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公开(公告)号：US08431285B2
公开(公告)日：2013-04-30
申请号：US11592581
申请日：2006-11-03
IPC分类号： H01M8/10
CPC分类号： H01M8/1044 , H01M8/0289 , H01M8/1053 , H01M8/106 , H01M2300/0082
摘要： Edge designs, especially for ePTFE-reinforced membranes for proton exchange membrane (PEM) fuel cells, wherein the designs provide a proton barrier at the electrode edge of the PEM fuel cell membrane electrode assembly (MEA) to provide, among other things, resistance to membrane chemical degradation. A portion of the ePTFE layer is imbibed with a proton-impermeable polymer at the electrode edge. The polymer can include, without limitation, B-staged epoxides, B-staged phenolics, hot melt thermoplastics, and/or thermosets or thermoplastics cast from liquid dispersions.
摘要翻译： 边缘设计，特别是用于质子交换膜（PEM）燃料电池的ePTFE增强膜，其中这些设计在PEM燃料电池膜电极组件（MEA）的电极边缘处提供质子势垒，以提供抗性 膜化学降解。 ePTFE层的一部分在电极边缘被吸收质子不可渗透的聚合物。 聚合物可以包括但不限于B级环氧化物，B阶酚醛树脂，热熔热塑性塑料和/或从液体分散体铸造的热固性材料或热塑性塑料。
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22.发明授权Fuel processor primary reactor and combustor startup via electrically-heated catalyst 有权燃料处理器主反应器和通过电加热催化剂的燃烧器启动公开(公告)号：US07862631B2
公开(公告)日：2011-01-04
申请号：US10360996
申请日：2003-02-07
CPC分类号： F23C13/02 , B01J19/2485 , B01J23/40 , B01J35/0033 , B01J2208/00716 , B01J2219/00063 , B01J2219/00135 , B01J2219/002 , B01J2219/00213 , B01J2219/00238 , B01J2219/00265 , C01B3/382 , C01B2203/00 , C01B2203/0233 , C01B2203/0244 , C01B2203/0283 , C01B2203/044 , C01B2203/047 , C01B2203/066 , C01B2203/0811 , C01B2203/0844 , C01B2203/085 , C01B2203/0866 , C01B2203/0883 , C01B2203/1023 , C01B2203/107 , C01B2203/1205 , C01B2203/1276 , C01B2203/1288 , C01B2203/142 , C01B2203/1604 , C01B2203/1619 , C01B2203/169 , C01B2203/82 , Y02P20/52
摘要： A primary reactor for a fuel processor system that employs steam and air to convert a liquid hydrocarbon fuel into a hydrogen-rich gas stream. The liquid fuel and an air-steam mixture are mixed in a mixing region within the reactor. The fuel mixture is then directed through an electrically heated catalyst region that heats the mixture to the operation temperature of a light-off catalyst at system start-up. The heated fuel mixture is then directed through a light-off catalyst monolith where the hydrocarbon fuel is dissociated. Once the fuel mixture is heated to the operating temperature of the light-off catalyst, the electrically heated catalyst region is turned off because the exothermic reaction in the light-off catalyst monolith generates the heat necessary to sustain the catalytic reaction.
摘要翻译： 用于燃料处理器系统的主反应器，其使用蒸汽和空气将液体烃燃料转化为富氢气流。 液体燃料和空气 - 蒸汽混合物在反应器内的混合区域中混合。 然后将燃料混合物引导通过电加热的催化剂区域，其在系统启动时将混合物加热至点火催化剂的操作温度。 然后将加热的燃料混合物引导通过烃燃料解离的点火催化剂整料。 一旦燃料混合物被加热到点火催化剂的操作温度，则电加热的催化剂区域被关闭，因为在关闭催化剂整体中的放热反应产生维持催化反应所需的热量。
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23.发明授权Pressurized coolant for stamped plate fuel cell without diffusion media in the inactive feed region 有权加压冷却液用于冲压板燃料电池，无扩散介质在惰性进料区域公开(公告)号：US07687182B2
公开(公告)日：2010-03-30
申请号：US11245969
申请日：2005-10-07
CPC分类号： H01M8/2483 , H01M8/0258 , H01M8/026 , H01M8/0265 , H01M8/0267 , H01M8/04074 , H01M8/241
摘要： Clearance gaps in the inactive feed regions of a fuel cell stack are controlled by non-bonded, non-nested bipolar plates to provide reactant flow uniformity and pressure within fuel cells and fuel cell stacks utilizing nested bipolar plates in the active feed regions and non-nested bipolar plates in the inactive feed regions.
