公开(公告)号：US20060110430A1

公开(公告)日：2006-05-25

申请号：US11271344

申请日：2005-11-10

Applicant: Jason Pearson ,  Max Weaver ,  Jean Fleischer

Inventor： Jason Pearson ,  Max Weaver ,  Jean Fleischer

IPC: C09B29/42 ,  A61F2/00

CPC classification number: A61L27/54 ,  A61L27/18 ,  A61L2300/204 ,  A61L2300/442 ,  A61L2430/16 ,  C09B69/106 ,  G02B1/043

Abstract: Polymerizable light absorbing azo dyes are disclosed useful as monomers in the formation of devices such as, but not limited to ocular lenses. Specifically, intraocular lenses (IOL) are disclosed wherein one or more of the light absorbing dye is covalently bonded to other structural polymers though ethylene unsaturated groups. The resulting IOLs possess light absorbing properties without significant amounts of free (un-bound) azo dye molecules present in the final structural polymer matrix.

Abstract translation: 公开了可聚合光吸收偶氮染料作为形成器件的单体，例如但不限于眼镜片。 具体地，公开了眼内透镜（IOL），其中一种或多种光吸收染料通过乙烯不饱和基团共价键合到其它结构聚合物。 所得的IOL具有光吸收性能，而没有显着量的存在于最终结构聚合物基质中的游离（未结合的）偶氮染料分子。

公开(公告)号：US20050277759A1

公开(公告)日：2005-12-15

申请号：US10855747

申请日：2004-05-27

Applicant: Jason Pearson ,  Max Weaver ,  Perry Murdaugh ,  Earl Howell

Inventor： Jason Pearson ,  Max Weaver ,  Perry Murdaugh ,  Earl Howell

IPC: C08G63/00 ,  C08G63/16 ,  C08G63/46 ,  C08G63/685 ,  C08G63/91 ,  C08K5/00 ,  C08K5/1535

CPC classification number: C08G63/916 ,  C08G63/46 ,  C08G63/6856 ,  C08K5/1535 ,  Y02P20/582 ,  C08L67/02

Abstract: A method for incorporating a UV light absorbing compound into a polyester prepared using direct esterification of reactants selected from a dicarboxylic acid and a diol, the method comprising reacting the reactants in an esterifying reactor under conditions sufficient to form an esterified product including at least one of an ester, an oligomer, or mixture having an ester and a mixture of low molecular weight polyester; polymerizing the esterified product in a polycondensation reactor to form a polyester; and adding the UV absorbing compound to the esterified products when at least 50% of the carboxy groups initially present in the reactants have been esterified to obtain a yield of UV absorbing compound incorporated into the polyester of greater than 40%. Articles utilizing the UV protected polyester are additionally disclosed.

Abstract translation: 一种将UV光吸收化合物引入到使用直接酯化选自二羧酸和二醇的反应物制备的聚酯中的方法，所述方法包括使反应物在酯化反应器中在足以形成酯化产物的条件下反应，所述条件足以形成酯化产物， 具有酯和低分子量聚酯的混合物的酯，低聚物或混合物; 在缩聚反应器中聚合酯化产物以形成聚酯; 并且当最初存在于反应物中的羧基的至少50％已被酯化时，将UV吸收化合物加入到酯化产物中，以获得掺入聚酯中的UV吸收化合物的产率大于40％。 另外公开了使用紫外线防护聚酯的制品。

公开(公告)号：US20050277716A1

公开(公告)日：2005-12-15

申请号：US10855612

申请日：2004-05-27

Applicant: Jason Pearson ,  Dale Blakely ,  Frederick Colhoun ,  Max Weaver

Inventor： Jason Pearson ,  Dale Blakely ,  Frederick Colhoun ,  Max Weaver

IPC: C08G63/02 ,  C08G63/685 ,  C08G63/78 ,  C08G63/82 ,  C08G63/83 ,  C08G63/86 ,  C08G63/87 ,  C08K5/1535 ,  C08K5/34

CPC classification number: C08G63/866 ,  C08G63/6856 ,  C08K5/1535 ,  C08L67/02

Abstract: A method for efficiently incorporating a UV absorber into a polyester resin. The method includes forming a reaction mixture comprising a diol component, a diacid component selected from the group consisting of dicarboxylic acids, dicarboxylic acid derivatives, and mixtures thereof, an antimony containing compound, a phosphorus containing compound, a metal containing compound, and a UV absorber. The reaction mixture is polymerized in a polycondensation reaction system. In another embodiment of the present invention, the UV absorber is added while the reaction products from one reactor are transferred to the next reactor in the polycondensation reaction system. The present invention is also directed to novel UV absorbing compounds as well as articles made from the polyester resin.

