公开(公告)号：US06538045B1

公开(公告)日：2003-03-25

申请号：US09471694

申请日：1999-12-23

申请人： Edward J. Murphy ,  Edward P. Zahora ,  Nancy Coster ,  Glenn Evans

发明人： Edward J. Murphy ,  Edward P. Zahora ,  Nancy Coster ,  Glenn Evans

IPC分类号： C08F246

CPC分类号： C03C25/106

摘要： A radiation-curable composition for an ink base, ink composition, outer primary composition, buffering material or matrix material for fiber optics includes, in the uncured state, a secondary amino or tertiary amino silicone-containing additive.

摘要翻译： 用于油墨基材的可辐射固化组合物，油墨组合物，外部初级组合物，用于光学纤维的缓冲材料或基质材料包括在未固化状态下含仲氨基或叔氨基含硅氧烷的添加剂。

公开(公告)号：US06301415B1

公开(公告)日：2001-10-09

申请号：US09129233

申请日：1998-08-05

申请人： Edward P. Zahora ,  Edward J. Murphy ,  David M. Szum

发明人： Edward P. Zahora ,  Edward J. Murphy ,  David M. Szum

IPC分类号： G02B604

CPC分类号： G02B6/4482 ,  C03C25/1065 ,  C09D4/06 ,  G02B6/4403 ,  G02B6/4498 ,  Y10T428/2938 ,  C08F290/14

摘要： Provided is a ribbon assembly containing a plurality of coated optical glass fibers and a matrix material which binds the plurality of coated optical glass fibers together. At least one of the coated optical glass fibers contains an ink coating or colored outer primary coating. At least one of the ink coating, the colored outer primary coating, or the matrix material contains a phospholipid.

摘要翻译： 提供了一种带状组件，其包含多个涂覆的光学玻璃纤维和将多个涂覆的光学玻璃纤维结合在一起的基质材料。 涂覆的光学玻璃纤维中的至少一个包含油墨涂层或着色的外部初级涂层。 油墨涂层，着色的外部初级涂层或基质材料中的至少一种含有磷脂。

公开(公告)号：US6040357A

公开(公告)日：2000-03-21

申请号：US84918

申请日：1998-05-28

申请人： Edward J. Murphy ,  Jeffrey Classey ,  David M. Szum

发明人： Edward J. Murphy ,  Jeffrey Classey ,  David M. Szum

IPC分类号： G02B6/44 ,  C03C25/10 ,  C09D11/10 ,  C09D11/00 ,  C03C17/34 ,  C09D11/02 ,  G02B1/12 ,  G02B6/04

CPC分类号： C09D11/101 ,  C03C25/1055 ,  C03C25/1065

摘要： Provided is radiation-curable ink composition containing a radiation-curable carrier system containing at least one radiation-curable monomer or oligomer and at least one pigment dispersed in the radiation-curable carrier system in an amount sufficient to provide a color which is visible without magnification. The pigment is substantially insoluble in the radiation-curable carrier system whereby the particulate shape of the pigment is substantially retained in the radiation-curable carrier system. The pigment having a particle size that substantially avoids pigment induced microbending of an optical glass fiber coated with the ink coating.

摘要翻译： 本发明提供的辐射固化油墨组合物含有可辐射固化的载体体系，该系统含有至少一种可辐射固化的单体或低聚物和至少一种分散在可辐射固化的载体体系中的颜料，其量足以提供在不放大的情况下可见的颜色 。 颜料基本上不溶于可辐射固化的载体体系，由此颜料的颗粒形状基本上保留在可辐射固化的载体体系中。 该颜料的粒径基本上避免颜料引起涂覆有油墨涂层的光学玻璃纤维的微弯曲。

