LOW CRYSTALLINITY GLASS-CERAMICS
    24.
    发明申请
    LOW CRYSTALLINITY GLASS-CERAMICS 有权
    低结晶玻璃 - 陶瓷

    公开(公告)号:US20150239772A1

    公开(公告)日:2015-08-27

    申请号:US14623674

    申请日:2015-02-17

    Abstract: Embodiments of the present disclosure pertain to crystallizable glasses and glass-ceramics that exhibit a black color and are opaque. In one or more embodiments, the crystallizable glasses and glass-ceramics include a precursor glass composition that exhibits a liquidus viscosity of greater than about 20 kPa*s. The glass-ceramics exhibit less than about 20 wt % of one or more crystalline phases, which can include a plurality of crystallites in the Fe2O3—TiO2—MgO system and an area fraction of less than about 15%. Exemplary compositions used in the crystallizable glasses and glass-ceramics include, in mol %, SiO2 in the range from about 50 to about 76, Al2O3 in the range from about 4 to about 25, P2O5+B2O3 in the range from about 0 to about 14, R2O in the range from about 2 to about 20, one or more nucleating agents in the range from about 0 to about 5, and RO in the range from about 0 to about 20.

    Abstract translation: 本公开的实施方案涉及显示黑色并且是不透明的可结晶玻璃和玻璃陶瓷。 在一个或多个实施方案中,可结晶玻璃和玻璃陶瓷包括表现出大于约20kPa·s的液相线粘度的前体玻璃组合物。 该玻璃陶瓷表现出小于约20重量%的一个或多个结晶相,其可以包括Fe2O3-TiO2-MgO体系中的多个微晶,小于约15%的面积分数。 在可结晶玻璃和玻璃陶瓷中使用的示例性组合物包括摩尔%,约50至约76的SiO 2,约4至约25的氧化铝,约0至约25的范围内的P 2 O 5 + B 2 O 3 14,R 2 O在约2至约20的范围内,一种或多种成核剂在约0至约5范围内,RO在约0至约20的范围内。

    Glass-ceramic articles, compositions, and methods of making the same

    公开(公告)号:US11370693B2

    公开(公告)日:2022-06-28

    申请号:US16750570

    申请日:2020-01-23

    Abstract: A glass-ceramic article that includes an article having a glass-ceramic composition, the composition including: SiO2 from about 45% to about 65%, Al2O3 from about 14% to about 28%, TiO2 from about 2% to about 4%, ZrO2 from about 3% to about 4.5%, MgO from about 4.5% to about 12%, and ZnO from about 0.1 to about 4% (by weight of oxide). The article can include a coefficient of thermal expansion (CTE) of about 20×10−7 K−1 to about 160×10−7 K−1, as measured over a temperature range from 25° C. to 300° C.

    TOUGH GLASS COMPOSITE AND METHOD
    28.
    发明申请

    公开(公告)号:US20210395142A1

    公开(公告)日:2021-12-23

    申请号:US17289263

    申请日:2019-10-25

    Abstract: Embodiments of a glass substrate including an alkali-containing bulk and an alkali-depleted surface layer, including a substantially homogenous composition with at least 51 mol % Al2O3 are disclosed. In some embodiments, the alkali-depleted surface layer includes about 0.5 atomic % alkali or less. The alkali-depleted surface layer can be substantially free of hydrogen and/or crystallites. Methods for forming a glass substrate with a modified surface layer are also provided.

    METHOD FOR FORMING GLASS-CERAMIC ARTICLES AND GLASS-CERAMIC ARTICLES FORMED THEREFROM

    公开(公告)号:US20210276913A1

    公开(公告)日:2021-09-09

    申请号:US17049600

    申请日:2019-04-18

    Abstract: A process for making a glass-ceramic article includes annealing an as-formed glass article formed from a glass-ceramic composition at a first temperature for a duration sufficient to nucleate a plurality of nuclei within a vitreous matrix of the as-formed glass article and forming a post-nucleation glass article. The process also includes annealing the post-nucleation glass article at a second temperature for a duration sufficient to grow crystalline grains within the vitreous matrix of the post-nucleation glass article and forming a glass-ceramic article. The first temperature is less than a glass transition temperature for the glass-ceramic composition and the second temperature is greater than the glass transition temperature for the glass-ceramic composition.

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