公开(公告)号：US20150353818A1

公开(公告)日：2015-12-10

申请号：US14832425

申请日：2015-08-21

Applicant: BASF SE*

Inventor： Christian Bittner ,  Günter Oetter ,  Jack Tinsley ,  Christian Spindler ,  Gabriela Alvarez-Juergenson ,  Sophie Vogel ,  Petra Neumann ,  Veronika Wloka ,  Martin Bock

IPC: C09K8/86 ,  E21B43/16

CPC classification number: C09K8/86 ,  C09K8/584 ,  E21B43/16

Abstract: The present invention relates to a process for mineral oil extraction by means of Winsor type III microemulsion flooding, in which an aqueous surfactant formulation comprising at least three ionic surfactants which are different with regard to the alkyl moiety (R1)(R2)—CH—CH2— and are of the general formula (R1)(R2)—CH—CH2—O-(D)n-(B)m-(A)l-XYa−a/bMb+ is injected through injection boreholes into a mineral oil deposit, and crude oil is withdrawn from the deposit through production boreholes. The invention further relates to surfactant formulations of ionic surfactants of the general formula.

Abstract translation: 本发明涉及一种通过Winsor III型微乳液淹水进行矿物油提取的方法，其中包含至少三种离子表面活性剂的水性表面活性剂制剂，其对于烷基部分（R 1）（R 2）-CH- CH 2 - 并且具有通式（R1）（R2）-CH-CH2-O-（D）n-（B）m-（A）1-XYa-a / bMb +通过注射钻孔注入矿物油 通过生产钻孔从存款中取出原油。 本发明还涉及通式为离子表面活性剂的表面活性剂制剂。

公开(公告)号：US20140288309A1

公开(公告)日：2014-09-25

申请号：US14299574

申请日：2014-06-09

Applicant: BASF SE

Inventor： Karin Schein ,  Arno Kochner ,  Ludwig Völkel ,  Christian Bittner ,  Ingo Münster ,  Frank Dietsche ,  Wolfgang Schrof ,  Hansgeorg Ernst ,  Karl Beck ,  Andrea Misske ,  Martin Scholtissek

IPC: C07D217/10

CPC classification number: C07D217/10 ,  C11D3/3927

Abstract: This invention relates to a process of producing compounds, which are useful as bleach boosters, as well as to the compounds, which are obtainable using said process, and to their use.

Abstract translation: 本发明涉及生产可用作漂白助剂的化合物的方法，以及可使用所述方法获得的化合物及其用途。

公开(公告)号：US20140182851A1

公开(公告)日：2014-07-03

申请号：US14201323

申请日：2014-03-07

Applicant: BASF SE ,  Board of Regents, The University of Texas System

Inventor： Upali P. Weerasooriya ,  Gary A. Pope ,  Christian Bittner ,  Gunter Oetter ,  Jack F. Tinsley ,  Christian Spindler ,  Gabriela Alvarez Jurgenson ,  Sophie Vogel

IPC: C09K8/584 ,  E21B43/16

CPC classification number: C09K8/584 ,  C07C305/10 ,  C07C309/10 ,  C08G65/2609 ,  C08G65/3344 ,  E21B43/16

Abstract: Compositions and methods of synthesis of anionic surfactants by alkoxylation of a Guerbet alcohol (GA) having 12 to 36 carbon atoms using butylene oxide, and optionally propylene oxide and/or ethylene oxide followed by the incorporation of a terminal anionic group are described herein. The GA of the present invention is made by a facile and inexpensive method that involves high temperature base catalyzed dimerization of alcohols with 6 to 18 carbon atoms. The large hydrophobe ether surfactants of the present invention find uses in enhanced oil recovery (EOR) applications where it is used for solubilization and mobilization of oil and for environmental cleanup. Further, the hydrophobe alkoxylated GA without anionic terminal group can be used as an ultra-high molecular weight non-ionic surfactant.

Abstract translation: 本文描述了通过使用环氧丁烷和任选的环氧丙烷和/或环氧乙烷烷氧基化具有12至36个碳原子的格伯特醇（GA），然后引入末端阴离子基团来合成阴离子表面活性剂的组合物和方法。 本发明的GA通过易于且廉价的方法制备，其涉及具有6至18个碳原子的醇的高温碱催化二聚。 本发明的大型疏水醚表面活性剂用于增强采油（EOR）应用中，其用于溶解和动员油并用于环境清洁。 此外，不含阴离子末端基团的疏水基烷氧基化GA可用作超高分子量非离子表面活性剂。