公开(公告)号：US5891930A

公开(公告)日：1999-04-06

申请号：US694781

申请日：1996-08-09

申请人： Stephen C. Lapin ,  Edward J. Murphy

发明人： Stephen C. Lapin ,  Edward J. Murphy

IPC分类号： C03C25/10 ,  C08F2/50 ,  C08G59/30 ,  C08G59/68 ,  C09D4/06

CPC分类号： C08G59/68 ,  C03C25/106 ,  C08G59/306 ,  C09D4/06

摘要： Provided is a radiation-curable optical glass fiber coating composition adapted to provide the combination of properties of:(i) enhanced resistance to thermal degradation when suitably cured; and(ii) a viscosity sufficient to provide a surface substantially free-of pitting.The composition is formulated from components including:(A) at least one epoxy silicone monomer or oligomer which is crosslinkable via actinic radiation, or mixture thereof;(B) at least one thermoplastic resin which is substantially unreactive to actinic radiation and which is soluble or dispersible in component (A), said thermoplastic resin being present in an amount to provide said composition with a viscosity suitable for application to an optical glass fiber; and(C) a catalytically effective amount of a photoinitiator for catalyzing the crosslinking reaction of component (A) and which is soluble or dispersible in component (A) or a mixture of said component (A) and said thermoplastic resin. Also provided is a method of making the radiation-curable coating composition and a coated optical glass fiber.

摘要翻译： 本发明提供一种可辐射固化光学玻璃纤维涂层组合物，其适用于提供以下特性的组合：（i）当适当固化时增强耐热降解性; 和（ii）足以提供基本上没有点蚀的表面的粘度。 组合物由以下组分配制，包括：（A）至少一种通过光化辐射可交联的环氧硅氧烷单体或低聚物，或其混合物; （B）至少一种对光化辐射基本上不反应并且可溶于或分散在组分（A）中的热塑性树脂，所述热塑性树脂的存在量为所述组合物提供适用于光学玻璃纤维的粘度 ; 和（C）催化有效量的用于催化组分（A）的交联反应并且可溶于或可分散在组分（A）中的光引发剂或所述组分（A）和所述热塑性树脂的混合物。 还提供了制造可辐射固化涂料组合物和涂覆的光学玻璃纤维的方法。

公开(公告)号：US5416126A

公开(公告)日：1995-05-16

申请号：US19365

申请日：1993-02-17

申请人： Edward J. Murphy ,  Edward P. Zahora ,  Sami A. Shama

发明人： Edward J. Murphy ,  Edward P. Zahora ,  Sami A. Shama

IPC分类号： C08F2/50 ,  D21H17/53 ,  D21H25/06 ,  D21H27/06 ,  G03G7/00 ,  B32B27/10 ,  C08F263/06

CPC分类号： D21H27/06 ,  D21H17/53 ,  D21H25/06 ,  G03G7/004 ,  Y10T428/2933 ,  Y10T428/3179 ,  Y10T428/31794

摘要： A composition which is cured upon exposure to ultraviolet light in the absence of solvent is disclosed. The liquid composition is prepared by combining a liquid maleate polyester and at least one of a vinyl compound and an allyl functional compound. A photoinitiator is then added to the polymerizable liquid composition. A substrate is impregnated with the polymerizable liquid composition and exposed to actinic energy of a sufficient dosage for a sufficient amount of time to polymerize the composition to a sufficient degree to impart useful properties to the substrate. The composition can be used as a binder for fiberglass insulation, in the manufacture of transparent or semi-transparent paper and to manufacture paper for use in photocopy machines.

