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公开(公告)号：US5571881A
公开(公告)日：1996-11-05
申请号：US476810
申请日：1995-06-07
申请人： Brian L. Goodall , George M. Benedikt , Lester H. McIntosh, III , Dennis A. Barnes , Larry F. Rhodes
发明人： Brian L. Goodall , George M. Benedikt , Lester H. McIntosh, III , Dennis A. Barnes , Larry F. Rhodes
IPC分类号： C08F4/70 , C08F4/30 , C08F4/42 , C08F4/80 , C08F32/00 , C08F32/08 , C08F36/04 , C08F36/20 , C08F210/14 , C08F232/08 , C08F236/20 , C08F4/76 , C08F4/78
CPC分类号： C08F232/08 , C08F32/08
摘要： Addition polymers derived from norbornene-functional monomers are terminated with an olefinic moiety derived from a chain transfer agent selected from a compound having a terminal olefinic double bond between adjacent carbon atoms, excluding styrenes, vinyl ethers, and conjugated dienes and at least one of said carbon atoms has two hydrogen atoms attached thereto. The addition polymers of this invention are prepared from a single or multicomponent catalyst system including a Group VIII metal ion source. The catalyst systems are unique in that they catalyze the insertion of the chain transfer agent exclusively at a terminal end of the polymer chain.
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22.发明授权Addition polymers derived from norbornene-functional monomers and process therefor 失效衍生自降冰片烯官能单体的加成聚合物及其工艺
公开(公告)号：US5569730A
公开(公告)日：1996-10-29
申请号：US339863
申请日：1994-11-15
申请人： Brian L. Goodall , George M. Benedikt , Lester H. McIntosh, III , Dennis A. Barnes , Larry F. Rhodes
发明人： Brian L. Goodall , George M. Benedikt , Lester H. McIntosh, III , Dennis A. Barnes , Larry F. Rhodes
IPC分类号： C08F4/70 , C08F4/30 , C08F4/42 , C08F4/80 , C08F32/00 , C08F32/08 , C08F36/04 , C08F36/20 , C08F210/14 , C08F232/08 , C08F236/20 , C08F10/00 , C08F32/02 , C08F34/00
CPC分类号： C08F232/08 , C08F32/08
摘要： Addition polymers derived from norbornene-functional monomers are terminated with an olefinic moiety derived from a chain transfer agent selected from a compound having a terminal olefinic double bond between adjacent carbon atoms, excluding styrenes, vinyl ethers, and conjugated dienes and at least one of said carbon atoms has two hydrogen atoms attached thereto. The addition polymers of this invention are prepared from a single or multicomponent catalyst system including a Group VIII metal ion source. The catalyst systems are unique in that they catalyze the insertion of the chain transfer agent exclusively at a terminal end of the polymer chain.
摘要翻译： 衍生自降冰片烯官能单体的加成聚合物由衍生自链转移剂的烯烃部分封端，所述链转移剂选自相邻碳原子之间具有末端烯属双键的化合物，不包括苯乙烯，乙烯基醚和共轭二烯，并且所述 碳原子上连有两个氢原子。 本发明的加成聚合物由包含VIII族金属离子源的单组分或多组分催化剂体系制备。 催化剂体系是独特的，因为它们催化仅在聚合物链的末端插入链转移剂。
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23.发明授权
公开(公告)号：US4478989A
公开(公告)日：1984-10-23
申请号：US545574
申请日：1983-10-26
CPC分类号： C08F110/00
摘要： A process for the stereospecific polymerization of an alpha olefin with at least three carbon atoms, with a catalyst system comprising (a) a titanium halide, and (b,i) a reaction product of an organoaluminum halide and an aromatic compound or (b,ii) a reaction product of an organoaluminum halide, an aromatic compound and a halogen-free organoaluminum compound, the aromatic compound being a hydroxy aromatic compound which comprises a sec. or tert. alkyl group in both ortho-positions in respect of the hydroxyl group.
摘要翻译： 具有至少三个碳原子的α-烯烃的立体有择聚合的方法，其催化剂体系包含（a）卤化钛和（b，i）有机铝卤化物和芳族化合物的反应产物或（b， ii）有机铝卤化物，芳族化合物和无卤素的有机铝化合物的反应产物，所述芳族化合物是包含第二步的羟基芳族化合物。 或叔。 在羟基的两个邻位的烷基。
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24.发明授权Olefin polymerization process with novel supported titanium catalyst compositions 失效烯烃聚合工艺与新型载体钛催化剂组合物
公开(公告)号：US4393182A
公开(公告)日：1983-07-12
申请号：US318649
申请日：1981-11-05
CPC分类号： C08F10/00
摘要： An olefin polymerization process comprises contacting the monomer to be polymerized with a catalyst composition comprising: an organoaluminum compound, a first electron donor, and a product obtained by contacting a solid component comprising a magnesium halide in which the atomic ratio of chlorine to magnesium is at least 1.2, a titanium halide and a second electron donor, with a halohydrocarbon and thereafter with a tetravalent titanium compound.