Abstract translation: 一种有效地将UV吸收剂结合到聚酯树脂中的方法。 该方法包括形成包含二醇组分，选自二羧酸，二羧酸衍生物及其混合物的二酸组分，含锑化合物，含磷化合物，含金属化合物和UV的反应混合物 吸收器。 反应混合物在缩聚反应体系中聚合。 在本发明的另一个实施方案中，加入UV吸收剂，同时将来自一个反应器的反应产物转移到缩聚反应体系中的下一个反应器中。 本发明还涉及新型UV吸收化合物以及由聚酯树脂制成的制品。

公开(公告)号：US20050065247A1

公开(公告)日：2005-03-24

申请号：US10666404

申请日：2003-09-19

Applicant: Douglas Carico ,  Max Weaver ,  Jason Pearson ,  Charles Foster ,  Jean Fleischer ,  Don Morris ,  Thauming Kuo

Inventor： Douglas Carico ,  Max Weaver ,  Jason Pearson ,  Charles Foster ,  Jean Fleischer ,  Don Morris ,  Thauming Kuo

IPC: C08G63/688 ,  C08L33/04 ,  C08L101/00 ,  C09D167/08 ,  C08K5/41

CPC classification number: C09D167/08 ,  C08G63/6884 ,  C08L33/04 ,  C08L101/00 ,  C08L2666/02 ,  C08L2666/04

Abstract: Liquid coating compositions are disclosed having improved whiteness. The compositions may comprise a polyester or alkyd polymer having copolymerized therein a toning amount of (A) a two-component colorant system comprising a blue toner dye and either a red or violet toner dye, or both; or (B) a single-component colorant system comprising a reddish-blue toner dye, optionally including one or more of the red or violet toner dyes. This toner polymer can act as a surfactant or a stabilizer, and may be added prior to an emulsion polymerization, or may be used as an additive in water-borne or solvent-borne coating compositions.

Abstract translation: 公开了具有改善的白度的液体涂料组合物。 组合物可以包含其中共聚有调色量的（A）包含蓝色调色剂染料和红色或紫色调色剂染料或两者的双组分着色剂体系的聚酯或醇酸聚合物; 或（B）包含红色调色剂染料的单组分着色剂体系，任选地包括一种或多种红色或紫色调色剂染料。 该调色剂聚合物可以用作表面活性剂或稳定剂，并且可以在乳液聚合之前加入，或者可以用作水性或溶剂型涂料组合物中的添加剂。

公开(公告)号：US20050049425A1

公开(公告)日：2005-03-03

申请号：US10647828

申请日：2003-08-25

Applicant: Jason Pearson ,  Max Weaver ,  Jean Fleischer

Inventor： Jason Pearson ,  Max Weaver ,  Jean Fleischer

IPC: C08F246/00 ,  C08F290/06 ,  C09B69/10 ,  C09B1/473 ,  C08F267/00

CPC classification number: C08F246/00 ,  C08F290/06 ,  C09B69/101

Abstract: This invention pertains to certain novel red anthraquinone colorant compounds containing one or more ethylenically-unsaturated (e.g., vinyl), photopolymerizable radicals that may be copolymerized (or cured) with ethylenically-unsaturated monomers to produce colored compositions such as colored acrylic polymers. Suitable compositions having the present colorants copolymerized therein include, e.g., polymers produced from acrylate and methacrylate esters, colored polystyrenes, and similar colored polymeric materials derived from other ethylenically-unsaturated monomers. The novel colorants possess good fastness (stability) to ultraviolet (UV) light, good solubility in vinyl monomers and good color strength. The present invention also pertains to processes for preparing the photopolymerizable colorant compounds. The ethylenically unsaturated colorant compounds may be suitable for use in coatings that are applied to wood, glass, paper, metal, thermoplastics and the like.

Abstract translation: 本发明涉及某些新颖的红色蒽醌着色剂化合物，其含有一个或多个烯键式不饱和（例如乙烯基）可光聚合的基团，其可以与烯键式不饱和单体共聚（或固化）以产生着色组合物如着色丙烯酸聚合物。 其中共聚有本发明着色剂的合适的组合物包括例如由丙烯酸酯和甲基丙烯酸酯衍生的聚合物，着色聚苯乙烯以及衍生自其它烯属不饱和单体的类似有色聚合物。 新型着色剂对紫外线（UV）光具有良好的牢度（稳定性），在乙烯基单体中具有良好的溶解性和良好的着色强度。 本发明还涉及制备可光聚合着色剂化合物的方法。 烯键式不饱和着色剂化合物可适用于施加到木材，玻璃，纸，金属，热塑性塑料等的涂料中。

