Abstract:
A lithographic printing plate precursor capable of forming an image without undergoing alkali development, which comprises a hydrophilic support and a laser-sensitive photopolymerizing layer, wherein the photopolymerizing layer contains a polymer compound having at least one of an ether group, an ester group and an amido group in its molecule, particularly, in its side chain.
Abstract:
A lithographic printing process comprises the steps of: imagewise exposing to infrared light a presensitized lithographic plate which comprises a hydrophilic support and an image-forming layer containing an infrared absorbing agent, a polymerization initiator and a binder polymer to polymerize the polymerizable compound within the exposed area; removing the image-forming layer within the unexposed area while mounting the lithographic plate on a cylinder of a printing press; and then printing with the lithographic plate while mounting the lithographic plate on the cylinder of the printing press. The polymerization initiator is a salt of an anion with a sulfonium ion. According to the present invention, a specific anion or a specific sulfonium ion is used in the polymerization initiator.
Abstract:
The present invention provides a polymerizable composition comprising (A) a compound including a polymerizable unsaturated group and (B) a macromolecular compound including, at a side chain thereof, a structure represented by the following general formula (I): Z−M+ General formula (I) wherein Z− represents COCOO−, COO−, SO3−, or SO2—N−—R where R represents a monovalent organic group and M+ represents an onium cation. The present invention also provides a negative type planographic printing plate precursor responsive to an infrared laser, the precursor being superior in recording sensitivity and printing durability and using the polymerizable compound as a recording layer.
Abstract translation:本发明提供一种聚合性组合物,其含有(A)包含聚合性不饱和基团的化合物和(B)高分子化合物,其侧链具有下述通式(I)所示的结构: -formulae description =“在线公式”end =“lead”?> Z - SUP> M + SUPER +通用公式(I)<?in-line-formula description =“ 其中Z 0表示COCOO,SO 3,SO 3,SO 3, 或其中R代表一价有机基团,并且M + 代表鎓阳离子。 本发明还提供了响应于红外激光器的负型平版印刷版前体,其前体具有优异的记录灵敏度和印刷耐久性,并且使用可聚合化合物作为记录层。
Abstract:
Disclosed are a positive working planographic printing plate material comprising an aluminum support and provided thereon, a light sensitive layer, wherein the light sensitive layer contains an alkali soluble resin and pigment having on the surface a development restrainer and a positive working planographic printing plate material comprising an aluminum support and provided thereon, a lower light sensitive layer and an upper light sensitive layer in that order, each layer containing an alkali soluble resin, wherein at least one of the lower and upper light sensitive layers contains a pigment having on the surface a development restrainer.
Abstract:
A lithographic printing plate precursor includes an image-recording layer which is capable of being removed with at least one of printing ink and dampening water and contains a compound represented by the following formula (I), a sensitizing dye and a compound having at least one addition-polymerizable ethylenically unsaturated bond: wherein R1 represents a monovalent substituent, R2, R3, R4, R5 and R6 each independently represents a hydrogen atom, a halogen atom or a monovalent substituent, and X− represents an anion.
Abstract:
A planographic printing plate precursor includes a support having disposed thereon a recording layer containing a water-insoluble and alkali-soluble resin, a development inhibitor and an infrared absorber and exhibiting enhanced solubility in an aqueous alkali solution through light exposure. The recording layer may have either a mono-layer construction or a multi-layer construction containing a lower layer and an upper layer. In the case of the multi-layer construction, a layer containing the water-insoluble and alkali-soluble resin is used as the lower layer, and a layer containing the water-insoluble and alkali-soluble resin and the development inhibitor and exhibiting enhanced solubility in an aqueous alkali solution through light exposure is used as the upper layer, and at least one of the lower layer and the upper layer contains the infrared absorber.
Abstract:
Disclosed is a planographic printing plate material comprising an aluminum support and provided thereon, a lower layer and an upper layer in that order, wherein the lower layer contains a first alkali soluble resin, the upper layer contains a second alkali soluble resin and a light-to-heat conversion material, the second alkali soluble resin being a modified novolak resin having in the side chain a heterocyclic ring group containing both —(C═O)— and —NH— in the ring or a ureido group represented by the following formula (1), and wherein at least one of the upper and lower layers contains a third alkali soluble resin which is a modified acryl resin having in the side chain a heterocyclic ring group containing both —(C═O)— and —NH— in the ring or a ureido group represented by the following formula (1), —NHCONHR Formula (1)
Abstract:
A planographic printing plate precursor includes a substrate and an image recording layer provided thereon, the image recording layer being capable of recording through exposure to an infrared ray and containing at least (A) an infrared absorbing agent, (B) a polymerization initiator comprising an onium salt formed by an onium cation and a carboxylic acid anion, where the carboxylic acid anion has an acid group, a hetero atom and an aromatic group, (C) a polymerizable compound and (D) a binder polymer. The planographic printing plate precursor is exposed imagewise with an infrared laser. Then, printing is carried out using the exposed planographic printing plate precursor, which is set in a printer without being subjected to any developing process, by feeding an oil based ink and an aqueous component onto the planographic printing plate precursor. Unexposed areas of the planographic printing plate precursor are removed during the printing process.
Abstract:
A color image-forming material capable of drawing an image by infrared laser exposure and excellent in image visibility, storage stability and white light stability, and an on-press development or non-processing (non-development) type lithographic printing plate precursor ensuring high sensitivity and high press life and being excellent in image visibility, on-press developability and the like, are provided, which are a color image-forming material comprising an image recording layer capable of drawing an image by infrared laser exposure, the color image-forming material forming a color image without passing through a development processing step after image recording, wherein the image recording layer comprises (A) an infrared absorbent, (B) a cyclic color-forming compound having a cyclic structure within the molecule and forming a dye by a ring opening, and (C) a dye stabilizer which is a compound interacting with the cyclic color-forming compound to stabilize the ring-opened dye body and cause color formation and which is released from the interaction upon laser exposure to decrease in the color formation; and a lithographic printing plate precursor using this color image-forming material.
Abstract:
A lithographic printing plate precursor comprising a support and an image-recording layer which contains (A) a cyanine dye including a solvent-soluble group and having an absorption maximum in an infrared wavelength region and is capable of being removed with at least one of printing ink and an aqueous component.