Methods for manufacturing functionalized inorganic oxides and polymers incorporating same
    23.
    发明授权
    Methods for manufacturing functionalized inorganic oxides and polymers incorporating same 失效
    制备官能化无机氧化物的方法和包含其的聚合物

    公开(公告)号:US08097229B2

    公开(公告)日:2012-01-17

    申请号:US11333559

    申请日:2006-01-17

    IPC分类号: C01B33/12

    摘要: Inorganic oxide substrates are functionalized with silicon-free organic functionalizing agents. The organic functionalizing agent has a bonding functional group for bonding to the substrate and a functionalizing moiety that is not bonded to the substrate for imparting a desired functionality to the substrate. The functionalized inorganic oxide substrates are manufactured by selecting a functionalizing agent and reaction conditions that allows the bonding functional group to bond to the inorganic material while leaving the functionalizing moiety available for providing the desired functionality. The functionalized inorganic oxides can be used as filler materials in polymers or to manufacture a supported nanoparticle catalyst.

    摘要翻译: 无机氧化物底物用无硅有机官能化剂官能化。 有机官能化剂具有用于与基材结合的键合官能团和不与基材结合以赋予基材所需官能度的官能化部分。 官能化无机氧化物基材是通过选择官能化试剂和允许键合官能团与无机材料结合的反应条件制备的,同时留下官能化部分可用于提供所需官能度。 官能化无机氧化物可以用作聚合物中的填料或制备负载型纳米颗粒催化剂。

    Methods for making immobilized aryl-containing ligands
    24.
    发明授权
    Methods for making immobilized aryl-containing ligands 失效
    制备固定化含芳基的配体的方法

    公开(公告)号:US07772154B2

    公开(公告)日:2010-08-10

    申请号:US12389522

    申请日:2009-02-20

    摘要: Organic ligands that contain at least one aryl group are immobilized on a solid support. The organic ligands are of the type used to form a catalyst complex suitable for carrying out a catalytic reaction, preferably an asymmetric reaction. To immobilize the organic ligands, a tethering group is bonded to the ligand using, for example, a Friedel-Crafts acylation or alkylation reaction. The immobilization of the organic ligand can be carried out using a single reaction with the organic ligand.

    摘要翻译: 含有至少一个芳基的有机配体固定在固体载体上。 有机配体是用于形成适于进行催化反应,优选不对称反应的催化剂络合物的类型。 为了固定有机配体,使用例如Friedel-Crafts酰化或烷基化反应将束缚基团键合到配体上。 有机配体的固定可以使用与有机配体的单一反应进行。

    CARBON NANOSTRUCTURES MANUFACTURED FROM CATALYTIC TEMPLATING NANOPARTICLES
    25.
    发明申请
    CARBON NANOSTRUCTURES MANUFACTURED FROM CATALYTIC TEMPLATING NANOPARTICLES 审中-公开
    由催化态纳米粒子制备的碳纳米管

    公开(公告)号:US20100125035A1

    公开(公告)日:2010-05-20

    申请号:US12693915

    申请日:2010-01-26

    IPC分类号: C01B31/04 B01J21/18

    摘要: Methods for manufacturing carbon nanostructures include: 1) forming a plurality of catalytic templating particles using a plurality of dispersing agent molecules; 2) forming an intermediate carbon nanostructure by polymerizing a carbon precursor in the presence of the plurality of templating nanoparticles; 3) carbonizing the intermediate carbon nanostructure to form a composite nanostructure; and 4) removing the templating nanoparticles from the composite nanostructure to yield the carbon nanostructures. The carbon nanostructures are well-suited for use as a catalyst support. The carbon nanostructures exhibit high surface area, high porosity, and high graphitization. Carbon nanostructures according to the invention can be used as a substitute for more expensive and likely more fragile carbon nanotubes.