摘要翻译： 公开了在不存在溶剂的情况下暴露于紫外线时固化的组合物。 通过将液体马来酸酯聚酯与乙烯基化合物和烯丙基官能化合物中的至少一种组合来制备液体组合物。 然后将光引发剂加入到可聚合液体组合物中。 用可聚合液体组合物浸渍基质并暴露于足够量的光化能量足够的时间以使组合物充分聚合以赋予基底有用的性质。 该组合物可用作玻璃纤维绝缘的粘合剂，用于制造透明或半透明纸并制造用于复印机的纸。

公开(公告)号：US4761435A

公开(公告)日：1988-08-02

申请号：US914989

申请日：1986-10-03

申请人： Edward J. Murphy ,  Ronald S. Conti

发明人： Edward J. Murphy ,  Ronald S. Conti

IPC分类号： C08F2/50 ,  C08F299/04 ,  C09D4/00 ,  C09D4/06 ,  C09D5/00 ,  C08G73/02 ,  C08F265/06

CPC分类号： C09D4/00 ,  C08F299/0435 ,  C09D4/06 ,  Y10S522/904

摘要： Ultraviolet-curable ethylenically unsaturated liquid coating composition are disclosed which consist essentially of:1--polyethylenically unsaturated material in which the ethylenically unsaturated groups are polymerizable groups which are not (meth)acrylate groups;2--a polyamine resin, preferably a polytertiary amine resin; and3--an aryl ketone photosensitizer.

摘要翻译： 公开了紫外线固化型烯属不饱和液体涂料组合物，其基本上由以下物质组成：其中烯属不饱和基团是不是（甲基）丙烯酸酯基团的可聚合基团的1-多烯属不饱和物质; 2-a多胺树脂，优选多胺胺树脂; 和3-芳基酮光敏剂。

公开(公告)号：US4113597A

公开(公告)日：1978-09-12

申请号：US745240

申请日：1976-11-26

申请人： Rafat T. Rabi ,  Edward J. Murphy ,  John A. Basoms

发明人： Rafat T. Rabi ,  Edward J. Murphy ,  John A. Basoms

IPC分类号： C25D13/06 ,  C09D5/44 ,  C25D13/10

CPC分类号： C09D5/4411

摘要： A simplified method for the cathodic electrodeposition of polyamine resin from a dispersion thereof in an aqueous electrocoating bath is provided in which the polyamine is selected to be stably dispersible in water in the form of a salt with a solubilizing acid at a pH of from 6.0-7.5, and this polyamine resin is substantially completely neutralized with carbonic acid and dispersed in water in the form of an amine carbonate or bicarbonate. A unidirectional electrical current is passed through an aqueous electrocoating bath containing the amine carbonate or bicarbonate to deposit the polyamine resin at the cathode and cause the release of carbon dioxide. In preferred practice, a proportion of the amine groups in the polyamine resin within the bath, low enough to maintain the pH of the bath at a pH of about 6.0 or higher, is reacted with a relatively nonvolatile solubilizing acid, and the polyamine resin solids in the electrocoating bath are replenished by adding to bath polyamine resin substantially completely neutralized with carbonic acid.

摘要翻译： 提供了一种用于将多胺树脂从其分散体阴极电沉积在水性电涂浴中的简化方法，其中选择多胺以与6.0％的pH下的增溶酸形式的盐稳定分散在水中， 7.5，并且该聚胺树脂基本上完全被碳酸中和并以碳酸亚烃或碳酸氢盐的形式分散在水中。 单向电流通过含有碳酸胺或碳酸氢盐的水性电泳浴，以在阴极上沉积多胺树脂并引起二氧化碳的释放。 在优选的实践中，浴中多胺树脂中的一部分胺基在低于足以将浴的pH保持在约6.0或更高的pH的条件下与相对不挥发的增溶酸反应，并且多胺树脂固体 在电镀浴中通过加入基本上完全用碳酸中和的浴多胺树脂来补充。

公开(公告)号：US20080241535A1

公开(公告)日：2008-10-02

申请号：US11955838

申请日：2007-12-13

申请人： Wendell Wayne CATTRON ,  Steven R. Schmid ,  Edward J. Murphy ,  John M. Zimmerman ,  Anthony Joseph Tortorello

发明人： Wendell Wayne CATTRON ,  Steven R. Schmid ,  Edward J. Murphy ,  John M. Zimmerman ,  Anthony Joseph Tortorello

