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公开(公告)号：US20080139852A1
公开(公告)日：2008-06-12
申请号：US11720279
申请日：2005-11-24
IPC分类号： C07C29/17
CPC分类号： C07C29/17 , C07B2200/07 , C07C29/172 , C07C45/002 , C07C2601/14 , C12C11/02 , C07C33/025 , C07C35/12 , C07C29/56 , C07C35/17 , C07C47/21
摘要： Processes comprising: (a) enantioselectively hydrogenating a starting material comprising a component selected from geraniol, nerol and mixtures thereof to form optically active citronellol; (b) converting the optically active citronellol to optically active citronellal; (c) cyclizing the optically active citronellal to form a mixture comprising optically active isopulegol; and (d) subjecting the mixture to further processing comprising: (i) separating the optically active isopulegol from the mixture and hydrogenating the separated optically active isopulegol to form optically active menthol; or (ii) hydrogenating the optically active isopulegol in the mixture to form optically active menthol and separating the optically active menthol from the mixture.
摘要翻译： 方法包括：（a）对对选择性氢化包含选自香叶醇，橙花醇及其混合物的组分的起始材料以形成光学活性香茅醇; （b）将光学活性香茅醇转化为光学活性香茅醛; （c）使光学活性香茅醛环化以形成包含光学活性异ule ol醇的混合物; 和（d）对所述混合物进行进一步处理，包括：（i）从混合物中分离光学活性异胡胶，并将分离的光学活性异胡醇氢化以形成光学活性薄荷醇; 或者（ⅱ）将混合物中的光学活性异ule）醇氢化以形成光学活性薄荷醇，并将该光学活性薄荷醇与该混合物分离。
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22.发明授权Use of a supported catalyst containing precious metal for oxidative dehydrogenation 有权使用含贵金属的载体催化剂进行氧化脱氢公开(公告)号：US08779212B2
公开(公告)日：2014-07-15
申请号：US12933441
申请日：2009-03-16
CPC分类号： B01J31/1616 , B01J21/16 , B01J23/007 , B01J23/38 , B01J23/50 , B01J23/72 , B01J23/8926 , B01J37/0219 , B01J37/086 , B01J2231/763 , B01J2531/17 , C07C45/38 , C07C47/21
摘要： The use of a supported noble metal catalyst obtainable by applying a sparingly soluble noble metal compound to a support from solution or suspension, and subsequently treating thermally, for preparing olefinically unsaturated carbonyl compounds.
摘要翻译： 使用负载的贵金属催化剂，其通过将溶于或悬浮液的微溶贵金属化合物施加到载体上，随后热处理，制备烯属不饱和羰基化合物。
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公开(公告)号：US08563785B2
公开(公告)日：2013-10-22
申请号：US13608577
申请日：2012-09-10
申请人： Michael Limbach , Joaquim Henrique Teles , Radwan Abdallah , Torsten Mäurer , Thorsten Johann , Manuel Danz
发明人： Michael Limbach , Joaquim Henrique Teles , Radwan Abdallah , Torsten Mäurer , Thorsten Johann , Manuel Danz
IPC分类号： C07C29/56
摘要： A process for isomerizing olefinically unsaturated alcohols over supported noble metal catalysts with a support based on carbon in an oxygenous atmosphere.
摘要翻译： 在含氧气氛中具有基于碳的载体的负载型贵金属催化剂上异构化烯属不饱和醇的方法。
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公开(公告)号：US20130006021A1
公开(公告)日：2013-01-03
申请号：US13608577
申请日：2012-09-10
申请人： Michael Limbach , Joaquim Henrique Teles , Radwan Abdallah , Torsten Mäurer , Thorsten Johann , Manuel Danz
发明人： Michael Limbach , Joaquim Henrique Teles , Radwan Abdallah , Torsten Mäurer , Thorsten Johann , Manuel Danz
IPC分类号： C07C29/56
摘要： A process for isomerizing olefinically unsaturated alcohols over supported noble metal catalysts with a support based on carbon in an oxygenous atmosphere.
摘要翻译： 在含氧气氛中具有基于碳的载体的负载型贵金属催化剂上异构化烯属不饱和醇的方法。
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公开(公告)号：US08263813B2
公开(公告)日：2012-09-11
申请号：US12920150
申请日：2009-02-27
申请人： Michael Limbach , Joaquim Henrique Teles , Radwan Abdallah , Torsten Mäurer , Thorsten Johann , Manuel Danz
发明人： Michael Limbach , Joaquim Henrique Teles , Radwan Abdallah , Torsten Mäurer , Thorsten Johann , Manuel Danz
摘要： A process for isomerizing olefinically unsaturated alcohols over supported noble metal catalysts with a support based on carbon in an oxygenous atmosphere.