公开(公告)号：US20140116690A1

公开(公告)日：2014-05-01

申请号：US14063013

申请日：2013-10-25

Applicant: BASF SE

Inventor： Christian Bittner ,  Günter Oetter ,  Jack Tinsley ,  Christian Spindler ,  Gabriela Alvarez-Juergenson ,  Sophie Maitro-Vogel

IPC: E21B43/16 ,  C09K8/584

CPC classification number: C09K8/584

Abstract: The present invention relates to a surfactant mixture comprising at least one secondary alkanesulfonate having 14 to 17 carbon atoms of the general formula (I) and at least one anionic surfactant of the general formula (II) where R1, R2, R3, R4, A0, k, X, o, Y, a, b, M are each as defined in the description and the claims. The invention further relates to the use and production thereof, and to aqueous surfactant formulations comprising the surfactant mixture, and to processes for producing mineral oil by means of Winsor type III microemulsion flooding, in which the aqueous surfactant formulation is injected through injection wells into a mineral oil deposit and crude oil is withdrawn through production wells from the deposit.

Abstract translation: 本发明涉及包含至少一种具有通式（I）的14至17个碳原子的仲烷基磺酸盐和至少一种通式（II）的阴离子表面活性剂的表面活性剂混合物，其中R1，R2，R3，R4，A0 ，k，X，o，Y，a，b，M各自如说明书和权利要求书中所定义。 本发明进一步涉及其使用和生产以及包含表面活性剂混合物的水性表面活性剂制剂，以及通过Winsor III型微乳液淹水制备矿物油的方法，其中水性表面活性剂制剂通过注入井注入到 矿床和原油通过生产井从矿床中撤出。

公开(公告)号：US20130102505A1

公开(公告)日：2013-04-25

申请号：US13659285

申请日：2012-10-24

Applicant: Basf SE

Inventor： Christian Bittner ,  Günter Oetter ,  Jack Tinsley ,  Christian Spindler ,  Gabriela Alvarez-Juergenson ,  Sophie Maitro-Vogel

IPC: C09K8/584

CPC classification number: C09K8/584

Abstract: The present invention relates to a surfactant mixture comprising at least three ionic surfactants which differ in terms of the hydrocarbyl moiety (R1)(R2)—CH—CH2— and are of the general formula (I) where R1, R2, A0, k, X, o, Y, a, b, M are each as defined in the description and the claims. The invention further relates to the use and preparation thereof, and to aqueous surfactant formulations comprising the mixtures, and to processes for producing mineral oil by means of Winsor type III microemulsion flooding, in which the aqueous surfactant formulation is injected into a mineral oil deposit through injection wells and crude oil is withdrawn from the deposit through production wells.

Abstract translation: 本发明涉及包含至少三种离子表面活性剂的表面活性剂混合物，它们在烃基部分（R 1）（R 2）-CH-CH 2 - 和通式（I）方面不同，其中R1，R2，A0，k ，X，o，Y，a，b，M各自如说明书和权利要求书中所定义。 本发明进一步涉及其使用和制备以及包含该混合物的含水表面活性剂制剂，以及通过Winsor III型微乳液淹水制备矿物油的方法，其中将表面活性剂水溶液注入矿物油沉积物中 注入井和原油通过生产井从沉积物中取出。

公开(公告)号：US11673854B2

公开(公告)日：2023-06-13

申请号：US16624964

申请日：2018-06-26

Applicant: BASF SE

Inventor： Bjoern Ludolph ,  Sophia Ebert ,  Christian Bittner

IPC: C07C229/08 ,  A61K8/44 ,  A61Q5/02 ,  A61Q19/10 ,  C07C227/18 ,  C11D3/33 ,  A61K8/41 ,  C08G59/52

CPC classification number: C07C229/08 ,  A61K8/41 ,  A61K8/44 ,  A61Q5/02 ,  A61Q19/10 ,  C07C227/18 ,  C08G59/52 ,  C11D3/33

Abstract: The present invention relates to alkoxylated esteramines of Formula (I) and salts thereof. Esteramines according to the present invention may be used in cleaning composition, for example in liquid laundry detergents. They lead to improved cleaning performance of said compositions, for example when used in cold water washing conditions. They surprisingly boost grease cleaning performance of liquid laundry detergents, especially under cold water washing conditions. Whiteness is also improved. The esteramine according to the present invention show improved compatibility in liquid laundry detergent formulations.

