公开(公告)号：US20200157027A1

公开(公告)日：2020-05-21

申请号：US16619167

申请日：2018-05-30

Applicant: Arkema France

Inventor： Laurent WENDLINGER ,  Dominique DEUR-BERT

IPC: C07C17/383

Abstract: The present invention relates to a method for producing high-purity 1,1,1,2,3,3-hexafluoropropane and a composition containing mainly 1,1,1,2,3,3-hexafluoropropane, suitable for use as a cleaning agent in the semiconductor industry.

公开(公告)号：US20190210943A1

公开(公告)日：2019-07-11

申请号：US16099208

申请日：2017-05-17

Applicant: Arkema France

Inventor： Dominique DEUR-BERT ,  Dominique GARRAIT ,  Anne PIGAMO ,  Laurent WENDLINGER

IPC: C07C17/20 ,  C07C21/18 ,  B01J8/04 ,  B01J19/02 ,  B01J38/12

CPC classification number: C07C17/206 ,  B01J8/0457 ,  B01J8/0492 ,  B01J19/02 ,  B01J38/12 ,  B01J2208/00371 ,  B01J2219/0286 ,  B01J2219/0295 ,  C07C21/18

Abstract: The present invention concerns a method for preparing tetrafluoropropene utilising three reactors and comprising the steps of (a) implementing, in the first and second reactors, at least one step of reacting, in the gas phase, a compound B in the presence of hydrofluoric acid and a catalyst, in alternation with a step of regenerating the catalyst by bringing it into contact with a regeneration flow comprising an oxidising agent, (b) implementing, in the third reactor, a preliminary step of producing the compound B, in alternation with a step of regenerating the preliminary catalyst with a regeneration flow comprising an oxidising agent. The step of regenerating the preliminary catalyst in the third reactor is implemented in the absence of a step of reacting the compound B in the presence of hydrofluoric acid in said first and second reactors. The present invention also concerns a facility configured to implement the present method.

公开(公告)号：US20180327341A1

公开(公告)日：2018-11-15

申请号：US16039447

申请日：2018-07-19

Applicant: Arkema France

Inventor： Dominique DEUR-BERT ,  Bertrand COLLIER ,  Laurent WENDLINGER

IPC: C07C17/25 ,  C07C17/383 ,  C01B7/19 ,  B01J37/12 ,  B01J37/24 ,  B01J37/26 ,  B01J23/26 ,  B01J23/86 ,  C07C17/20

CPC classification number: C07C17/25 ,  B01J23/26 ,  B01J23/866 ,  B01J27/132 ,  B01J37/12 ,  B01J37/24 ,  B01J37/26 ,  C01B7/191 ,  C07C17/206 ,  C07C17/38 ,  C07C17/383 ,  C07C19/08 ,  C07C21/18

Abstract: The present invention provides a process for preparing 2,3,3,3-tetrafluoropropene from 1,1,1,2,3-pentachloropropane and/or 1,1,2,2,3-pentachloropropane, comprising the following steps: (a) catalytic reaction of 1,1,1,2,3-pentachloropropane and/or 1,1,2,2,3-pentachloropropane with HF into a reaction mixture comprising HCl, 2-chloro-3,3,3-trifluoropropene, 2,3,3,3-tetrafluoropropene, unreacted HF, and optionally 1,1,1,2,2-pentafluoropropane; (b) separating the reaction mixture into a first stream comprising HCl and 2,3,3,3-tetrafluoropropene and a second stream comprising HF, 2-chloro-3,3,3-trifluoropropene and optionally 1,1,1,2,2-pentafluoropropane; (c) catalytic reaction of the second stream into a reaction mixture comprising 2,3,3,3-tetrafluoropropene, HCl, unreacted 2-chloro-3,3,3-trifluoropropene, unreacted HF and optionally 1,1,1,2,2-pentafluoropropane and (d) feeding the reaction mixture of step (c) directly without separation to step (a).

