公开(公告)号：US06998179B2

公开(公告)日：2006-02-14

申请号：US10872749

申请日：2004-06-21

Applicant: Duane D. Fansler ,  Todd D. Jones ,  Babu N. Gaddam ,  Robert T. Fitzsimons ,  Steven M. Heilmann ,  John J. Cael

Inventor： Duane D. Fansler ,  Todd D. Jones ,  Babu N. Gaddam ,  Robert T. Fitzsimons ,  Steven M. Heilmann ,  John J. Cael

IPC: B32B27/30

CPC classification number: G02B5/3033 ,  B32B7/00 ,  B32B27/08 ,  C08F8/30 ,  C08F2800/20 ,  Y10S428/91 ,  Y10T428/31855 ,  Y10T428/31909 ,  Y10T428/31924 ,  Y10T428/31928 ,  Y10T428/31935 ,  Y10T428/31938 ,  C08F2220/1858

Abstract: A process for preparing a polarizer is described whereby an article comprising an oriented, vinylalcohol polymer film layer, and an acid donor layer comprising a photoacid generator, is exposed to radiant energy at a temperature sufficient to effect a partial dehydration of the vinylalcohol polymer to a vinylalcohol/poly(acetylene) copolymer.

公开(公告)号：US06911510B2

公开(公告)日：2005-06-28

申请号：US10820204

申请日：2004-04-07

Applicant: Kevin M. Lewandowski ,  Duane D. Fansler ,  Michael S. Wendland ,  Steven M. Heilmann ,  Babu N. Gaddam

Inventor： Kevin M. Lewandowski ,  Duane D. Fansler ,  Michael S. Wendland ,  Steven M. Heilmann ,  Babu N. Gaddam

IPC: C07D263/42 ,  C08F2/38 ,  C08F2/50 ,  C08F293/00 ,  C08F4/00

CPC classification number: C07D263/42 ,  C08F2/38 ,  C08F293/005 ,  C08F2438/03

Abstract: Chain transfer agents for controlled radical polymerizations (RAFT) are described. The chain transfer agents have an azlactone or ring-opened azlactone moiety to provide telechelic (co)polymers.

Abstract translation: 描述了用于受控自由基聚合（RAFT）的链转移剂。 链转移剂具有吖内酯或开环的吖内酯部分以提供遥爪（共）聚合物。

公开(公告)号：US06841637B2

公开(公告)日：2005-01-11

申请号：US10807007

申请日：2004-03-23

Applicant: Kevin M. Lewandowski ,  Duane D. Fansler ,  Michael S. Wendland ,  Babu N. Gaddam ,  Steven M. Heilmann

Inventor： Kevin M. Lewandowski ,  Duane D. Fansler ,  Michael S. Wendland ,  Babu N. Gaddam ,  Steven M. Heilmann

IPC: C08F2/38 ,  C08F2/50 ,  C08F4/40 ,  C08F4/00

CPC classification number: C08F2/38

Abstract: Chain transfer agents for controlled radical polymerizations (RAFT) are described. The chain transfer agents have an azlactone or ring-opened azlactone moiety to provide telechelic (co)polymers.

Abstract translation: 描述了用于受控自由基聚合（RAFT）的链转移剂。 链转移剂具有吖内酯或开环的吖内酯部分以提供遥爪（共）聚合物。

公开(公告)号：US06818716B2

公开(公告)日：2004-11-16

申请号：US10822479

申请日：2004-04-12

Applicant: Michael S. Wendland ,  Kevin M. Lewandowski ,  Duane D. Fansler ,  Babu N. Gaddam ,  Steven M. Heilmann

Inventor： Michael S. Wendland ,  Kevin M. Lewandowski ,  Duane D. Fansler ,  Babu N. Gaddam ,  Steven M. Heilmann

IPC: C08F400

CPC classification number: C08F2/50 ,  C08F4/00 ,  C08F26/02

Abstract: Photoiniferters for controlled radical polymerizations and telechelic copolymers comprising polymerized units of one or more free radically (co)polymerizable monomers having a first azalactone terminal group and a second dithiocarbamate terminal group are described.

Abstract translation: 描述了用于受控自由基聚合的光引发剂和遥爪共聚物，其包含具有第一氮杂内酯末端基团和第二二硫代氨基甲酸酯末端基团的一种或多种自由基（共）可聚合单体的聚合单元。

公开(公告)号：US06635690B2

公开(公告)日：2003-10-21

申请号：US09884173

申请日：2001-06-19

Applicant: Steven M. Heilmann ,  Babu N. Gaddam ,  Ahmed S. Abuelyaman ,  Duane D. Fansler ,  Todd D. Jones ,  Maureen A. Kavanagh ,  Kevin M. Lewandowski ,  Michael S. Wendland

