公开(公告)号：US10177313B2

公开(公告)日：2019-01-08

申请号：US15264183

申请日：2016-09-13

Applicant: BASF SE

Inventor： Pascal Hayoz ,  Olivier Aebischer ,  Mathias Duggeli ,  Hans Jurg Kirner ,  Marta Fonrodona Turon

IPC: H01L51/00 ,  C07D487/04 ,  C07D519/00 ,  C08G61/12 ,  H01B1/12 ,  C09B57/00 ,  C09B69/10 ,  H01L51/05 ,  H01L51/42

Abstract: The present invention relates to polymers comprising one or more (repeating) unit(s) of the formula (I) which are characterized in that Ar1 and Ar1′ are independently of each other are an annulated (aromatic) heterocyclic ring system, containing at least one thiophene ring, which may be optionally substituted by one, or more groups, and their use as organic semiconductor in organic devices, especially in organic photovoltaics (solar cells) and photodiodes, or in a device containing a diode and/or an organic field effect transistor. The polymers according to the invention have excellent solubility in organic solvents and excellent film-forming properties. In addition, high efficiency of energy conversion, excellent field-effect mobility, good on/off current ratios and/or excellent stability can be observed, when the polymers according to the invention are used in organic field effect transistors, organic photovoltaics (solar cells) and photodiodes.

公开(公告)号：US09978943B2

公开(公告)日：2018-05-22

申请号：US14361129

申请日：2012-12-03

Applicant: BASF SE

Inventor： Patrice Bujard ,  Natalia Chebotareva ,  Thomas Weitz ,  Pascal Hayoz

IPC: H01L29/08 ,  H01L51/00 ,  C09B57/00 ,  C09B69/10 ,  C08G61/12 ,  C08L65/00 ,  H01L51/05

CPC classification number: H01L51/0003 ,  C08G61/124 ,  C08G61/126 ,  C08G2261/1412 ,  C08G2261/226 ,  C08G2261/228 ,  C08G2261/3223 ,  C08G2261/344 ,  C08G2261/364 ,  C08G2261/411 ,  C08G2261/91 ,  C08G2261/92 ,  C08G2261/95 ,  C08L65/00 ,  C08L2205/02 ,  C09B57/004 ,  C09B69/105 ,  C09B69/109 ,  H01L51/002 ,  H01L51/0035 ,  H01L51/0036 ,  H01L51/0043 ,  H01L51/005 ,  H01L51/0053 ,  H01L51/0068 ,  H01L51/0072 ,  H01L51/0512 ,  H01L51/0545 ,  H01L51/0558

Abstract: The present invention provides an electronic component or device comprising a gate electrode, a source electrode and a drain electrode, wherein said component or device further comprising an organic semiconducting (OSC) material that is provided between the source and drain electrode, wherein the OSC material comprises (a) a polymer represented by formula: (I), and (b) a compound of formula (II). High quality OFETs can be fabricated by the choice of a semiconductor material, which is comprised of a polymer represented by formula I and (b) a compound of formula II.

公开(公告)号：US09748487B2

公开(公告)日：2017-08-29

申请号：US14435619

申请日：2013-11-05

Applicant: BASF SE

Inventor： Pascal Hayoz ,  Bernd Tieke ,  Haichang Zhang

IPC: C08F30/06 ,  C08F28/06 ,  H01L21/00 ,  C07D487/00 ,  C07D307/77 ,  H01L51/00 ,  C08G61/12 ,  C07D519/00 ,  C07D487/04 ,  C07D493/04 ,  C08F226/10 ,  C08F232/00 ,  C08F234/02 ,  C08F234/04 ,  H01L51/05 ,  H01L51/42

CPC classification number: H01L51/0035 ,  C07D487/04 ,  C07D493/04 ,  C07D519/00 ,  C08F226/10 ,  C08F232/00 ,  C08F234/02 ,  C08F234/04 ,  C08G61/124 ,  C08G61/125 ,  C08G61/126 ,  C08G2261/1412 ,  C08G2261/312 ,  C08G2261/314 ,  C08G2261/3222 ,  C08G2261/3223 ,  C08G2261/3241 ,  C08G2261/3327 ,  C08G2261/344 ,  C08G2261/364 ,  C08G2261/411 ,  C08G2261/51 ,  C08G2261/59 ,  C08G2261/91 ,  C08G2261/92 ,  H01L51/0007 ,  H01L51/0036 ,  H01L51/0043 ,  H01L51/0558 ,  H01L51/42 ,  Y02E10/549

Abstract: The present invention relates to polymers comprising one or more (repeating) unit(s) of the formula (I), and compounds of formula (III), wherein Y, Y15, Y16 and Y17 are independently of each other a group of formula and their use as IR absorber, organic semiconductor in organic devices, especially in organic photovoltaics and photodiodes, or in a device containing a diode and/or an organic field effect transistor. The polymers and compounds according to the invention can have excellent solubility in organic solvents and excellent film-forming properties. In addition, high efficiency of energy conversion, excellent field-effect mobility, good on/off current ratios and/or excellent stability can be observed, when the polymers and compounds according to the invention are used in organic field effect transistors, organic photovoltaics and photodiodes.