    摘要翻译: 制造碳纳米结构的方法包括:1)使用多个分散剂分子形成多个催化模板颗粒; 2)通过在多个模板纳米颗粒的存在下聚合碳前体形成中间碳纳米结构; 3)碳化中间碳纳米结构以形成复合纳米结构; 和4)从复合纳米结构中去除模板纳米颗粒以产生碳纳米结构。 碳纳米结构非常适合用作催化剂载体。 碳纳米结构表现出高的表面积,高孔隙率和高石墨化。 根据本发明的碳纳米结构可用作更昂贵且可能更脆弱的碳纳米管的替代物。

    NANOFIBERS AND METHODS OF MAKING SAME AND USING SAME IN HUMIDITY SENSORS
    26.
    发明申请
    NANOFIBERS AND METHODS OF MAKING SAME AND USING SAME IN HUMIDITY SENSORS 失效
    NANOFIBERS及其制造方法和在湿度传感器中使用相同的方法

    公开(公告)号:US20100043529A1

    公开(公告)日:2010-02-25

    申请号:US12544989

    申请日:2009-08-20

    IPC分类号: G01N19/10 B29C47/00

    摘要: A new type of highly efficient and self-cleaning humidity sensor based on Mg2+/Na+-doped TiO2 nanofiber mats is provided. Examples show the response and recovery characteristic curves for ten circles with the RH changing from 11% to 95%. The nanofibers are manufactured by mixing together a metal salt comprising titanium, a magnesium compound, a sodium compound, and a high molecular weight material to form a mixture, electrospinning the mixture to form composite nanofibers, and calcining the composite nanofibers to yield a TiO2 nanofiber material doped with magnesium and sodium.

    摘要翻译: 提供了一种基于Mg2 + / Na +掺杂的TiO2纳米纤维垫的新型高效自清洁湿度传感器。 示例显示了10个圆的响应和恢复特性曲线,RH从11%变化到95%。 纳米纤维通过将包含钛,镁化合物,钠化合物和高分子量材料的金属盐混合在一起而制备,以形成混合物,静电纺混合物以形成复合纳米纤维,并煅烧复合纳米纤维以产生TiO 2纳米纤维 掺杂镁和钠的材料。

    Reforming nanocatalysts and method of making and using such catalysts
    27.
    发明授权
    Reforming nanocatalysts and method of making and using such catalysts 失效
    纳米催化剂的改性及制备和使用这些催化剂的方法

    公开(公告)号:US07569508B2

    公开(公告)日:2009-08-04

    申请号:US11101241

    申请日:2005-04-07

    摘要: Reforming nanocatalysts are formed using a dispersing agent to increase the activity, selectivity and longevity of the catalyst when used in a reforming process. The nanocatalyst particles are formed using a dispersing agent having at least one functional group selected from the group of a hydroxyl, a carboxyl, a carbonyl, an amide, an amine, a thiol, a sulfonic acid, sulfonyl halide, an acyl halide, an organometallic complex, and combinations of these. The dispersing agent is particularly useful for forming multicomponent catalysts comprising an alloy, combination, mixture, decoration, or interspersion of platinum and one or more of tin, rhenium or iridium. The formation of the nanoparticles may include a heat treating process performed in an inert or oxidative environment to maintain the catalyst atoms in a non-zero oxidation state to thereby maintain a stronger bond between the dispersing agent and the catalyst atoms. Multicomponent reforming catalysts having anchored nanocatalyst particles exhibit particularly good activity, selectivity and longevity when used in the reforming of naphtha and/or formation of BTX.

    摘要翻译: 使用分散剂形成纳米催化剂的重整,以提高催化剂在重整过程中的活性,选择性和使用寿命。 纳米催化剂颗粒使用具有至少一个选自羟基,羧基,羰基,酰胺,胺,硫醇,磺酸,磺酰卤,酰基卤, 有机金属络合物,以及它们的组合。 分散剂特别可用于形成包含铂和锡,铼或铱中的一种或多种的合金,组合,混合物,装饰或间隙的多组分催化剂。 纳米颗粒的形成可以包括在惰性或氧化环境中进行的热处理工艺,以保持催化剂原子处于非零氧化态,从而在分散剂和催化剂原子之间保持更强的键。 具有锚定的纳米催化剂颗粒的多组分重整催化剂在用于石脑油重整和/或形成BTX时表现出特别好的活性,选择性和寿命。