Inventor： Steven M. Heilmann ,  Babu N. Gaddam ,  Ahmed S. Abuelyaman ,  Duane D. Fansler ,  Todd D. Jones ,  Maureen A. Kavanagh ,  Kevin M. Lewandowski ,  Michael S. Wendland

IPC: C08L8700

CPC classification number: C09D201/005 ,  C09D201/08

Abstract: The present invention provides novel compositions prepared from a first oligomer containing reactive functional groups capable of reaction at effective rates (at normal processing temperatures) with a co-reactive second component possessing functionality that is complementary to that of the first oligomer. The compositions may be used as coatings, including hard surface coatings, clear coatings, powder coatings and pattern coatings; as adhesives, including pressure sensitive adhesives and hot melt adhesives; as sealants; as optical coatings; as blown microfibers (BMF); as high refractive index optical materials; as barrier films; in microreplication; as low adhesion backsizes, (LABs) and as release coatings.

公开(公告)号：US5679779A

公开(公告)日：1997-10-21

申请号：US447852

申请日：1995-05-23

Applicant: Steven M. Heilmann ,  Gary J. Drtina ,  Louis C. Haddad ,  Frederick W. Hyde ,  Dean M. Moren ,  Robert A. Pranis

Inventor： Steven M. Heilmann ,  Gary J. Drtina ,  Louis C. Haddad ,  Frederick W. Hyde ,  Dean M. Moren ,  Robert A. Pranis

IPC: B01J31/06 ,  A61K47/32 ,  C08F20/36 ,  C08F212/36 ,  C08F220/20 ,  C08F220/34 ,  C08F220/36 ,  C08F220/56 ,  C08G18/64 ,  C08G18/72 ,  C12N11/08 ,  C08K17/02

CPC classification number: C08G18/728 ,  C08F20/36 ,  C08F220/36 ,  C08G18/6446 ,  C12N11/08 ,  Y10S530/815

Abstract: Insoluble supports are prepared which possess high surface areas and efficiently dispersed isocyanate groups. These reactive supports are useful for covalently binding proteins which preferably are enzymes and provide catalysts for conducting organic reactions.

Abstract translation: 制备具有高表面积和有效分散的异氰酸酯基团的不溶性载体。 这些反应性支持物可用于共价结合蛋白质，其优选为酶并提供用于进行有机反应的催化剂。

公开(公告)号：US5614105A

公开(公告)日：1997-03-25

申请号：US425585

申请日：1995-04-20

Applicant: Steven M. Heilmann ,  Gary J. Drtina ,  Philip D. Eitzman ,  Louis C. Haddad ,  Frederick W. Hyde ,  Todd W. Johnson

Inventor： Steven M. Heilmann ,  Gary J. Drtina ,  Philip D. Eitzman ,  Louis C. Haddad ,  Frederick W. Hyde ,  Todd W. Johnson

IPC: B01D39/14 ,  C12M1/40 ,  C12N11/00 ,  C12N11/02 ,  C12N11/04 ,  C12N11/08 ,  B01D37/00

CPC classification number: B01D39/14 ,  C12N11/02 ,  C12N11/04 ,  C12N11/08

Abstract: Insolubilized enzyme particulates are located on the upstream surface of a filtration layer of a filtering element which can be used in a cartridge filter. Employed in a recycling flow reaction system at relatively high flux rates, the cartridges are useful for conducting catalyzed chemical reactions of dissolved solutes, for example, esterifications, isomerizations, oxidations, reductions, and cyclizations.

Abstract translation: 不溶解的酶微粒位于可用于筒式过滤器的过滤元件的过滤层的上游表面上。 在相对较高的通量速率下在回收流动反应系统中使用，所述筒可用于进行溶解的溶质的催化化学反应，例如酯化，异构化，氧化，还原和环化。

公开(公告)号：US5292840A

公开(公告)日：1994-03-08

申请号：US335835

申请日：1989-04-10

Applicant: Steven M. Heilmann ,  Jerald K. Rasmussen ,  Larry R. Krepski ,  Dean S. Milbrath ,  Patrick L. Coleman ,  Margaret M. Walker

Inventor： Steven M. Heilmann ,  Jerald K. Rasmussen ,  Larry R. Krepski ,  Dean S. Milbrath ,  Patrick L. Coleman ,  Margaret M. Walker

IPC: B01J20/281 ,  A61K39/395 ,  B01J20/26 ,  C07K17/08 ,  C08F8/00 ,  C08F8/48 ,  C08F20/58 ,  C08F26/00 ,  C08F26/06 ,  C08J5/18 ,  C12N11/08 ,  G01N30/88 ,  C08F22/38

CPC classification number: A61K39/39525 ,  B01J20/26 ,  C07K17/08 ,  C08F20/58 ,  C08F8/00 ,  C08F8/12 ,  C08F8/16 ,  C08F8/32 ,  C08F8/48 ,  C12N11/08 ,  C08F2800/10 ,  C08F2800/20 ,  C08F2810/20