公开(公告)号：US10669371B2

公开(公告)日：2020-06-02

申请号：US15543637

申请日：2016-01-15

Applicant: BASF SE

Inventor： Pascal Hayoz ,  Daniel Kaelblein ,  Iain McCulloch ,  Wan Yue

IPC: C08G61/12 ,  C09K11/06 ,  H01B1/12 ,  H01L51/00 ,  H01L51/05

Abstract: Polymers comprising at least one unit of formula (1) and their use as semiconducting materials.

公开(公告)号：US20190027690A9

公开(公告)日：2019-01-24

申请号：US15364893

申请日：2016-11-30

Applicant: BASF SE

Inventor： Mathias Duggeli ,  Mahmoud Zaher Eteish ,  Pascal Hayoz ,  Olivier Frederic Aebischer ,  Marta Fonrodona Turon ,  Margherita Fontana ,  Marian Lanz ,  Mathieu G.R. Turbiez ,  Beat Schmidhalter ,  Jean-Charles Flores

IPC: H01L51/00 ,  C08G61/12

Abstract: The present invention relates to polymers comprising a repeating unit of the formula I, or III and their use as organic semiconductor in organic devices, especially an organic field effect transistor (OFET), or a device containing a diode and/or an organic field effect transistor. The polymers according to the invention have excellent solubility in organic solvents and excellent film-forming properties. In addition, high efficiency of energy conversion, excellent field-effect mobility, good on/off current ratios and/or excellent stability can be observed, when the polymers according to the invention are used in organic field effect transistors.

公开(公告)号：US20180331296A1

公开(公告)日：2018-11-15

申请号：US16043966

申请日：2018-07-24

Applicant: BASF SE

Inventor： Mathias Duggeli ,  Mahmoud Zaher Eteish ,  Pascal Hayoz ,  Olivier Aebischer ,  Marta Fonrodona Turon ,  Margherita Fontana ,  Marian Lanz ,  Mathieu G. R. Turbiez ,  Beat Schmidhalter ,  Jean-Charles Flores

IPC: H01L51/00 ,  C08G61/12 ,  H01L27/28 ,  H01L51/05

Abstract: The present invention relates to polymers comprising a repeating unit of the formula I, or III and their use as organic semiconductor in organic devices, especially an organic field effect transistor (OFET), or a device containing a diode and/or an organic field effect transistor. The polymers according to the invention have excellent solubility in organic solvents and excellent film-forming properties. In addition, high efficiency of energy conversion, excellent field-effect mobility, good on/off current ratios and/or excellent stability can be observed, when the polymers according to the invention are used in organic field effect transistors.

公开(公告)号：US09478745B2

公开(公告)日：2016-10-25

申请号：US14308766

申请日：2014-06-19

Applicant: BASF SE

Inventor： Pascal Hayoz ,  Olivier Frédéric Aebischer ,  Mathias Düggeli ,  Hans Jürg Kirner ,  Marta Fonrodona Turon

IPC: H01L51/00 ,  C07D487/04 ,  C07D519/00 ,  C08G61/12 ,  H01B1/12 ,  C09B57/00 ,  C09B69/10

CPC classification number: H01L51/0036 ,  C07D487/04 ,  C07D519/00 ,  C08G61/124 ,  C08G61/126 ,  C08G2261/124 ,  C08G2261/1412 ,  C08G2261/18 ,  C08G2261/228 ,  C08G2261/3223 ,  C08G2261/3241 ,  C08G2261/3243 ,  C08G2261/334 ,  C08G2261/598 ,  C08G2261/91 ,  C08G2261/92 ,  C08G2261/94 ,  C08G2261/95 ,  C09B57/004 ,  C09B69/109 ,  H01B1/127 ,  H01L51/0003 ,  H01L51/0035 ,  H01L51/0043 ,  H01L51/0053 ,  H01L51/0558 ,  H01L51/42 ,  Y02E10/549