摘要翻译： 在含氧气氛中具有基于碳的载体的负载型贵金属催化剂上异构化烯属不饱和醇的方法。
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26.发明授权公开(公告)号：US07495132B2
公开(公告)日：2009-02-24
申请号：US10587191
申请日：2005-01-28
申请人： Christian Walsdorff , Thorsten Johann , Beatrice Roessler , Hartmut Hibst , Joaquim Henrique Teles , Sebastian Storck , Jens Klein
发明人： Christian Walsdorff , Thorsten Johann , Beatrice Roessler , Hartmut Hibst , Joaquim Henrique Teles , Sebastian Storck , Jens Klein
CPC分类号： C07C45/65 , B01J23/6445 , B01J23/6447 , B01J23/6522 , B01J23/681 , B01J23/8973 , B01J35/008 , B01J37/0201 , B01J37/0221 , B01J37/03 , C07C47/21 , C07C49/603
摘要： The present invention relates to a catalytically active composition comprising as active component Pd and Bi and at least one element selected from the group (a) consisting of Rh, Au, Sb, V, Cr, W, Mn, Fe, Co, Ni, Na, Cs and Ba, or Pd, Rh and Bi and optionally an element selected from the group (a′) consisting of Au, Sb, V, Cr, W, Mn, Fe, Co, Ni, Pt, Cu, Ag, Na, Cs, Mg, Ca and Ba. The present invention further provides a process for dehydrogenating hydrocarbons, preferably oxo-functionalized hydrocarbons such as cyclopentanone, cyclohexanone and isovaleraldehyde, using the catalytically active composition.
摘要翻译： 本发明涉及包含作为活性成分Pd和Bi的至少一种元素的催化活性组合物和选自由Rh，Au，Sb，V，Cr，W，Mn，Fe，Co，Ni组成的组（a）中的至少一种元素， Na，Cs和Ba或Pd，Rh和Bi以及任选的选自Au，Sb，V，Cr，W，Mn，Fe，Co，Ni，Pt，Cu，Ag， Na，Cs，Mg，Ca和Ba。 本发明还提供了一种使用催化活性组合物使烃优选氧化官能化烃如环戊酮，环己酮和异戊醛脱氢的方法。
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27.发明授权Method for producing olefinically unsaturated carbonyl compounds by oxidative dehydrogenation of alcohols 有权通过醇的氧化脱氢制备烯属不饱和羰基化合物的方法公开(公告)号：US08410315B2
公开(公告)日：2013-04-02
申请号：US12920139
申请日：2009-02-27
IPC分类号： C07C45/38
摘要： A process for preparing olefinically unsaturated carbonyl compounds by oxidative dehydrogenation in an oxygenous atmosphere over a supported catalyst which comprises gold and optionally further noble metals at temperatures in the range from 50 to 240° C.
摘要翻译： 一种在含氧气氛中通过氧化脱氢制备烯属不饱和羰基化合物的方法，所述载体催化剂包括金和任选的其它贵金属，温度范围为50-240℃。
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公开(公告)号：US20110004032A1
公开(公告)日：2011-01-06
申请号：US12920150
申请日：2009-02-27
申请人： Michael Limbach , Joaquim Henrique Teles , Radwan Abdallah , Torsten Mäurer , Thorsten Johann , Manuel Danz
发明人： Michael Limbach , Joaquim Henrique Teles , Radwan Abdallah , Torsten Mäurer , Thorsten Johann , Manuel Danz
IPC分类号： C07C29/56
摘要： A process for isomerizing olefinically unsaturated alcohols over supported noble metal catalysts with a support based on carbon in an oxygenous atmosphere.
摘要翻译： 在含氧气氛中具有基于碳的载体的负载型贵金属催化剂上异构化烯属不饱和醇的方法。
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29.发明申请公开(公告)号：US20110004025A1
公开(公告)日：2011-01-06
申请号：US12920139
申请日：2009-02-27
IPC分类号： C07C45/38
摘要： A process for preparing olefinically unsaturated carbonyl compounds by oxidative dehydrogenation in an oxygenous atmosphere over a supported catalyst which comprises gold and optionally further noble metals at temperatures in the range from 50 to 240° C.
摘要翻译： 一种在含氧气氛中通过氧化脱氢制备烯属不饱和羰基化合物的方法，所述载体催化剂包括金和任选的其它贵金属，温度范围为50-240℃。
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公开(公告)号：US20090312581A1
公开(公告)日：2009-12-17
申请号：US12307925
申请日：2007-07-09
申请人： Heiko Urtel , Soo Yin Chin , Thorsten Johann
发明人： Heiko Urtel , Soo Yin Chin , Thorsten Johann
IPC分类号： C07C45/00
CPC分类号： C07C45/002 , B01J23/6447 , B01J23/8973 , C07C47/06 , C07C49/08 , C07C47/02 , C07C47/04
摘要： A method for dehydrogenating primary or secondary alcohols having 1 to 12 carbon atoms to give the corresponding aldehydes or ketones in which the alcohol is brought into contact with a catalytically active composition comprising an active component of the formula PdaBibYcZd, where Y is selected from the group consisting of Co, Rh, Pt, Ag, Au, and Z is selected from the group consisting of Na, Cs, Mg, Ca, Ba, V, Cr, W, Fe, Ni, Cu, Sb where the indices a, b, c and d give the mass ratios of the respective elements to one another, where a=0.1-3, b=0.1-3, c=0-3, d=0-1.
摘要翻译： 一种使具有1至12个碳原子的伯醇或仲醇脱氢得到相应的醛或酮，其中醇与包含式PdaBibYcZd的活性组分的催化活性组合物接触，其中Y选自 由Co，Rh，Pt，Ag，Au和Z组成的组分选自Na，Cs，Mg，Ca，Ba，V，Cr，W，Fe，Ni，Cu，Sb， ，c和d给出各元素彼此的质量比，其中a = 0.1-3，b = 0.1-3，c = 0-3，d = 0-1。
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