Abstract: Azlactone-functional polymer supports are useful reactive supports for the attachment of functional materials to provide novel adduct beads. The adduct beads are useful as complexing agents, catalysts, polymeric reagents, chromatographic supports, and as enzyme- or other biologically active supports. Novel carboxylate-functional polymer beads, are intermediates in the preparation of the azlactone-functional beads.Azlactone-functional supports have units of the formula: ##STR1## wherein R.sup.1 is H or CH.sub.3,R.sup.2 and R.sup.3 independently can be an alkyl group having 1 to 14 carbon atoms, a cycloalkyl group having 3 to 14 carbon atoms, an aryl group having 5 to 12 ring atoms, an arenyl group having 6 to 26 carbon and 0 to 3 S, N, and nonperoxidic O heteroatoms, or R.sup.2 and R.sup.3 taken together with the carbon to which they are joined can form a carbocyclic ring containing 4 to 12 ring atoms, andn is an integer 0 or 1,the azlactone functional supports having 0.1 to 99 molar parts of crosslinking monomer incorporated therein.

Abstract translation: 吖内酯官能聚合物载体是用于附着功能材料以提供新型加合珠的有用的反应性载体。 加合珠可用作络合剂，催化剂，聚合物试剂，色谱载体，以及酶或其它生物活性载体。 新型羧酸盐官能化聚合物珠粒是制备吖内酯官能团珠粒的中间体。 吖内酯官能载体具有下式的单元：（*化学结构*）V其中R 1为H或CH 3，R 2和R 3可独立地为具有1至14个碳原子的烷基，具有3至14个碳原子的环烷基， 具有5至12个环原子的芳基，具有6至26个碳和0至3个S，N和非过氧O的杂原子的芳基，或与其连接的碳一起的R 2和R 3可以形成碳环 含有4〜12个环原子，n为0或1的整数，所述吖内酯官能团的载体中含有0.1〜99摩尔份的交联单体。

公开(公告)号：US5292514A

公开(公告)日：1994-03-08

申请号：US903367

申请日：1992-06-24

Applicant: John T. Capecchi ,  Steven M. Heilmann ,  Larry R. Krepski ,  Oh-Seung Kwon ,  David B. Olson

Inventor： John T. Capecchi ,  Steven M. Heilmann ,  Larry R. Krepski ,  Oh-Seung Kwon ,  David B. Olson

IPC: A61L27/00 ,  A61L27/28 ,  A61L27/34 ,  A61L27/50 ,  C07C45/71 ,  C07C49/84 ,  C08F8/30 ,  A61F2/14 ,  C08K5/15

CPC classification number: C08F8/30 ,  A61F2/14 ,  A61L27/28 ,  A61L27/34 ,  A61L27/50 ,  C07C45/71 ,  C07C49/84 ,  C08K5/15

Abstract: Azlactone-functional substrates, (especially hydrogels), mammalian body implants, and methods of making and using them are disclosed. The azlactone-functional substrates are the reaction product of substrates having azlactone-reactive nucleophilic surfaces and a multi-functional azlactone composition having at least two azlactone moieties, where at least one moiety covalently couples to the azlactone-reactive nucleophilic surface and at least one moiety remains available for further nucleophilic reaction, such as with a biologically active material. A preferred use of azlactone-functional hydrogel is as the optical element of a corneal prosthesis which enhances epithethial cell growth.

Abstract translation: 公开了吖内酯功能底物（特别是水凝胶），哺乳动物体植入物及其制备和使用方法。 吖内酯功能底物是具有吖内酯反应性亲核表面的底物和具有至少两个吖内酯部分的多功能吖内酯组合物的反应产物，其中至少一个部分共价连接到吖内酯反应性亲核表面和至少一个部分 仍然可用于进一步的亲核反应，例如用生物活性物质。 吖内酯功能水凝胶的优选用途是作为增强上皮细胞生长的角膜假体的光学元件。

公开(公告)号：US5210248A

公开(公告)日：1993-05-11

申请号：US749926

申请日：1991-08-26

Applicant: Stefan A. Babirad ,  Dean M. Moren ,  Steven M. Heilmann ,  Larry R. Krepski ,  Jerald K. Rasmussen

Inventor： Stefan A. Babirad ,  Dean M. Moren ,  Steven M. Heilmann ,  Larry R. Krepski ,  Jerald K. Rasmussen

IPC: C07F7/10 ,  C07F7/18 ,  C08F30/08 ,  C08F130/08 ,  C08F230/08

CPC classification number: C08F30/08 ,  C07F7/1836

Abstract: The present invention provides novel fluorinated acrylamide silane monomers which are useful as adhesion promoting agents in optical fiber cladding compositions. Polymerization of the novel monomers, optionally in the presence compatible ethylenically-unsaturated monomers, provides homopolymers and copolymers which are useful as non-wetting agents.