Abstract: The present invention relates to polymers comprising one or more (repeating) unit(s) of the formula (I) which are characterized in that Ar1 and Ar1′ are independently of each other are an annulated (aromatic) heterocyclic ring system, containing at least one thiophene ring, which may be optionally substituted by one, or more groups, and their use as organic semiconductor in organic devices, especially in organic photovoltaics (solar cells) and photodiodes, or in a device containing a diode and/or an organic field effect transistor. The polymers according to the invention have excellent solubility in organic solvents and excellent film-forming properties. In addition, high efficiency of energy conversion, excellent field-effect mobility, good on/off current ratios and/or excellent stability can be observed, when the polymers according to the invention are used in organic field effect transistors, organic photovoltaics (solar cells) and photodiodes.

Abstract translation: 本发明涉及包含一种或多种式（I）的（重复）单元的聚合物，其特征在于Ar1和Ar1'彼此独立地为环状（芳族）杂环体系，至少含有 一个噻吩环，其可以任选地被一个或多个基团取代，并且它们在有机器件中的用途，特别是有机光伏（太阳能电池）和光电二极管中的有机半导体，或者在含有二极管和/或有机场的器件中 效应晶体管。 根据本发明的聚合物在有机溶剂中具有优异的溶解性和优异的成膜性能。 此外，当根据本发明的聚合物用于有机场效应晶体管，有机光伏（太阳能电池）中时，可以观察到高效率的能量转换，优异的场效应迁移率，良好的开/关电流比和/或优异的稳定性 ）和光电二极管。

公开(公告)号：US09276215B2

公开(公告)日：2016-03-01

申请号：US14362500

申请日：2012-12-03

Applicant: BASF SE

Inventor： Pascal Hayoz ,  Patrice Bujard

IPC: C08G75/00 ,  H01L51/00 ,  C09B57/00 ,  C09B69/10 ,  H01L51/05

CPC classification number: H01L51/0043 ,  C08G61/124 ,  C08G61/126 ,  C08G2261/1412 ,  C08G2261/226 ,  C08G2261/228 ,  C08G2261/3223 ,  C08G2261/344 ,  C08G2261/364 ,  C08G2261/411 ,  C08G2261/91 ,  C08G2261/92 ,  C08G2261/95 ,  C08L65/00 ,  C08L2205/02 ,  C09B57/004 ,  C09B69/105 ,  C09B69/109 ,  H01L51/0003 ,  H01L51/002 ,  H01L51/0035 ,  H01L51/0036 ,  H01L51/005 ,  H01L51/0053 ,  H01L51/0068 ,  H01L51/0541 ,  H01L51/0545 ,  H01L51/0558 ,  Y02E10/549

Abstract: The present invention relates to polymers (I), or (II), and their use as organic semiconductor in organic devices, especially in organic photovoltaics (solar cells) and photodiodes, or in a device containing a diode and/or an organic field effect transistor. The polymers according to the invention have excellent solubility in organic solvents and excellent film-forming properties. In addition, high efficiency of energy conversion, excellent field-effect mobility, good on/off current ratios and/or excellent stability can be observed, when the polymers according to the invention are used in organic field effect transistors, organic photovoltaics (solar cells) and photodiodes.

Abstract translation: 本发明涉及聚合物（I）或（II），以及它们在有机器件中的有机半导体的用途，特别是在有机光伏（太阳能电池）和光电二极管中，或在含有二极管和/或有机场效应的器件中 晶体管。 根据本发明的聚合物在有机溶剂中具有优异的溶解性和优异的成膜性能。 此外，当根据本发明的聚合物用于有机场效应晶体管，有机光伏（太阳能电池）中时，可以观察到高效率的能量转换，优异的场效应迁移率，良好的开/关电流比和/或优异的稳定性 ）和光电二极管。

公开(公告)号：US09240551B2

公开(公告)日：2016-01-19

申请号：US14349773

申请日：2012-10-03

Applicant: BASF SE

Inventor： Pascal Hayoz ,  Mathias Dueggeli

IPC: H01L35/24 ,  H01L51/00 ,  C08G61/12 ,  H01L51/05 ,  C09B57/00 ,  C09B69/10 ,  C09B69/00 ,  H01L51/42

CPC classification number: H01L51/0003 ,  C08G61/124 ,  C08G61/126 ,  C08G2261/124 ,  C08G2261/1412 ,  C08G2261/226 ,  C08G2261/228 ,  C08G2261/3222 ,  C08G2261/3223 ,  C08G2261/3243 ,  C08G2261/344 ,  C08G2261/411 ,  C08G2261/91 ,  C08G2261/92 ,  C09B57/00 ,  C09B69/008 ,  C09B69/102 ,  C09B69/109 ,  H01L51/0036 ,  H01L51/0037 ,  H01L51/0043 ,  H01L51/0558 ,  H01L51/42 ,  Y02E10/549 ,  Y02P70/521

