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公开(公告)号：US4098835A
公开(公告)日：1978-07-04
申请号：US829301
申请日：1977-08-31
CPC分类号： C07C2/42 , C07C2103/64 , C07C2531/14 , C07C2531/22
摘要： Processes for preparing vinyl nortricyclane (I) and its hydrogenated derivative, ethyl nortricyclane (II) are disclosed. The nortricyclane (II) can be used as a high energy fuel or a fuel diluent. Process involves codimerization of norbornadiene and ethylene in the presence of a homogeneous catalytic system of cobaltic or cobaltous acetylacetonate, 1,2-bisdiphenylphosphino ethane and an alkyl aluminum chloride to yield the vinyl nortricyclane (I). The latter can be hydrogenated to ethylnortricyclane.
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公开(公告)号：US5019671A
公开(公告)日：1991-05-28
申请号：US378334
申请日：1989-07-10
IPC分类号： B01J23/889 , B01J23/88 , B01J27/053 , C07B61/00 , C07C5/22 , C07C5/27 , C07C9/16
CPC分类号： C07C5/2213 , C07C5/2781 , C07C2521/06 , C07C2523/656 , C07C2523/745 , C07C2523/75 , C07C2523/889
摘要： A sulfated calcined solid catalyst which comprises (1) oxide or hydroxide of Group III or Group IV, e.g. zirconium, metal, (2) oxide or hydroxide of Group V, Group VI or Group VII, e.g. manganese or molybdenum, metal and (3) oxide or hydroxide of Group VIII, e.g. iron, or cobalt metal, is used to isomerize normal alkanes having 4 to 7 carbon atoms per molecule in the liquid phase to obtain high octane number blending components for motor fuel and/or valuable chemical and fuel intermediates.
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23.发明授权
公开(公告)号：US4225735A
公开(公告)日：1980-09-30
申请号：US7113
申请日：1979-01-29
IPC分类号： C10L5/40 , B01J21/00 , B01J29/00 , C06D5/00 , C07B61/00 , C07C1/00 , C07C2/52 , C07C5/22 , C07C5/27 , C07C13/64 , C07C67/00 , C07C13/28 , C07C15/12
CPC分类号： C07C5/2206 , C07C5/2213 , C07C2521/04 , C07C2521/16 , Y02E50/30 , Y02T50/678
摘要： Isomerization of a liquid, saturated endo-endo norbornadiene hexacyclic dimer involves the use of a catalytic amount of acidic alumina or a montmorillonite. The resulting isomeric product is solid, at ambient temperature, and can be used as a missile fuel.
摘要翻译： 液体饱和内端降冰片二烯六环二聚体的异构化包括使用催化量的酸性氧化铝或蒙脱石。 得到的异构产物在环境温度下是固体，并且可以用作导弹燃料。
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公开(公告)号：US4107198A
公开(公告)日：1978-08-15
申请号：US812208
申请日：1977-07-01
IPC分类号： C07C255/45 , C07C120/00 , C07C121/46
CPC分类号： C07C255/45
摘要： Norbornadiene and acrylonitrile are catalytically codimerized in the presence of a three-component homogeneous catalytic system consisting of nickel acetylacetonate, triphenylphosphine and an alkyl aluminum chloride. The codimer can be used as a precursor for missile fuel.
摘要翻译： 在由乙酰丙酮镍，三苯基膦和烷基氯化铝组成的三组分均相催化体系的存在下，降冰片二烯和丙烯腈被催化共聚。 编码器可用作导弹燃料的前体。
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公开(公告)号：US4142055A
公开(公告)日：1979-02-27
申请号：US812209
申请日：1977-07-01
IPC分类号： C07C69/74
CPC分类号： C07C67/347 , C07C2103/86
摘要： Norbornadiene and an acrylic acid ester, e.g., methyl acrylate, are catalytically codimerized in the presence of a two-component homogeneous catalytic system consisting of nickel acetylacetonate and an alkyl aluminum chloride. The resulting codimer can be used as a precursor for a missile fuel. The ester portion of the acrylic acid ester is the radical RCH.sub.2 O-- wherein the R is an H or an alkyl containing up to 10 carbon atoms.
摘要翻译： 降冰片二烯和丙烯酸酯如丙烯酸甲酯在由乙酰丙酮镍和烷基氯化铝组成的双组分均相催化体系存在下进行催化共聚。 所得到的编码剂可用作导弹燃料的前体。 丙烯酸酯的酯部分是自由基RCH2O-，其中R是H或含有至多10个碳原子的烷基。
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公开(公告)号：US4139714A
公开(公告)日：1979-02-13
申请号：US812206
申请日：1977-07-01
IPC分类号： C07C69/74
CPC分类号： C07C67/343 , C07C2103/86
摘要： Norbornadiene and an acrylic acid ester, e.g. methyl acrylate, are catalytically codimerized in the presence of a three-component homogeneous catalytic system consisting of nickel acetylacetonate, an alkyl aluminum chloride and triphenylphosphine. The resulting codimer can be used as a precursor for missile fuel. The ester portion of the acrylic acid ester is the radical RCH.sub.2 O- wherein the R is an H or an alkyl containing up to 10 carbon atoms.