IPC分类号： B32B17/02 ,  C08L75/04 ,  B32B17/10 ,  C03C25/34

CPC分类号： G02B1/12 ,  C03C25/1065 ,  C08G18/672 ,  C08G18/724 ,  C09D163/00 ,  C09D175/14 ,  C09D175/16 ,  Y10T428/2938 ,  Y10T428/2964 ,  C08G18/48

摘要： The invention relates to a Radiation Curable Secondary Coating composition for use on an Optical Fiber. The Radiation Curable Secondary Coating composition is a urethane-free Alpha Oligomer prepared by reaction of the following: (a) an acrylate compound selected from an alcohol-containing acrylate or alcohol-containing methacrylate compound, (b) an anhydride compound, (c) an epoxy-containing compound, (d) optionally an extender compound, and (e) optionally a catalyst. The invention also relates to a coated wire and to a coated optical fiber.

摘要翻译： 本发明涉及一种用于光纤的辐射固化二次涂料组合物。 辐射固化二次涂料组合物是通过以下反应制备的不含氨基甲酸酯的α-低聚物：（a）选自含醇丙烯酸酯或含醇甲基丙烯酸酯化合物的丙烯酸酯化合物，（b）酸酐化合物，（c） 含环氧基的化合物，（d）任选的增量化合物，和（e）任选的催化剂。 本发明还涉及涂覆线和涂覆光纤。

公开(公告)号：US20080226912A1

公开(公告)日：2008-09-18

申请号：US11955547

申请日：2007-12-13

申请人： Tyson Dean NORLIN ,  Steven R. Schmid ,  Edward J. Murphy ,  John M. Zimmerman ,  Anthony Joseph Tortorello

发明人： Tyson Dean NORLIN ,  Steven R. Schmid ,  Edward J. Murphy ,  John M. Zimmerman ,  Anthony Joseph Tortorello

IPC分类号： B32B17/02 ,  C08L75/00 ,  B32B17/10 ,  C03C25/34

CPC分类号： C09D175/08 ,  C03C25/1065 ,  C03C25/326 ,  C08G18/672 ,  C09D5/002 ,  C09D175/16 ,  G02B6/02395 ,  Y10T428/2964 ,  C08G18/48

摘要： Radiation curable coatings for use as a Primary Coating for optical fibers, optical fibers coated with said coatings and methods for the preparation of coated optical fibers. The present invention provides a radiation curable Primary Coating composition comprising: an oligomer; first diluent monomer; a second diluent monomer; a third diluent monomer; a first light stabilizer; a first photoinitiator; a second photoinitiator; an antioxidant; a second light stabilizer; and an adhesion promoter; wherein said oligomer is the reaction product of hydroxyl-containing acrylate; an isocyanate; a polyether polyol; a polymerization inhibitor; a catalyst; and a diluent; wherein said oligomer has a number average molecular weight of from at least about 4000 g/mol to less than or equal to about 15,000 g/mol; and wherein said catalyst is selected from the group consisting of copper naphthenate; cobalt naphthenate; zinc naphthenate; triethylamine; triethylenediamine; 2-methyltriethyleneamine; dibutyl tin dilaurate; metal carboxylates, including, but not limited to: organobismuth catalysts such as bismuth neodecanoate; zinc neodecanoate; zirconium neodecanoate; zinc 2-ethylhexanoate; sulfonic acids, including but not limited to dodecylbenzene sulfonic acid, methane sulfonic acid; amino or organo-base catalysts, including, but not limited to, 1,2-dimethylimidazole and diazabicyclooctane; triphenyl phosphine; alkoxides of zirconium and titanium, including, but not limited to Zirconium butoxide and Titanium butoxide; and Ionic liquid phosphonium salts; and tetradecyl(trihexyl) phosphonium chloride; and wherein a cured film of said radiation curable Primary Coating composition has a peak tan □ Tg of from about −25° C. to about −55° C.; and a modulus of from about 0.85 MPa to about 1.10 MPa.

