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    Soluble anionic polymerization initiators and preparation thereof
    22.
    发明授权
    Soluble anionic polymerization initiators and preparation thereof 失效
    可溶性阴离子聚合引发剂及其制备方法

    公开(公告)号：US5329005A

    公开(公告)日：1994-07-12

    申请号：US955582

    申请日：1992-10-02

    申请人： David F. Lawson ,  Koichi Morita ,  Yoichi Ozawa ,  Mark L. Stayer, Jr. ,  Ryota Fujio

    发明人： David F. Lawson ,  Koichi Morita ,  Yoichi Ozawa ,  Mark L. Stayer, Jr. ,  Ryota Fujio

    IPC分类号： B60C1/00 ,  C07F1/02 ,  C08F4/00 ,  C08F4/08 ,  C08F4/42 ,  C08F4/48 ,  C08F36/00 ,  C08F36/04 ,  C08K3/04 ,  C08L9/00 ,  C08L21/00 ,  C07D487/08 ,  C07D295/00

    CPC分类号： C08F36/04

    摘要： The present invention is directed toward anionic polymerization initiators which are soluble in hydrocarbon solvents. The initiators include a lithio amine having the general formula ALi. The component A is a dialkyl or dicycloalkyl amine radical or a cyclic amine. The invention is also directed toward polymers and other products made using the initiator, and methods therefor. Further, the invention contemplates a polymer, a polymer composition and products therefrom, which include a functional group from the reaction product of an amine and an organolithium compound. The resulting polymers may be terminated with a terminating, coupling or linking agent, which may provide the polymer with a multifunctionality.

    摘要翻译： 本发明涉及可溶于烃溶剂的阴离子聚合引发剂。 引发剂包括具有通式ALi的锂胺。 组分A是二烷基或二环烷基胺基或环胺。 本发明还涉及使用引发剂制备的聚合物和其它产品及其方法。 此外，本发明涉及聚合物，聚合物组合物及其产物，其包括来自胺和有机锂化合物的反应产物的官能团。 所得聚合物可以用终止的，偶联或连接剂终止，其可以为聚合物提供多功能性。

    Diene polymers having reduced hysteresis and improved raw viscosity incorporating primary partial coupling and terminals formed from aromatic nitrile compounds
    23.
    发明授权
    Diene polymers having reduced hysteresis and improved raw viscosity incorporating primary partial coupling and terminals formed from aromatic nitrile compounds 失效
    二烯聚合物具有降低的滞后性和改善的原始粘度，其中包括由芳族腈化合物形成的初级部分偶联和末端

    公开(公告)号：US5254628A

    公开(公告)日：1993-10-19

    申请号：US794105

    申请日：1991-11-18

    申请人： David F. Lawson ,  Mark L. Stayer, Jr. ,  Thomas A. Antkowiak

    发明人： David F. Lawson ,  Mark L. Stayer, Jr. ,  Thomas A. Antkowiak

    IPC分类号： C08C19/44 ,  C08L9/00 ,  C08L47/00 ,  C08L53/02

    CPC分类号： C08C19/44

    摘要： Diene polymers or copolymers having improved raw polymer viscosity and reduced hysteresis in the cured and carbon black reinforced state are provided. These diene polymers or copolymers comprise a mixture of diene polymer or copolymer chains containing carbon-tin bonds in the main polymer or copolymer chains and diene polymer or copolymer chains containing terminals derived from aromatic nitrile coumpounds.The diene polymer or copolymers are prepared by first coupling a portion of the living diene polymer or copolymer chains obtained by anionic polymerization using a tin polyhalide coupling agent and then terminating the remaining living diene polymer or copolymer chains using aromatic nitrile compounds. The resultant diene polymers or copolymers have improved raw polymer viscosity and when compounded with carbon black and cured have reduced hysteresis properties. The polymers can be utilized to form elastomer compositions for tire treads having reduced rolling resistance.

    摘要翻译： 提供了在固化和炭黑增强状态下具有改进的原料聚合物粘度和降低的滞后的二烯聚合物或共聚物。 这些二烯聚合物或共聚物包含在主要聚合物或共聚物链中含有碳 - 锡键的二烯聚合物或共聚物链的混合物，以及含有衍生自芳香族腈基的末端的二烯聚合物或共聚物链。 二烯聚合物或共聚物通过首先将一部分活性二烯聚合物或通过阴离子聚合获得的共聚物链与多卤化锡偶合剂偶联，然后使用芳族腈化合物终止剩余的活性二烯聚合物或共聚物链来制备。 所得二烯聚合物或共聚物具有改善的原始聚合物粘度，并且当与炭黑复合并固化时具有降低的滞后性能。 聚合物可用于形成具有降低的滚动阻力的轮胎胎面的弹性体组合物。