公开(公告)号：US20180141885A1

公开(公告)日：2018-05-24

申请号：US15861873

申请日：2018-01-04

Applicant: Arkema France

Inventor： Philippe BONNET ,  Bertrand COLLIER ,  Dominique DEUR-BERT ,  Dominique GARRAIT ,  Anne PIGAMO ,  Laurent WENDLINGER

IPC: C07C17/20 ,  B01J7/00 ,  C07C17/21 ,  C07C17/25 ,  C07C21/18 ,  C07C19/08

CPC classification number: C07C17/206 ,  B01J7/00 ,  C07C17/21 ,  C07C17/25 ,  C07C21/18 ,  C07C19/08

Abstract: The invention relates to a method for producing a fluorinated compound, comprising: the provision of a gaseous flow comprising hydrofluoric acid; the provision of at least one liquid flow of a chlorinated compound and the vapourisation thereof by mixing with said gaseous flow, the resulting mixture being a gaseous mixture; and the catalytic reaction of the chlorinated compound with hydrofluoric acid in a gaseous phase and the collection of a product flow. The invention also relates to a facility for carrying out said method.

公开(公告)号：US20170327442A1

公开(公告)日：2017-11-16

申请号：US15533406

申请日：2014-12-11

Applicant: Arkema France

Inventor： Laurent WENDLINGER

IPC: C07C17/354 ,  C07C17/25

CPC classification number: C07C17/354 ,  C07C17/25 ,  C07C17/38 ,  Y02P20/582 ,  C07C21/18 ,  C07C19/12

Abstract: The present invention provides a process for the preparation of 1-chloro-2,2-difluoroethane comprising the following stages: (i) dehydrofluorinating 1,1,1-trifluoro-2-chloroethane to form a product stream comprising 1-chloro-2,2-difluoroethylene, optionally separation of 1-chloro-2,2-difluoroethylene from the product stream and (ii) hydrogenating 1-chloro-2,2-difluoroethylene obtained in stage (i) to give 1-chloro-2,2-difluoroethane.

公开(公告)号：US20170226032A1

公开(公告)日：2017-08-10

申请号：US15518607

申请日：2015-10-07

Applicant: Arkema France

Inventor： Anne PIGAMO ,  Dominique DEUR-BERT ,  Laurent WENDLINGER ,  Bertrand COLLIER

IPC: C07C17/20 ,  C07C19/01

CPC classification number: C07C17/206 ,  C07C17/20 ,  C07C17/21 ,  C07C19/01 ,  C07C21/18

Abstract: The invention first relates to a composition comprising at least 99 wt. % of 1,1,1,3,3-pentachloropropane and at least one compound selected from a list of additional compounds consisting of dichloropropanes, trichloropropanes, tetrachloropropanes, pentachloropropanes different from 1,1,1,3,3-pentachloropropane, hexachloropropanes, heptachloropropanes, chloropropenes, dichloropropenes, trichloropropenes, tetrachloropropenes, pentachloropropenes and hexachloropropene, the weight content of said compound in the composition being lower than or equal to 500 ppm.

公开(公告)号：US20170174589A1

公开(公告)日：2017-06-22

申请号：US15453992

申请日：2017-03-09

Applicant: Arkema France

Inventor： Dominique DEUR-BERT ,  Anne PIGAMO ,  Nicolas DOUCET ,  Laurent WENDLINGER

IPC: C07C17/383 ,  B01J27/125 ,  B01J23/86 ,  C07C17/25 ,  C07C17/20

CPC classification number: C07C17/383 ,  B01J23/866 ,  B01J27/125 ,  C07C17/206 ,  C07C17/25 ,  C07C17/42 ,  C07C19/08 ,  C07C21/18

Abstract: The present invention provides a process of catalytic fluorination in gas phase of product 1,1,1,2,3-pentachloropropane or/and 1,1,2,2,3-pentachloropropane into product 2,3,3,3-tetrafluoropropene in presence of a catalyst.

公开(公告)号：US20160107957A1

公开(公告)日：2016-04-21

申请号：US14980979

申请日：2015-12-28

Applicant: Arkema France

Inventor： Anne PIGAMO ,  Laurent WENDLINGER ,  Philippe BONNET

IPC: C07C17/087 ,  C07C17/25

CPC classification number: C07C17/087 ,  C07C17/25 ,  C07C19/10 ,  C07C21/18

Abstract: Process of catalytic fluorination in liquid phase of product 2-chloro-3,3,3-trifluoropropene into product 2-chloro-1,1,1,2-tetrafluoropropane, with an ionic liquid based catalyst. Process for manufacturing 2,3,3,3-tetrafluoropropene.