摘要翻译： 用作光纤的主要涂层的辐射固化涂层，涂覆有所述涂层的光纤以及用于制备涂覆的光纤的方法。 本发明提供了一种可辐射固化的初级涂料组合物，其包含：低聚物; 第一稀释剂单体; 第二稀释剂单体; 第三稀释剂单体; 第一光稳定剂; 第一种光引发剂; 第二光引发剂; 抗氧化剂 第二种光稳定剂; 和粘合促进剂; 其中所述低聚物是含羟基的丙烯酸酯的反应产物; 异氰酸酯; 聚醚多元醇; 阻聚剂; 催化剂 和稀释剂; 其中所述低聚物的数均分子量为至少约4000g / mol至小于或等于约15,000g / mol; 并且其中所述催化剂选自环烷酸铜; 环烷酸钴; 环烷酸锌; 三乙胺 三亚乙基二胺 2-甲基三亚乙基胺; 二月桂酸二丁基锡; 金属羧酸盐，包括但不限于：有机铋催化剂如新戊酸铋; 新癸酸锌; 新癸酸锆; 2-乙基己酸锌; 磺酸，包括但不限于十二烷基苯磺酸，甲磺酸; 氨基或有机碱催化剂，包括但不限于1,2-二甲基咪唑和二氮杂双环辛烷; 三苯基膦 锆和钛的醇盐包括但不限于丁氧基锆和丁醇钛; 和离子液体鏻盐; 和十四烷基（三己基）鏻氯化物; 并且其中所述可辐射固化的初级涂层组合物的固化膜具有约-25℃至约-55℃的峰值tanδTg。 和约0.85MPa至约1.10MPa的模量。

公开(公告)号：US06107361A

公开(公告)日：2000-08-22

申请号：US168290

申请日：1998-10-08

申请人： Anthony J. Tortorello ,  Edward J. Murphy

发明人： Anthony J. Tortorello ,  Edward J. Murphy

IPC分类号： C03C25/24 ,  C03C25/10 ,  C08F2/06 ,  C08F2/50 ,  C08F8/30 ,  C08F290/12 ,  C08G18/62 ,  C08G18/81 ,  C09D4/06 ,  G03F7/027 ,  G03F7/038 ,  C08G18/10 ,  C08G18/12

CPC分类号： G03F7/0388 ,  C03C25/1055 ,  C03C25/106 ,  C03C25/1065 ,  C08G18/6229 ,  C08G18/8158 ,  G03F7/027 ,  Y10T428/2938

摘要： The invention relates to a solvent-free radiation curable, optical glass fiber coating composition containing:a) a urethane oligomer having a functional group capable of polymerization in the presence of actinic radiation, with an average functionality of at least about 1.2, having a vinyl addition polymer as backbone.b) a urethane compound having a functional group capable of polymerization in the presence of actinic radiation, with an average functionality of at least about 1, containing an organic moiety having about 5 or more carbon atoms as backbone.c) a reactive diluent.Furthermore, the invention relates to a solvent-free method for producing a solvent-free, radiation curable urethane oligomer composition.

摘要翻译： 本发明涉及无溶剂的可辐射固化的光学玻璃纤维涂料组合物，其含有：a）具有能在光化辐射存在下能够聚合的官能团的氨基甲酸酯低聚物，平均官能度至少为约1.2，具有乙烯基 加成聚合物作为骨架。 b）具有能够在光化辐射存在下能够聚合的官能团的氨基甲酸酯化合物，其平均官能度为至少约1，其含有具有约5个或更多个碳原子的有机部分作为主链。 c）反应性稀释剂。 此外，本发明涉及一种无溶剂的无辐射固化型氨基甲酸酯低聚物组合物的制造方法。