Abstract: The present invention relates to polymers comprising one or more (repeating) unit(s) of the formula (I), and compounds of formula (III), wherein Y, Y15, Y16 and Y17 are independently of each other a group of formula (A), (B) or (C) and their use as IR absorber, organic semiconductor in organic devices, especially in organic photovoltaics and photodiodes, or in a device containing a diode and/or an organic field effect transistor. The polymers and compounds according to the invention can have excellent solubility in organic solvents and excellent film-forming properties. In addition, high efficiency of energy conversion, excellent field-effect mobility, good on/off current ratios and/or excellent stability can be observed, when the polymers and compounds according to the invention are used in organic field effect transistors, organic photovoltaics and photodiodes.

Abstract translation: 本发明涉及包含式（I）的一种或多种（重复）单元和式（III）的化合物的聚合物，其中Y，Y15，Y16和Y17彼此独立地是式 A），（B）或（C）以及它们在有机器件中的有机半导体，特别是有机光伏和光电二极管中的有机半导体，或者含有二极管和/或有机场效应晶体管的器件中的有机半导体。 根据本发明的聚合物和化合物可以在有机溶剂中具有优异的溶解性和优异的成膜性能。 另外，当根据本发明的聚合物和化合物用于有机场效应晶体管，有机光伏和有机光电池中时，可以观察到能量转换的高效率，优异的场效应迁移率，良好的开/关电流比和/或优异的稳定性 光电二极管

公开(公告)号：US20150087109A1

公开(公告)日：2015-03-26

申请号：US14555367

申请日：2014-11-26

Applicant: BASF SE

Inventor： Pascal Hayoz ,  Mathias Düggeli ,  Natalia Chebotareva ,  Olivier Frédéric Aebischer

IPC: C08G61/12 ,  H01L51/00

CPC classification number: C08G61/125 ,  B82Y10/00 ,  C08F232/08 ,  C08F234/04 ,  C08G61/124 ,  C08G61/126 ,  C08G2261/12 ,  C08G2261/141 ,  C08G2261/18 ,  C08G2261/3221 ,  C08G2261/3222 ,  C08G2261/3223 ,  C08G2261/3241 ,  C08G2261/344 ,  C08G2261/364 ,  C08G2261/411 ,  C08G2261/5222 ,  C08G2261/91 ,  C08G2261/92 ,  C09B69/109 ,  C09K11/06 ,  C09K2211/1475 ,  C09K2211/1483 ,  C09K2211/1491 ,  H01L51/0003 ,  H01L51/0035 ,  H01L51/0036 ,  H01L51/0043 ,  H01L51/0047 ,  H01L51/0055 ,  H01L51/0056 ,  H01L51/0094 ,  H01L51/0512 ,  H01L51/0525 ,  H01L51/0545 ,  H01L51/424 ,  H01L51/4253 ,  H05B33/14 ,  Y02E10/549

Abstract: The present invention relates to polymers comprising one or more (repeating) unit(s) of the formula *A-D* (I), or a polymer of formula *A-DxB-Dy* (II), or *A-DrB-DsA-EtB-Eu (III), and their use as organic semiconductor in organic devices, especially in organic photovoltaics (solar cells) and photodiodes, or in a device containing a diode and/or an organic field effect transistor. The polymers according to the invention have excellent solubility in organic solvents and excellent film-forming properties. In addition, high efficiency of energy conversion, excellent field-effect mobility, good on/off current ratios and/or excellent stability can be observed, when the polymers according to the invention are used in organic field effect transistors, organic photovoltaics (solar cells) and photodiodes.

Abstract translation: 本发明涉及包含一种或多种式（Ⅸ）的（重复）单元的聚合物，或式（Ⅸ）所示的聚合物，或* 它们用作有机器件中的有机半导体，特别是在有机光伏（太阳能电池）和光电二极管中的有机半导体，或者在含有二极管和/ 或有机场效应晶体管。 根据本发明的聚合物在有机溶剂中具有优异的溶解性和优异的成膜性能。 此外，当根据本发明的聚合物用于有机场效应晶体管，有机光伏（太阳能电池）中时，可以观察到高效率的能量转换，优异的场效应迁移率，良好的开/关电流比和/或优异的稳定性 ）和光电二极管。