Continuous production of a PPG-based TPU

    公开(公告)号:US12168712B2

    公开(公告)日:2024-12-17

    申请号:US17309421

    申请日:2019-11-29

    Applicant: BASF SE

    Abstract: A thermoplastic polyurethane having a glass transition temperature of the soft phase of not more than −25° C. measured using DMA and a heating rate of 2K/min at 1 Hz under torsion based on DIN EN ISO 6721: 2016; maximum G″ can be obtained by a process at least including the reaction of a polyol composition including a polypropylene glycol, wherein the proportion of the secondary terminal OH groups based on the total number of terminal OH groups of the polypropylene glycol is in the range of more than 90%, with a polyisocyanate to obtain a polyol composition including a prepolymer and the reaction of the polyol composition including the prepolymer with a polyisocyanate composition including at least one polyisocyanate and at least one chain extender having a molecular weight

    Thermoplastic polyurethane
    24.
    发明授权

    公开(公告)号:US12060450B2

    公开(公告)日:2024-08-13

    申请号:US16478701

    申请日:2018-02-13

    Applicant: BASF SE

    CPC classification number: C08G18/3215 C08G18/4854 C08G18/6674 C08G18/7671

    Abstract: The present invention relates to thermoplastic polyurethanes obtainable or obtained by reaction of at least one polyisocyanate composition which comprises 4,4′-MDI and at least one further polyisocyanate, at least one chain extender of general formula (I) and at least one polyol composition. The present invention further relates to a production process for such thermoplastic polyurethanes and to the use of a thermoplastic polyurethane according to the invention or of a thermoplastic polyurethane obtainable or obtained by a process according to the invention for producing extrusion products, films and molded articles.

    Thermoplastic polyurethane from recycled raw materials

    公开(公告)号:US11999816B2

    公开(公告)日:2024-06-04

    申请号:US16980084

    申请日:2019-03-12

    Applicant: BASF SE

    Abstract: The present invention relates to a process for producing a thermoplastic polyurethane reacting at least one thermoplastic polyurethane (TPU-1) or a polyurethane mixture comprising a thermoplastic polyurethane (TPU-1) with at least one compound (V1) comprising two hydroxyl groups to obtain a mixture (G-a) comprising a thermoplastic polyurethane (TPU-2) and the reaction of the mixture (G-a) with a mixture (G-b) comprising an isocyanate composition (ZI) comprising at least one diisocyanate and optionally and a polyol composition (ZP) comprising at least one polyol (P2) to obtain a thermoplastic polyurethane (TPU target), wherein the proportion of the employed components (ZI) and (ZP) is matched to the hard segment content of the employed thermoplastic polyurethane (TPU-1), (V1) and the hard segment content of the thermoplastic polyurethane (TPU target). The invention further relates to a thermoplastic polyurethane obtained or obtainable by such a process and to the use thereof for producing extruded, injection molded and pressed articles as well as foams, cable sheathings, hoses, profiles, drive belts, fibers, nonwovens, films, moldings, soles, sporting goods, shoes, plugs, housings, damping elements for the electricals industry, automotive industry, mechanical engineering, 3D printing, medicine and consumer goods.

    Nucleating agent for compact thermoplastic polyurethanes

    公开(公告)号:US10927253B2

    公开(公告)日:2021-02-23

    申请号:US16078070

    申请日:2017-02-22

    Applicant: BASF SE

    Abstract: The present invention relates to a process for producing a composition (I) at least comprising a compact thermoplastic polyurethane (P1), comprising the providing of at least one compact thermoplastic polyurethane (P1) or a reaction mixture for production of a compact thermoplastic polyurethane (R-P1), the adding of at least one compound (N) that has a conjugated, nitrogen-containing aromatic structure as nucleating agent to the at least one thermoplastic polyurethane (P1) or to the reaction mixture for production of a compact thermoplastic polyurethane (R-P1), wherein the compound (N) is a solid; and the mixing of the nucleating agent and the thermoplastic polyurethane (P1) or the reaction mixture (R-P1) to obtain a composition (I). The nucleating agent is used here in an amount in the range from 0.01% by weight to 2.0% by weight, based on the thermoplastic polyurethane (P1) or the reaction mixture (R-P1). Further relates the present composition comprising at least one compact thermoplastic polyurethane and at least one compound (N) that has a conjugated, nitrogen-containing aromatic structure as nucleating agent, wherein the compound (N) is a solid, and the use of the compounds mentioned as nucleating agents for a compact thermoplastic polyurethane.

    CROSSLINKED POLYURETHANE
    30.
    发明申请

    公开(公告)号:US20190071535A1

    公开(公告)日:2019-03-07

    申请号:US16086667

    申请日:2017-03-17

    Applicant: BASF SE

    Abstract: A crosslinked polyurethane obtainable by a process is disclosed wherein polyisocyanates are mixed with polymeric compounds having at least two hydrogen atoms reactive toward isocyanate groups and comprising at least one diene block copolymer which has at least two hydrogen atoms reactive toward isocyanate and has a polydiene main chain and at least one side chain or terminal chain composed of a polyether and/or a polyester, where the proportion by weight of the polydiene main chain is, based on the total weight of the diene block copolymer, from 25 to 95% by weight, to give a reaction mixture that is cured. Composites and blends composed of crosslinked polyurethane and rubber are also disclosed, as well as the use of crosslinked polyurethane in the production of tires or parts of tires, cable sheathing, shoe sole, roller or hose.

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