公开(公告)号：US11649396B2

公开(公告)日：2023-05-16

申请号：US16972823

申请日：2019-06-03

Applicant: BASF SE

Inventor： Bjoern Langlotz ,  Christian Bittner ,  Stefan Stein

IPC: C09K8/588 ,  C08F220/56 ,  C08K5/42 ,  E21B43/16 ,  C09K8/035

CPC classification number: C09K8/588 ,  C08F220/56 ,  C08K5/42 ,  C09K8/035 ,  C08F220/56 ,  C08F220/06 ,  C08F220/34

Abstract: The present invention relates to a process for the preparation of a water-soluble copolymer comprising the step of reacting a monomer (a) of formula (I), wherein Q1, Q2, R1 to R7 and X have the meaning as indicated in the description and claims with at least one monoethylenically unsaturated, anionic monomer (b), preferably representing a monoethylenically unsaturated monomer comprising at least one carboxy, phosphonate or sulfonate group and salts thereof, preferably their ammonium salts or alkaline-earth metal salts or alkali metal salts; and at least one monoethylenically unsaturated, non-ionic monomer (c). The present invention further relates to a copolymer obtainable by said process and its use in enhanced oil recovery (EOR), a formulation comprising said copolymer and a method of oil production uses said formulation.

公开(公告)号：US10538724B2

公开(公告)日：2020-01-21

申请号：US15743848

申请日：2016-07-01

Applicant: BASF SE

Inventor： Christian Bittner ,  Guenter Oetter ,  Andrei Honciuc ,  Andreas Klipp ,  Simon Braun

IPC: C11D11/00 ,  C11D1/12 ,  G03F7/42 ,  G03F7/40

Abstract: The present invention relates to the use of a composition comprising one or more ammonium salt(s) of one or more compounds selected from the group consisting of sulfobutanedioic acid diester(s), (sulfomethyl)-butanedioic acid diester(s), methyl-sulfobutanedioic acid diester(s), sulfoglutaric acid diester(s), and sulfotricarballic acid triester(s), for cleaning or rinsing a product comprising a substrate and supported thereon a patterned material layer having line-space structures with a line width of 50 nm and below. The invention also relates to a corresponding method of making a cleaned or rinsed product comprising a substrate and supported thereon a patterned material layer having line-space structures with a line width of 50 nm or below. The invention also relates to a solution with color of HAZEN number below 1000 and/or a turbidity in the range of from 0.08 to 10 NTU, wherein the solution comprises water and one or more ammonium salt(s) and optionally one or more organic solvent compounds. The invention also relates to a method of making a corresponding solution.

公开(公告)号：US10385295B2

公开(公告)日：2019-08-20

申请号：US14412737

申请日：2013-07-01

Applicant: BASF SE

Inventor： Andreas Klipp ,  Andrei Honciuc ,  Guenter Oetter ,  Christian Bittner

IPC: C11D1/62 ,  C11D11/00 ,  C11D1/40 ,  C11D1/00 ,  G03F7/20 ,  G03F7/32 ,  G03F7/40

Abstract: A method of reducing defects of a semiconductor substrate whereby the substrate is rinsed with an aqueous composition containing a gemini additive of the general formula I after the development of a photoresist or a photolithographic mask wherein X is a divalent group, R1, R2, R3 and R4 are substituted or unsubstituted monovalent groups, n is an integer from 1 to 5, or 1 to 10000 depending on R3 and R4, z is an integer, which is chosen so that the overall surfactant is electrically uncharged, and Z is a counter-ion.

公开(公告)号：US20190203103A1

公开(公告)日：2019-07-04

申请号：US16296904

申请日：2019-03-08

Applicant: BASF SE

Inventor： Christian Bittner ,  Günter Oetter ,  Sebastian Weiße ,  Hans-Christian Raths ,  Jack Tinsley ,  Marcel Kienle

IPC: C09K8/584 ,  E21B43/20 ,  C09K8/86 ,  C09K8/60 ,  B01F17/00

CPC classification number: C09K8/584 ,  B01F17/0085 ,  C09K8/524 ,  C09K8/602 ,  C09K8/86 ,  C09K2208/28 ,  E21B43/20

Abstract: The present invention relates to a method for producing mineral oil from underground mineral oil deposits, in which an aqueous formulation comprising at least a mixture of alkyl ether carboxylate and corresponding alkyl ether alcohol, where the alkyl ether carboxylate has been prepared from the alkyl ether alcohol and the molar ratio in the mixture of alkyl ether carboxylate:alkyl ether alcohol is from 51:49 to 92:8, is injected through at least one injection well into a mineral oil deposit, where the deposit has a deposit temperature of 55° C. to 150° C., a crude oil having more than 20° API and a deposit water having more than 100 ppm of divalent cations, and crude oil is withdrawn through at least one production well from the deposit. The invention further relates to the preparation of the mixture and to a concentrate comprising the mixture.