1986-11-11

申请号：US699149

申请日：1985-02-07

Applicant: Michael Geist ,  Gunther Ott

Inventor： Michael Geist ,  Gunther Ott

IPC: C08G59/00 ,  C08G59/50 ,  C08G59/52 ,  C08G59/58 ,  C08G59/62 ,  C09D5/44 ,  C09D17/00 ,  C09D163/00 ,  C09D201/02 ,  C09D201/06 ,  C25D13/06 ,  C08G59/14 ,  C08G59/16

CPC classification number: C08G59/625 ,  C08G59/58 ,  C09D163/00 ,  C09D17/00 ,  C09D5/4446 ,  C09D5/4488 ,  Y10T428/31529 ,  Y10T428/31681 ,  Y10T428/31699

Abstract: The invention relates to a self-crosslinking heat-curable binder, in particular for electrocoating finishes, based on an organic synthetic resin which contains primary and/or secondary hydroxyl groups, esterified carboxyl groups and quaternary ammonium groups and can be diluted with water as a result of partial or complete neutralization with acids. The esterified carboxyl groups are activated in the alcohol component by a substituent which has a negative inductive effect.

Abstract translation: 本发明涉及一种自交联热固化性粘合剂，特别是电泳涂料，其基于含有伯和/或仲羟基，酯化羧基和季铵基团的有机合成树脂，并且可以用水稀释 部分或完全用酸中和的结果。 酯化的羧基在醇组分中通过具有负诱导作用的取代基活化。

公开(公告)号：US4563492A

公开(公告)日：1986-01-07

申请号：US574963

申请日：1984-01-30

Applicant: Hirotoshi Umemoto ,  Hisaki Tanabe ,  Akihiro Kanakura ,  Shinji Nakano

Inventor： Hirotoshi Umemoto ,  Hisaki Tanabe ,  Akihiro Kanakura ,  Shinji Nakano

IPC: C09D161/20 ,  C08G18/08 ,  C08G63/685 ,  C09D161/32 ,  C09D167/00 ,  C09D175/00 ,  C09D175/04 ,  C09D175/06 ,  C09D201/02 ,  C08L67/08 ,  C08K5/34

CPC classification number: C09D161/32 ,  C08G18/0833 ,  C08G63/685 ,  C09D167/00

Abstract: A resinous composition for coating use comprising an amphoteric resin having an acidic resinous component and a basic component of a basic compound, and an amino-formaldehyde resin etherified with monohydric alcohol having 1 to 4 carbon atoms and/or isocyanate compound, which is characterized by the fact that the basic component of a said amphoteric resin consists of a basic compound whose titration midpoint potential in non-aqueous potentiometric titration, when incorporated into the resin, is less than 450 mV, and the basicity of the amphoteric resin is within the range of 1.0.times.10.sup.-2 to 1.0 m mol/g solid. This composition can exhibit excellent pigment dispersibility and is useful as resinous vehicle for a coating composition to be used as a top coat for automobile bodies and the like.

Abstract translation: 一种涂料用树脂组合物，其包含具有酸性树脂成分和碱性化合物碱性成分的两性树脂和与1〜4个碳原子的一元醇醚化的氨基甲醛树脂和/或异氰酸酯化合物，其特征在于， 所述两性树脂的基本成分由在非水电位滴定中的滴定中点电位（当结合到树脂中）小于450mV的碱性化合物组成时，两性树脂的碱度在 为1.0×10 -2〜1.0m mol / g固体。 该组合物可以表现出优异的颜料分散性，并且可用作用作汽车车身等的顶涂层的涂料组合物的树脂载体。

公开(公告)号：US4539359A

公开(公告)日：1985-09-03

申请号：US520685

申请日：1983-08-05

Applicant: Yasushi Kato ,  Hisao Furukawa

Inventor： Yasushi Kato ,  Hisao Furukawa

IPC: C08F8/42 ,  C08K5/52 ,  C08L57/00 ,  C08L57/06 ,  C09D133/04 ,  C09D143/04 ,  C09D157/06 ,  C09D201/02 ,  C09J11/06 ,  C09J157/06 ,  C09K3/10 ,  C08F8/40

CPC classification number: C09D143/04

Abstract: A one component moisture curable composition containing (A) a hydrolyzable silyl group-containing vinyl polymer and (B) an acid phosphoric compound having ##STR1## linkage in the molecule as a hardener, which has excellent recoatability, curing property and adhesion to other paint films and is particularly suitable as a coating composition for use in multicoat coating.

