公开(公告)号：US20160152535A1

公开(公告)日：2016-06-02

申请号：US15014583

申请日：2016-02-03

Applicant: Arkema France

Inventor： Philippe BONNET ,  Anne PIGAMO ,  Laurent WENDLINGER ,  Nicolas DOUCET

IPC: C07C17/25 ,  B01J23/86 ,  C07C17/42

Abstract: The present invention provides a process of catalytic fluorination in gas phase of product 1,1,1,2,3-pentachloropropane or/and 1,1,2,2,3-pentachloropropane into product 2-chloro-3,3,3-trifluoropropene in presence of a catalyst and oxygen.

Abstract translation: 本发明提供了在产物1,1,1,2,3-五氯丙烷或/和1,1,2,2,3-五氯丙烷的气相中催化氟化产物2-氯-3,3,3 - 三氟丙烯在催化剂和氧气存在下反应。

公开(公告)号：US20160176789A1

公开(公告)日：2016-06-23

申请号：US15055738

申请日：2016-02-29

Applicant: Arkema France

Inventor： Anne PIGAMO ,  Laurent WENDLINGER ,  Nicolas DOUCET

IPC: C07C17/20 ,  B01J23/86

CPC classification number: C07C17/206 ,  B01J23/866 ,  B01J23/90 ,  B01J23/92 ,  B01J23/94 ,  B01J27/125 ,  B01J37/14 ,  B01J37/26 ,  B01J38/12 ,  C07C17/20 ,  C07C17/25 ,  Y02P20/584 ,  C07C21/18

Abstract: The invention relates to a fluorination process, alternately comprising reaction stages and regeneration stages, wherein the reaction stages comprise reacting a chlorinated compound with hydrogen fluoride in gas phase in the presence of a fluorination catalyst to produce a fluorinated compound, and the regeneration stages comprise contacting the fluorination catalyst with an oxidizing agent-containing gas flow.

Abstract translation: 本发明涉及氟化方法，交替包括反应阶段和再生阶段，其中反应步骤包括在氟化催化剂存在下使气相中的氯化化合物与氟化氢反应以产生氟化化合物，并且再生阶段包括接触 含有含氧化剂气体的氟化催化剂。

公开(公告)号：US20170174589A1

公开(公告)日：2017-06-22

申请号：US15453992

申请日：2017-03-09

Applicant: Arkema France

Inventor： Dominique DEUR-BERT ,  Anne PIGAMO ,  Nicolas DOUCET ,  Laurent WENDLINGER

IPC: C07C17/383 ,  B01J27/125 ,  B01J23/86 ,  C07C17/25 ,  C07C17/20

CPC classification number: C07C17/383 ,  B01J23/866 ,  B01J27/125 ,  C07C17/206 ,  C07C17/25 ,  C07C17/42 ,  C07C19/08 ,  C07C21/18

Abstract: The present invention provides a process of catalytic fluorination in gas phase of product 1,1,1,2,3-pentachloropropane or/and 1,1,2,2,3-pentachloropropane into product 2,3,3,3-tetrafluoropropene in presence of a catalyst.

公开(公告)号：US20180230074A1

公开(公告)日：2018-08-16

申请号：US15951645

申请日：2018-04-12

Applicant: Arkema France

Inventor： Anne PIGAMO ,  Nicolas DOUCET ,  Laurent WENDLINGER

IPC: C07C17/20 ,  B01J27/125 ,  B01J23/86 ,  B01J38/12

CPC classification number: C07C17/206 ,  B01J21/04 ,  B01J21/20 ,  B01J23/06 ,  B01J23/34 ,  B01J23/75 ,  B01J23/755 ,  B01J23/86 ,  B01J23/864 ,  B01J23/866 ,  B01J23/90 ,  B01J23/94 ,  B01J27/125 ,  B01J37/0201 ,  B01J37/14 ,  B01J37/26 ,  B01J38/12 ,  C07C17/25 ,  Y02P20/584 ,  C07C21/18 ,  C07C19/08

Abstract: The present invention relates to a fluorination process, comprising: an activation stage comprising contacting a fluorination catalyst with to an oxidizing agent-containing gas flow for at least one hour; and at least one reaction stage comprising reacting a chlorinated compound with hydrogen fluoride in gas phase in the presence of the fluorination catalyst, so as to produce a fluorinated compound.