Abstract translation: 将产物2-氯-3,3,3-三氟丙烯在液相中催化氟化的方法转化成产物2-氯-1,1,1,2-四氟丙烷，与离子液体基催化剂。 制备2,3,3,3-四氟丙烯的方法。

公开(公告)号：US20160046548A1

公开(公告)日：2016-02-18

申请号：US14773645

申请日：2014-02-24

Applicant: ARKEMA FRANCE

Inventor： Philippe BONNET ,  Bertrand COLLIER ,  Dominique DEUR-BERT ,  Laurent WENDLINGER

IPC: C07C21/18 ,  C01B7/19

Abstract: An azeotropic or quasi-azeotropic composition including hydrogen fluoride, 3,3,3-trifluoropropene and one or more (hydro)halogen-carbon compounds including between 1 and 3 carbon atoms. Also, a preferred azeotropic or quasi-azeotropic composition including hydrogen fluoride, 3,3,3-trifluoropropene, and one or more compounds selected from among 1,1,1,2,2-pentafluoropropane, 2,3,3,3-tetrafluoropropene, 1,3,3,3-tetrafluoropropene, 3,3,3-trifluoro-2-chloropropene, E-3,3,3-trifluoro-l-chloropropene, trifluoropropyne, 1,1,1,3,3-pentafluoropropane, 1,1,1,3,3-pentafluoropropane, 1,1,1,3,3-pentafluoropropene, 1,1,1,2,3-pentafluoropropene and 2-chloro, 1,1,1,2-tetrafluoropropane.

Abstract translation: 共沸或准共沸组合物，包括氟化氢，3,3,3-三氟丙烯和一种或多种（氢）卤素 - 碳化合物，包括1至3个碳原子。 此外，优选的共沸或准共沸组合物包括氟化氢，3,3,3-三氟丙烯和一种或多种选自1,1,1,2,2-五氟丙烷，2,3,3,3-三氟丙烷， 四氟丙烯，1,3,3,3-四氟丙烯，3,3,3-三氟-2-氯丙烯，E-3,3,3-三氟-1-氯丙烯，三氟丙炔，1,1,1,3,3-四氟丙烯， 五氟丙烷，1,1,1,3,3-五氟丙烷，1,1,1,3,3-五氟丙烯，1,1,1,2,3-五氟丙烯和2-氯，1,1， 四氟丙烷。

公开(公告)号：US20160023176A1

公开(公告)日：2016-01-28

申请号：US14773537

申请日：2014-02-24

Applicant: ARKEMA FRANCE

Inventor： Philippe BONNET ,  Bertrand COLLIER ,  Dominique DEUR-BERT ,  Laurent WENDLINGER

IPC: B01F17/00 ,  C09K5/04 ,  B01D53/26 ,  H01B3/56 ,  C09G1/06 ,  C09K3/00 ,  C09K3/30

CPC classification number: B01F17/0085 ,  B01D53/26 ,  C01B7/191 ,  C07C21/18 ,  C09G1/06 ,  C09K3/00 ,  C09K3/30 ,  C09K5/04 ,  C09K5/044 ,  H01B3/56

Abstract: An azeotropic or quasi-azeotropic composition including hydrogen fluoride, 3,3,3-trifluoro-2-chloropropene and one or more (hydro)halogen-carbon compounds including between 1 and 3 carbon atoms. Also an azeotropic or quasi-azeotropic composition including hydrogen fluoride, 3,3,3-trifluoro-2-chloropropene, and one or more compounds selected from among 1,3,3,3-tetrafluoropropene, 1,1,1,2,2-pentafluoropropane, 2,3,3,3-tetrafluoropropene, 3,3,3-trifluoropropene, E-3,3,3-trifluoro-1-chloropropene, trifluoropropyne, 1,1,3,3-pentafluoropropane, 1,1,1,3,3-pentafluoropropane, 1,1,1,3,3-pentafluoropropene, 1,1,1,2,3-pentafluoropropene and 2-chloro,1,1,1,2-1 tetrafluoropropane.

Abstract translation: 共沸或准共沸组合物包括氟化氢，3,3,3-三氟-2-氯丙烯和一种或多种（氢）卤素 - 碳化合物，包括1至3个碳原子。 还有一种共沸或准共沸组合物，包括氟化氢，3,3,3-三氟-2-氯丙烯和一种或多种选自1,3,3,3-四氟丙烯，1,1,1,2， 2-五氟丙烷，2,3,3,3-四氟丙烯，3,3,3-三氟丙烯，E-3,3,3-三氟-1-氯丙烯，三氟丙炔，1,1,3,3-五氟丙烷， 1,1,3,3-五氟丙烷，1,1,1,3,3-五氟丙烯，1,1,1,2,3-五氟丙烯和2-氯1,1,1,2-四氟丙烷。