Abstract translation: 含有（A）含水解性甲硅烷基的乙烯基聚合物和（B）分子中具有“IMAGE”键的酸性磷酸化合物作为硬化剂的单组分湿气固化组合物，其具有优异的可再涂性，固化性能和与其它涂料的粘合性 并且特别适用于用于多涂层的涂料组合物。

公开(公告)号：US4528318A

公开(公告)日：1985-07-09

申请号：US462235

申请日：1983-01-31

Applicant: Sakuichi Konishi ,  Naohito Shingo ,  Mathuo Shibayama

Inventor： Sakuichi Konishi ,  Naohito Shingo ,  Mathuo Shibayama

IPC: C09D5/00 ,  C09D5/02 ,  C09D201/00 ,  C09D201/02 ,  C09D201/06 ,  C09D201/08 ,  C08L51/00

CPC classification number: C09D201/06

Abstract: An aqueous coating composition which comprises an aqueous resin having a carboxyl group (I) and a water-insoluble resin powder (II), the aqueous resin (I) being the one dispersible or soluble into an aqueous medium by ionization when the carboxyl group is neutralized with a basic substance, and the water-insoluble resin powder (II) being the one of 5 to 100 in acid value obtained by reaction between a carboxyl group-containing resin of 20 to 300 in acid value in a solid state at room temperature and a monoepoxy compound or a monoisocyanate compound.

Abstract translation: 一种水性涂料组合物，其包含具有羧基（I）和水不溶性树脂粉末（II）的水性树脂，所述水性树脂（I）是当所述羧基为羧基时，通过离子化可分散或溶解于水性介质中的水性树脂 用碱性物质中和，水溶性树脂粉末（II）为酸值的5〜100的酸值，通过在室温下的固体状态的酸值为20〜300的羧基树脂反应而得到 和单环氧化合物或单异氰酸酯化合物。

公开(公告)号：US4507437A

公开(公告)日：1985-03-26

申请号：US564905

申请日：1983-12-23

Applicant: Yasushi Kato ,  Hisao Furukawa

Inventor： Yasushi Kato ,  Hisao Furukawa

IPC: C08K5/00 ,  C08K5/17 ,  C08K5/52 ,  C08K5/521 ,  C08L33/00 ,  C08L33/02 ,  C08L101/00 ,  C08L101/10 ,  C09D201/02 ,  C09D201/10 ,  C09J11/06 ,  C09J201/10 ,  C09K3/10 ,  C08F8/00

CPC classification number: C08K5/521

Abstract: A moisture curable composition comprising (I) a hydrolyzable silyl group-containing vinyl polymer and (II) a combined curing catalyst system of (a) an organic phosphorus-containing compound such as an organic acid phosphate, an organic acid phosphite, or an acid titanium phosphate such as those known as titanate coupling agent and (b) an amine compound. The composition has well balanced pot life and curability and provides a cured product having an excellent appearance, and the curability can be arbitrarily controlled according to the purposes by selecting the ratio of the components (a) and (b).

Abstract translation: 一种防湿固化组合物，其包含（I）含水解性甲硅烷基的乙烯基聚合物和（II）（a）有机磷化合物如有机磷酸酯，有机酸亚磷酸酯或酸的组合固化催化剂体系 磷酸钛如钛酸酯偶联剂和（b）胺化合物。 该组合物具有良好的适用期和固化性，并且提供具有优异外观的固化产物，并且可以通过选择组分（a）和（b）的比例根据目的任意控制固化性。

公开(公告)号：US4506052A

公开(公告)日：1985-03-19

申请号：US584858

申请日：1984-02-29

Applicant: Hisao Furukawa ,  Yasushi Kato

Inventor： Hisao Furukawa ,  Yasushi Kato

IPC: C08K5/00 ,  C08K5/07 ,  C08K5/10 ,  C08K5/54 ,  C08L33/00 ,  C08L33/02 ,  C08L101/00 ,  C08L101/02 ,  C09D201/02

CPC classification number: C08K5/54

Abstract: A one component room temperature setting composition having an excellent storage stability comprising a hydrolyzable silyl group-containing vinyl polymer, a hardener and a stabilizer selected from a hydrolyzable ester compound and a .beta.-diketone compound, which may further contain a pigment and a solvent. The storage stability of the composition containing the hydrolyzable silyl group-containing vinyl polymer which is crosslinkable in the presence of water to harden at room temperature, can be remarkably improved by the presence of the above stabilizer.