摘要翻译： 燃料电池堆的非活性进料区间隙间隙由非粘结非嵌套双极板控制，以在燃料电池和燃料电池堆中提供反应物流动均匀性和压力，利用活性进料区域中的嵌套双极板， 在非活性进料区域嵌套的双极板。
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24.发明授权Fuel processor module for hydrogen production for a fuel cell engine using pressure swing adsorption 有权用于使用变压吸附的燃料电池发动机的氢气生产的燃料处理器模块公开(公告)号：US07276095B2
公开(公告)日：2007-10-02
申请号：US10389375
申请日：2003-03-14
申请人： Craig S. Gittleman , John B. Ruhl , Yan Zhang , William H. Pettit
发明人： Craig S. Gittleman , John B. Ruhl , Yan Zhang , William H. Pettit
IPC分类号： C10K3/04
CPC分类号： B01D53/0473 , B01D53/06 , B01D2253/102 , B01D2253/104 , B01D2253/108 , B01D2257/102 , B01D2257/304 , B01D2257/406 , B01D2257/502 , B01D2257/504 , B01D2257/7022 , B01D2257/80 , B01D2259/40001 , B01D2259/40005 , B01D2259/40052 , B01D2259/40064 , B01D2259/4566 , C01B3/34 , C01B3/48 , C01B3/56 , C01B2203/00 , C01B2203/0244 , C01B2203/0283 , C01B2203/0405 , C01B2203/0425 , C01B2203/0495 , C01B2203/066 , C01B2203/0811 , C01B2203/0822 , C01B2203/0827 , C01B2203/0844 , C01B2203/0866 , C01B2203/0883 , C01B2203/1211 , C01B2203/1247 , C01B2203/1288 , C01B2203/146 , C01B2203/147 , C01B2203/1604 , Y02C10/08 , Y02P20/128 , Y02P20/152
摘要： A stand-alone fuel processor (10) for producing hydrogen from a hydrocarbon fuel for a fuel cell engine in a vehicle. The fuel processor (10) includes a primary reactor (14) that dissociates hydrogen and other by-products from the hydrocarbon fuel as a reformate gas. The reformate gas is applied to a WGS reactor (48) to convert carbon monoxide and water to hydrogen and carbon dioxide. The WGS reactor (14) may include an adsorbent for adsorbing carbon monoxide. The reformate gas from the WGS reactor (48) is then sent to a rapid-cycle PSA device (12) for adsorbing the undesirable by-products in the gas and generates a stream of pure hydrogen. A liquid water separator (70) separates water from the reformate gas before it is applied to the PSA device (12). The PSA device (12) uses a portion of the separated hydrogen as a desorbing gas to purify the adsorbent in the PSA device (12). The by-products of the reformate gas can be used as a fuel in a combustor (30) that generates heat for the primary reactor (14).
摘要翻译： 一种用于从车辆中的燃料电池发动机的烃燃料产生氢的独立燃料处理器（10）。 燃料处理器（10）包括将氢气和其它副产物从作为重整气体的烃燃料中解离的初级反应器（14）。 将重整气体施加到WGS反应器（48）以将一氧化碳和水转化为氢气和二氧化碳。 WGS反应器（14）可以包括用于吸附一氧化碳的吸附剂。 然后将来自WGS反应器（48）的重整气体送至快速循环PSA装置（12），以吸附气体中不希望的副产物并产生纯氢气流。 液体水分离器（70）在将其施加到PSA装置（12）之前将水与重整气体分离。 PSA装置（12）使用一部分分离的氢气作为解吸气体来净化PSA装置（12）中的吸附剂。 重整气体的副产物可以用作为主反应器（14）产生热量的燃烧器（30）中的燃料。
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25.发明授权Compact partial oxidation/steam reactor with integrated air preheater, fuel and water vaporizer 有权紧凑型部分氧化/蒸汽反应堆，集成空气预热器，燃料和水蒸发器公开(公告)号：US06936238B2
公开(公告)日：2005-08-30
申请号：US10236828
申请日：2002-09-06
CPC分类号： C01B3/48 , B01B1/005 , B01J8/0411 , B01J2208/00309 , C01B3/382 , C01B3/384 , C01B2203/0233 , C01B2203/0244 , C01B2203/0255 , C01B2203/0261 , C01B2203/0283 , C01B2203/044 , C01B2203/047 , C01B2203/066 , C01B2203/0844 , C01B2203/1276 , C01B2203/142 , C01B2203/1604 , C01B2203/80 , C01B2203/82 , H01M8/0612 , H01M8/0662 , Y02P20/129
摘要： A compact autothermal (partial oxidation and steam reforming) fuel reactor is provided for implementation with a fuel cell system. The reactor includes a premixing chamber for premixing a volume of air, steam and fuel into an effluent, a thermal POX reactor, a first stage reforming segment, a post-premix chamber, and a second stage reforming segment. Further provided are a water/fuel vaporizer for supplying steam and fuel as a gas to the premix chamber and an airflow cavity disposed about the reactor for pre-heating air supplied to the premix chamber. The thermal POX segment operates during an initial start-up period for pre-heating the other components of the reactor. Once the other components achieve an operation temperature, the first and second stage reforming segments catalytically reform the effluent. The premix and post-premix chambers enable variance in the O/C and S/C ratios to be achieved as the effluent is reformed through the multiple stages.