公开(公告)号：US20050008885A1

公开(公告)日：2005-01-13

申请号：US10855723

申请日：2004-05-27

Applicant: Dale Blakely ,  Frederick Colhoun ,  Max Weaver ,  Jason Pearson

Inventor： Dale Blakely ,  Frederick Colhoun ,  Max Weaver ,  Jason Pearson

IPC: B32B27/36 ,  C08G63/00 ,  C08G63/02 ,  C08G63/54 ,  C08G63/78 ,  C08G63/82 ,  C08G63/83 ,  C08G63/86 ,  C08G63/87 ,  C08K3/22 ,  C08K5/098

CPC classification number: C08G63/86 ,  C08G63/83 ,  C08K3/2279 ,  C08K5/098 ,  Y10T428/31786

Abstract: The present invention is a method for efficiently incorporating a UV absorber into a polyester resin. The method includes forming a reaction mixture comprising a diol component, a diacid component selected from the group consisting of dicarboxylic acids, dicarboxylic acid derivatives, and mixtures thereof, an antimony containing compound, a phosphorus containing compound, a metal containing compound, and a UV absorber. The reaction mixture is polymerized in a polycondensation reaction system. In another embodiment of the present invention, the UV absorber is added while the reaction products from one reactor are transferred to the next reactor in the polycondensation reaction system. A polyester composition having the UV absorber incorporated therein is also disclosed.

Abstract translation: 本发明是一种有效地将UV吸收剂并入聚酯树脂中的方法。 该方法包括形成包含二醇组分，选自二羧酸，二羧酸衍生物及其混合物的二酸组分，含锑化合物，含磷化合物，含金属化合物和UV的反应混合物 吸收器。 反应混合物在缩聚反应体系中聚合。 在本发明的另一个实施方案中，加入UV吸收剂，同时将来自一个反应器的反应产物转移到缩聚反应体系中的下一个反应器中。 还公开了其中并入UV吸收剂的聚酯组合物。

公开(公告)号：US20080045629A1

公开(公告)日：2008-02-21

申请号：US11859208

申请日：2007-09-21

Applicant: Max Weaver ,  Jason Pearson ,  Dale Blakely ,  Frederick Colhoun

Inventor： Max Weaver ,  Jason Pearson ,  Dale Blakely ,  Frederick Colhoun

IPC: C08G63/183 ,  C08K5/3435 ,  C08K5/50

CPC classification number: C08G63/6856 ,  C08G63/866 ,  C08K5/18 ,  C08K5/34 ,  C09B23/04 ,  C09B23/105 ,  C09B23/141 ,  C08L67/02

Abstract: The present invention is a method for efficiently incorporating a nitrogen containing methine light absorber into a polyester resin. The method includes forming a reaction mixture comprising combining a diol component, a diacid component selected from the group consisting of dicarboxylic acids, dicarboxylic acid derivatives, and mixtures thereof, an antimony containing compound, a phosphorus containing compound, a metal containing compound, and a nitrogen containing methine light absorber. The reaction mixture is polymerized in a polycondensation reaction system. In another embodiment the light absorber is added while the reaction products of one reactor are being transferred to the next reactor in the polycondensation reaction system. The present invention is also directed articles made from the polyester resin.

Abstract translation: 本发明是一种有效地将含氮次甲基光吸收剂并入聚酯树脂中的方法。 该方法包括形成反应混合物，其包括将二醇组分，选自二羧酸，二羧酸衍生物及其混合物的二酸组分，含锑化合物，含磷化合物，含金属化合物和 含氮次甲基光吸收剂。 反应混合物在缩聚反应体系中聚合。 在另一个实施方案中，加入光吸收剂，同时将一个反应器的反应产物转移到缩聚反应体系中的下一个反应器中。 本发明还涉及由聚酯树脂制成的制品。

公开(公告)号：US20070207331A1

公开(公告)日：2007-09-06

申请号：US11368580

申请日：2006-03-06

Applicant: Jason Pearson ,  Max Weaver ,  Jean Fleischer ,  Greg King

Inventor： Jason Pearson ,  Max Weaver ,  Jean Fleischer ,  Greg King

IPC: B32B27/00 ,  C08K5/23 ,  C07D409/02 ,  C07D401/02

CPC classification number: C08K5/23 ,  C07D213/85 ,  C07D401/12 ,  Y10T428/31855

Abstract: Disclosed are azo colorant compounds containing one or more ethylenically-unsaturated groups polymerizable or copolymerizable with ethylenically-unsaturated compositions typically used in coating compositions. The azo colorantcompounds are polymerizable by photopolymerization or free radical polymerization techniques with ethylenically-unsaturated monomers. The copolymerized colorants produce colored compositions such as colored acrylic polymers, e.g., polymers produced from acrylate and methacrylate esters, colored polystyrenes, and similar colored polymeric materials derived from other ethylenically-unsaturated monomers. The ethylenically-unsaturated colorant compounds may be used in coatings that are applied to wood, glass, metal, thermoplastics and the like.