    Diene polymers and copolymers jumped by partial crosslinking and terminated with a substituted imine
    24.
    发明授权
    Diene polymers and copolymers jumped by partial crosslinking and terminated with a substituted imine 失效
    DIANE聚合物和共聚物通过部分交联和终止与替代的内酰胺

    公开(公告)号：US5227431A

    公开(公告)日：1993-07-13

    申请号：US684106

    申请日：1991-04-12

    申请人： David F. Lawson ,  Mark L. Stayer, Jr. ,  Thomas A. Antkowiak ,  John R. Schreffler

    发明人： David F. Lawson ,  Mark L. Stayer, Jr. ,  Thomas A. Antkowiak ,  John R. Schreffler

    IPC分类号： C08C19/26 ,  B60C1/00 ,  C08C19/44 ,  C08F4/48 ,  C08F8/42 ,  C08F36/04 ,  C08F236/00 ,  C08F236/10 ,  C08L9/06

    CPC分类号： C08C19/44 ,  B60C1/0016 ,  C08F36/04

    摘要： Diene polymer or copolymer compositions having reduced hysteresis are provided. The compositions comprise a mixture of diene polymers or copolymers containing carbon-tin bonds in the main polymer or copolymer chains prepared by coupling polymer or copolymer chains with tin polyhalides and diene polymers or copolymer chains containing terminals derived from substituted imines having the formula: ##STR1## wherein R.sub.1 and R.sub.2 are selected from the group consisting of H, alkyl, cycloalkyl, aryl, dialkylaminoaryl, aralkyl and aprotic O, N and S- containing alkyl, cycloalkyl, aryl and aralkyl groups; wherein R.sub.3 is selected from the group consisting of alkyl, cycloalkyl, aryl, dialkylaminoaryl, aralkyl and aprotic O, N, and S- containing alkyl, cycloalkyl, aryl and aralkyl groups; with the proviso that at least one of the R.sub.1, R.sub.2 and R.sub.3 groups must be a dialkylaminoaryl group and that not all of the R.sub.1, R.sub.2 and R.sub.3 groups must be a dialkylaminoaryl group and that not all of the R.sub.1, R.sub.2 and R.sub.3 groups must be a dialkylaminoaryl group and that not all of the R.sub.1, R.sub.2 and R.sub.3 groups can be aryl groups. The resultant diene polymer or copolymer compositions have reduced hysteresis and improved processability and can be utilized to form elastomer compositions for tire treads having reduced rolling resistance.

    Diene polymers and copolymers terminated by reaction with N-alkyl and N-aryl imines
    25.
    发明授权
    Diene polymers and copolymers terminated by reaction with N-alkyl and N-aryl imines 失效
    通过与N-烷基和N-亚氨基反应终止的二烯聚合物和共聚物

    公开(公告)号：US5066729A

    公开(公告)日：1991-11-19

    申请号：US506306

    申请日：1990-04-09

    申请人： Mark L. Stayer, Jr. ,  Thomas A. Antkowiak ,  David F. Lawson ,  Russell W. Koch

    发明人： Mark L. Stayer, Jr. ,  Thomas A. Antkowiak ,  David F. Lawson ,  Russell W. Koch

    IPC分类号： C08C19/22 ,  B60C1/00 ,  C08C19/44 ,  C08F8/30 ,  C08F36/00 ,  C08F36/04 ,  C08F136/04 ,  C08F236/10 ,  C08L47/00

    CPC分类号： C08C19/44 ,  B60C1/0016

    摘要： A process is provided for preparing a terminally functionalized polymer from a living polymer obtained by anionic polymerization of a diene monomer or mixture of a diene monomer and a vinyl aromatic hydrocarbon monomer which comprises reacting the living polymer with a compound having the formula: ##STR1## wherein R.sub.1 and R.sub.2 are selected from the group consisting of H, alkyl, cycloalkyl, aryl, dialkylaminoaryl, aralkyl, and aprotic O, N and S- containing alkyl, cycloalkyl, aryl and aralkyl groups; wherein R.sub.3 is selected from the group consisting of alkyl, cycloalkyl, aryl, dialkylaminoaryl, aralkyl, and aprotic O, N and S- containing alkyl, cycloalkyl, aryl and aralkyl groups; with the proviso that at least one of the R.sub.1, R.sub.2 and R.sub.3 groups must be a dialkylaminoaryl group and that not all of the R.sub.1, R.sub.2 and R.sub.3 groups can be aryl groups.The resultant terminally functionalized polymer has reduced hysteresis properties and may be utilized to prepare elastomer compositions and tire treads having reduced rolling resistance.