摘要翻译： 降冰片二烯和丙烯酸酯，例如 丙烯酸甲酯在由乙酰丙酮镍，烷基氯化铝和三苯基膦组成的三组分均相催化体系存在下进行催化共聚。 所得到的同源二聚体可用作导弹燃料的前体。 丙烯酸酯的酯部分是自由基RCH2O-，其中R是H或含有至多10个碳原子的烷基。
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公开(公告)号：US5648590A
公开(公告)日：1997-07-15
申请号：US292164
申请日：1994-08-17
CPC分类号： C07C5/2781 , C07C2521/06 , C07C2523/656 , C07C2523/745 , C07C2523/75 , C07C2523/889
摘要： Acyclic hydrocarbons having 4 to 7 carbon atoms per molecule are isomerized in the liquid phase by contact with a solid superacid catalyst comprising sulfated oxide or hydroxide of a metal selected from the group consisting of Group III and Group IV metals, to obtain high octane number blending components for motor fuel and/or valuable chemical and fuel intermediates.
摘要翻译： 每分子具有4至7个碳原子的非环状烃通过与包含选自III和IV族金属的金属的硫酸化氧化物或氢氧化物的固体超强酸催化剂接触而在液相中异构化，以获得高辛烷值共混 汽车燃料和/或有价值的化学和燃料中间体的组分。
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28.发明授权
公开(公告)号：US4222800A
公开(公告)日：1980-09-16
申请号：US964855
申请日：1978-11-30
CPC分类号： C10L1/04 , C07C13/64 , C07C5/03 , C07C5/29 , C07C2103/90 , C07C2521/04
摘要： The endo-endo olefinic hexacyclic dimer of 2,5-norbornadiene is isomerized using an acidic alumina catalyst. The isomerization temperatures ranges from between about an ambient temperature to about 300.degree. C. The isomerized product, after hydrogenation, can be used as a high density missile fuel.
摘要翻译： 使用酸性氧化铝催化剂将2,5-降冰片二烯的内 - 内烯烃六环二聚体异构化。 异构化温度范围为约环境温度至约300℃。氢化后的异构化产物可用作高密度导弹燃料。
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公开(公告)号：US4207080A
公开(公告)日：1980-06-10
申请号：US640107
申请日：1975-12-11
CPC分类号： C10L1/06 , B01J31/143 , B01J31/2234 , B01J31/2404 , C07C2/42 , B01J2531/842 , B01J2531/845 , C07C2103/90 , C07C2531/14 , C07C2531/22 , C07C2531/24
摘要： Norbornadiene [bicyclo(2.2.1)heptadiene-2,5] is dimerized to the exo-exo stereoisomer of the hexacyclic dimer of norbornadiene at both an excellent selectivity and conversion using an effective amount of a three component catalytic system of diethylaluminum chloride, ferric or ferrous or cobaltic or cobaltous acetylacetonate and bis(1,2-diphenylphosphino)ethane. The reaction rate is rapid. After hydrogenation the exo-exo hexacyclic dimer can be used as a component of high energy fuel for either jet or rocket propulsion.
摘要翻译： 降冰片二烯[双环（2.2.1）庚二烯-2,5]被二聚化为降冰片二烯的六环二聚体的外 - 外立体异构体，同时具有优异的选择性和转化率，使用有效量的三乙基氯化铝三元催化体系 或亚铁或钴酸或乙醇酸乙酯和双（1,2-二苯基膦基）乙烷。 反应速度快。 在氢化之后，外部六环二聚体可用作喷射或火箭推进的高能燃料的组分。
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公开(公告)号：US4139715A
公开(公告)日：1979-02-13
申请号：US812207
申请日：1977-07-01
IPC分类号： C07C69/74
CPC分类号： C07C67/347 , C07C2103/86
摘要： Norbornadiene and an acrylic acid ester, e.g. methyl acrylate, are catalytically codimerized in the presence of a three-component homogeneous catalytic system consisting of nickel acetylacetonate, an alkyl aluminum chloride and 1,2-bisdiphenylphosphino ethane. The resulting codimer can be used as a precursor for missile fuel. The ester portion of the acrylic acid ester is the radical RCH.sub.2 O-- wherein the R is an H or an alkyl containing up to 10 carbon atoms.
摘要翻译： 降冰片二烯和丙烯酸酯，例如 丙烯酸甲酯在由乙酰丙酮镍，烷基氯化铝和1,2-双二苯基膦基乙烷组成的三组分均相催化体系的存在下进行催化共聚。 所得到的同源二聚体可用作导弹燃料的前体。 丙烯酸酯的酯部分是自由基RCH2O-，其中R是H或含有至多10个碳原子的烷基。
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