Abstract translation: 公开了含有一种或多种烯键式不饱和基团的偶氮着色剂化合物，其可通过用于涂料组合物中的烯属不饱和组合物可聚合或可共聚。 偶氮着色剂化合物可通过光聚合或自由基聚合技术与烯键式不饱和单体聚合。 共聚的着色剂产生着色的组合物，例如着色的丙烯酸聚合物，例如由丙烯酸酯和甲基丙烯酸酯制得的聚合物，着色的聚苯乙烯和衍生自其它烯属不饱和单体的类似的有色聚合物。 烯键式不饱和着色剂化合物可用于施加到木材，玻璃，金属，热塑性塑料等的涂料中。

公开(公告)号：US20050288401A1

公开(公告)日：2005-12-29

申请号：US11204869

申请日：2005-08-16

Applicant: Jason Pearson ,  Douglas McWilliams ,  Gether Irick ,  Max Weaver

Inventor： Jason Pearson ,  Douglas McWilliams ,  Gether Irick ,  Max Weaver

IPC: C08G63/20 ,  C08K5/34 ,  C08K5/52 ,  C08K5/524 ,  C08K5/5393 ,  C08L67/02 ,  C08L69/00 ,  C08K5/49

CPC classification number: C08L67/02 ,  C08G63/20 ,  C08K5/34 ,  C08K5/5205 ,  C08K5/524 ,  C08K5/5393 ,  C08L69/00 ,  C08L2205/02 ,  C08L2666/18

Abstract: Disclosed are polymer compositions comprising: (A) at least one polyester prepared by the reaction of at least one diol with at least one dicarboxylic acid or dialkyl ester thereof in the presence of a metallic catalyst; and (B) at least one salt prepared from the reaction of one or more acidic phosphorus-containing compounds and one or more basic organic compounds which contain nitrogen. The polyester compositions exhibit improved color, especially when used as a component of a polyester/polycarbonate blend. Also disclosed are polymer compositions comprising a polycarbonate in combination with components (A) and (B).

Abstract translation: 公开了聚合物组合物，其包含：（A）通过至少一种二醇与至少一种二羧酸或其二烷基酯在金属催化剂的存在下反应制备的至少一种聚酯; 和（B）由一种或多种酸性含磷化合物和一种或多种含氮的碱性有机化合物的反应制备的至少一种盐。 聚酯组合物表现出改善的颜色，特别是当用作聚酯/聚碳酸酯共混物的组分时。 还公开了包含与组分（A）和（B）组合的聚碳酸酯的聚合物组合物。

公开(公告)号：US20050277758A1

公开(公告)日：2005-12-15

申请号：US10855722

申请日：2004-05-27

Applicant: Perry Murdaugh ,  Earl Howell ,  Cory Wells ,  Max Weaver ,  Jason Pearson

Inventor： Perry Murdaugh ,  Earl Howell ,  Cory Wells ,  Max Weaver ,  Jason Pearson

IPC: C08G63/21 ,  C08G63/685 ,  C08G63/688 ,  C08G63/78 ,  C08G63/02

CPC classification number: C08G63/6886 ,  C08G63/21 ,  C08G63/6856 ,  C08G63/78 ,  Y02P20/582

Abstract: A method for incorporating a UV light absorbing compound into a polyester prepared using direct esterification of reactants selected from a dicarboxylic acid and a diol. The method comprises reacting the reactants in an esterifying reactor under conditions sufficient to form an esterified product including at least one of an ester, an oligomer, or mixture having an ester and a mixture of low molecular weight polyester; polymerizing the esterified product in a polycondensation reactor to form a polyester; and adding the UV absorbing compound to the esterified products when at least 50% of the carboxy groups initially present in the reactants have been esterified to obtain a yield of UV absorbing compound incorporated into the polyester of greater than 25%. Articles utilizing the UV protected polyester prepared by the method of the invention are additionally disclosed.

Abstract translation: 一种将UV光吸收化合物引入使用直接酯化选自二羧酸和二醇的反应物制备的聚酯中的方法。 该方法包括使反应物在酯化反应器中在足以形成酯化产物的条件下反应，所述酯化产物包括具有酯和低分子量聚酯的混合物的酯，低聚物或混合物中的至少一种; 在缩聚反应器中聚合酯化产物以形成聚酯; 并且当最初存在于反应物中的羧基的至少50％已被酯化时，将UV吸收化合物加入到酯化产物中，以获得掺入聚酯中的UV吸收化合物的产率大于25％。 另外公开了利用通过本发明的方法制备的防UV聚酯的制品。