公开(公告)号：US4501833A

公开(公告)日：1985-02-26

申请号：US495306

申请日：1983-05-16

Applicant: Joseph F. Bosso ,  William J. Geiger

Inventor： Joseph F. Bosso ,  William J. Geiger

IPC: C09D5/44 ,  C09D161/32 ,  C09D163/00 ,  C09D201/00 ,  C09D201/02 ,  C08L63/00

CPC classification number: C09D163/00 ,  C09D161/32 ,  C09D5/4453 ,  C09D5/4496 ,  Y10S524/901

Abstract: Aminoplast curable cationic coating compositions are disclosed. The coating compositions contain an onium salt group-containing polymer and an aminoplast curing agent which has at least one group of the structure: ##STR1## wherein R.sub.1 is carbon derived from an aldehyde or a ketone.

Abstract translation: 公开了氨基塑料固化阳离子涂料组合物。 涂料组合物含有含鎓盐基团的聚合物和氨基塑料固化剂，其具有至少一个以下结构的基团：其中R1是衍生自醛或酮的碳。

公开(公告)号：US4477642A

公开(公告)日：1984-10-16

申请号：US526071

申请日：1983-08-24

Applicant: Michael Geist ,  Horst Diefenbach

Inventor： Michael Geist ,  Horst Diefenbach

IPC: C08G18/08 ,  C08G18/32 ,  C08G59/42 ,  C08G59/56 ,  C08G59/58 ,  C09D5/44 ,  C09D163/00 ,  C09D175/00 ,  C09D201/02 ,  C08G18/34

CPC classification number: C08G18/0814 ,  C08G18/3221 ,  C08G59/4284 ,  C08G59/56 ,  C08G59/58 ,  C09D5/4446 ,  C09D5/4488 ,  Y10T428/31529 ,  Y10T428/31605

Abstract: The invention relates to a selfcrosslinking heat-hardenable binder, in particular for electropaints, which is based on an organic synthetic resin which contains hydroxyl groups and esterified carboxyl groups in the form of carbalkoxymethyl ester groups and is water-dilutable by partial or complete acid-neutralization of amino groups present in the resin.

Abstract translation: 本发明涉及一种自交联热硬化性粘合剂，特别是用于电极的自交联热粘合剂，其基于含有羟基的有机合成树脂和以烷氧基甲基酯基形式的酯化羧基，并且可通过部分或完全酸 - 中和树脂中存在的氨基。

公开(公告)号：US4452948A

公开(公告)日：1984-06-05

申请号：US298387

申请日：1981-09-01

Applicant: Alistair R. Marrion ,  Susan Roy ,  Frank E. Rowe

Inventor： Alistair R. Marrion ,  Susan Roy ,  Frank E. Rowe

IPC: C09D5/00 ,  C08L33/06 ,  C09D133/04 ,  C09D133/06 ,  C09D135/00 ,  C09D157/04 ,  C09D167/00 ,  C09D201/02 ,  C09D201/06 ,  C08F20/08

CPC classification number: C09D167/00 ,  C09D133/066 ,  C09D135/00 ,  C09D157/04 ,  C09D201/06 ,  C08L33/064

Abstract: A coating composition comprises a hydroxy component having at least two free hydroxyl groups per molecule and an anhydride component which is a polymer-containing cyclic carboxylic acid anhydride groups derived from an olefinically unsaturated cyclic carboxylic acid anhydride, the two components being packaged separately during storage of the composition and being compatible on mixing. At least one of the components is a film-forming polymer. The composition includes a catalytically effective amount of amine groups for accelerating the curing reaction between the hydroxyl groups and the anhydride groups. The amine groups are present in the molecule of the hydroxy component or in a separate amine compound. The hydroxy component is preferably a film-forming acrylic copolymer having pendent hydroxyl and dialkyl-amino-alkyl groups. The composition is particularly useful as a glossy pigmented coating for rigid substrates such as vehicle bodies where hardening of the coating at ambient temperature is required.

Abstract translation: 涂料组合物包含每分子具有至少两个游离羟基的羟基组分和一种酸酐组分，其是衍生自烯属不饱和环状羧酸酐的含聚合物的环状羧酸酐基团，该两种组分在储存期间分别包装 组合物和混合物相容。 至少一种组分是成膜聚合物。 组合物包含催化有效量的胺基，用于加速羟基和酸酐基团之间的固化反应。 胺基存在于羟基组分的分子中或分开的胺化合物中。 羟基成分优选为具有侧基羟基和二烷基 - 氨基 - 烷基的成膜性丙烯酸共聚物。 该组合物特别可用作用于刚性基材的光泽着色涂层，例如需要在环境温度下硬化涂层的车体。