摘要翻译： 烯烃聚合方法包括使待聚合的单体与催化剂组合物接触，所述催化剂组合物包含：有机铝化合物，第一电子给体和通过使包含氯与镁的原子比在其中的卤化镁的固体组分 至少1.2，卤化钛和第二电子给体，与卤代烃，然后用四价钛化合物。
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公开(公告)号：US4252987A
公开(公告)日：1981-02-24
申请号：US123871
申请日：1980-02-22
IPC分类号： C07C2/30 , B01J31/00 , B01J31/22 , C07B61/00 , C07C1/00 , C07C2/34 , C07C11/02 , C07C11/113 , C07C67/00 , C07C2/24
CPC分类号： B01J31/0237 , B01J31/143 , B01J31/2295 , C07C2/34 , B01J2231/323 , B01J2531/46 , C07C2531/02 , C07C2531/14 , C07C2531/22
摘要： Dimerization of alpha,beta-unsubstituted 1-alkenes, having at least three carbon atoms, in the presence of a catalyst comprising(a) a titanium-containing component of the formulaCp.sub.2 TiXY,wherein Cp represents an optionally alkyl-substituted cyclopentadienyl group, X represents a halogen atom or an alkyl group, and Y represents a halogen atom,(b) an alkylaluminum halide, and(c) a nitrogen Lewis base,is characterized by high reaction selectivity to certain dimer products and little formation of higher polymers.
摘要翻译： 在包含（a）式Cp2TiXY的含钛组分的催化剂存在下，具有至少三个碳原子的α，β-未取代的1-烯烃的二聚，其中Cp表示任选烷基取代的环戊二烯基，X 表示卤素原子或烷基，Y表示卤素原子，（b）烷基卤化铝和（c）氮路易斯碱，其特征在于对某些二聚物产物的高反应选择性和较高聚合物的形成很少。
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26.发明授权公开(公告)号：US07041758B2
公开(公告)日：2006-05-09
申请号：US11053811
申请日：2005-02-09
IPC分类号： C08F4/80
CPC分类号： C08F32/04 , C08F4/70 , C08F120/14 , C08F232/04 , C08F220/14
摘要： A process for polymerizing and copolymerizing cyclic olefins, such as, norbornene is disclosed. The disclosed process uses a catalyst complex that exhibit a high activity for the polymerization and co-polymerization of cyclic olefins and improved stability toward heat, oxygen and moisture.
摘要翻译： 公开了降冰片烯等环状烯烃的聚合和共聚方法。 所公开的方法使用对环烯烃的聚合和共聚具有高活性并提高对热，氧和水分的稳定性的催化剂络合物。
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公开(公告)号：US07037987B2
公开(公告)日：2006-05-02
申请号：US11054631
申请日：2005-02-09
CPC分类号： C08F10/02 , B01J31/1805 , B01J31/2208 , B01J31/226 , B01J31/2265 , B01J2231/12 , B01J2531/0238 , B01J2531/46 , B01J2531/48 , B01J2531/847 , C07F7/00 , C07F7/28 , C07F15/04 , C08F4/65912 , C08F10/00 , C08F110/02 , C08F4/659 , C08F4/64041 , C08F4/7019
摘要： A polymerization catalyst for the polymerization and copolymerization of olefin monomers and the copolymerization of olefin monomers with other monomers selected from, for example, norbornenes and styrenes are disclosed. The polymerization catalysts disclosed contain a metal center selected from Ti, Zr, Hf, Ni and Pd with at least one chelating ligand.
摘要翻译： 公开了用于烯烃单体的聚合和共聚的聚合催化剂和烯烃单体与选自例如降冰片烯和苯乙烯的其它单体的共聚。 所公开的聚合催化剂含有选自Ti，Zr，Hf，Ni和Pd中的至少一种螯合配体的金属中心。
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公开(公告)号：US06825307B2
公开(公告)日：2004-11-30
申请号：US10196525
申请日：2002-07-16
申请人： Brian L. Goodall
发明人： Brian L. Goodall
IPC分类号： C08F3208
CPC分类号： C08F32/08 , C08F32/00 , Y02P20/582
摘要： Methods for the addition polymerization of cycloolefins using a cationic Group 10 metal complex and a weakly coordinating anion of the formula: [(R′)zM(L′)x(L″)y]b[WCA]d wherein [(R′)zM(L′)x(L″)y] is a cation complex where M represents a Group 10 transition metal; R′ represents an anionic hydrocarbyl containing ligand; L′ represents a Group 15 neutral electron donor ligand; L″ represents a labile neutral electron donor ligand; x is 1 or 2; and y is 0, 1, 2, or 3; and z is 0 or 1, wherein the sum of x, y, and z is 4; and [WCA] represents a weakly coordinating counteranion complex; and b and d are numbers representing the number of times the cation complex and weakly coordinating counteranion complex are taken to balance the electronic charge on the overall catalyst complex.
