Process for preparing catalysts
    22.
    发明授权
    Process for preparing catalysts 失效
    制备催化剂的方法

    公开(公告)号:US4490483A

    公开(公告)日:1984-12-25

    申请号:US495966

    申请日:1983-05-19

    摘要: A process for preparing novel catalysts of increased activity which comprises (1) mixing alumina with at least a Group IVB metal compound and a molybdenum compound and an aqueous solution containing at least one dissolved compound therein that imparts to said aqueous solution a pH below 6 and (2) thereafter adding to the resulting product at least one metal compound not previously added thereto.

    摘要翻译: 一种制备增加活性的新型催化剂的方法,其包括(1)将氧化铝与至少一种IVB族金属化合物和钼化合物混合,以及含有至少一种溶解的化合物的水溶液,其中所述水溶液的pH低于6, (2)之后,向所得到的产物中加入至少一种以前未加入的金属化合物。

    Impregnating solution for hydrogenation catalyst manufacture and
production thereof
    23.
    发明授权
    Impregnating solution for hydrogenation catalyst manufacture and production thereof 失效
    用于氢化催化剂的浸渍溶液的制造及其生产

    公开(公告)号:US4399058A

    公开(公告)日:1983-08-16

    申请号:US241018

    申请日:1981-03-06

    CPC分类号: B01J23/883

    摘要: An aqueous, alkaline impregnating solution for the one-step impregnation of nickel and molybdenum onto a catalyst support is provided by admixing nickel sulfate, preferably an ammoniacal solution of nickel sulfate and an ammoniacal solution of Mo.sup.+VI oxide to form a compatible impregnating solution. Nickel and sulfate ions are present in a ratio of substantially 1 to 1. The use of nickel sulfate in a predissolved ammoniacal solution for admixture with the ammoniacal solution of the Mo.sup.+VI oxide permits a higher metals loading of the impregnating solution and renders the resulting impregnating solution highly suitable for impregnation of nickel and molybdenum onto a catalyst support by the incipient wetness technique in one-step. The catalyst produced using the present impregnating solution is highly active for desulfurization of naphthas, middle distillate oils and asphalt-containing oils.

    摘要翻译: 通过将硫酸镍,优选硝酸镍的氨溶液和Mo + VI氧化物的氨溶液混合以形成相容的浸渍溶液来提供用于将镍和钼一步浸渍到催化剂载体上的水性碱性浸渍溶液。 镍和硫酸根离子以基本上1比1的比例存在。在预溶解的氨溶液中使用硫酸镍与Mo + VI氧化物的氨溶液混合,允许浸渍溶液的较高的金属负载,并使得到 浸渍溶液非常适合于通过初始润湿技术在一步中将镍和钼浸渍到催化剂载体上。 使用本发明的浸渍溶液制备的催化剂对于石脑油,中间馏分油和含沥青的油的脱硫具有高度的活性。

    Lubricating oil hydrotreating process
    25.
    发明授权
    Lubricating oil hydrotreating process 失效
    润滑油加氢处理工艺

    公开(公告)号:US4285807A

    公开(公告)日:1981-08-25

    申请号:US72232

    申请日:1979-09-04

    摘要: A lube oil feedstock is subjected to hydrotreating in the presence of hydrogen and a fluorine-promoted catalyst comprising nickel and molybdenum on a support wherein the nickel and fluorine are derived from an ammoniacal solution of nickel fluoride. The catalyst can be prepared by contacting the support with an alkaline impregnating solution consisting essentially of NH.sub.4.sup.+, Ni.sup.++, MO.sup.+VI and F.sup.-, said Ni.sup.++ and F.sup.- being supplied from nickel fluoride, in a single step employing the incipient wetness technique. The impregnated support is thereafter heated to drive off the alkaline component of the solution and thereby deposit the fluorine, nickel and molybdenum on the support.

    摘要翻译: 润滑油原料在氢气存在下进行加氢处理,在载体上含有镍和钼的氟促进催化剂,其中镍和氟源自硝酸镍的氨溶液。 催化剂可以通过使载体与基本上由NH4 +,Ni ++,MO + VI和F-组成的碱性浸渍溶液接触来制备,所述Ni ++和F-由氟化镍提供,采用初始润湿技术的单步骤。 然后将浸渍的载体加热以驱除溶液的碱性组分,从而将氟,镍和钼沉积在载体上。