摘要:
Preparation of butyl rubber based graft co-polymers from halobutyl elastomers using phase transfer catalysts in the presence of a solution of an alkali metal salt of an oxygen or sulfur nucleophile that is bound to a polymeric substrate. Graft co-polymers can be produced of a butyl polymer (isobutene-co-isoprene) and polymeric substrates such as polyethylene, polypropylene, polystyrene, polybutadiene, polysilanes, polysiloxanes, polyethylene glycol, polyethylene oxide, polyphosphazenes, polyferrocenes or their hybrids.
摘要:
The present invention relates to a process for producing peroxide curable high multiolefin halobutyl ionomers prepared by reacting a halogenated butyl polymer having a high mol percent of multiolefin with at least one nitrogen and/or phosphorus based nucleophile. The resulting high multiolefin halobutyl ionomer comprises from about 2 to 10 mol % multiolefin. The present invention is also directed to the high multiolefin halobutyl ionomer.
摘要:
The present invention relates to a continuous process for producing polymers at conversions ranging from 50% to 95% having a Mooney viscosity of at least 25 Mooney-units and a gel content of less than 15 wt. % containing repeating units derived from at least one isoolefin monomer, more than 4.1 mol % of repeating units derived from at least one multiolefin monomer and optionally further copolymerizable monomers in the presence of AlCl3 and a suitable proton source (e.g. water) or cationogen and at least one multiolefin cross-linking agent wherein the process is conducted in the absence of transition metal compounds and organic nitro compounds.
摘要:
The present invention relates to silica-filled halogenated butyl elastomers, such as bromobutyl elastomers (BIIR). Further, the present invention also relates to bromobutyl elastomers with improved scorch safety.
摘要:
The invention relates to peroxide cured thermoplastic vulcanizates comprising a thermoplastic and an isomonoolefin-multiolefin elastomer, such as butyl rubber. More particularly, the invention relates to peroxide cured thermoplastic vulcanizates wherein the elastomer comprises at least 3.5 mol % of multiolefin in order to facilitate peroxide curing. The thermoplastic vulcanizates according to the present invention are useful in the preparation of shaped articles for high purity applications, such as condenser caps, medical components and fuel cell components.
摘要:
The present invention provides a process for preparing a filled halobutyl elastomer, which includes mixing a halobutyl elastomer, particles of filler an additive containing both amino and alcohol functional groups, and one or more hydrated metal halogens and optional curing the filled elastomer with sulfur or other curative systems. The compositions of the present invention have improved properties when compared to known carbon black-filled halobutyl elastomeric compositions combined with an enhanced scorch safety. This present invention has the advantages of (a) not evolving alcohol either during the manufacture or subsequent use of the article manufactured from the compound, and (b) maintaining good processability of the compound.
摘要:
The present invention provides a process for preparing a filled halobutyl elastomer, which includes mixing a halobutyl elastomer with at least one mineral filler and at least one dry liquid modifier and optionally curing the filled elastomer with sulfur or other curative systems. Filled halobutyl elastomers prepared according to the present invention possess improved levels of filler dispersion which results in a reduction in the hardness of the compound and an increased tensile strength.
摘要:
The invention provides a process for preparing a filled halobutyl elastomer, which includes mixing a halobutyl elastomer with at least one mineral filler that has been reacted with at least one organic compound containing at least one basic nitrogen-containing group and at least one hydroxyl group and, optionally, with at least one silazane compound before admixing the filler with the halobutyl elastomer and optionally curing the filled elastomer with sulfur or other curative systems. This invention has the advantages of (a) not evolving alcohol either during the manufacture or subsequent use of the article manufactured from the compound, (b) improving the scorch safety of filled halobutyl elastomer compounds which employ silica as the mineral filler and a hydroxyl- and amine-containing additive as a dispersing aid and (c) significantly reducing the cost of the compound compared to analogous compounds currently known in the art.
摘要:
The present invention provides compositions containing halobutyl elastomers, at least one mineral filler and at least one oligomeric polyol compound or mixture of at least one oligomeric polyol compound and an additive which contains at least one hydroxyl group and at least one functional group having a basic amine group.The present invention also provides a process for preparing silica reinforced elastomer compounds with improved scorch safety including admixing halobutyl elastomers, at least one silica mineral filler and at least one oligomeric polyol compound or mixture of at least one oligomeric polyol compound and an additive which contains at least one hydroxyl group and at least one functional group having a basic amine group and curing the resulting filled halobutyl elastomer mixture.
摘要:
The present invention provides a process for preparing a filled halobutyl elastomer, which includes mixing a halobutyl elastomer, mineral filler and a silylated additive. The present invention also provides a filled halobutyl elastomer containing a mineral filler and a silylated additive.