摘要翻译： 提供紧凑型自热（部分氧化和蒸汽重整）燃料反应器用于实施燃料电池系统。 反应器包括预混合室，用于将体积的空气，蒸汽和燃料预先混合到流出物中，热POX反应器，第一级重整段，后预混合室和第二级重整段。 还提供了一种用于将蒸汽和燃料作为气体供应到预混合室的水/燃料蒸发器和设置在反应器周围的用于预加热供应到预混合室的空气的气流腔。 热POX段在初始启动期间运行，用于预热反应堆的其他部件。 一旦其它组分达到操作温度，第一和第二阶段重整段催化改性流出物。 预混合和预混合室可以实现O / C和S / C比的变化，因为流出物通过多级重整。
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公开(公告)号：US06926748B2
公开(公告)日：2005-08-09
申请号：US09993453
申请日：2001-11-19
CPC分类号： F28C3/08 , B01B1/005 , C01B3/48 , C01B2203/0244 , C01B2203/0283 , C01B2203/044 , C01B2203/047 , C01B2203/066 , C01B2203/0811 , C01B2203/0822 , C01B2203/0827 , C01B2203/0844 , C01B2203/1288 , C01B2203/142 , C01B2203/82 , H01M8/04022 , H01M8/0618 , H01M8/0668 , Y02P20/128
摘要： A fuel processor for rapidly achieving operating temperature during startup. The fuel processor includes a reformer, a shift reactor, and a preferential oxidation reactor is provided for deriving hydrogen for use in creating electricity in a plurality of fuel cells. A first combustion heater system is coupled to at least one of the reformer, the shift reactor, and the preferential oxidation reactor to preheat the component during a rapid startup sequence. That is, the first combustion heater system is operable to produce thermal energy as a product of the combustion of air and fuel in the form of a first heated exhaust stream. This first heated exhaust stream is then used to heat the component directly or by using a heat exchanger type system. The first heated exhaust stream is also used by a second combustion device as a source of oxygen or diluent.
摘要翻译： 一种用于在启动期间快速达到工作温度的燃料处理器。 燃料处理机包括重整器，变换反应器和优先氧化反应器，用于产生用于在多个燃料电池中产生电力的氢。 第一燃烧加热器系统耦合到重整器，换档反应器和优先氧化反应器中的至少一个，以在快速启动顺序期间预热元件。 也就是说，第一燃烧加热器系统可操作以产生作为第一加热排气流形式的空气和燃料燃烧产物的热能。 然后使用该第一加热排气流直接加热组件或使用热交换器型系统。 第一加热废气流也被第二燃烧装置用作氧气或稀释剂的来源。
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公开(公告)号：US5571484A
公开(公告)日：1996-11-05
申请号：US428746
申请日：1995-04-25
IPC分类号： F01N3/20
CPC分类号： F01N3/2033 , F23N2041/14 , Y02T10/26
摘要： A burner type catalytic converter heater composed of an air intake housing having a peripheral mounting flange for universal mounting to an exhaust system upstream of the catalytic converter. A nozzle body is provided having a central portion whereat an orifice delivers atomized fuel and an annular flange portion which interfaces with the air intake housing to define an air intake chamber on an upstream side thereof. A cylindrical combustion chamber housing is provided and a single-stage vortex body is connected to one end of the combustion chamber housing, wherein vanes of the vortex body adjoin a downstream side of the annular flange portion.