摘要翻译： 使用阳离子10族金属络合物和下式的弱配位阴离子进行环烯加成聚合的方法：其中[（R'）z M（L'）x（L“）y]是阳离子络合物，其中M表示 第10组过渡金属; R'表示含阴离子烃基的配体; L'表示15族中性电子给体配体; L“表示不稳定的中性电子给体配体; x为1或2; y为0,1,2或3; 且z为0或1，其中x，y和z之和为4; 和[WCA]代表弱协调的对抗综合体; b和d是表示阳离子络合物和弱配位抗衡阴离子络合物在总体催化剂络合物上平衡电荷的次数的数字。
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29.发明授权Photoresist compositions comprising polycyclic polymers with acid labile pendant groups 失效包含具有酸不稳定侧基的多环聚合物的光致抗蚀剂组合物公开(公告)号：US06232417B1
公开(公告)日：2001-05-15
申请号：US08928573
申请日：1997-09-12
申请人： Larry F Rhodes , Andrew Bell , Saikumar Jayaraman , John-Henry Lipian , Brian L. Goodall , Robert A. Shick
发明人： Larry F Rhodes , Andrew Bell , Saikumar Jayaraman , John-Henry Lipian , Brian L. Goodall , Robert A. Shick
IPC分类号： C08F480
CPC分类号： G03F7/0045 , C08G61/08 , G03F7/038 , G03F7/039 , Y10S430/109 , Y10S430/111 , Y10S430/115
摘要： The present invention relates to a radiation sensitive photoresist composition comprising a photoacid initiator and a polycyclic polymer comprising repeating units that contain pendant acid labile groups. Upon exposure to an imaging radiation source the photoacid initiator generates an acid which cleaves the pendant acid labile groups effecting a polarity change in the polymer. The polymer is rendered soluble in an aqueous base in the areas exposed to the imaging source. The polymer repeating units are polymerized from polycyclic monomers in the presence of single or multicomponent catalyst systems containing a Group VIII metal
摘要翻译： 本发明涉及包含光酸引发剂和包含含有酸不稳定基团的重复单元的多环聚合物的辐射敏感性光致抗蚀剂组合物。 在暴露于成像辐射源时，光酸引发剂产生酸，该酸切割引起聚合物极性变化的侧链酸不稳定基团。 聚合物在暴露于成像源的区域中变得可溶于碱性水溶液。 聚合物重复单元在含有VIII族金属的单组分或多组分催化剂体系存在下由多环单体聚合
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30.发明授权
公开(公告)号：US4923936A
公开(公告)日：1990-05-08
申请号：US312150
申请日：1989-02-21
申请人： Brian L. Goodall , Larry F. Rhodes
发明人： Brian L. Goodall , Larry F. Rhodes
CPC分类号： C08G61/08 , B01J31/0239 , B01J31/0268 , B01J31/143
摘要： This invention pertains to the use of organoammonium, organophosphonium, organoarsonium heteropolymolybdates and heteropolytungstates, and mixtures thereof, as catalysts in a metathesis catalyst system in polymerization of cycloolefin monomers by ring opening polymerization. Polymerization can be by reaction injection molding in absence of a solvent whereby a thermoset polymer is produced or by solution polymerization in presence of a suitable solvent whereby a thermosetting or a thermoplastic polymer is produced. The cycloolefin monomers are selected from monocycloolefins except cyclohexane, polycycloolefins containing at least one norbornene group, and mixtures thereof.
摘要翻译： 本发明涉及有机铵，有机鏻，有机砷杂多钼酸盐和杂多钨酸盐及其混合物作为复分解催化剂体系中的环烯烃单体通过开环聚合反应的催化剂。 可以通过在不存在溶剂的情况下通过反应注射成型聚合，由此制备热固性聚合物，或者通过在合适的溶剂存在下通过溶液聚合制备热固性或热塑性聚合物。 环烯烃单体选自除环己烷以外的单环烯烃，含有至少一个降冰片烯基团的聚环烯烃及其混合物。
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