    摘要翻译： 提供了一种通过二烯单体或二烯单体和乙烯基芳族烃单体的混合物的阴离子聚合获得的活性聚合物制备末端官能化聚合物的方法，其包括使活性聚合物与具有下式的化合物反应： 其中R 1和R 2选自H，烷基，环烷基，芳基，二烷基氨基芳基，芳烷基和非质子O，N和S-含烷基，环烷基，芳基和芳烷基; 其中R 3选自烷基，环烷基，芳基，二烷基氨基芳基，芳烷基和非质子O，N和S-含烷基，环烷基，芳基和芳烷基; 条件是R1，R2和R3基团中的至少一个必须是二烷基氨基芳基，并且不是所有的R 1，R 2和R 3基团都可以是芳基。 所得的末端官能化聚合物具有降低的滞后性能，并且可用于制备具有降低的滚动阻力的弹性体组合物和轮胎胎面。

    Process for the production of phosphazene polymers
    26.
    发明授权
    Process for the production of phosphazene polymers 失效
    磷腈聚合物的制备方法

    公开(公告)号：US4128710A

    公开(公告)日：1978-12-05

    申请号：US845009

    申请日：1977-10-25

    申请人： John W. Fieldhouse ,  Daniel F. Graves ,  William M. Cole ,  Mark L. Stayer ,  Steven L. Fenske

    发明人： John W. Fieldhouse ,  Daniel F. Graves ,  William M. Cole ,  Mark L. Stayer ,  Steven L. Fenske

    IPC分类号： C08G79/00 ,  C08G79/02 ,  C08G73/00 ,  C08J3/00

    CPC分类号： C08G79/025

    摘要： The production of phosphazene polymers represented by the general formula ##STR1## WHEREIN R and R' are organic radicals hereinafter defined, and wherein n is an integer from 20 to upwards of 50,000 wherein one or more kinds of OR or OR' groups is attached to the phosphorus atoms in a substantially linear chain of alternating P and N atoms, the groups when more than one group is present being randomly distributed along the PN backbone, as described in copending United States Patent Application Ser. No. 824,004 filed Aug. 12, 1977, is enhanced by an improved procedure for the separation of the sodium chloride by-product from the derivatized phosphazene polymer. By treating the reaction mixture with carbon dioxide, in the presence of water and preferably with an additional alkali metal salt, agglomeration of the sodium chloride is accomplished, and a clean separation of the NaCl from the polyphosphazene ester is more readily achieved.

    摘要翻译： {PG，1}由通式{r1 {tc，1 {rb {ab，44 {m，1 {sb，21 {m，2 {ob，5 {mr，1P {M， 3 {AB，2 OR {MR，3 {AB，6 OR {40 {MR，3 {AD，444 N {M，4 {AB，44 {MR，4 {S，15 {MY，2 {CB，5 {BL，88 {S，6 {HD n {re {PS {PS WHEREIN R和R {40 {0是下文定义的有机基团，其中{1为20至高达50,000的整数，其中一个或多个 OR或OR的种类（40个O基团连接在交替的P和N原子的基本线性链中的磷原子，当存在多于一个基团时的基团沿着PN骨架随机分布，如共同未决United 国家专利申请 1977年8月12日提交的No.824,004通过用于从衍生的磷腈聚合物分离氯化钠副产物的改进方法得到增强。 通过用二氧化碳处理反应混合物，在水的存在下，优选用另外的碱金属盐，完成氯化钠的附聚，更容易实现NaCl与聚磷腈酯的清洁分离。

    Sulfenyl halide polymerization terminators
    27.
    发明授权
    Sulfenyl halide polymerization terminators 有权
    磺酰卤聚合终止子

    公开(公告)号：US06476143B2

    公开(公告)日：2002-11-05

    申请号：US09878077

    申请日：2001-06-08

    申请人： David F. Lawson ,  Mark L. Stayer ,  Thomas A. Antkowiak

    发明人： David F. Lawson ,  Mark L. Stayer ,  Thomas A. Antkowiak

    IPC分类号： C08F834

    CPC分类号： C08C19/44

    摘要： A method of preparing a functionalized polymer comprising the steps of initiating the formation and propagation of an anionically-polymerized living polymer, and terminating the propagation of the living polymer by reacting the polymer with a terminating agent selected from the group of agents defined by the formulas (III), (IV), and (V) where C is a carbon atom, S is a sulfur atom, X is a halogen atom, R2 and R4 are independently selected from hydrogen and carbon-based moieties, and where the phenyl groups are selected from unsubstituted and substituted phenyl groups.

    摘要翻译： 一种制备官能化聚合物的方法，包括以下步骤：引发阴离子聚合的活性聚合物的形成和扩散，并通过使聚合物与选自由式 （III），（IV）和（V）其中C是碳原子，S是硫原子，X是卤素原子，R2和R4独立地选自氢和碳基部分，并且其中苯基 选自未取代的和取代的苯基。