摘要翻译： 一种燃烧器型催化转化器加热器，其由具有用于通用安装到催化转化器上游的排气系统的外围安装法兰的进气口构成。 提供一种喷嘴体，其具有中心部分，其中孔口传送雾化燃料;以及环形凸缘部分，其与进气口连接以在其上游侧限定进气室。 提供圆柱形燃烧室壳体，并且单级涡流体连接到燃烧室壳体的一端，其中涡流体的叶片与环形凸缘部分的下游侧相邻。
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28.发明授权Compliant feed region in stamped metal flowfield of a fuel cell plate to eliminate bias 有权燃料电池板的冲压金属流场中的合格进料区域以消除偏压公开(公告)号：US08257881B2
公开(公告)日：2012-09-04
申请号：US12175511
申请日：2008-07-18
CPC分类号： H01M8/026 , H01M8/0258 , H01M8/0267 , H01M8/241 , H01M8/248 , H01M2008/1095
摘要： A fuel cell plate assembly is disclosed that comprises a first plate having a plurality of protuberances formed in a bottom of flow channels formed thereon, wherein the protuberances abut a bottom of flow channels formed on a second plate when the first plate and the second plate are disposed adjacent one another.
摘要翻译： 公开了一种燃料电池板组件，其包括具有形成在其上形成的流动通道的底部中的多个突起的第一板，其中当第一板和第二板是第二板时，突起邻接形成在第二板上的流动通道的底部 彼此相邻放置。
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公开(公告)号：US20120052408A1
公开(公告)日：2012-03-01
申请号：US12868487
申请日：2010-08-25
CPC分类号： H01M8/04992 , H01M8/04097 , H01M8/04111 , H01M8/04231 , H01M8/04402 , H01M8/04462 , H01M8/04746 , H01M8/04791
摘要： A system and method for correcting an estimation of nitrogen in an anode side of a fuel cell stack. The system includes a fuel cell stack and a pressure sensor for measuring pressure in an anode sub-system. The system also includes a controller configured to control the estimation of nitrogen permeation from the cathode side to the anode side of the stack, where the controller determines if the pressure in the anode sub-system equilibrates with atmospheric pressure in a shorter period of time after shutdown compared to the time necessary for the anode sub-system to reach approximately atmospheric pressure after a previous shutdown or calibrated time value, and corrects the estimation of nitrogen in the anode side of the stack if the pressure equilibrates in a shorter period of time.
摘要翻译： 一种用于校正燃料电池堆的阳极侧的氮的估计的系统和方法。 该系统包括用于测量阳极子系统中的压力的燃料电池堆和压力传感器。 该系统还包括控制器，其被配置为控制从堆的阴极侧到阳极侧的氮气渗透的估计，其中控制器确定阳极子系统中的压力是否在大气压力之后在更短的时间段内平衡 与阳极子系统在先前停机或校准时间值之后达到大致压力所需的时间相比，如果压力在更短的时间内平衡，则校正堆叠阳极侧的氮气的估计。
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公开(公告)号：US07976991B2
公开(公告)日：2011-07-12
申请号：US11130825
申请日：2005-05-17
CPC分类号： H01M8/04119 , H01M8/04253 , H01M2008/1095
摘要： A model uses various operating characteristics of a fuel cell to predict the relative humidity profile that is occurring within the fuel cell as a function of the reaction progress. The model is used to predict the relative humidity profile that will occur in response to changes to one or more of the operating characteristics of the fuel cell. A high frequency resistance of the fuel cell can also be used as a measure that is indicative of the humidity within the fuel cell. The model and/or the high frequency resistance can be used in a closed-loop feedback system to control the operation of the fuel cell to maintain the humidification of the MEA and fuel cells within a desired range to achieve a desired fuel cell performance.
摘要翻译： 模型使用燃料电池的各种操作特性来预测在燃料电池内发生的相对湿度分布作为反应进程的函数。 该模型用于预测响应于燃料电池的一个或多个操作特性的变化而发生的相对湿度分布。 燃料电池的高频电阻也可以用作指示燃料电池内的湿度的措施。 该模型和/或高频阻抗可以用在闭环反馈系统中以控制燃料电池的操作，以将MEA和燃料电池的加湿保持在期望的范围内，以实现期望的燃料电池性能。
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