公开(公告)号：US20170313638A1

公开(公告)日：2017-11-02

申请号：US15644973

申请日：2017-07-10

Applicant: Arkema France

Inventor： Anne PIGAMO ,  Laurent WENDLINGER ,  Nicolas DOUCET

IPC: C07C17/20 ,  B01J38/12 ,  B01J37/26 ,  C07C17/25 ,  B01J23/94 ,  B01J23/92 ,  B01J23/86 ,  B01J37/14 ,  B01J27/125 ,  B01J23/90

CPC classification number: C07C17/206 ,  B01J23/866 ,  B01J23/90 ,  B01J23/92 ,  B01J23/94 ,  B01J27/125 ,  B01J37/14 ,  B01J37/26 ,  B01J38/12 ,  C07C17/20 ,  C07C17/25 ,  Y02P20/584 ,  C07C21/18

Abstract: The invention relates to a fluorination process, alternately comprising reaction stages and regeneration stages, wherein the reaction stages comprise reacting a chlorinated compound with hydrogen fluoride in gas phase in the presence of a fluorination catalyst to produce a fluorinated compound, and the regeneration stages comprise contacting the fluorination catalyst with an oxidizing agent-containing gas flow.

公开(公告)号：US20170174587A1

公开(公告)日：2017-06-22

申请号：US15453986

申请日：2017-03-09

Applicant: Arkema France

Inventor： Anne PIGAMO ,  Nicolas DOUCET ,  Laurent WENDLINGER

IPC: C07C17/20 ,  B01J27/125 ,  B01J38/12 ,  B01J23/86

CPC classification number: C07C17/206 ,  B01J21/04 ,  B01J21/20 ,  B01J23/06 ,  B01J23/34 ,  B01J23/75 ,  B01J23/755 ,  B01J23/86 ,  B01J23/864 ,  B01J23/866 ,  B01J23/90 ,  B01J23/94 ,  B01J27/125 ,  B01J37/0201 ,  B01J37/14 ,  B01J37/26 ,  B01J38/12 ,  C07C17/25 ,  Y02P20/584 ,  C07C21/18 ,  C07C19/08

Abstract: The present invention relates to a fluorination process, comprising: an activation stage comprising contacting a fluorination catalyst with an oxidizing agent-containing gas flow for at least one hour; and at least one reaction stage comprising reacting a chlorinated compound with hydrogen fluoride in gas phase in the presence of the fluorination catalyst, so as to produce a fluorinated compound.

公开(公告)号：US20160221899A1

公开(公告)日：2016-08-04

申请号：US15096603

申请日：2016-04-12

Applicant: Arkema France

Inventor： Anne PIGAMO ,  Nicolas DOUCET ,  Laurent WENDLINGER

IPC: C07C17/20 ,  B01J23/86

CPC classification number: C07C17/206 ,  B01J21/04 ,  B01J21/20 ,  B01J23/06 ,  B01J23/34 ,  B01J23/75 ,  B01J23/755 ,  B01J23/86 ,  B01J23/864 ,  B01J23/866 ,  B01J23/90 ,  B01J23/94 ,  B01J27/125 ,  B01J37/0201 ,  B01J37/14 ,  B01J37/26 ,  B01J38/12 ,  C07C17/25 ,  Y02P20/584 ,  C07C21/18 ,  C07C19/08

Abstract: The present invention relates to a fluorination process, comprising: an activation stage comprising contacting a fluorination catalyst with an oxidizing agent-containing gas flow for at least one hour; and at least one reaction stage comprising reacting a chlorinated compound with hydrogen fluoride in gas phase in the presence of the fluorination catalyst, so as to produce a fluorinated compound.

Abstract translation: 本发明涉及一种氟化方法，包括：活化阶段，包括使含氟化催化剂与含氧化剂气流接触至少1小时; 以及至少一个反应阶段，包括在氟化催化剂存在下，使气相中的氯化化合物与氟化氢反应，从而制备氟化物。

公开(公告)号：US20160145175A1

公开(公告)日：2016-05-26

申请号：US15008896

申请日：2016-01-28

Applicant: Arkema France

Inventor： Dominique DEUR-BERT ,  Anne PIGAMO ,  Nicolas DOUCET ,  Laurent WENDLINGER

IPC: C07C17/20 ,  C07C17/383

CPC classification number: C07C17/383 ,  B01J23/866 ,  B01J27/125 ,  C07C17/206 ,  C07C17/25 ,  C07C17/42 ,  C07C19/08 ,  C07C21/18

Abstract: The present invention provides a process of catalytic fluorination in gas phase of product 1,1,1,2,3-pentachloropropane or/and 1,1,2,2,3-pentachloropropane into product 2,3,3,3-tetrafluoropropene in presence of a catalyst.

Abstract translation: 本发明提供在产物1,1,1,2,3-五氯丙烷或/和1,1,2,2,3-五氯丙烷的气相中催化氟化的方法制备成产物2,3,3,3-四氟丙烯 在催化剂存在下。